CN101733984A - 黑色的涂布制品 - Google Patents
黑色的涂布制品 Download PDFInfo
- Publication number
- CN101733984A CN101733984A CN200910206502A CN200910206502A CN101733984A CN 101733984 A CN101733984 A CN 101733984A CN 200910206502 A CN200910206502 A CN 200910206502A CN 200910206502 A CN200910206502 A CN 200910206502A CN 101733984 A CN101733984 A CN 101733984A
- Authority
- CN
- China
- Prior art keywords
- layer
- refractory metal
- goods
- nonferrous
- zirconium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003870 refractory metal Substances 0.000 claims abstract description 44
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000001301 oxygen Substances 0.000 claims abstract description 37
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 37
- 238000000576 coating method Methods 0.000 claims abstract description 24
- 239000011248 coating agent Substances 0.000 claims abstract description 23
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 9
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 33
- 229910052799 carbon Inorganic materials 0.000 claims description 33
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 24
- 229910052726 zirconium Inorganic materials 0.000 claims description 24
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 15
- 239000003245 coal Substances 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 8
- 229910052735 hafnium Inorganic materials 0.000 claims description 5
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052715 tantalum Inorganic materials 0.000 claims description 5
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 5
- 229910001069 Ti alloy Inorganic materials 0.000 claims description 4
- PMTRSEDNJGMXLN-UHFFFAOYSA-N titanium zirconium Chemical compound [Ti].[Zr] PMTRSEDNJGMXLN-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910000449 hafnium oxide Inorganic materials 0.000 claims description 2
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical group [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 claims description 2
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 claims description 2
- 229910001936 tantalum oxide Inorganic materials 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 30
- 229910052759 nickel Inorganic materials 0.000 abstract description 15
- 229920000642 polymer Polymers 0.000 abstract description 7
- 239000010410 layer Substances 0.000 description 69
- 238000000151 deposition Methods 0.000 description 12
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 12
- 230000008021 deposition Effects 0.000 description 11
- 239000007789 gas Substances 0.000 description 11
