CN101703454A - Washing-off type skin cleaning and nursing composite - Google Patents
Washing-off type skin cleaning and nursing composite Download PDFInfo
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- CN101703454A CN101703454A CN200910193610A CN200910193610A CN101703454A CN 101703454 A CN101703454 A CN 101703454A CN 200910193610 A CN200910193610 A CN 200910193610A CN 200910193610 A CN200910193610 A CN 200910193610A CN 101703454 A CN101703454 A CN 101703454A
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- washing
- skin cleaning
- type skin
- surfactant
- water
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Abstract
The invention discloses a washing-off type skin cleaning and nursing composite which comprises the following components by weight percent; about 10%-60% of surface active agent, about 0.05%-6% of water-soluble anionic polymer, about 0.1%-20% of water-soluble humectant and the balance of water. The washing-off type skin cleaning and nursing composite can be easily washed out, can provide good skin cleaning feeling, and has excellent water-retaining property, moisture retention and absorptivity.
Description
Technical field
The present invention relates to household chemicals field, particularly a kind of washing-off type skin cleaning and nursing composite.
Background technology
The washing-off type skin cleaning and nursing product is to be the soap series products of Main Ingredients and Appearance with soap traditionally, the pH value deflection alkalescence of this series products, human body skin pH value deflection is acid, thereby the bigger zest of generation, and degreasing power is strong, can excessively remove after the use and keep the sebum of moisture of skin to make skin become coarse, now the washing-off type skin cleaning and nursing product generally is to be main surfactant with synthetic anion surfactant on the market, cooperate nonionic, amphion, cationic surfactant is as cosurfactant, the pH value slant acidity of this series products is near human body skin acidity, thereby reduce the zest of surfactant, but be difficult to rinse well skin.
Summary of the invention
The purpose of this invention is to provide a kind of washing-off type skin cleaning and nursing composite, it has overcome the shortcoming that general surfactant type skin clean product is difficult to rinse well, but also have preserve moisture, the effect of skin care.
The object of the present invention is achieved like this: a kind of washing-off type skin cleaning and nursing composite, and count by weight percentage and comprise following component:
A) 10% to 60% surfactant;
B) 0.05% to 6% water-soluble anionic polymer;
C) 0.1% to 20% water solublity wetting agent;
D) water surplus.
Described cosmetic composition, wherein said surfactant are selected from one or more mixing in anion surfactant, cationic surfactant, non-ionic surface active agent, amphoteric surfactant, the zwitterionic surfactant; The mixture of anion surfactant and zwitterionic surfactant or amphoteric surfactant preferably; It more preferably is anion surfactant.
Washing-off type skin cleaning and nursing composite of the present invention is rinsed well easily, and advantages of good skin cleaning sensation can be provided, and water-retaining property, moisture retention, absorbability excellence.
The specific embodiment
The present invention is a kind of washing-off type skin cleaning and nursing composite, counts by weight percentage to comprise following component: about 10% to about 60% surfactant; About 0.05% to about 6% water-soluble anionic polymer; About 0.1% to about 20% water solublity wetting agent; Water surplus.
Surfactant
Surface active agent composition provides clean-up performance for described compositions.Described surface active agent composition is selected from one or more the combination in anion surfactant, amphion or the amphoteric detersive surfactants.Such surfactant should be at physics and chemically compatible with solvent described herein, or should not damage stability, aesthetic property or the performance of product inadequately.
The anion surfactant component should be enough to the cleaning and the foaming effect that provide required by weight; The preferred anionic surfactants surfactant is that aliphatic alcohol sulfate or these materials of fatty alcohol polyoxyethylene ether sulfate have expression formula separately: ROSO
3M or RO (C
2H
4O) xSO
3M, wherein R has about 8 alkyl or alkenyls to about 18 carbon atoms, and R preferably about 10 is to the alkyl or the alkenyl of about 14 carbon atoms, R is the alkyl or the alkenyl of 12 carbon atoms more preferably from about, X is 1 to 5 integer, and is preferred 3, and M is a cation, as ammonium, alkanolamine, as triethanolamine, univalent metal is as sodium and potassium, and multivalent metal cation, as calcium and magnesium.Preferred univalent sodium metal of M and potassium.
