CN101709179A - No-solvent ultraviolet curing glass printing ink and preparation method thereof - Google Patents
No-solvent ultraviolet curing glass printing ink and preparation method thereof Download PDFInfo
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Abstract
The invention relates to a no-solvent ultraviolet curing glass printing ink and a preparation method thereof; the ink takes high-tractility photochemical active polyester acrylic ester as main ingredient, takes initiator and assistant initiator as curing agents and takes defoamer and flatting agents as auxiliary materials, and then inorganic or organic pigment is mixed, and a functional acrylic ester activated monomer is used as a viscosity regulator; the proportion of the ingredients of the no-solvent ultraviolet curing glass printing ink is as follows: 20-60 parts of multi-functional polyester acrylic ester, 3-8 parts of initiators, 2-5 parts of assistant initiator, 1-3 parts of defoamers, 0-1 part of flatting agent, 8-50 parts of inorganic pigments, 8-15 parts of organic pigments and 10-30 parts of functional acrylic ester activated monomers; the preparation method comprises batching, rolling dispersion and tempering steps; the no-solvent ultraviolet curing glass printing ink has the advantages that: 1. the ink is a 100-percent curing system, has no solvent volatilization and is harm to human body. 2. the curing performance is good, two mercury high pressure lamps with 80-120w/cm are adopted, and complete curing can be realized within 3-6 seconds. 3. the activated monomer is used to regulate the system viscosity, the ink is applied to pad transferring or silk-screen printing, and the universality is strong.
Description
Technical field
The present invention relates to carbon black dispersant and preparation method thereof, mainly is a kind of no-solvent ultraviolet curing glass printing ink and preparation method.
Background technology
The picture and text printing of glass surface for many years mainly adopts screen printing mode to print the solvent type ink of high temperature sintering printing ink and low-temperature curing.In recent years, there are documents and materials and patent to propose the low temperature solidified glass printing ink of aqueous, environmental protective.1), high temperature sintering type product but the printing ink of above processes pattern and use has weak point:, need the above high temperature of 600 degree, the consumes energy amount is big; 2), the solvent-borne type product, use volatile solvent, environment is polluted; 3), the water color ink curing speed is slow, still needs the above condition of cure of 160 degree, just can reach maximum firmness after generally need depositing for 1 week; 4), mode of printing is single, all can only adopt the mode of silk screen printing, can't on products such as the vial of some three-dimensional shapes, glass sphere, print, so it is used and all has been subjected to strict restriction in many aspects.
In Environmental awareness intensive today day by day, aqueous product and ultraviolet light polymerization product obtain application more and more widely.And the fast setting performance of UV curable ink has improved production efficiency of products more greatly, more and more obtains user's favor.
Summary of the invention
The objective of the invention is in order to overcome above-mentioned deficiency, and a kind of no-solvent ultraviolet curing glass printing ink and preparation method who is used on the glass material is provided, harmless, curing speed is fast, and mode of printing is efficient flexibly, environmental protection printing ink.
The present invention solves the technical scheme that its technical problem adopts: this no-solvent ultraviolet curing glass printing ink, and the weight proportion of its each component is as follows: polyfunctionality polyester acrylate 20-60 part; Initiator 3-8 part, aided initiating 2-5 part; Defoamer 1-3 part; Flow agent 0-1 part; Mineral dye 8-50 part; Pigment dyestuff 8-15 part; Acrylate-functional reactive monomer 10-30 part.
As preferably, described polyfunctionality polyester acrylate is the combination of a kind of of three-functionality-degree polyester acrylate, difunctionality polyester acrylate or two kinds.
As preferably, described initiator selects 2 for use, 4,6 (trimethylbenzoyl) diphenyl phosphine oxide, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone, 1-hydroxyl-cyclohexyl-phenyl ketone or 2, one or more combinations of 4-diethyl thioxanthone; Aided initiating is selected one or more combinations of the different monooctyl ester of p-(dimethylamino)-benzoic acid, p-(dimethylamino)-benzoic acid isopentyl ester or (dimethylamino)-ethyl benzoate for use.
