CN101731789A - Elastic composite sole and preparation method thereof - Google Patents

Elastic composite sole and preparation method thereof Download PDF

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Publication number
CN101731789A
CN101731789A CN200810158655A CN200810158655A CN101731789A CN 101731789 A CN101731789 A CN 101731789A CN 200810158655 A CN200810158655 A CN 200810158655A CN 200810158655 A CN200810158655 A CN 200810158655A CN 101731789 A CN101731789 A CN 101731789A
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China
Prior art keywords
rubber strip
elastic
elastic rubber
percent
substrate
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CN200810158655A
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CN101731789B (en
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晏军
林瀚
高明
崔伟
王福全
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WEIHAI JINHOU GROUP CO Ltd
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WEIHAI JINHOU GROUP CO Ltd
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  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention relates to an elastic composite sole and a preparation method thereof. A common rubber material is used as a base, a forming hole is arranged in the middle of the base, the forming hole is provided with a flexible elastic rubber strip, the elastic rubber strip and the base are compounded into a whole, and the elastic rubber strip comprises the following components by weight percent: 70-85 percent of natural rubber, 7-15 percent of white carbon black, 5-10 percent of cyclic burning oil, 2-5 percent of accelerating agent and active agent and 1-2 percent of anti-aging agent. Stably combining two different rubber material layers into a whole, the invention ensures that the whole sole has abrasive resistance and better elasticity, particularly the middle elastic rubber strip has the advantages of better elasticity, flexibility with the maximum flexibility quantity of 5mm, stressed modeling expansion, strong adaptability, comfortable wearing, reasonable structure, reliable performance and wide application range, has a function of modeling and achieves the aim of fitting the feet, thereby greatly improving the elasticity and adaptability of the sole.

