CN1017259B - Process for preparation of goose down powder puff and fur - Google Patents
Process for preparation of goose down powder puff and furInfo
- Publication number
- CN1017259B CN1017259B CN 88109145 CN88109145A CN1017259B CN 1017259 B CN1017259 B CN 1017259B CN 88109145 CN88109145 CN 88109145 CN 88109145 A CN88109145 A CN 88109145A CN 1017259 B CN1017259 B CN 1017259B
- Authority
- CN
- China
- Prior art keywords
- goose
- goose down
- fur
- salt
- synthetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
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Abstract
The present invention relates to a preparation method of a goose down powder puff and goose down fur. After an emulsifying agent of an organic solvent is used for degreasing goose fur and removing dirt, a synthetic tanning agent containing aldehyde, particularly containing modified glutaraldehyde, is used for tanning, and then formic acid is used for acidification. The goose fur is bleached before the acidification. In the technology, white goose down fur is reduced and bleached by a synthetic bleaching agent of sodium sulfite and sodium metabisulfite, and grey goose down fur is faded by hydrogen peroxide, etc. and then bleached. The goose down fur is coated with fat liquor and then mechanically treated to obtain goose down fur with flexible leather and a white down surface. A powder puff made of the fur has the advantages of strong powder attaching capability, beautiful appearance and comfortable skin feeling.
Description
The present invention relates to a kind of fowl velour leather system fur coat of using, particularly use the method for goose down leather fur coat.
It is perfect day by day at present to prepare the technology of fur coat with skin of mammal, but also is among the exploitation exploration with the method that the fowl velour leather prepares fur coat.This is the difficulty that causes its processing owing to the special construction of fowl skin.With regard to the higher goose down skin of economic worth, though also as skin of mammal by keratinous protein, collagenic protein, interfibrillar substance, compositions such as fat, but horrida cutis lipid content height, hair follicle are dark and pass that corium, corium are very thin, the loose fragility of dermatotome fiber etc., be difficult to process fur coat with general working method.
The purpose of this invention is to provide a kind of method that is equipped with fur coat by the goose down leather.
The objective of the invention is to reach: a kind of method that is equipped with fur coat with the goose down leather by following measure, it is characterized in that a, the salt dry plate is given birth to the goose down skin containing zellon, be at least partially skimmed by stirring in the water of emulsifying agent, b, with containing aldehyde, sodium bicarbonate, the synthetic tanning agent of salt is in the temperature that is lower than 30 ℃, the pH value is under 7.5～8 the condition, by stirring tanning goose down skin, C(1) with containing S-WAT, Sodium Metabisulfite, salt, the synthetic SYNTHETIC OPTICAL WHITNER of wetting agent, in the temperature stirring that is lower than 30 ℃ the goose down skin is bleached, perhaps (2) are with containing ferrous sulfate, ammonium chloride, the aqueous solution of salt carries out pre-treatment being lower than to stir under 30 ℃ the temperature, again with containing hydrogen peroxide, ammoniacal liquor, trisodium phosphate, glycerine, the aqueous solution of salt is 32～34 ℃ temperature, the pH value be 8～9 be interrupted to stir repeat C(1 again after 4～5 hours) step, grey goose down skin faded bleach, d, containing formic acid, tschermigite, stir in the water of salt, make the acidifying of goose down skin, e, with zellon or trieline with the degreasing of goose down skin, f, to contain the lanolin that is dissolved in the Virahol, sulfited fish oil, the negatively charged ion synthetic fat liquor, ammoniacal liquor, the water of peregal is heated to 45 ℃, after fully stirring, brush on the goose down dermatotome its stuffing, g, make further mechanical treatment after the drying.Used aldehyde is modified glutaraldehyde in above-mentioned steps b.In the pickling liquid of above-mentioned steps d, also contain white dyes.
The main flow process of method of the present invention is: raw material skin degreasing-aldehyde processing-bleaching-acidifying-degreasing-stuffing-aftertreatment.
