CN101716492B - Antibacterial adsorbent selectively adsorbing nicotine and carbon monoxide in smoke and application in wrap paper thereof - Google Patents
Antibacterial adsorbent selectively adsorbing nicotine and carbon monoxide in smoke and application in wrap paper thereof Download PDFInfo
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- CN101716492B CN101716492B CN200910218381XA CN200910218381A CN101716492B CN 101716492 B CN101716492 B CN 101716492B CN 200910218381X A CN200910218381X A CN 200910218381XA CN 200910218381 A CN200910218381 A CN 200910218381A CN 101716492 B CN101716492 B CN 101716492B
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Abstract
The invention provides antibacterial adsorbent and a method for applying the adsorbent in wrap paper. The antibacterial adsorbent mainly selectively adsorbs nicotine and carbon monoxide in smoke, and has certain adsorbing effect to tar, NO, gas phase radical, benzopyrene and nitrite. The aim can be realized through the following technical means: the antibacterial adsorbent comprises the followingcompositions in parts by weight: 10 to 20 parts of tea polyphenol, 40 to 60 parts of copper-carrying zeolite molecular sieve, 20 to 30 parts of medical stone, and 30 to 50 parts of bentonite, whereinthe granularity of each composition is between 100 and 200 meshes; and the tea polyphenol is dissolved in binder, after the copper-carrying zeolite molecular sieve, the medical stone and the bentonite are mixed and ground until the granularity is between 100 and 200 meshes, the mixture is adsorbed on the surface of the wrap base paper which is coated on one side of a filter stick through the binder dissolving the tea polyphenol, or is adsorbed on the surface of the wrap base paper in parallel arrangement, or is adhered on two sides of the wrap base paper to form an adsorption layer with thickness of between 0.05 to 0.1mm.
Description
Technical field
The present invention relates to a kind of cigarette and use adsorbent, more particularly, the cigarette that relates to a kind of adsorbent of selecting to adsorb oxious component in the flue gas and band sorbing material is used forming paper.
Background technology
Contain multiple composition in the smog that discharges during cigarette combustion, wherein main matter is nicotine (nicotine) and tar, also contains harmful substances such as carbon monoxide, nitrogen oxide, hydro carbons, aldehydes, ammonia and free radical in addition.Aldehydes has spread effect to respiratory tract; The nicotine class can stimulate sympathetic nerve, causes the endangium infringement; Tar, Benzpyrene all have carcinogenesis; Carbon monoxide can lower red blood cell oxygen is transported to the ability that whole body goes.Though harm of smoking is in health as you know,, smokers still are difficult to smoking cessation, and this is because 1. special fragrance can bring pleasant sensation to groups of people, causes psychological dependence; 2. when smoking, nicotine only needs just can arrive brain more than 7 seconds, makes the smoker feel a kind of sensation of soft happiness, make central nervous system excited earlier after inhibition, cause on the physiology dependence to cigarette; 3. tar can make cigarette tool that very strong suction flavor is arranged; 4. smoking can be eliminated fatigue, increases notice and mediator's mood etc.Since cigarette is the thing that a lot of smokers also be unable to do without all one's life, but human body there is disadvantageous one side, so, content of harmful in the flue gas reduced, improve the security of sucking of cigarette, keep cigarette simultaneously again is the direction that tobacco enterprise is made great efforts to smoker's attraction always.
As everyone knows, in the flue gas harmful components because of the tobacco place of production, kind, drying means, difference such as prescription, production technology and have different, so also difference to some extent of the method that is used for reducing harmful substance.Just as we all know, tar is crossed to hang down and can be had a strong impact on cigarette suction flavor, nicotine amount in the flue gas, be that nicotine can make the people excited and calm, nicotine is very fast in the speed of health intracellular metabolite,, harmless substantially under the normal condition after basic half an hour to the people just along with the urine discharge, if can too much also can be unfavorable to human body.So, if nicotine, tar are also cut in a large number in harm reduction, can have influence on suction quality, reduce attraction to the smoker; And if nicotine, tar are too much, again can be unfavorable to human body.So, do not adopt unified harm reduction product and method if do not distinguish the cigarette smoke harmful components, not having of can causing that this subtracts in the flue gas is up to standard, but having been subtracted of should rationally controlling is a lot, not only influences suction quality, and can increase some unnecessary costs.In a word, must be to the harm reason of falling of cigarette at the different mining of harmful components in the flue gas with different harm reduction products.