- 238000007747 plating Methods 0.000 description 10
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- 238000005260 corrosion Methods 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- 238000001704 evaporation Methods 0.000 description 7
- 230000008020 evaporation Effects 0.000 description 7
- 229910001369 Brass Inorganic materials 0.000 description 6
- 239000010951 brass Substances 0.000 description 5
- 238000010891 electric arc Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000037452 priming Effects 0.000 description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000005240 physical vapour deposition Methods 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000013047 polymeric layer Substances 0.000 description 3
- -1 pottery Substances 0.000 description 3
- 239000011241 protective layer Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 229910000906 Bronze Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 239000010974 bronze Substances 0.000 description 2
- 239000010406 cathode material Substances 0.000 description 2
- 239000011195 cermet Substances 0.000 description 2
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 2
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 239000011253 protective coating Substances 0.000 description 2
- 238000005546 reactive sputtering Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 239000013077 target material Substances 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 241000080590 Niso Species 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910001093 Zr alloy Inorganic materials 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical class [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 229940024464 emollients and protectives zinc product Drugs 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000011145 styrene acrylonitrile resin Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/0015—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterized by the colour of the layer
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/02—Pretreatment of the material to be coated
- C23C14/024—Deposition of sublayers, e.g. to promote adhesion of the coating
- C23C14/025—Metallic sublayers
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/08—Oxides
- C23C14/083—Oxides of refractory metals or yttrium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
- C23C28/322—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer only coatings of metal elements only
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
- C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