At first immersion process is to adopt the emulsion of organic solvent, not only can remove most of grease and dirt but also can not cause the bad broken face that produces of dermatotome folding, it is the living goose down dermatotome of salt dry plate to be placed contain zellon, in the water of emulsifying agent, the part by weight that the salt dry plate is given birth to goose down dermatotome and water is 1: 18, and every premium on currency adds 8 milliliters of zellons, 1 milliliter of emulsifying agent, be interrupted stirring 3 hours 25～30 ℃ temperature, preferably stirred 5 minutes every half an hour, the goose down dermatotome is eased back, dissolving part soluble protein and interfibrillar substance are to remove most of fat and dirt.Goose down skin after the dehydration is placed the liquid of every premium on currency with 0.5 milliliter of salt 20 gram, wetting agent, under 20 ℃ temperature, soaked 18～24 hours, the goose down skin is further eased back be beneficial to following fleshing.Remove non-collagenous tissue with mechanical means and keep corium.With containing aldehyde such as formaldehyde, modified glutaraldehyde preferably, the sodium bicarbonate of adjust pH and prevent that the synthetic tanning agent of dermatotome expansible salt is in the temperature that is lower than 30 ℃, preferably at 27～30 ℃, pH value is to stir 8～24 hours tanning goose down skins by being interrupted under 7.0～7.5 the condition, and the composition of this synthetic tanning agent is to add 40 gram salt, 4～5 gram sodium bicarbonate, 4～5 milliliters aldehyde in every premium on currency.It can make the protein of goose down skin fix, and adopts modified glutaraldehyde can not make the flavescence of goose down skin, and makes plate matter have very high intensity, good extensibility and fullness ratio, and anti-washing is indeformable, temperature resistance reaches 78 ℃, easily makes dye coloring.
Tanned goose down skin is through dewatering, wash, bleaching after the dehydration.Kind difference because of goose, goose down is adularescent and grey roughly, directly carry out reduction bleaching promptly with containing the relatively mild synthetic SYNTHETIC OPTICAL WHITNER of reductive action of S-WAT, Sodium Metabisulfite, salt, wetting agent for white goose down micromicro in the temperature that is lower than 30 ℃, preferably bleach in 23～27 ℃ of scopes, with the gloss of the elasticity, mercerising sense and the fur that keep suede.Be interrupted to stir after 2 hours and left standstill 8～16 hours, the composition of this synthetic SYNTHETIC OPTICAL WHITNER is to add 22.5 gram S-WATs, 8.5 gram Sodium Metabisulfites, 20 gram salt, 0.5 milliliter of wetting agent in every premium on currency.To carry out fade treatment for grey goose down skin, make it to be white in color or oyster white after bleach again or dye.Its technology of fading is to adopt the aqueous solution that contains ferrous sulfate catalyst, ammonium chloride reaction moderator, salt in the temperature that is lower than 30 ℃, and preferably 26～28 ℃, the time is 4～6 hours.This composition that gives treatment solution is to add ferrous sulfate 5～7 grams, ammonium chloride 5 grams, salt 20 grams in every premium on currency.This dehydration of goose down skin, washing of giving processing is removed unabsorbed molysite again after dehydration, with the aqueous solution of hydrogen peroxide, ammoniacal liquor, trisodium phosphate, glycerine, salt 32～34 ℃ temperature, pH value be 8～9 be interrupted stir 4～5 hours after, repeat bleaching process again through washing dehydration to white goose down skin.The composition of its above-mentioned oxidation liquid of this oxidation-reduction process bleaching is to add 5 milliliters of 35% 2～2.5 