It is also many at present the product and the method for harm reason to be fallen in cigarette, as application number is that 200720155554.4 Chinese patent file discloses and a kind of Pu'er tea is coated on the forming paper by bonding agent, make the cigaratte filter forming paper with Pu'er tea adsorption layer, this forming paper is mainly used in nitrite, BaP, the tar that reduces in the flue gas; Application number is that 200510010716.0 Chinese patent file discloses a kind of cigaratte filter forming paper with activated adoption layer, by on the filter tip forming paper, applying in molecular sieve or medical stone, active carbon, ion exchange resin, polysaccharide, natural, the natural plants powder one or more, on forming paper, form and have active adsorption layer, reach in the process of sucking and be adsorbed with harmful substances, thereby play reducing poison function.Though present harmful product falls and method many,, all do not have selectively to adsorb at the kind and the quantity of oxious component in the flue gas, in use will have the situation that harm reduction is excessive or harm reduction is not enough.
Summary of the invention
The present invention aims to provide a kind of antibacterial adsorbent and this adsorbent and is applied to method on the forming paper, this antibacterial adsorbent mainly selects to adsorb nicotine and the carbon monoxide in the flue gas, secondly tar, NO, gaseous phase free radical, BaP, nitrite is also had certain suction-operated.
The present invention realizes above-mentioned purpose by following technological means:
Antibacterial adsorbent is counted by weight, by Tea Polyphenols 10-20 part, and copper-loaded zeolite molecular sieve 40-60 part, medical stone 20-30 part, bentonite 30-50 part is formed, and each composition granularity is the 100-200 order.
More preferably, antibacterial adsorbent is counted by weight, by Tea Polyphenols 12-18 part, and copper-loaded zeolite molecular sieve 45-55 part, medical stone 22-28 part, bentonite 38-45 part is formed.
Can in such a way above-mentioned antibacterial adsorbent be applied on the forming paper:
Tea Polyphenols is dissolved in the binding agent, copper-loaded zeolite molecular sieve, medical stone and bentonite mixed grinding to granularity be behind the 100-200 order binding agent by being dissolved with Tea Polyphenols to form thickness attached to the moulding body paper surface of parcel filter stick one side be the adsorption layer of 0.05-0.1mm.
Also copper-loaded zeolite molecular sieve, medical stone and bentonite can be arranged in parallel attached on the moulding body paper surface by the binding agent that is dissolved with Tea Polyphenols respectively;
Described binding agent is one or more a mixture in beta cyclodextrin, polyvinyl alcohol or the amylan;
Also the Tea Polyphenols of above-mentioned dosage, copper-loaded zeolite molecular sieve, medical stone and bentonite can be bonded at the two sides of moulding body paper respectively.
Beneficial effect of the present invention is:
1. adopt antibacterial adsorbent of the present invention, nicotine can reduce 2-6% in the flue gas, carbon monoxide can reduce 3-6%, tar can reduce 2-4%, gaseous phase free radical clearance rate 10-15%, BaP clearance rate 3-7%, nitrite clearance rate 4-8%, NO clearance rate 10-16%, sensory evaluating smoking's result show, can keep the cigarette suction quality substantially.
When 2. being applied on the forming paper, sorbing material is arranged in parallel to be bonded on the moulding body paper surface, can avoid each sorbing material to cover mutually and reduces adsorption effect.
The specific embodiment
The invention will be described further below in conjunction with specific embodiment.