The preferred anionic surfactants surfactant that is used for the present composition is selected from one or more mixing of following material: sodium lauryl sulfate; sodium laureth sulfate; the lauryl sulfate triethylamine; laureth sulphuric acid triethylamine; triethanolamine lauryl sulfate; lauryl polrvinyl chloride ether sulphuric acid triethanolamine; lauryl sulfate monoethanolamine; laureth sulphuric acid monoethanolamine; lauryl sulfate diethanolamine; laureth sulphuric acid diethanolamine; lauryl sulphate acid amine; lauryl polrvinyl chloride ether ammonium sulfate; Glyceryl Monolaurate sodium sulfate; lauryl potassium sulfate; lauryl polyoxyethylene acid potassium sulfate; sodium lauryl sarcosinate; sodium lauroyl sarcosine; the sarcosine lauryl; the cocoyl sarcosine; cocoyl ammonium sulfate; lauroyl ammonium sulfate; cocoyl sodium sulfate; lauroyl sodium sulfate; the cocoyl potassium sulfate; lauryl potassium sulfate; cocoyl sulphuric acid monoethanolamine; lauryl sulfate monoethanol tridecyl benzene sulfonic acid sodium salt; dodecylbenzene sodium sulfonate; the cocoyl sodium isethionate; Ammonium cocoyl isethionate, most preferred anion surfactant are sodium lauryl sulfate; sodium laureth sulfate.Its content is about 10% to about 60% to be preferably about 20% to about 40%.
Water-soluble anionic polymer
The water-soluble anionic polymer of the present composition, its content are about 0.05% to about 6%, are preferably about 0.1% to about 4%.Water-soluble anionic polymer is water miscible or easy and the blended polymer of water, it has the ability of enhancing composition viscosity, and compatible with remaining ingredient, be used for surfactant and water solublity wetting agent, so that these components can not separated with stable manner dispersion aqueous carrier.Water-soluble polymer also provides suitable viscosity and rheological properties to be easy to sprawl compositions for compositions.Owing to comprise alkyl group in the polymer, so carboxylic acid/carboxylate copolymer can not make the compositions generation make us not wishing the viscosity that exists.
Being fit to carboxylic acid/carboxylate copolymer of the present invention is the acrylic acid/alkyl acrylate copolymer with following formula:
R wherein
1For hydrogen or have 1 alkyl (at least one R wherein to about 40 carbon atoms
1Be hydrogen), R
2For hydrogen or have 1 alkyl to about 40 carbon atoms; N, n ', m and m ' are integer, and wherein n+n '+m+m ' is about 30 to 120, n, and " be 1 to about 40 integer, λ is defined so that the molecular weight of copolymer is about 400,000 to about 4,000,000.
Being used for commercially available carboxylic acid/carboxylate copolymer of the present invention comprises: the CTFA name is called acrylate/C10-30 alkyl acrylate cross-linked copolymer, its commodity are called Pemulene TR-1, Pemulene TR-2, Carbopol 1342, Carbopol 1382 and Carbopol ETD 2020, Carbopol Ultrez 20, Carbopol Ultrez 21 these materials all can be available from Lubrizol company, and most preferably Carbopol Ultrez 20.Compositions can comprise nertralizer with in and the water-soluble polymer of anionic property.The non-limiting example of these nertralizers comprises one or more mixing in sodium hydroxide, potassium hydroxide, ammonium hydroxide, monoethanolamine, diethanolamine, triethanolamine, diisopropanolamine (DIPA), amino methyl propanol, tromethane, the tetrahydroxypropyl ethylenediamine.
The water solublity wetting agent
The present composition comprises the water solublity wetting agent, and its content elects about 0.1% as to about 20%, is preferably about 0.5% to about 10% described water solublity wetting agent and provides moistening effect for skin.