- C23C28/3455—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer with a refractory ceramic layer, e.g. refractory metal oxide, ZrO2, rare earth oxides or a thermal barrier system comprising at least one refractory oxide layer
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
- C23C28/347—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with layers adapted for cutting tools or wear applications
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Physical Vapour Deposition (AREA)
- Laminated Bodies (AREA)
Abstract
本发明涉及黑色的涂布制品。该制品涂有黑色的涂层。在优选的实施方案中，该涂层包括镍或聚合物底涂层，和由富氧高熔点金属碳氧化物组成的第一有色层，包括富氧高熔点金属碳氧化物的第二有色层，和高熔点金属氧化物的顶层。
Description
技术领域
本发明涉及制品，特别是例如具有黑色外观的装饰性和防护性涂层的龙头的制品。
背景技术
对于各种黄铜制品，例如龙头、龙头孔罩、门钮、门把手、门锁孔等，现有工业实践是首先将制品的表面打磨和抛光至高光泽度，然后在该抛光表面上施涂保护性有机涂层，例如由丙烯酸类、氨基甲酸酯、环氧化物等组成的涂层。这种系统具有打磨和抛光操作属于劳动密集型的缺点，特别是如果该制品具有复杂的形状。此外，已知的有机涂料并不总是如所需那样耐用，并对由于酸的侵蚀敏感。因此，如果黄铜制品，或实际上塑料的、陶瓷的或金属的其它制品可以配有向制品提供外观装饰以及提供耐磨性、抗磨耗性和耐腐蚀性的涂层，则将是非常有利的。
US 7,270,895代表这种技术的最新发展。该专利公开了一种用深色涂层涂布的制品。优选，颜色为暗灰色或暗青铜色。该涂层包括颜色和保护层，所述保护层由其中氧含量大于碳含量的高熔点金属碳氧化物组成。该高熔点金属典型地为锆。对于在以前不能得到的新外观的研究在继续。
发明内容
本发明涉及一种用黑色的涂层涂布的制品。该涂布的制品具有黑色并且包括基材，该基材具有表面和在该表面的至少一部分上具有顺次包括以下层的多层涂层：
具有氧含量和碳含量的高熔点金属碳氧化物的第一层，其中氧含量大于碳含量，
第一有色层上的第二有色层，其中该第二有色层包括具有氧含量和碳含量的高熔点金属碳氧化物层，其中氧含量大于碳含量；和其中第二有色层的氧含量和碳含量大于第一有色层的氧含量和碳含量；和
第二有色层上的高熔点金属氧化物层。
在优选实施方案中，两个薄的半透明光学层的组合沉积在较厚的暗灰色层上。这三个层的结合性能产生比先前所能实现的暗黑得多的外观。两个薄的光学层沉积在较厚的暗灰色层上。基底层具有灰色，碳氧化锆是优选的。下一个层也是碳氧化锆，但是沉积有更高的氧和碳含量。这一层使外观发黑，并具有光学抵消通常在顶层中看到的黄色的作用，所述黄色为氧化锆。这三个层的结合性能产生比先前所能实现的暗黑得多的外观。
附图说明
图1为其上具有本发明的黑色的一部分基材的不按比例的剖视图。
具体实施方式
本发明涉及一种制品，例如塑料、陶瓷、金属陶瓷或金属制品，其具有沉积在至少一部分表面上的装饰性和防护性涂层。更具体地涉及一种制品或基材，特别是金属制品，例如不锈钢、铝、黄铜或锌制品，具有沉积在表面上的在此所述的层。该涂层是装饰性的，还提供耐腐蚀性、耐磨性和抗磨耗性。该涂层提供黑色外观。
优选，第一有色层的高熔点金属为铪、钽、锆、钛或锆-钛合金。更优选，第一有色层的高熔点金属为锆。第一有色层的高熔点金属碳氧化物为碳氧化锆。优选，第一有色层的高熔点金属碳氧化物为30至40原子百分数氧，10至20原子百分数碳和50至60原子百分数高熔点金属。更优选，第一有色层的高熔点金属碳氧化物为10原子百分数碳和30至40原子百分数氧。
第二有色层的高熔点金属优选为铪、钽、锆、钛或锆-钛合金。更优选，第二有色层的高熔点金属为锆。优选，第二有色层的高熔点金属碳氧化物为碳氧化锆。优选，第二有色层的高熔点金属碳氧化物为30至50原子百分数氧，10至30原子百分数碳和30至50原子百分数高熔点金属。更优选，第二有色层的高熔点金属碳氧化物为10原子百分数碳和30至50原子百分数氧。
通常，高熔点金属氧化物顶层为氧化铪、氧化钽、氧化锆或氧化钛。优选高熔点金属氧化物顶层为氧化锆。
图1显示制品10包括基材12。基材12可以由任何材料组成，其上可以施加板状层，例如塑料，例如ABS、聚烯烃、聚氯乙烯和苯酚甲醛，陶瓷，金属陶瓷，金属或金属合金。在一个实施方案中，其由例如铜、钢、黄铜、锌、铝、镍合金等的金属或金属合金组成。
在本发明中，如图1中所示，第一层或系列层通过镀覆，例如在镍底涂层的情况下电镀，施加在制品表面上。在聚合物底涂层的情况下，聚合物由传统方法施涂。第二系列层由汽相沉积施加在一个或多个底涂层的表面上。聚合物或电镀层特别起使制品表面平整的底涂层的作用，和起提高耐腐蚀性的腐蚀阻挡层的作用。在本发明的一个实施方案中，镍层14可以沉积在制品表面上。镍层可以为由镀覆沉积的任何常规镍，例如光亮镍、半光亮镍、缎纹镍等。镍层14可以由常规和公知的电镀方法沉积在基材12的至少一部分表面上。层14可以为一个或多个铜、镍和铬层。这些腐蚀保护层是本领域中公知的。
层14可以由施涂在制品10表面上的聚合物组成作为底涂层。第二系列层由汽相沉积施加在聚合物层的表面上。聚合物层特别起使制品表面平整的底涂层的作用，和起提高耐腐蚀性的腐蚀阻挡层的作用。在本发明中，聚合物层14可以沉积在制品表面上。
聚合物底涂层14可以由热塑性和热固性聚合物或树脂材料组成。这些聚合物或树脂材料包括公知的、常规的和市售的聚碳酸酯、环氧型聚氨酯、聚丙烯酸酯、聚甲基丙烯酸酯、尼龙、聚酯、聚丙烯、聚环氧、醇酸树脂和含苯乙烯聚合物，例如聚苯乙烯、苯乙烯-丙烯腈(SAN)、苯乙烯-丁二烯、丙烯腈-丁二烯-苯乙烯(ABS)，及其共混物和共聚物。层14的聚合物是本领域公知的。
