CN101721976B - Antimicrobial adsorbent for selectively absorbing carbon monoxide and aldehydes in smoke and application thereof in wrap paper - Google Patents
Antimicrobial adsorbent for selectively absorbing carbon monoxide and aldehydes in smoke and application thereof in wrap paper Download PDFInfo
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- CN101721976B CN101721976B CN2009102183824A CN200910218382A CN101721976B CN 101721976 B CN101721976 B CN 101721976B CN 2009102183824 A CN2009102183824 A CN 2009102183824A CN 200910218382 A CN200910218382 A CN 200910218382A CN 101721976 B CN101721976 B CN 101721976B
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- tea polyphenols
- soluble protein
- aldehydes
- carbon monoxide
- copper
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Abstract
The invention provides an antimicrobial adsorbent and a method for applying the antimicrobial adsorbent to a shaping paper. The antimicrobial adsorbent mainly selectively adsorbs carbon monoxide and aldehydes in smoke, and has certain absorption effects on ammonia, gas-phase free radicals, benzopyrene and nitrite. To achieve the functions, the following technical means is adopted: the antimicrobial adsorbent is composed of the following components by weight parts: 20-30 parts of tea polyphenols, 10-20 parts of soluble protein, and 5-10 parts of active aluminium oxide containing copper, the granularity of each component is 100-200mesh; the tea polyphenols and soluble protein are dissolved in prepared bonding agent, the active aluminium oxide containing copper is attached on the shaping paper surface through the bonding agent dissolved with the tea polyphenols and soluble protein to form an adsorption layer with a thickness of 0.05-0.15mm, or the soluble protein, tea polyphenols and active aluminium oxide containing copper are respectively crushed to the granularity of 100-200mesh, and are attached on the shaping paper surface through the bonding agent in a parallel arrangement.
Description
Technical field
The present invention relates to a kind of cigarette and use adsorbent, more particularly, the cigarette that relates to a kind of adsorbent of selecting to adsorb oxious component in the flue gas and band sorbing material is used forming paper.
Background technology
Contain multiple composition in the smog that discharges during cigarette combustion, wherein main matter is nicotine (nicotine) and tar, also contains harmful substances such as carbon monoxide, nitrogen oxide, hydro carbons, aldehydes, ammonia and free radical in addition.Aldehydes has spread effect to respiratory tract; The nicotine class can stimulate sympathetic nerve, causes the endangium infringement; Tar, Benzpyrene all have carcinogenesis; Carbon monoxide can lower red blood cell oxygen is transported to the ability that whole body goes.Though harm of smoking is in health as you know,, smokers still are difficult to smoking cessation, and this is because 1. special fragrance can bring pleasant sensation to groups of people, causes psychological dependence; 2. when smoking, nicotine only needs just can arrive brain more than 7 seconds, makes the smoker feel a kind of sensation of soft happiness, make central nervous system excited earlier after inhibition, cause on the physiology dependence to cigarette; 3. tar can make cigarette tool that very strong suction flavor is arranged; 4. smoking can be eliminated fatigue, increases notice and mediator's mood etc.Since cigarette is the thing that a lot of smokers also be unable to do without all one's life, but human body there is disadvantageous one side, so, content of harmful in the flue gas reduced, improve the security of sucking of cigarette, keep cigarette simultaneously again is the direction that tobacco enterprise is made great efforts to smoker's attraction always.