As preferably, described defoamer is selected polyoxyethylene propylene glycol or poly-hydroxyl dimethyl siloxane for use; Flow agent is selected for use with siloxane bond and (Si-O-Si-) is the response type polysiloxane that skeleton is formed.
As preferably, described functional vinylformic acid reactive monomer is selected from a kind of of acryloyl morpholine or vinylformic acid laurate or two kinds of combinations.
The preparation method of this no-solvent ultraviolet curing glass printing ink of the present invention, it is as follows that the method comprising the steps of:
(1), batching: can stir in the opening scuffing of cylinder bore at certain volumetrical, at first add polyfunctionality polyester acrylate, part of functions acrylate reactive monomer, initiator and aided initiating, mineral dye or pigment dyestuff, adopt disc type stirring rake middling speed (200rpm-500rpm) pre-dispersed 30 minutes, and required temperature of charge to reach more than 50 ℃;
(2), rolling dispersion forms base China ink: by feeding the rolling roller temperature of cooling water control at 50-55 ℃, pressure 40-50Bar, rolling twice, require fineness to reach below the 10 μ m;
(3), modified: that the base China ink that disperses to finish is passed through to add defoamer and flow agent, add a certain amount of acrylate-functional reactive monomer then and regulate suitable viscosity, viscosity controller is at 5000-15, in the 000mPas/25 ℃ of scope, this process adopts the butterfly stirring rake, acrylate-functional reactive monomer of every interpolation, need middling speed (200-500rpm) to stir 5-10 minute, the stirring rake of oscilaltion simultaneously is with the even unification of guarantee system, after the fineness, viscosity, curing speed performance by the check product, be finished product at last.
Advantage of the present invention: 1, this printing ink is 100% curing system, and solvent-free volatilization is harmless, is a Green Product.2, products solidifying excellent property, the high voltage mercury lamp of 2 80-120W/cm of employing can be realized completely solidified at 3-6 in second.3, can pass through supporting reactive monomer, regulation system viscosity is applied to bat printing or silk screen printing dual mode, highly versatile.4, product detects by the SGS heavy metal, and not containing has ITX and benzophenone initiator than major injury to human body, and low halogen (Halothane iodine) content meets the ROHS of European Union requirement and food, cosmetic package print request fully.5, adopt continuous production technology, realize uninterrupted high efficiency production.
Embodiment
Below in conjunction with embodiment the present invention is further described, but should understand these embodiment limits the scope of the invention, under the situation of the spirit and scope of the present invention, those skilled in the art can make changes and improvements so that it is fit to different service conditions, condition and embodiment to the present invention.
This no-solvent ultraviolet curing glass printing ink, it is a main component with high ductibility photochemical activity polyester acrylate, with environment-friendly type ultraviolet initiator and aided initiating is solidifying agent, with defoamer, flow agent etc. is auxiliary material, being mixed with inorganic or pigment dyestuff, is viscosity modifier with the acrylate-functional reactive monomer.The weight proportion of its each component is as follows: polyfunctionality polyester acrylate 20-60 part; Initiator 3-8 part, aided initiating 2-5 part; Defoamer 1-3 part; Flow agent 0-1 part; Mineral dye 8-50 part; Pigment dyestuff 8-15 part; Acrylate-functional reactive monomer 10-30 part.Its production technique comprises batching, rolling dispersion, three phases such as modified.This printing ink does not add any volatilizable solvent, adopts the 80-120W/cm high voltage mercury lamp radiation to solidify, and curing speed can reach 10-20m/min.
Wherein, the polyfunctionality polyester acrylate is selected from one or more of three-functionality-degree and difunctionality polyester acrylate, and preliminary election takes into account the product of rerum naturas such as snappiness is good, gloss is high, sticking power is good, range of viscosities 30,000-50,000mPas/30 ℃, elongation 80%-200%.