Embodiment 1
Three kinds of main harmful substance contents in the pending cigarette smoke: tar content 13mg, nicotine amount 1.2mg, CO content 14mg, adsorbent is counted by weight, by 10 parts of Tea Polyphenols, 50 parts of copper-loaded zeolite molecular sieves, 30 parts of medical stones, 40 parts of compositions of bentonite, Tea Polyphenols is dissolved in 5 parts of beta cyclodextrin bonding agents, with copper-loaded zeolite molecular sieve, medical stone and bentonite mixed grinding to granularity is 150 orders, be bonded on the moulding body paper surface that contacts with filter stick by the beta cyclodextrin that is dissolved with Tea Polyphenols, forming thickness is the adsorption layer of 0.05mm.
After being applied to this forming paper on the above-mentioned cigarette with special adsorption layer, method according to GB GB/T19069-2004, GB5606.5-2005 and rower YC/T185-2004 regulation is tested, harmful substance contents is in its flue gas: nicotine amount 1.164mg, reduce 3%, CO content 13.44mg, reduce 4%, tar content 12.74mg, reduce 2%, gaseous phase free radical clearance rate 11%, BaP clearance rate 4%, nitrite clearance rate 5%, NO clearance rate 12%, forming paper has antibacterial action.Sensory evaluating smoking's result shows that the test cigarette has kept original style and jealous substantially.
Embodiment 2
Three kinds of main harmful substance contents in the pending cigarette smoke: tar content 13mg, nicotine amount 1.2mg, CO content 14mg, adsorbent is counted by weight, by 15 parts of Tea Polyphenols, 45 parts of copper-loaded zeolite molecular sieves, 35 parts of medical stones, 35 parts of compositions of bentonite, Tea Polyphenols is dissolved in 6 parts of polyvinyl alcohol bonding agents, with copper-loaded zeolite molecular sieve, medical stone and bentonite mixed grinding to granularity is 200 orders, be arranged in parallel attached on the moulding body paper surface by the polyvinyl alcohol that is dissolved with Tea Polyphenols, forming thickness is the adsorption layer of 0.08mm.
After being applied to this forming paper on the above-mentioned cigarette with special adsorption layer, method according to GB GB/T19069-2004, GB5606.5-2005 and rower YC/T185-2004 regulation is tested, harmful substance contents is in its flue gas: nicotine amount 1.176mg, reduce 2%, CO content 13.3mg, reduce 5%, tar content 12.74mg, reduce 3%, gaseous phase free radical clearance rate 12%, BaP clearance rate 5%, nitrite clearance rate 4%, NO clearance rate 13%, forming paper has antibacterial action.Sensory evaluating smoking's result shows that the test cigarette has kept original style and jealous substantially.
Embodiment 3
Three kinds of main harmful substance contents in the pending cigarette smoke: tar content 13mg, nicotine amount 1.1mg, CO content 13mg, adsorbent is counted by weight, by 20 parts of Tea Polyphenols, 40 parts of copper-loaded zeolite molecular sieves, 30 parts of medical stones, 40 parts of compositions of bentonite, Tea Polyphenols is dissolved in 4 parts of beta cyclodextrin bonding agents, with copper-loaded zeolite molecular sieve, medical stone and bentonite mixed grinding to granularity is 100 orders, be bonded at respectively on the moulding body paper two sides by the beta cyclodextrin that is dissolved with Tea Polyphenols, form the adsorption layer that thickness is 0.06mm respectively.
After being applied to this forming paper on the above-mentioned cigarette with special adsorption layer, method according to GB GB/T19069-2004, GB5606.5-2005 and rower YC/T185-2004 regulation is tested, harmful substance contents is in its flue gas: nicotine amount 1.034mg, reduce 6%, CO content 12.22mg, reduce 6%, tar content 12.61mg, reduce 3%, gaseous phase free radical clearance rate 14%, BaP clearance rate 7%, nitrite clearance rate 8%, NO clearance rate 16%, forming paper has antibacterial action.Sensory evaluating smoking's result shows that the test cigarette has kept original style and jealous substantially.