Be applicable to that water solublity wetting agent of the present invention comprises polyhydric alcohol such as glycerol, sorbitol, propylene glycol, butanediol, hexanediol, ethoxylated glucose, 1,2 one hexanediol, hexanetriol, dipropylene glycol, one or more mixing in two glycerol, xylitol, maltose alcohol, hyaluronate sodium, sodium lactate, the pyrrolidone carboxylic acid salt.
Be applicable to that water solublity wetting agent of the present invention comprises the water soluble alkoxylated non-ionic polymers, Polyethylene Glycol and polypropylene glycol as molecular weight the most about 5000, it is to be obtained by oxirane dehydration polycondensation being called those materials of PEG-200, PEG-400, PEG-600, PEG-1000 or two or more mixing as having the CTFA name.Most preferably PEG-400, glycerol, pyrrolidone carboxylic acid salt or their mixture.
Aqueous carrier
The present composition (under environmental condition) is the form of dumpable liquid.Therefore said composition will typically comprise the Heshui carrier; Its content be about 50% to about 80%, preferably its content is about 60% to about 70%.
Annexing ingredient
The non-limiting example that is used for the compositions optional components comprises: viscosity modifier, foam booster, non-volatile solvents or diluent (water miscible or water-insoluble), pearlescent additive, additional amphoteric surfactant or non-ionic surface active agent, pH regulator agent, spice.Antiseptic, extract of chelating agen, sunscreen, UV absorbent, vitamin, mineral, herbaceous plant/fruit/food or the like.
The following example further describes and the interior embodiment of for example clear scope of the invention.These embodiment only are illustrative, rather than limit the scope of the invention, because can carry out multiple change under the condition that does not deviate from spirit and scope of the invention.Unless explanation is arranged below in addition, each composition all provides with chemical name or CTFA title.The component definition: (1) sodium laureth sulfate (70%) is available from Kening Co.,Ltd, (2) sodium lauryl sulfate is available from Kening Co.,Ltd, (3) carbomer (Carbopol Ultrez 20) is available from Lubrizol company, and (4) pyrrolidone sodium carboxylate (PCA-Na) is available from Japanese aginomoto (AJINOMOTO) company.
Preparation method
Embodiment 1 to 14 can be by the methods known in the art manufacturing, its suitable preparation method is as follows: carbomer is slowly joined to make in the part deionized water be stirred to no granule after its complete wetting and add nertralizer then and be stirred to transparent, add sodium laureth sulfate (70%) at last successively, sodium lauryl sulfate, cocoamidopropyl, glycerol, 1.3-butanediol, glycol distearate, cocos nucifera oil acyl monoethanolamine, methyl parahydroxybenzoate, propyl p-hydroxybenzoate, making it be warmed up to 75～80 ℃ of insulated and stirred dissolves it fully. and cool to below 50 ℃ and will add PEG-400 successively, pyrrolidone sodium carboxylate, the EDTA-2Na aqueous solution, sodium-chloride water solution, DMDM Hydantoin, spice, the residue deionized water and stirring makes it dissolve mix homogeneously fully, is chilled to room temperature.
The required characteristic of embodiment 1 to 14 cosmetics care composition is to provide the characteristics of advantages of good skin cleaning sensation, water-retaining property, moisture retention.The feeling of the said advantages of good skin of the present invention cleaning is meant the more easily flushing in the process of using of this product, and the water conservation of indication of the present invention and moisture retention are meant that this product can provide the sensation of the skin moisturizing of long period.Choose 100 person on probations, compare analysis, draw to draw a conclusion by relatively using product of the present invention and commercially available prod:
Claims (9)
1. washing-off type skin cleaning and nursing composite, count by weight percentage and comprise following component:
A) 10% to 60% surfactant;
B) 0.05% to 6% water-soluble anionic polymer;
C) 0.1% to 20% water solublity wetting agent;
D) water surplus.
2. washing-off type skin cleaning and nursing composite according to claim 1 is characterized in that: described surfactant is selected from one or more mixing in anion surfactant, cationic surfactant, non-ionic surface active agent, amphoteric surfactant, the zwitterionic surfactant.