Description

A kind of elastic composite sole and preparation method thereof
Technical field
The present invention relates to macromolecular material manufacturing technology field, specifically a kind of elastic composite sole and preparation method thereof.
Background technology
We know that traditional leather shoes sole generally adopts polyolefin plastics to make, and also has at the bottom of rubber soles and the polyurethane shoe.Polyolefin plastics elasticity is better, but wearability is relatively poor; The rubber soles quality is comparatively closely knit, and wearability is better, but poor flexibility, and weight is bigger.Present most of leather shoes sole is all made by homogenous material, and the functional and properties of product of footwear material have many deficiencies.
Summary of the invention in recent years, various functional shoe are also come out one after another on the market, and people are for the size that makes footwear and pin is fit to, and have designed and changed group footwear, sole changeable shoes, changed with footwear respectively etc., the shoe tree type of field replaceable unit and set-back must be abided by and be sought certain rules, to the designing requirement height.
Technical problem to be solved by this invention is to overcome above-mentioned the deficiencies in the prior art, and a kind of rational in infrastructure, dependable performance is provided, and processing cost is low, good springiness, but sole transversal stretching, elastic composite sole comfortable and easy to wear and preparation method thereof.
The technical scheme that the present invention solves the problems of the technologies described above employing is: a kind of elastic composite sole, it is characterized in that: it makes substrate with the General Purpose Rubber material, be provided with the excipient hole in the middle of the substrate, the excipient hole is provided with the telescopic elastic rubber strip, and elastic rubber strip and substrate are compound to be one, and the component of described elastic rubber strip is: natural gum 70-85%, white carbon 7-15%, ring oil firing 5-10%, promoter and activating agent 2-5%, age resister 1-2%.
The above-mentioned elastic composite preparation of soles of the present invention method, it is characterized in that adopting following steps: after the first, base material prepares by component, joining banbury carries out mixing, monitor by the rubber process monitor, mixing time is 5-10 minute, 110 ℃~130 ℃ of temperature, slice, cooling stack; The second, after elastic rubber strip prepares by component, join banbury and carry out mixingly, mixing time is 5-10 minute, 110 ℃~130 ℃ of temperature, and slice, cooling stack; Three, above-mentioned elastic sheet rubber is put into the middle bar groove of mould that designs and vulcanized, curing temperature is 160 ± 2 ℃, and cure time is 5-10 minute, the clout that the elastic rubber strip both sides after cleaning then, the stamping-out sulfuration have more; Four, the substrate rubbers sheet is put into the mould and the elastic rubber strip that design again and vulcanized together, the rubber composition is fused mutually be bonded to one, curing temperature is 160 ± 2 ℃, and cure time is 5 minutes and 30 seconds; Five, slice, stamping-out are made the elastic composite sole.
The present invention firmly is combined into one two kinds of different rubber material layers, and against existing technologies, the present invention makes sole integral body have wearability and better elasticity concurrently, particularly the elastic rubber strip in the middle of the substrate excipient hole has better elasticity, and is scalable, stressed changeable type expansion, laterally the maximal dilation amount can reach 5mm, give the function of modification, reach the purpose of fitting, applicability is strong, and has a higher-strength, wear is comfortable, and day is difficult for into splitting or ftractureing long afterwards, increases the service life.Its rational in infrastructure, dependable performance improves the elasticity and the applicability of sole greatly, and is applied widely.
Description of drawings
The invention will be further described below in conjunction with drawings and Examples:
Fig. 1 is a structural representation of the present invention.
1. substrates among the figure, 2. elastic rubber strip, 3. elastic rubber strip.
The specific embodiment
As can be seen from Figure 1, a kind of elastic composite sole, it makes substrate 1 with the General Purpose Rubber material, is provided with the excipient hole in the middle of the substrate 1, and the excipient hole is provided with telescopic elastic rubber strip 2,3, elastic rubber strip and substrate are compound to be one, the component of described elastic rubber strip is: natural gum 70-85%, white carbon 7-15%, ring oil firing 5-10%, promoter and activating agent 2-5%, age resister 1-2%.Above-mentioned promoter becomes to belong to known technology with activating agent, age resister, is not giving unnecessary details.Substrate of the present invention is made for the General Purpose Rubber material, its material component is: natural gum 30-50%, butadiene-styrene rubber 5-10%, cis-butadiene cement 10-20%, white carbon 15-20%, black carbon black 5-10%, ring oil firing 2-8%, promoter and activating agent 2-7%, sulphur 1-2%, stearic acid 1-2%, calcium carbonate 2-5%, age resister 1-2%.The processing of substrate and material are formed and are belonged to prior art.
Embodiment 1: a kind of elastic composite sole, it makes substrate 1 with the General Purpose Rubber material, be provided with the excipient hole in the middle of the substrate 1, the excipient hole is provided with telescopic elastic rubber strip 2,3, and elastic rubber strip and substrate are compound to be one, and the component of described elastic rubber strip is: natural gum 80%, hard charcoal 10%, ring oil firing 6%, promoter and activating agent 3%, age resister 1%.
The above-mentioned elastic composite preparation of soles of the present invention method, it adopts following steps: after the first, base material prepares by component, join banbury and carry out mixingly, monitor by the rubber process monitor, mixing time is 5-10 minute, 110 ℃~130 ℃ of temperature, slice, cooling stack (folded temperature≤40 ℃), and per car sampling back is detected on vulcameter, play 58 seconds sulphur time, 2 minutes and 40 seconds sulfuric time, hardness 65 ± 3 degree, density 1.16g/mm 3The second, after elastic rubber strip prepares by component, join banbury and carry out mixingly, monitor by the rubber process monitor, mixing time is 5-10 minute, 110 ℃~130 ℃ of temperature, and slice, cooling stack (folded temperature≤40 ℃); Three, above-mentioned elastic sheet rubber is put into the middle bar groove of mould that designs and vulcanized, curing temperature is 160 ± 2 ℃, and cure time is 5-10 minute, the clout that the elastic rubber strip both sides after cleaning then, the stamping-out sulfuration have more; Four, the elastic rubber strip of again the substrate rubbers sheet being put into after the mould that designs and the sulfuration vulcanizes together, the rubber composition is fused mutually be bonded to one, and curing temperature is 160 ± 2 ℃, and cure time is 5 minutes and 30 seconds; Five, slice, stamping-out are made the elastic composite sole.Technical indicator reaches after tested: rubber-sole hardness 65 ± 3 degree; Pansy elastic rubber strip hardness 35 ± 3 degree, maximal dilation amount 5mm.
The invention has the advantages that: two kinds of different rubber material layers firmly are combined into one, make sole integral body have wearability and better elasticity concurrently, particularly Zhong Jian elastic rubber strip is pansy, has better elasticity, scalable, stressed changeable type expansion, laterally the maximal dilation amount can reach 5mm, gives the function of modification, reach the purpose of fitting, applicability is strong, and has higher-strength, and wear is comfortable.
Embodiment 2: a kind of elastic composite sole, it makes substrate with the General Purpose Rubber material, be provided with the excipient hole in the middle of the substrate, the excipient hole is provided with telescopic elastic rubber strip 2,3, and elastic rubber strip and substrate are compound to be one, and the component of described elastic rubber strip is: natural gum 70%, hard charcoal 15%, ring oil firing 8%, promoter and activating agent 5%, age resister 2%.Above-mentioned elastic composite preparation of soles method is with embodiment 1.
Embodiment 3: a kind of elastic composite sole, it makes substrate with the General Purpose Rubber material, be provided with the excipient hole in the middle of the substrate, the excipient hole is provided with telescopic elastic rubber strip 2,3, and elastic rubber strip and substrate are compound to be one, and the component of described elastic rubber strip is: natural gum 85%, hard charcoal 7%, ring oil firing 5%, promoter and activating agent 2%, age resister 1%.Above-mentioned elastic composite preparation of soles method is with embodiment 1.