通过汽相沉积，例如物理汽相沉积或化学汽相沉积，在层14上沉积保护性和装饰性的有色层16。有色层16由一层具有氧含量和碳含量的高熔点金属碳氧化物组成，其中氧含量大于碳含量。
第二有色层18沉积在第一有色层16上。第二有色层18包括具有氧含量和碳含量的高熔点金属碳氧化物层，其中氧含量大于碳含量；和其中第二有色层18的氧含量和碳含量大于第一有色层16的氧含量和碳含量。
有色和保护层16和18的厚度为至少有效提供暗灰色颜色和提供抗磨耗性、抗划性和耐磨性的厚度。通常，该厚度为至少约1,000
优选至少约1,500
和更优选至少约2,500
厚度上限范围通常并非关键，取决于例如成本的次要因素。通常厚度不应超过约7500优选约5000
层16和18由常规的和公知的技术沉积，所述技术包括汽相沉积技术，例如阴极电弧蒸发(CAE)或溅射等。溅射和CAE技术和设备特别公开在J.Vossen和W.Kern“Thin Film Processes II”，Academic Press，1991；R.Boxman等人，“Handbook of Vacuum Arc Science and Technology”，Noyes Pub.，1995；及US 4,162,954和4,591,418中，在此将其全部引入作为参考。
沉积层16和18的一个方法是通过利用反应性溅射或反应性阴极电弧蒸发的物理汽相沉积。反应性阴极电弧蒸发和反应性溅射通常类似于普通的溅射和阴极电弧蒸发，除了将反应性气体引入腔室与驱出的(dislodged)目标材料反应。
接下来，高熔点金属氧化物层20沉积在第二有色层18上。高熔点金属氧化物包括铪、钽、锆、钛和钛-锆合金的氧化物。通常，层20的厚度为至少约60
优选至少约120
和更优选至少约250
但是层20通常不应厚于约1.2μm，优选约0.5μm，和更优选约0.25μm。
层20由常规的和公知的汽相沉积技术沉积，所述技术包括物理汽相沉积技术，例如阴极电弧蒸发(CAE)或溅射。简要地，在溅射沉积方法中，高熔点金属(例如钛或锆)目标物，其为阴极，与基材一起放入真空室中。抽空腔室中的空气，在腔室中产生真空状态。将惰性气体，例如氩气，引入腔室中。使气体颗粒离子化，并使其向目标物加速，以驱出钛或锆原子。驱出的目标材料然后通常以涂膜的形式沉积在基材上。
在阴极电弧蒸发中，通常几百安培的电弧冲击在例如锆或钛的金属阴极的表面上。电弧使阴极材料汽化，其然后凝结在基材上形成涂层。
为了可以更容易地理解本发明，提供以下实施例。实施例是说明性的，本发明并不限于实施例。
实施例I
将黄铜龙头放入常规的浸泡清洁剂浴中，所述浴包含标准的和公知的皂、洗涤剂、去污剂(defloculant)等，保持在8.9-9.2的pH和180-200°F的温度约10分钟。然后将黄铜龙头放入常规的超声波碱性清洁剂浴中。该超声波清洁剂浴具有8.9-9.2的pH，保持在约160-180°F的温度下，包含常规的和公知的皂、洗涤剂、去污剂等。超声清洁龙头之后，冲洗龙头并将其放入常规的碱性电镀清洁剂浴中。
电镀清洁剂浴保持在约140-180°F的温度，约10.5-11.5的pH下，并且包含标准的和常规的洗涤剂。然后冲洗龙头两次并放入常规的酸活化剂浴中。酸活化剂浴具有约2.0-3.0的pH，处于环境温度，并包含氟化钠基酸性盐。然后冲洗龙头两次并放入光亮镀镍浴中约12分钟。光亮镍浴通常为保持在约130-150°F的温度，约4.0的pH下，包含NiSO4、NiCl2、硼酸和增亮剂的常规浴。在龙头表面上沉积约10μm的平均厚度的光亮镍层。
冲洗该光亮镀镍龙头三遍，然后放入使用常规镀铬设备的常规市售六价铬镀覆浴中约七分钟。该六价铬浴为包含约32盎司/加仑铬酸的常规和公知的浴。该浴还包含常规和公知的镀铬添加剂。浴保持在约112-116°F的温度下，并使用混合的硫酸盐/氟化物催化剂。铬酸对硫酸盐比率为约200∶1。在光亮镍层表面上沉积约0.25μm的铬层。在去离子水中彻底冲洗龙头，然后干燥。
将镀铬龙头放入阴极电弧蒸发镀覆容器中。该容器通常为包含适合于通过泵抽空的真空室的圆柱形罩。通过调节阀将氩气源连接到该室，所述调节阀用于改变氩气进入室的流速。此外，通过调节阀将甲烷和氧气源连接到该室，所述调节阀用于改变甲烷和氧气进入室的流速。
将圆柱形阴极安装在室中心并连接到可变D.C.电源的负输出端。将电源的正极侧连接到室壁。阴极材料包括锆。
将镀覆的龙头安装在转轴上，所述转轴安装在围绕阴极外侧的环上。整个环围绕阴极旋转，同时每个转轴还围绕其自身轴旋转，产生所谓的行星运动，这样使得围绕每个转轴安装的多个龙头均匀暴露于阴极。该环通常以几rpm旋转，同时环每转一圈，每个转轴旋转几圈。转轴与室电隔离，并装有可旋转触点，使得在涂布过程中可以向基材施加偏压。
将真空室抽空至约10-5至10-7托的压力，并加热至约150℃。
然后使电镀龙头经历高偏压电弧等离子体清洁，在其中向电镀龙头施加约-600伏的(负)偏压，同时大约500安培的电弧在阴极上冲击和持续。清洁的持续时间为大约五分钟。
现在沉积碳氧化锆有色层16。将甲烷流引入真空室，同时以大约500安培继续电弧放电。为了增加涂层的暗色，也可以将全部气流的总计30至40％的氧气流引入室中，以产生暗灰色颜色。提高甲烷流速，由此所得层包含10至20原子百分数的碳含量。
接下来在层16上沉积碳氧化锆有色层18。将甲烷流引入真空室，同时以大约500安培继续电弧放电。为了增加涂层的暗色，也可以将全部气流的总计30至40％的氧气流引入室中，以产生暗灰色颜色。提高甲烷流速，由此所得层包含10至20原子百分数的碳含量。该碳氧化锆层沉积之后，引入每分钟大约100至500标准升的氧气流大约10至60秒。形成厚度为约20至100
的氧化锆薄层。熄灭电弧，放空真空室，以及移出涂布的制品。
该碳氧化锆层沉积之后，引入每分钟大约100至500标准升的氧气流约1至5分钟。形成厚度为约100至1000
的氧化锆薄层。一至五分钟时段期间沉积平均厚度为约0.1μm的氧化锆层(顶层20)。熄灭电弧，放空真空室，以及移出涂布的制品。阴极电弧淀积方法包括向阴极施加D.C.电源，获得约500安培的电流，在容器中引入氩气，使容器中的压力保持在约1至5毫托，以上述行星方式旋转龙头。