3. washing-off type skin cleaning and nursing composite according to claim 2 is characterized in that: described surfactant is selected from anion surfactant.
4. according to claim 2 or 3 described washing-off type skin cleaning and nursing composites, it is characterized in that: described anion surfactant is selected from fatty alcohol polyoxyethylene ether sulfate or aliphatic alcohol sulfate.
5. according to claim 2 or 3 described washing-off type skin cleaning and nursing composites, it is characterized in that: the general formula of molecular structure of described anion surfactant is ROSO
3M or RO (C
2H
4O) xSO
3M, wherein R is alkyl or the alkenyl with about 8 to 18 carbon atoms, X is 1 to 5 integer, and M is a cation.
6. washing-off type skin cleaning and nursing composite according to claim 1 is characterized in that: described water-soluble anionic polymer is selected from acrylate/C10-30 alkyl acrylate cross-linked copolymer.
7. washing-off type skin cleaning and nursing composite according to claim 1 is characterized in that: described water solublity wetting agent is selected from polyhydric alcohol or water soluble alkoxylated non-ionic polymers.
8. washing-off type skin cleaning and nursing composite according to claim 7, it is characterized in that: described polyhydric alcohol is selected from sorbitol, propylene glycol, butanediol, hexanediol, ethoxylated glucose, 1,2 one hexanediol, hexanetriol, dipropylene glycol, one or more mixing in glycerol, xylitol, maltose alcohol, hyaluronate sodium, sodium lactate, the pyrrolidone carboxylic acid salt.
9. washing-off type skin cleaning and nursing composite according to claim 7 is characterized in that: described water soluble alkoxylated non-ionic polymers is selected from Polyethylene Glycol, polypropylene glycol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910193610A CN101703454A (en) | 2009-11-03 | 2009-11-03 | Washing-off type skin cleaning and nursing composite |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910193610A CN101703454A (en) | 2009-11-03 | 2009-11-03 | Washing-off type skin cleaning and nursing composite |
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| Publication Number | Publication Date |
|---|---|
| CN101703454A true CN101703454A (en) | 2010-05-12 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910193610A Pending CN101703454A (en) | 2009-11-03 | 2009-11-03 | Washing-off type skin cleaning and nursing composite |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102178611A (en) * | 2011-04-22 | 2011-09-14 | 杭州珀莱雅控股股份有限公司 | High-pearly-lustre high-foam soap base cleansing cream and preparation method thereof |
| CN102973434A (en) * | 2012-12-05 | 2013-03-20 | 广东名臣有限公司 | Washing personal skin cleaning composition and preparation method thereof |
| CN106496599A (en) * | 2016-10-10 | 2017-03-15 | 上海建华精细生物制品有限公司 | High viscosity hyaluronic acid sodium gel and preparation method thereof |
| US9622951B2 (en) | 2012-10-29 | 2017-04-18 | The Procter & Gamble Company | Personal care compositions |
-
2009
- 2009-11-03 CN CN200910193610A patent/CN101703454A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102178611A (en) * | 2011-04-22 | 2011-09-14 | 杭州珀莱雅控股股份有限公司 | High-pearly-lustre high-foam soap base cleansing cream and preparation method thereof |
| CN102178611B (en) * | 2011-04-22 | 2012-12-05 | 珀莱雅(湖州)化妆品有限公司 | High-pearly-lustre high-foam soap base cleansing cream and preparation method thereof |
| US9622951B2 (en) | 2012-10-29 | 2017-04-18 | The Procter & Gamble Company | Personal care compositions |
| CN102973434A (en) * | 2012-12-05 | 2013-03-20 | 广东名臣有限公司 | Washing personal skin cleaning composition and preparation method thereof |
| CN106496599A (en) * | 2016-10-10 | 2017-03-15 | 上海建华精细生物制品有限公司 | High viscosity hyaluronic acid sodium gel and preparation method thereof |
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Open date: 20100512 |