As everyone knows, in the flue gas harmful components because of the tobacco place of production, kind, drying means, difference such as prescription, production technology and have different, so also difference to some extent of the method that is used for reducing harmful substance.Just as we all know, tar is crossed to hang down and can be had a strong impact on cigarette suction flavor, nicotine amount in the flue gas, be that nicotine can make the people excited and calm, nicotine is very fast in the speed of health intracellular metabolite,, harmless substantially under the normal condition after basic half an hour to the people just along with the urine discharge, if can too much also can be unfavorable to human body.So, if nicotine, tar are also cut in a large number in harm reduction, can have influence on suction quality, reduce attraction to the smoker; And if nicotine, tar are too much, again can be unfavorable to human body.So, do not adopt unified harm reduction product and method if do not distinguish the cigarette smoke harmful components, not having of can causing that this subtracts in the flue gas is up to standard, but having been subtracted of should rationally controlling is a lot, not only influences suction quality, and can increase some unnecessary costs.In a word, must be to the harm reason of falling of cigarette at the different mining of harmful components in the flue gas with different harm reduction products.
It is also many at present the product and the method for harm reason to be fallen in cigarette, as application number is that 200720155554.4 Chinese patent file discloses and a kind of Pu'er tea is coated on the forming paper by bonding agent, make the cigaratte filter forming paper with Pu'er tea adsorption layer, this forming paper is mainly used in nitrite, BaP, the tar that reduces in the flue gas; Application number is that 200510010716.0 Chinese patent file discloses a kind of cigaratte filter forming paper with activated adoption layer, by on the filter tip forming paper, applying in molecular sieve or medical stone, active carbon, ion exchange resin, polysaccharide, natural, the natural plants powder one or more, on forming paper, form and have active adsorption layer, reach in the process of sucking and be adsorbed with harmful substances, thereby play reducing poison function.Though present harmful product falls and method many,, all do not have selectively to adsorb at the kind and the quantity of oxious component in the flue gas, in use will have the situation that harm reduction is excessive or harm reduction is not enough.
Summary of the invention
The present invention aims to provide a kind of antibacterial adsorbent and this adsorbent and is applied to method on the forming paper, this antibacterial adsorbent mainly selects to adsorb carbon monoxide and the aldehydes in the flue gas, secondly ammonia, gaseous phase free radical, BaP, nitrite is also had certain suction-operated.
The present invention realizes above-mentioned purpose by following technological means:
Antibacterial adsorbent is counted by weight, by Tea Polyphenols 20-30 part, and soluble protein 10-20 part, copper-containing active aluminium oxide 5-10 part is formed, and each composition granularity is the 100-200 order.
More preferably, antibacterial adsorbent is counted by weight, by Tea Polyphenols 2-28 part, and soluble protein 12-18 part, copper-containing active aluminium oxide 6-8 part is formed.
Can in such a way above-mentioned antibacterial adsorbent be applied on the forming paper:
Tea Polyphenols and soluble protein are dissolved in the binding agent for preparing, and copper-containing active alumina lap to granularity is that the binding agent by being dissolved with Tea Polyphenols and soluble protein is the adsorption layer of 0.05-0.15mm attached to forming thickness on the moulding body paper surface behind the 100-200 order.
Also soluble protein, Tea Polyphenols, copper-containing active aluminium oxide can be arranged in parallel attached on the moulding body paper surface by binding agent respectively;
Described binding agent is one or more a mixture in beta cyclodextrin, polyvinyl alcohol or the amylan;
Also Tea Polyphenols, soluble protein and the copper-containing active aluminium oxide of above-mentioned dosage can be bonded at the two sides of moulding body paper respectively.
Beneficial effect of the present invention is:
1. adopt antibacterial adsorbent of the present invention, carbon monoxide can reduce 3-5% in the flue gas, aldehydes clearance rate 4-10%, ammonia clearance rate 10-15%, gaseous phase free radical clearance rate 12-15%, BaP clearance rate 2-6%, nitrite clearance rate 3-8%, the nicotine amount reduces 3-5%, and tar reduces 1-3%, sensory evaluating smoking's result shows, can keep the cigarette suction quality substantially.
When 2. being applied on the forming paper, sorbing material is arranged in parallel to be bonded on the moulding body paper surface, can avoid each sorbing material to cover mutually and reduces adsorption effect.
The specific embodiment
The invention will be described further below in conjunction with specific embodiment.