milliliters of 8～12 milliliters in hydrogen peroxide, ammoniacal liquor, trisodium phosphate 5～8 grams, glycerine in every premium on currency, and the goose down skin after the bleaching is placed on through dehydration and carries out leaving standstill 4 hours last pH values after the acidifying heating makes the liquid temperature be to stir 2 hours 32 ℃ of intermittences in the water that contains salt, tschermigite, organic acid such as formic acid and reach 3.8～4.Particularly adopt the organic acid acidifying by this process, sluggish not only, but also can remove free aldehyde, make plate matter softness, plentiful, the plate suede free from extraneous odour of staple.Be preferably in the acidizing fluid and add the Fluorescent optical brightener, can make that goose down is pure white, nature and have gloss.The composition of this acidizing fluid is salt 40 grams, tschermigite 25 grams, 1 milliliter in formic acid, 2 milliliters of Fluorescent optical brighteners.The preparation of this Fluorescent light whitening fluid is to add 1 gram Fluorescent light powder, 0.002 gram XiLi to lead in a premium on currency.Method of the present invention adopts when acidifying makes bleaching after the first tanning pH value stable, and bleaching process is smooth, guarantees that simultaneously the damage in this process of dermatotome and fine hair is reduced to bottom line.With the goose down skin dehydration of acidifying, dry in the ventilation.Make water content 22～25%.Above-mentioned dried goose down skin is carried out grease on the degreasing Ex-all goose down skin with solvent such as trieline or zellon in degreasing machine.Wherein the dry goose down skin of per kilogram is used 4 liters of degreasings of trieline 8～10 minutes, and desolventizing 5～6 minutes is in oven dry below 55 ℃.Can be after oven dry as need dyeing, dyeing finishes need not get damp again and purifies dye liquor and directly carry out stuffing, prevent the dermatotome drying, make soft.The aqueous solution that will contain the lanolin that is dissolved in the Virahol, sulfited fish oil, negatively charged ion synthetic fat liquor, ammoniacal liquor, peregal is heated to 45 ℃, brushes equably on the dermatotome of goose down skin its stuffing after stirring again.The lanolin that are formulated as 25 grams of fat liquor are added in 50 milliliters the Virahol, add 60 milliliters of sulfited fish oils, 100 milliliters of negatively charged ion synthetic fat liquors, 2 milliliters of ammoniacal liquor, 5 gram peregals after the stirring and dissolving, add water to one liter at last.At the ventilation hang airing, make it the skin water content 20～22%, then carry out mechanical treatment again.The goose down skin that above-mentioned drying is good carries out aftertreatment, promptly per hundred goose down skins with 50 kilograms of refining wood powders, 3 liters of silicon emulsions, 25 liters of zellons, put into the rotary drum lift-over 1 hour, make goose down add lustre to, antistatic, prevent that goose down from polluting.The Ex-all wood powder launches the goose down skin, with the whole suede shape of combing machine for fur comb fine hair is unfolded.
Have higher intensity, good extensibility and a fullness ratio with the goose fur coat plate matter of method of the present invention preparation is pliable and tough, it is smooth flexibly that water resisting property is indeformable, shrinkage temperature reaches 78 ℃, the pure white exquisiteness of goose down face, staple.Compare with existing various powder puffs with the goose fur coat powder puff of the inventive method preparation have good looking appearance, elegance is luxurious, powder coatings ability is strong, easy to use, advantage such as the skin sense is comfortable.