The environment-friendly type ultraviolet initiator is selected from 2,4,6 (trimethylbenzoyl) diphenyl phosphine oxide (TPO), 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone (IRG 907), 1-hydroxyl-cyclohexyl-phenyl ketone (184), 2,4-diethyl thioxanthone (DETX); Aided initiating is selected from the different monooctyl ester of p-(dimethylamino)-benzoic acid (EHA), p-(dimethylamino)-benzoic acid isopentyl ester (DMBI), one or more combinations of (dimethylamino)-ethyl benzoate (EDBA).
Wherein, defoamer is selected polyoxyethylene propylene glycol or poly-hydroxyl dimethyl siloxane for use; Flow agent is selected for use with siloxane bond and (Si-O-Si-) is the photochemically reactive response type polysiloxane that has of skeleton composition.
Wherein, mineral dye and pigment dyestuff comprise titanium dioxide, carbon black, fuchsin (57:1), No. 13 Huangs, 15:3 phthalocyanine blue, 15:4 phthalocyanine blue etc.The preferred Rutile type Titanium Dioxide of titanium dioxide, TiO2 content is higher than 93%, particle size range 210-310nm, oil number 17-20g/100g, one or more between the pH value 7.0-8.0; Carbon black is selected gas method colour black or oven process colour black, and preferred oven process carbon black, average primary particle diameter 20-28nm, specific surface area 90-130m2/g, ash content be less than 0.5%, oil number 50-100ml/100g, one or both between the pH value 2-3; Fuchsin, Huang, phthalocyanine blue etc. are selected corresponding trade mark product, preferred median size 50-200nm, the product of oil number 30-70g/100g.
Wherein, the acrylate-functional reactive monomer is selected from acryloyl morpholine (ACMO), one or more of vinylformic acid laurate (LA) etc.
The preparation method of this no-solvent ultraviolet curing glass printing ink of the present invention, it is as follows that the method comprising the steps of:
(1), batching: can stir in the opening scuffing of cylinder bore at certain volumetrical, at first add polyfunctionality polyester acrylate, part of functions acrylate reactive monomer, initiator and aided initiating, mineral dye or pigment dyestuff, adopt disc type stirring rake middling speed (200rpm-500rpm) pre-dispersed 30 minutes, and required temperature of charge to reach more than 50 ℃;
(2), rolling dispersion forms base China ink: adopt a kind of of ball mill, three-roller or be used, by feeding the rolling roller temperature of cooling water control at 50-55 ℃, pressure 40-50Bar, rolling twice, detect dispersity with double flute scraper plate instrument (0-25 μ m), it is following for qualified to require fineness to reach 10 μ m.
(3), modified: the base China ink that disperses to finish is passed through to add defoamer and flow agent, add a certain amount of acrylate-functional reactive monomer then and regulate suitable viscosity, viscosity controller is at 5000-15, in the 000mPas/25 ℃ of scope, preferred 10,000-13,000mPas/25 ℃, can be applicable to the bat printing printing, viscosity controller is at 600-1, in the 500mPas/25 ℃ of scope, and preferred 800-1,000mPas/25 ℃, can be applicable to silk screen printing.This process adopts the butterfly stirring rake, acrylate-functional reactive monomer of every interpolation, need middling speed (200-500rpm) to stir 5-10 minute, the stirring rake of oscilaltion simultaneously is with the even unification of guarantee system, after the fineness, viscosity, curing speed performance by the check product, be finished product at last.
Embodiment one (chalk)
With 20 parts of three-functionality-degree polyester acrylates, 5 parts of functional monomer LA, 907 3 parts of light triggers, 0.3 part of DETX, 2 parts of TPO, 2 parts of aided initiating EHA, 25 parts of 20 parts of titanium dioxide R-706 and R-900, pre-stir that system is warming up to more than 50 ℃ after 30 minutes, by rolling 2 roads of three-roller (pressure 40Bar, roller temperature 45-50 ℃), obtain below the fineness 10 μ m, viscosity 30,000mPas/25 ℃ Ji Mo.Add defoamer S430.5 part when modified, 2 parts of Arix920, behind 0.3 part of the flow agent RAD2200,8 parts of reactive monomer ACMO, viscosity drop to 10, can be applicable to the bat printing printing by 500mPas/25 ℃.After adding 15 parts of reactive monomer ACMO again, viscosity drop can be applicable to silk screen printing to 950mPas/25 ℃.