Embodiment 1
Three kinds of main harmful substance contents in the pending cigarette smoke: tar content 13mg, nicotine amount 1.2mg, CO content 14mg, adsorbent is counted by weight, by 20 parts of Tea Polyphenols, 10 parts of soluble protein, 5 parts of compositions of copper-containing active aluminium oxide, Tea Polyphenols and soluble protein are dissolved in the bonding agent for preparing with beta cyclodextrin, the use amount of beta cyclodextrin is a Tea Polyphenols, 3% of soluble protein and copper-containing active aluminium oxide total amount, with copper-containing active aluminium oxide mixed grinding to granularity is 100 orders, be bonded on the moulding body paper surface that contacts with filter stick by the beta cyclodextrin that is dissolved with Tea Polyphenols, forming thickness is the adsorption layer of 0.08mm.
After being applied to this forming paper on the above-mentioned cigarette with special adsorption layer, method according to GB GB/T19069-2004, GB5606.5-2005 and rower YC/T185-2004 regulation is tested, harmful substance contents is in its flue gas: CO content 13.58mg, reduce 3%, tar content 12.74mg, reduce 2%, nicotine amount 1.07mg, reduce 3%, aldehydes clearance rate 6%, ammonia clearance rate 11%, gaseous phase free radical clearance rate 13%, BaP clearance rate 5%, nitrite clearance rate 5%, forming paper has antibacterial action.Sensory evaluating smoking's result shows that the test cigarette has kept original style and jealous substantially.
Embodiment 2
Three kinds of main harmful substance contents in the pending cigarette smoke: tar content 13mg, nicotine amount 1.1mg, CO content 14mg, adsorbent is counted by weight, by 22 parts of Tea Polyphenols, 15 parts of soluble protein, 7 parts of compositions of copper-containing active aluminium oxide, Tea Polyphenols and soluble protein are dissolved in the bonding agent for preparing with beta cyclodextrin, the use amount of beta cyclodextrin is a Tea Polyphenols, 3.5% of soluble protein and copper-containing active aluminium oxide total amount, with copper-containing active aluminium oxide mixed grinding to granularity is 120 orders, be bonded on the moulding body paper surface that contacts with filter stick by the beta cyclodextrin that is dissolved with Tea Polyphenols, forming thickness is the adsorption layer of 0.10mm.
After being applied to this forming paper on the above-mentioned cigarette with special adsorption layer, method according to GB GB/T19069-2004, GB5606.5-2005 and rower YC/T185-2004 regulation is tested, harmful substance contents is in its flue gas: CO content 12.35mg, reduce 5%, tar content 12.35mg, reduce 5%, nicotine amount 1.056mg, reduce 4%, aldehydes clearance rate 7%, ammonia clearance rate 10%, gaseous phase free radical clearance rate 13%, BaP clearance rate 5%, nitrite clearance rate 6%, forming paper has antibacterial action.Sensory evaluating smoking's result shows that the test cigarette has kept original style and jealous substantially.
Embodiment 3
Three kinds of main harmful substance contents in the pending cigarette smoke: tar content 12mg, nicotine amount 1.0mg, CO content 13mg, adsorbent is counted by weight, by 30 parts of Tea Polyphenols, 20 parts of soluble protein, 10 parts of compositions of copper-containing active aluminium oxide, Tea Polyphenols and soluble protein are dissolved in the bonding agent for preparing with amylan, the use amount of amylan is a Tea Polyphenols, 4% of soluble protein and copper-containing active aluminium oxide total amount, with copper-containing active aluminium oxide mixed grinding to granularity is 150 orders, be bonded on the moulding body paper surface that contacts with filter stick by the amylan that is dissolved with Tea Polyphenols, forming thickness is the adsorption layer of 0.15mm.