Embodiment 1
The process for tanning of white goose skin (1) immersion: the living white goose velour leather of salt dry plate is placed the water that contains zellon, emulsifying agent, and the part by weight of dried rawhide and water is 1: 18, and every premium on currency adds 8 milliliters of zellons, 1 milliliter of emulsifying agent.Solution temperature wheeled agitator (hereinafter to be referred as agitator) with 20 rev/mins in the time of 30 ℃ is interrupted stirring 3 hours, stirs 5 minutes every half an hour therebetween.Taking out the back dewatered 20 minutes in water extracter.(2) soak again: the goose down skin after will dewatering places the solution of every premium on currency with 0.5 milliliter of salt 20 gram, wetting agent (JFC), is interrupted stirring and left standstill 4～6 hours after 2 hours when 20 ℃ of liquid temperature.(3) fleshing: remove non-collagenous tissue with special machinery (being commonly called as fleshing machine) or craft and keep corium.(4) aldehyde is handled: place every premium on currency to be added with the synthetic tanning agent of 5 milliliters of salt 40 gram sodium bicarbonate 4 grams, modified glutaraldehyde the goose down skin behind the fleshing, left standstill 8～16 hours after stirring 2 hours in interruption under the condition of 27 ℃ of pH values 7.5～8 of liquid temperature, then with its dehydration 10～20 minutes, stirred 10 minutes simultaneously with flushing with clean water the back, dewatered at last 10 minutes.(5) bleaching: the goose down skin after will wash places every premium on currency with 0.5 milliliter of salt 20 gram, wetting agent, in the synthetic SYNTHETIC OPTICAL WHITNER of S-WAT 22.5 grams, Sodium Metabisulfite 8.5 grams when 27 ℃ of liquid temperature stirring leave standstill after 2 hours and dewatered then in 8～16 hours 20 minutes.(6) acidifying: the white goose velour leather after will bleaching places every premium on currency to be added with the liquid of 2 milliliters of salt 40 grams, 1 milliliter in formic acid, tschermigite 25 grams, Fluorescent optical brightener.It is that 32 ℃ of employing agitators intermittently stir that heating makes the liquid temperature, stirs first 15～20 minutes, stirs 5 minutes every 1 hour afterwards, stirs altogether and leaves standstill then for three times 4～6 hours, and last solution pH value reaches 3.8～4.The preparation of Fluorescent optical brightener: add Fluorescent light whitening powder (CIBA CO.LTD.(SWISS) in the liter water) 1 gram XiLi logical (CELLI TON BLVE FFR West Germany BASF Aktiengesellschaft), 0.002 gram.(7) drying: after the goose down skin after acidifying dehydration 1 hour, the goose down skin open and flat at the ventilation hang airing to water content 22～25%.(8) degreasing and moisture regain: the dry skin of per kilogram is with zellon or trieline 4 liter degreasings desolventizing 6 minutes after 10 minutes, 55 ℃ of oven dry down.It is 30～35% that the oven dry back makes the horrida cutis water content by moisture regain.(9) stuffing: with banister brush the even scrubbing brush of fat liquor on dermatotome.The preparation of fat liquor: the lanolin of 25 grams are dropped in 50 milliliters the Virahol, stirring and dissolving adds 60 milliliters of sulfited fish oils, 100 milliliters of negatively charged ion synthetic fat liquors, 2 milliliters of ammoniacal liquor, peregal 5 grams after evenly and adds water to a liter and get final product.Aforesaid liquid is heated to 45 ℃ and fully stir, to be mixedly can brushes usefulness after evenly.(10) mechanical treatment: the goose down skin behind the fat liquoring is suspended on the ventilation dries, make the horrida cutis water content 20～22%.Again with per hundred hang up dry hide with 50 kilograms of refining wood powders, silicon emulsion 3 liters, 2.5 liters of zellons, put into the rotary drum lift-over 1 hour, the Ex-all wood powder trails skin then, through decorticating mill dermatotome is polished.Put in order the suede type, make staple unfold, can obtain the pure white white goose skin of the pliable and tough matte of dermatotome with combing machine for fur at last.
Embodiment 2
The salt dry plate is given birth to the grey goose down skin repeat the operation of (1), (2), (3), (4) step in the example 1 as raw material, wherein to adopt the pH values of 5 milliliters of formaldehyde, 5 gram sodium bicarbonate, solution be 8 to carry out under 30 ℃ temperature to the aldehyde treatment step.(5) bleaching: the goose down skin after will washing places every premium on currency to be added with ferrous sulfate 6 grams, ammonium chloride 5 grams, under 28 ℃ of temperature, give in the solution of salt 20 grams and handling 5 hours, through washing again dehydration be placed on and add 10 milliliters in 35% hydrogen peroxide in every premium on currency, 2 milliliters of ammoniacal liquor, trisodium phosphate 8 grams, in the solution that glycerine is 5 milliliters, temperature at 32 ℃, pH value is to be interrupted under 8～9 the condition to stir after 5 hours, repeat the operation of step among the embodiment 1 (5) and back thereof behind washing dehydration again, it is pliable and tough to obtain the dermatotome that is equipped with by the grey goose down leather, the goose-fur that matte is pure white.