Embodiment two (tusche)
With 25 parts of three-functionality-degree polyester acrylates, 15 parts of difunctionality polyester acrylates, 10 parts of functional monomer LA, 907 3 parts of light trigger Irg, 1 part of DETX, 2 parts of TPO, 1 part of aided initiating DMBI, 1 part of EDAB, 8 parts of carbon blacks, pre-stir that system is warming up to more than 50 ℃ after 30 minutes, by rolling 2 roads of three-roller (pressure 40Bar, roller temperature 45-50 ℃), obtain below the fineness 10 μ m, viscosity 33,000mPas/25 ℃ Ji Mo.Add 3 parts of Arix920 when modified, behind 0.3 part of the flow agent RAD2300,8 parts of reactive monomer ACMO, viscosity drop to 12, can be applicable to the bat printing printing by 500mPas/25 ℃.After adding 20 parts of reactive monomer ACMO again, viscosity drop to 1, can be applicable to silk screen printing by 200mPas/25 ℃.
Embodiment three (red China ink)
With 25 parts of three-functionality-degree polyester acrylates, 15 parts of difunctionality polyester acrylates, 10 parts of functional monomer LA, 907 3 parts of light trigger Irg, 1 part of DETX, 1843 parts of Irg, 1 part of aided initiating EDAB, 1 part of EHA, 12 parts in lily BHA fuchsin (57:1), pre-stir that system is warming up to more than 50 ℃ after 30 minutes, by rolling 2 roads of three-roller (pressure 40Bar, roller temperature 45-50 ℃), obtain below the fineness 10 μ m, viscosity 28,000mPas/25 ℃ Ji Mo.Add 1 part of defoamer EFKA-4050 when modified, 0.5 part of KS66, behind 0.3 part of the flow agent BYK-306,7 parts of reactive monomer ACMO, viscosity drop to 11, can be applicable to the bat printing printing by 500mPas/25 ℃.After adding 20 parts of reactive monomer ACMO again, viscosity drop to 1, can be applicable to silk screen printing by 100mPas/25 ℃.
Embodiment four (Lan Mo)
With 20 parts of three-functionality-degree polyester acrylates, 10 parts of difunctionality polyester acrylates, 10 parts of functional monomer LA, 907 4 parts of light trigger Irg, 0.3 part of DETX, 2 parts of TPO, 2 parts of aided initiating EDAB, 1 part of EHA, 15 parts of Haimen BGS phthalocyanine blues, pre-stir that system is warming up to more than 50 ℃ after 30 minutes, by rolling 2 roads of three-roller (pressure 40Bar, roller temperature 45-50 ℃), obtain below the fineness 10 μ m, viscosity 35,000mPas/25 ℃ Ji Mo.Add 920 0.5 parts of defoamer Arix when modified, behind 0.3 part of the flow agent BYK-163,10 parts of reactive monomer ACMO, viscosity drop to 13, can be applicable to the bat printing printing by 500mPas/25 ℃.After adding 22 parts of reactive monomer ACMO again, viscosity drop to 1, can be applicable to silk screen printing by 450mPas/25 ℃.
Above-mentioned prescription can be finished curing at the high voltage mercury lamp radiation 3-6 of 80W/cm intensity second, and the performance index that no-solvent ultraviolet (UV) curing glass printing ink reaches are as follows:
Sticking power test (3M adhesive tape, the test of hundred lattice): 100/100
Anti-alcohol test (95% ethanol): 100 times
Anti-acetone test: 50 times
Acid proof test (5% sulfuric acid): 16 hours
Alkali resistance test (5% sodium hydroxide): 12 hours
Water boiling resistance (100 ℃ of boiling water): 1 hour, do not come off
In an embodiment, all starting material are technical grade, and wherein light trigger, aided initiating and pigment content require to reach more than 99%.
In sum, no-solvent ultraviolet of the present invention (UV) curing glass printing ink curing speed is fast, becomes film hardness good, and chemical resistance is good, cooperates multiple mode of printing, and the scope of application is wider.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of requirement of the present invention.