实施例II
实施例I中，层16和18的最终颜色的色域为灰色和青铜色。使用D65发光体，在彩色分光光度计上测量这些。
如已知的，通过三个特殊参数确定颜色的测量，其中“L”为物体亮度的量度，“a”为红色(正值)或绿色(负值)的量度，和“b”为黄色(正值)或蓝色(负值)的量度。这三个参数一起确定特殊的颜色。
测定的制品10的黑色落入以下范围。
制品10
黑色：
L*＝40.0+/-5.0
a*＝0.00+/-2.0
b*＝0.00+/-3.0
基底层具有灰色，碳氧化锆是优选的。下一个层也是碳氧化锆，但是沉积有更高的氧和碳含量。这一层使外观发黑，并具有光学抵消通常在顶层中看到的黄色的作用，所述黄色为氧化锆。这三个层的结合性能产生比先前所能实现的暗黑得多的外观。
虽然已经为了说明的目的描述了一些本发明的实施方案，但是应理解在本发明的总体范围内可以存在各种实施方案和改进。
Claims (15)
1.一种黑色的涂布制品，包括具有表面和在该表面至少一部分上具有多层涂层的基材，所述多层涂层依次包括：
具有氧含量和碳含量的高熔点金属碳氧化物的第一层，其中氧含量大于碳含量，
第一有色层上的第二有色层，其中该第二有色层包括具有氧含量和碳含量的高熔点金属碳氧化物层，其中氧含量大于碳含量；和其中第二有色层的氧含量和碳含量大于第一有色层的氧含量和碳含量；和
第二有色层上的高熔点金属氧化物层。
2.权利要求1的制品，其中第一有色层的高熔点金属为铪、钽、锆、钛或锆-钛合金。
3.权利要求1的制品，其中第一有色层的高熔点金属为锆。
4.权利要求1的制品，其中第一有色层的高熔点金属碳氧化物为碳氧化锆。
5.权利要求1的制品，其中第一有色层的高熔点金属碳氧化物为30至40原子百分数氧，10至20原子百分数碳和50至60原子百分数高熔点金属。
6.权利要求1的制品，其中第一有色层的高熔点金属碳氧化物为10原子百分数碳和30至40原子百分数氧。
7.权利要求1的制品，其中第二有色层的高熔点金属为铪、钽、锆、钛或锆-钛合金。
8.权利要求1的制品，其中第二有色层的高熔点金属为锆。
9.权利要求1的制品，其中第二有色层的高熔点金属碳氧化物为碳氧化锆。
10.权利要求1的制品，其中第二有色层的高熔点金属碳氧化物为30至50原子百分数氧，10至30原子百分数碳和30至50原子百分数高熔点金属。
11.权利要求1的制品，其中第二有色层的高熔点金属碳氧化物为10原子百分数碳和30至50原子百分数氧。
12.权利要求1的制品，其中高熔点金属氧化物顶层为氧化铪、氧化钽、氧化锆或氧化钛。
13.权利要求1的制品，其中高熔点金属氧化物顶层为氧化锆。
14.权利要求1的制品，其中第一层具有暗灰色，第二层具有暗灰色，顶层具有黄色，和制品具有黑色。
15.权利要求1的制品，其中第一层为厚层，第二层为薄层，顶层为薄层。
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|---|---|
| US (1) | US8007928B2 (zh) |
| EP (1) | EP2186927B1 (zh) |
| CN (1) | CN101733984B (zh) |
| CA (1) | CA2679759C (zh) |
| ES (1) | ES2452066T3 (zh) |
| PL (1) | PL2186927T3 (zh) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104029447A (zh) * | 2013-03-08 | 2014-09-10 | 韦伯科技有限公司 | 深色涂覆制品 |
| CN113050205A (zh) * | 2019-12-27 | 2021-06-29 | 比亚迪股份有限公司 | 黑色材料及其制备方法和应用 |
| CN113549872A (zh) * | 2020-04-07 | 2021-10-26 | 纳峰真空镀膜（上海）有限公司 | 黑色涂层 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10202679B2 (en) | 2013-03-08 | 2019-02-12 | Vapor Technologies | Coated article having a vivid color |
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| US5928977A (en) * | 1996-12-23 | 1999-07-27 | Smh Management Services Ag | Zirconia based ceramic article as wear-resistant exterior part for wristwatch |
| US6132889A (en) * | 1999-07-30 | 2000-10-17 | Vapor Technologies, Inc. | Coated article |
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| US4591418A (en) * | 1984-10-26 | 1986-05-27 | The Parker Pen Company | Microlaminated coating |
| US4714660A (en) * | 1985-12-23 | 1987-12-22 | Fansteel Inc. | Hard coatings with multiphase microstructures |
| CH664377A5 (de) * | 1986-01-16 | 1988-02-29 | Balzers Hochvakuum | Dekorative schwarze verschleissschutzschicht. |
| CH673071B5 (zh) | 1988-06-24 | 1990-08-15 | Asulab Sa | |