Claims (3)
1, a kind of preparation method of goose-fur is characterized in that:
A, the salt dry plate given birth to the goose down skin in the water that contains zellon, emulsifying agent, be at least partially skimmed by stirring,
B, with the synthetic tanning agent that contains aldehyde, sodium bicarbonate, salt be at the temperature, the pH value that are lower than 30 ℃ under 7.5～8 the condition by stirring tanning goose down skin,
C, (1) with containing S-WAT, Sodium Metabisulfite, salt, the synthetic SYNTHETIC OPTICAL WHITNER of wetting agent, the white goose velour leather is bleached being lower than to stir under 30 ℃ the temperature, or (2) are with containing ferrous sulfate, ammonia chloride, the aqueous solution of salt gives processing being lower than to stir under 30 ℃ the temperature, again with containing hydrogen peroxide, ammoniacal liquor, trisodium phosphate, the aqueous solution of glycerine salt is 32～34 ℃ temperature, pH value is 8～9, be interrupted and stir the step that repeated C (1) in 4～5 hours afterwards again, the grey goose down skin faded bleach
D, in the water that contains formic acid, tschermigite, salt, stir, till pH value to 3.8～4, make the acidifying of goose down skin,
E, with solvent zellon or trieline with the degreasing of goose down skin,
F, the water that will contain the lanolin that is dissolved in the Virahol, sulfited fish oil, negatively charged ion synthetic fat liquor, ammoniacal liquor, peregal are heated to 45 ℃, brushes on the goose down dermatotome its stuffing through fully stirring the back,
Make further mechanical treatment after g, the drying.
2, the preparation method of goose-fur according to claim 1 is characterized in that: used aldehyde is modified glutaraldehyde among the step b.
3, the preparation method of goose-fur according to claim 1 and 2 is characterized in that: also contain white dyes in the pickling liquid of steps d.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88109145 CN1017259B (en) | 1988-10-12 | 1988-10-12 | Process for preparation of goose down powder puff and fur |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88109145 CN1017259B (en) | 1988-10-12 | 1988-10-12 | Process for preparation of goose down powder puff and fur |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1041795A CN1041795A (en) | 1990-05-02 |
| CN1017259B true CN1017259B (en) | 1992-07-01 |
Family
ID=4835355
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 88109145 Expired CN1017259B (en) | 1988-10-12 | 1988-10-12 | Process for preparation of goose down powder puff and fur |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1017259B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1051112C (en) * | 1997-04-09 | 2000-04-05 | 辽阳春晖鹅业综合开发有限公司 | Method for manufacturing goose down fur |
| CN102108425A (en) * | 2009-12-25 | 2011-06-29 | 华斯农业开发股份有限公司 | Mink skin decolorization improving technique |
| CN102492788A (en) * | 2011-11-24 | 2012-06-13 | 北京泛博化学股份有限公司 | Treatment method of animal fur and animal fur product |
| CN102817227B (en) * | 2012-08-14 | 2014-07-02 | 安徽舒城县翰文运动用品有限责任公司 | Feather decolorization treatment process |
| CN103485186B (en) * | 2013-08-16 | 2016-02-10 | 陕西科技大学 | A kind of method improving eider down bulking intensity |
| CN104498646B (en) * | 2014-11-25 | 2016-08-24 | 浙江中辉皮草有限公司 | A kind of process copying ecru mink fur with chalybeate mink fur |
| CN109156972A (en) * | 2018-08-30 | 2019-01-08 | 廖伟汉 | A kind of imitation genuine fecula is flutterred |
-
1988
- 1988-10-12 CN CN 88109145 patent/CN1017259B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CN1041795A (en) | 1990-05-02 |
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