Three kinds of main harmful substance contents in the pending cigarette smoke: tar content 13mg, nicotine amount 1.1mg, CO content 13mg, adsorbent is counted by weight, by 20 parts of Tea Polyphenols, 50 parts of copper-loaded zeolite molecular sieves, 30 parts of medical stones, 50 parts of compositions of bentonite, Tea Polyphenols is dissolved in 5 parts of amylan bonding agents, with copper-loaded zeolite molecular sieve, medical stone and bentonite mixed grinding to granularity is 200 orders, be bonded at respectively on the moulding body paper two sides by the amylan that is dissolved with Tea Polyphenols, form the adsorption layer that thickness is 0.1mm respectively.
After being applied to this forming paper on the above-mentioned cigarette with special adsorption layer, method according to GB GB/T19069-2004, GB5606.5-2005 and rower YC/T185-2004 regulation is tested, harmful substance contents is in its flue gas: nicotine amount 1.045mg, reduce 5%, CO content 12.35mg, reduce 5%, tar content 12.48mg, reduce 4%, gaseous phase free radical clearance rate 11%, BaP clearance rate 6%, nitrite clearance rate 7%, NO clearance rate 14%, forming paper has antibacterial action.Sensory evaluating smoking's result shows that the test cigarette has kept original style and jealous substantially.
Embodiment 5
Three kinds of main harmful substance contents in the pending cigarette smoke: tar content 13mg, nicotine amount 1.2mg, CO content 13mg, adsorbent is counted by weight, by 20 parts of Tea Polyphenols, 60 parts of copper-loaded zeolite molecular sieves, 30 parts of medical stones, 50 parts of compositions of bentonite, Tea Polyphenols is dissolved in 6 parts of polyvinyl alcohol bonding agents, with copper-loaded zeolite molecular sieve, medical stone and bentonite mixed grinding to granularity is 200 orders, be bonded at respectively on the moulding body paper two sides by the polyvinyl alcohol that is dissolved with Tea Polyphenols, form the adsorption layer that thickness is 0.09mm respectively.
After being applied to this forming paper on the above-mentioned cigarette with special adsorption layer, method according to GB GB/T19069-2004, GB5606.5-2005 and rower YC/T185-2004 regulation is tested, harmful substance contents is in its flue gas: nicotine amount 1.14mg, reduce 5%, CO content 12.48mg, reduce 4%, tar content 12.48mg, reduce 4%, gaseous phase free radical clearance rate 12%, BaP clearance rate 5%, nitrite clearance rate 7%, NO clearance rate 13%, forming paper has antibacterial action.Sensory evaluating smoking's result shows that the test cigarette has kept original style and jealous substantially.
Claims (9)
1. an antibacterial adsorbent of selecting to adsorb nicotine and carbon monoxide in the flue gas is characterized in that, by weight meter, by Tea Polyphenols 10-20 part, copper-loaded zeolite molecular sieve 40-60 part, medical stone 20-30 part, bentonite 30-50 part is formed, and each composition granularity is the 100-200 order.
2. a kind of antibacterial adsorbent of selecting to adsorb nicotine and carbon monoxide in the flue gas according to claim 1 is characterized in that, by Tea Polyphenols 12-18 part, and copper-loaded zeolite molecular sieve 45-55 part, medical stone 22-28 part, bentonite 38-45 part is formed.
3. method of utilizing the antibacterial adsorbent production forming paper of nicotine and carbon monoxide in the described selection of the claim 1 absorption flue gas, it is characterized in that, produce in such a way: Tea Polyphenols is dissolved in the binding agent, and forming thickness by the binding agent that is dissolved with Tea Polyphenols attached to parcel filter stick moulding body paper surface simultaneously after copper-loaded zeolite molecular sieve, medical stone and bentonite mix is the adsorption layer of 0.05-0.1mm.