After being applied to this forming paper on the above-mentioned cigarette with special adsorption layer, method according to GB GB/T19069-2004, GB5606.5-2005 and rower YC/T185-2004 regulation is tested, harmful substance contents is in its flue gas: CO content 13.3mg, reduce 4%, tar content 11.52mg, reduce 4%, nicotine amount 0.96mg, reduce 4%, aldehydes clearance rate 6%, ammonia clearance rate 11%, gaseous phase free radical clearance rate 13%, BaP clearance rate 6%, nitrite clearance rate 8%, forming paper has antibacterial action.Sensory evaluating smoking's result shows that the test cigarette has kept original style and jealous substantially.
Embodiment 4
Three kinds of main harmful substance contents in the pending cigarette smoke: tar content 13mg, nicotine amount 1.1mg, CO content 13mg, adsorbent is counted by weight, by 28 parts of Tea Polyphenols, 18 parts of soluble protein, 10 parts of compositions of copper-containing active aluminium oxide, Tea Polyphenols and soluble protein are dissolved in the bonding agent for preparing with amylan, the use amount of amylan is a Tea Polyphenols, 4% of soluble protein and copper-containing active aluminium oxide total amount, with copper-containing active aluminium oxide mixed grinding to granularity is 150 orders, be bonded on the moulding body paper surface that contacts with filter stick by the amylan that is dissolved with Tea Polyphenols, forming thickness is the adsorption layer of 0.05mm.
After being applied to this forming paper on the above-mentioned cigarette with special adsorption layer, method according to GB GB/T19069-2004, GB5606.5-2005 and rower YC/T185-2004 regulation is tested, harmful substance contents is in its flue gas: CO content 12.35mg, reduce 5%, tar content 12.35mg, reduce 5%, nicotine amount 1.056mg, reduce 4%, aldehydes clearance rate 8%, ammonia clearance rate 13%, gaseous phase free radical clearance rate 13%, BaP clearance rate 5%, nitrite clearance rate 5%, forming paper has antibacterial action.Sensory evaluating smoking's result shows that the test cigarette has kept original style and jealous substantially.
Embodiment 5
Three kinds of main harmful substance contents in the pending cigarette smoke: tar content 12mg, nicotine amount 1.1mg, CO content 13mg, adsorbent is counted by weight, by 20 parts of Tea Polyphenols, 12 parts of soluble protein, 8 parts of compositions of copper-containing active aluminium oxide, Tea Polyphenols and soluble protein are dissolved in the bonding agent for preparing with amylan, the use amount of amylan is a Tea Polyphenols, 5% of soluble protein and copper-containing active aluminium oxide total amount, with copper-containing active aluminium oxide mixed grinding to granularity is 200 orders, be bonded on the moulding body paper surface that contacts with filter stick by the amylan that is dissolved with Tea Polyphenols, forming thickness is the adsorption layer of 0.075mm.
After being applied to this forming paper on the above-mentioned cigarette with special adsorption layer, method according to GB GB/T19069-2004, GB5606.5-2005 and rower YC/T185-2004 regulation is tested, harmful substance contents is in its flue gas: CO content 12.61mg, reduce 3%, tar content 12.35mg, reduce 5%, nicotine amount 1.14mg, reduce 5%, aldehydes clearance rate 8%, ammonia clearance rate 11%, gaseous phase free radical clearance rate 13%, BaP clearance rate 6%, nitrite clearance rate 7%, forming paper has antibacterial action.Sensory evaluating smoking's result shows that the test cigarette has kept original style and jealous substantially.
Claims (9)
1. an antibacterial adsorbent of selecting to adsorb carbon monoxide and aldehydes in the flue gas is characterized in that, meter by weight, and by Tea Polyphenols 20-30 part, soluble protein 10-20 part, copper-containing active aluminium oxide 5-10 part is formed, and each composition granularity is the 100-200 order.
2. a kind of antibacterial adsorbent of selecting to adsorb carbon monoxide and aldehydes in the flue gas according to claim 1 is characterized in that, by Tea Polyphenols 20-28 part, and soluble protein 12-18 part, copper-containing active aluminium oxide 6-8 part is formed.