Claims (6)
1. no-solvent ultraviolet curing glass printing ink, it is characterized in that: the weight proportion of its each component is as follows: polyfunctionality polyester acrylate 20-60 part; Initiator 3-8 part, aided initiating 2-5 part; Defoamer 1-3 part; Flow agent 0-1 part; Mineral dye 8-50 part; Pigment dyestuff 8-15 part; Acrylate-functional reactive monomer 10-30 part.
2. no-solvent ultraviolet curing glass printing ink according to claim 1, its feature: described polyfunctionality polyester acrylate is the combination of a kind of of three-functionality-degree polyester acrylate, difunctionality polyester acrylate or two kinds.
3. no-solvent ultraviolet curing glass printing ink according to claim 1, its feature: described initiator selects 2 for use, 4,6 (trimethylbenzoyl) diphenyl phosphine oxide, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone, 1-hydroxyl-cyclohexyl-phenyl ketone or 2, one or more combinations of 4-diethyl thioxanthone; Aided initiating is selected one or more combinations of the different monooctyl ester of p-(dimethylamino)-benzoic acid, p-(dimethylamino)-benzoic acid isopentyl ester or (dimethylamino)-ethyl benzoate for use.
4. no-solvent ultraviolet curing glass printing ink according to claim 1, its feature: described defoamer is selected polyoxyethylene propylene glycol or poly-hydroxyl dimethyl siloxane for use; Flow agent is selected for use with siloxane bond and (Si-0-Si-) is the response type polysiloxane that skeleton is formed.
5. no-solvent ultraviolet curing glass printing ink according to claim 1, its feature: described functional vinylformic acid reactive monomer is selected from a kind of of acryloyl morpholine or vinylformic acid laurate or two kinds of combinations.
6. method for preparing no-solvent ultraviolet curing glass printing ink as claimed in claim 1, it is characterized in that: it is as follows that the method comprising the steps of:
(1), batching: can stir in the opening scuffing of cylinder bore at certain volumetrical, at first add polyfunctionality polyester acrylate, part of functions acrylate reactive monomer, initiator and aided initiating, mineral dye or pigment dyestuff, adopt disc type stirring rake middling speed (200rpm-500rpm) pre-dispersed 30 minutes, and required temperature of charge to reach more than 50 ℃;
(2), rolling dispersion forms base China ink: by feeding the rolling roller temperature of cooling water control at 50-55 ℃, pressure 40-50Bar, rolling twice, require fineness to reach below the 10 μ m;
(3), modified: that the base China ink that disperses to finish is passed through to add defoamer and flow agent, add a certain amount of acrylate-functional reactive monomer then and regulate suitable viscosity, viscosity controller is at 5000-15, in the 000mPas/25 ℃ of scope, this process adopts the butterfly stirring rake, acrylate-functional reactive monomer of every interpolation, need middling speed (200-500rpm) to stir 5-10 minute, the stirring rake of oscilaltion simultaneously is with the even unification of guarantee system, after the fineness, viscosity, curing speed performance by the check product, be finished product at last.