Claims (2)

1. elastic composite sole, it is characterized in that: it makes substrate with the General Purpose Rubber material, be provided with the excipient hole in the middle of the substrate, the excipient hole is provided with the telescopic elastic rubber strip, and elastic rubber strip and substrate are compound to be one, and the component of described elastic rubber strip is: natural gum 70-85%, white carbon 7-15%, ring oil firing 5-10%, promoter and activating agent 2-5%, age resister 1-2%.
2. elastic composite preparation of soles method according to claim 1, it is characterized in that: it adopts following steps: after the first, base material prepares by component, joining banbury carries out mixing, monitor by the rubber process monitor, mixing time is 5-10 minute, 110 ℃~130 ℃ of temperature, slice, cooling stack; The second, after elastic rubber strip prepares by component, join banbury and carry out mixingly, mixing time is 5-10 minute, 110 ℃~130 ℃ of temperature, and slice, cooling stack; Three, above-mentioned elastic sheet rubber is put into the middle bar groove of mould that designs and vulcanized, curing temperature is 160 ± 2 ℃, and cure time is 5-10 minute, the clout that the elastic rubber strip both sides after cleaning then, the stamping-out sulfuration have more; Four, the substrate rubbers sheet is put into the mould and the elastic rubber strip that design again and vulcanized together, the rubber composition is fused mutually be bonded to one, curing temperature is 160 ± 2 ℃, and cure time is 5 minutes and 30 seconds; Five, slice, stamping-out are made the elastic composite sole.
CN2008101586556A 2008-11-07 2008-11-07 Elastic composite sole and preparation method thereof Expired - Fee Related CN101731789B (en)

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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102304239A (en) * 2011-09-07 2012-01-04 际华三五三七制鞋有限责任公司 Black bi-vulcanized rubber outsole for mat high-modulus shoe and preparation method thereof
CN103238983A (en) * 2013-05-23 2013-08-14 金猴集团威海鞋业有限公司 Sole with massage function and preparation method of sole
CN103600448A (en) * 2013-11-27 2014-02-26 际华三五一五皮革皮鞋有限公司 Mold moving method of rubber
CN103709462A (en) * 2013-12-26 2014-04-09 金猴集团威海鞋业有限公司 Rubber magnetic shoe sole pad and preparation method thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1071115A (en) * 1991-09-27 1993-04-21 于光宗 The foam process of rubber pange moulding sole
US5743027A (en) * 1995-11-29 1998-04-28 Barma; Tarachand S. Rubber footwear and method of making same
CN1323689A (en) * 2001-06-18 2001-11-28 卓辉雄 Double-density rubber shoe sole and its single-forming production process

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102304239A (en) * 2011-09-07 2012-01-04 际华三五三七制鞋有限责任公司 Black bi-vulcanized rubber outsole for mat high-modulus shoe and preparation method thereof
CN102304239B (en) * 2011-09-07 2013-06-05 际华三五三七制鞋有限责任公司 Black bi-vulcanized rubber outsole for high-modulus shoe and preparation method thereof
CN103238983A (en) * 2013-05-23 2013-08-14 金猴集团威海鞋业有限公司 Sole with massage function and preparation method of sole
CN103600448A (en) * 2013-11-27 2014-02-26 际华三五一五皮革皮鞋有限公司 Mold moving method of rubber
CN103709462A (en) * 2013-12-26 2014-04-09 金猴集团威海鞋业有限公司 Rubber magnetic shoe sole pad and preparation method thereof

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