3. method of utilizing the antibacterial adsorbent production forming paper of carbon monoxide and aldehydes in the described selection of the claim 1 absorption flue gas, it is characterized in that, produce in such a way: Tea Polyphenols and soluble protein are dissolved in the binding agent for preparing, and copper-containing active alumina lap to granularity is that the binding agent by being dissolved with Tea Polyphenols and soluble protein is the adsorption layer of 0.05-0.15mm attached to forming thickness on the moulding body paper surface behind the 100-200 order.
4. method of utilizing the antibacterial adsorbent production forming paper of carbon monoxide and aldehydes in the described selection of the claim 2 absorption flue gas, it is characterized in that, produce in such a way: Tea Polyphenols and soluble protein are dissolved in the binding agent for preparing, and copper-containing active alumina lap to granularity is that the binding agent by being dissolved with Tea Polyphenols and soluble protein is the adsorption layer of 0.05-0.15mm attached to forming thickness on the moulding body paper surface behind the 100-200 order.
5. method of utilizing the antibacterial adsorbent production forming paper of carbon monoxide and aldehydes in the described selection of the claim 1 absorption flue gas, it is characterized in that, produce in such a way: it is the 100-200 order that soluble protein, Tea Polyphenols, copper-containing active aluminium oxide are ground to granularity respectively, is arranged in parallel attached on the moulding body paper surface by binding agent.
6. method of utilizing the antibacterial adsorbent production forming paper of carbon monoxide and aldehydes in the described selection of the claim 2 absorption flue gas, it is characterized in that, produce in such a way: it is the 100-200 order that soluble protein, Tea Polyphenols, copper-containing active aluminium oxide are ground to granularity respectively, is arranged in parallel attached on the moulding body paper surface by binding agent.
7. select the method for the antibacterial adsorbent production forming paper of carbon monoxide and aldehydes in the absorption flue gas according to any described utilization among the claim 3-6, it is characterized in that described binding agent is one or more a mixture in beta cyclodextrin, polyvinyl alcohol or the amylan.
8. select the method for the antibacterial adsorbent production forming paper of carbon monoxide and aldehydes in the absorption flue gas according to any described utilization among the claim 3-6, it is characterized in that, Tea Polyphenols, soluble protein and the copper-containing active aluminium oxide of above-mentioned dosage is bonded at the two sides of moulding body paper respectively.
9. the method for the antibacterial adsorbent production forming paper of carbon monoxide and aldehydes in the utilization selection absorption flue gas according to claim 7, it is characterized in that, Tea Polyphenols, soluble protein and the copper-containing active aluminium oxide of above-mentioned dosage is bonded at the two sides of moulding body paper respectively.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009102183824A CN101721976B (en) | 2009-12-17 | 2009-12-17 | Antimicrobial adsorbent for selectively absorbing carbon monoxide and aldehydes in smoke and application thereof in wrap paper |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009102183824A CN101721976B (en) | 2009-12-17 | 2009-12-17 | Antimicrobial adsorbent for selectively absorbing carbon monoxide and aldehydes in smoke and application thereof in wrap paper |
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| CN101721976A CN101721976A (en) | 2010-06-09 |
| CN101721976B true CN101721976B (en) | 2011-11-09 |
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| CN104399440A (en) * | 2014-10-21 | 2015-03-11 | 繁昌县倍思生产力促进中心有限公司 | Deodorization face mask adsorbent and preparation method thereof |
| CN108014759A (en) * | 2015-07-31 | 2018-05-11 | 邵素英 | A kind of preparation method of biological cleaning carrier for wastewater treatment |
| CN111647292A (en) * | 2020-06-19 | 2020-09-11 | 中国科学院宁波材料技术与工程研究所 | Water-based inorganic aluminum-rich high-temperature-resistant coating and preparation method and application thereof |
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