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Cited By (13)
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| CN102241920A (en) * | 2011-08-15 | 2011-11-16 | 江苏海田技术有限公司 | Ultraviolet (UV) transfer ink |
| CN102702849A (en) * | 2012-06-05 | 2012-10-03 | 无锡金桥精细油墨有限公司 | Ultraviolet-light-cured glass transparent ink and preparation method thereof |
| CN103013222A (en) * | 2011-09-27 | 2013-04-03 | 中钞特种防伪科技有限公司 | Ultraviolet light cured ink and application and preparation method thereof |
| CN103373065A (en) * | 2012-04-18 | 2013-10-30 | 星云电脑股份有限公司 | Digital inkjet printer with transparent ink |
| CN103666055A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Photo-cured and environment-friendly screen printing ink and preparation method thereof |
| CN103666035A (en) * | 2013-11-23 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV curing printing ink for screen printing and preparation method thereof |
| CN103666028A (en) * | 2013-11-23 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Ultraviolet curing glass printing ink for digital product and preparation method of ultraviolet curing glass printing ink |
| CN104497697A (en) * | 2014-12-23 | 2015-04-08 | 广州市尤特新材料有限公司 | LED-UV photocurable screen printing halogen-free glass ink |
| CN104530816A (en) * | 2014-12-12 | 2015-04-22 | 惠州市至上新材料有限公司 | Bendable UV colored silk-screen printing ink for polished aluminum plates of suspended ceilings |
| CN104995023A (en) * | 2013-03-08 | 2015-10-21 | 富士胶片株式会社 | Multilayer structure, multilayer structure manufacturing method and composition set |
| CN108795272A (en) * | 2018-09-30 | 2018-11-13 | 佛山阳光逸采涂料科技有限公司 | A kind of UV LED UV-curable waterbornes kitchen and bath's coatings for furniture and preparation method thereof |
| CN108822614A (en) * | 2018-07-06 | 2018-11-16 | 深圳市海中辉新材料科技有限公司 | A kind of low energy consumption HUV/LEC printing ink and preparation method thereof |
| CN111057446A (en) * | 2019-12-31 | 2020-04-24 | 嘉兴晶铸生物科技有限公司 | UVLED (ultraviolet light emitting diode) solidified glass slide sealing method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102241920A (en) * | 2011-08-15 | 2011-11-16 | 江苏海田技术有限公司 | Ultraviolet (UV) transfer ink |
| CN103013222A (en) * | 2011-09-27 | 2013-04-03 | 中钞特种防伪科技有限公司 | Ultraviolet light cured ink and application and preparation method thereof |
| CN103013222B (en) * | 2011-09-27 | 2014-12-24 | 中钞特种防伪科技有限公司 | Ultraviolet light cured ink and application and preparation method thereof |
| CN103373065A (en) * | 2012-04-18 | 2013-10-30 | 星云电脑股份有限公司 | Digital inkjet printer with transparent ink |
| CN102702849A (en) * | 2012-06-05 | 2012-10-03 | 无锡金桥精细油墨有限公司 | Ultraviolet-light-cured glass transparent ink and preparation method thereof |
| CN104995023A (en) * | 2013-03-08 | 2015-10-21 | 富士胶片株式会社 | Multilayer structure, multilayer structure manufacturing method and composition set |
| CN103666035A (en) * | 2013-11-23 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV curing printing ink for screen printing and preparation method thereof |
| CN103666028A (en) * | 2013-11-23 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Ultraviolet curing glass printing ink for digital product and preparation method of ultraviolet curing glass printing ink |
| CN103666028B (en) * | 2013-11-23 | 2016-05-04 | 铜陵方正塑业科技有限公司 | A kind of ultraviolet curing glass printing ink for digital product and preparation method thereof |
| CN103666035B (en) * | 2013-11-23 | 2016-05-04 | 铜陵方正塑业科技有限公司 | A kind of UV cured printing ink and preparation method thereof for serigraphy |
| CN103666055A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Photo-cured and environment-friendly screen printing ink and preparation method thereof |
| CN104530816A (en) * | 2014-12-12 | 2015-04-22 | 惠州市至上新材料有限公司 | Bendable UV colored silk-screen printing ink for polished aluminum plates of suspended ceilings |
| CN104497697A (en) * | 2014-12-23 | 2015-04-08 | 广州市尤特新材料有限公司 | LED-UV photocurable screen printing halogen-free glass ink |
| CN108822614A (en) * | 2018-07-06 | 2018-11-16 | 深圳市海中辉新材料科技有限公司 | A kind of low energy consumption HUV/LEC printing ink and preparation method thereof |
| CN108795272A (en) * | 2018-09-30 | 2018-11-13 | 佛山阳光逸采涂料科技有限公司 | A kind of UV LED UV-curable waterbornes kitchen and bath's coatings for furniture and preparation method thereof |
| CN111057446A (en) * | 2019-12-31 | 2020-04-24 | 嘉兴晶铸生物科技有限公司 | UVLED (ultraviolet light emitting diode) solidified glass slide sealing method |
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Application publication date: 20100519 |