4. method of utilizing the antibacterial adsorbent production forming paper of nicotine and carbon monoxide in the described selection of the claim 2 absorption flue gas, it is characterized in that, produce in such a way: Tea Polyphenols is dissolved in the binding agent, and forming thickness by the binding agent that is dissolved with Tea Polyphenols attached to parcel filter stick moulding body paper surface simultaneously after copper-loaded zeolite molecular sieve, medical stone and bentonite mix is the adsorption layer of 0.05-0.1mm.
5. method of utilizing the antibacterial adsorbent production forming paper of nicotine and carbon monoxide in the described selection of the claim 1 absorption flue gas, it is characterized in that, produce in such a way: it is the 100-200 order that copper-loaded zeolite molecular sieve, medical stone and bentonite are ground to granularity respectively, is arranged in parallel attached on the moulding body paper surface by the binding agent that is dissolved with Tea Polyphenols.
6. method of utilizing the antibacterial adsorbent production forming paper of nicotine and carbon monoxide in the described selection of the claim 2 absorption flue gas, it is characterized in that, produce in such a way: it is the 100-200 order that copper-loaded zeolite molecular sieve, medical stone and bentonite are ground to granularity respectively, is arranged in parallel attached on the moulding body paper surface by the binding agent that is dissolved with Tea Polyphenols.
7. select the method for the antibacterial adsorbent production forming paper of nicotine and carbon monoxide in the absorption flue gas according to any described utilization among the claim 3-6, it is characterized in that described binding agent is one or more a mixture in beta cyclodextrin, polyvinyl alcohol or the amylan.
8. select the method for the antibacterial adsorbent production forming paper of nicotine and carbon monoxide in the absorption flue gas according to any described utilization among the claim 3-6, it is characterized in that, the Tea Polyphenols of above-mentioned dosage, copper-loaded zeolite molecular sieve, medical stone and bentonite are bonded at the two sides of moulding body paper respectively.
9. the method for the antibacterial adsorbent production forming paper of nicotine and carbon monoxide in the utilization selection absorption flue gas according to claim 7, it is characterized in that, the Tea Polyphenols of above-mentioned dosage, copper-loaded zeolite molecular sieve, medical stone and bentonite are bonded at the two sides of moulding body paper respectively.
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| Application Number | Priority Date | Filing Date | Title |
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| CN200910218381XA CN101716492B (en) | 2009-12-17 | 2009-12-17 | Antibacterial adsorbent selectively adsorbing nicotine and carbon monoxide in smoke and application in wrap paper thereof |
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| CN200910218381XA CN101716492B (en) | 2009-12-17 | 2009-12-17 | Antibacterial adsorbent selectively adsorbing nicotine and carbon monoxide in smoke and application in wrap paper thereof |
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| CN101716492B true CN101716492B (en) | 2011-12-28 |
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| CN103330286B (en) * | 2013-06-28 | 2014-11-05 | 湖北中烟工业有限责任公司 | Cigarette filter tip comprising natural Chinese herbal medicine antibacterial agent and manufacturing method |
| CN105755898A (en) * | 2016-03-28 | 2016-07-13 | 柳州联海科技有限公司 | Nicotine adsorbent and preparation method |
| CN105749883A (en) * | 2016-03-28 | 2016-07-13 | 柳州联海科技有限公司 | Adsorbent for adsorbing harmful substances in cigarette smoke |
| CN107376846A (en) * | 2017-06-22 | 2017-11-24 | 南京汉旗新材料科技有限公司 | A kind of nicotine scavenger |
| CN109864341B (en) * | 2019-04-12 | 2021-07-13 | 滁州卷烟材料厂 | Recyclable cigarette composite filter tip and recycling process thereof |
| CN110192495A (en) * | 2019-06-27 | 2019-09-03 | 贵州省贵福菌业发展有限公司 | A kind of methods and applications using tobacco rod preparation oil tea mushroom culture medium |
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| CN1145206A (en) * | 1995-09-13 | 1997-03-19 | 北京卷烟厂 | Low free radical and low toxicity cigarette and its prodn. method |
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