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| KR100250587B1 (ko) * | 1994-10-04 | 2000-04-01 | 구라우치 노리타카 | 피복 경질합금 |
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| US5704995A (en) | 1996-07-16 | 1998-01-06 | Globe Motors, A Division Of Labinal Components And Systems, Inc. | Method for forming a black, adherent coating on a metal substrate |
| KR100366248B1 (ko) * | 1998-08-03 | 2002-12-31 | 시티즌 도케이 가부시키가이샤 | 유색 피막을 갖는 장신구 및 그 제조 방법 |
| US6245435B1 (en) | 1999-03-01 | 2001-06-12 | Moen Incorporated | Decorative corrosion and abrasion resistant coating |
| US7264668B2 (en) * | 2001-10-16 | 2007-09-04 | The Chinese University Of Hong Kong | Decorative hard coating and method for manufacture |
| US7135220B1 (en) | 2002-11-27 | 2006-11-14 | Vapor Technologies Inc. | Coated article |
| JP2004284003A (ja) * | 2003-02-28 | 2004-10-14 | Mitsubishi Materials Corp | 硬質被覆層がすぐれた耐チッピング性を発揮する表面被覆サーメット製切削工具 |
| US7179546B1 (en) | 2004-12-03 | 2007-02-20 | Vapor Technologies, Inc. | Decorative and protective coating |
| US7270895B2 (en) | 2005-04-05 | 2007-09-18 | Vapor Technologies, Inc. | Coated article with dark color |
-
2008
- 2008-11-07 US US12/291,331 patent/US8007928B2/en active Active
-
2009
- 2009-09-21 CA CA2679759A patent/CA2679759C/en active Active
- 2009-10-16 CN CN200910206502.9A patent/CN101733984B/zh active Active
- 2009-11-09 ES ES09175394.7T patent/ES2452066T3/es active Active
- 2009-11-09 PL PL09175394T patent/PL2186927T3/pl unknown
- 2009-11-09 EP EP09175394.7A patent/EP2186927B1/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5928977A (en) * | 1996-12-23 | 1999-07-27 | Smh Management Services Ag | Zirconia based ceramic article as wear-resistant exterior part for wristwatch |
| US6132889A (en) * | 1999-07-30 | 2000-10-17 | Vapor Technologies, Inc. | Coated article |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104029447A (zh) * | 2013-03-08 | 2014-09-10 | 韦伯科技有限公司 | 深色涂覆制品 |
| CN113050205A (zh) * | 2019-12-27 | 2021-06-29 | 比亚迪股份有限公司 | 黑色材料及其制备方法和应用 |
| CN113050205B (zh) * | 2019-12-27 | 2021-09-21 | 比亚迪股份有限公司 | 黑色材料及其制备方法和应用 |
| CN113549872A (zh) * | 2020-04-07 | 2021-10-26 | 纳峰真空镀膜（上海）有限公司 | 黑色涂层 |
| CN113549872B (zh) * | 2020-04-07 | 2023-11-17 | 纳峰真空镀膜（上海）有限公司 | 黑色涂层 |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2452066T3 (es) | 2014-03-31 |
| CA2679759C (en) | 2012-04-17 |
| CA2679759A1 (en) | 2010-05-07 |
| US20100119873A1 (en) | 2010-05-13 |
| CN101733984B (zh) | 2014-10-22 |
| PL2186927T3 (pl) | 2014-06-30 |
| EP2186927A1 (en) | 2010-05-19 |
| EP2186927B1 (en) | 2013-12-18 |
| US8007928B2 (en) | 2011-08-30 |
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