CN101697940B - Hair care composition and preparation method thereof - Google Patents
Hair care composition and preparation method thereof Download PDFInfo
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- CN101697940B CN101697940B CN2009101938263A CN200910193826A CN101697940B CN 101697940 B CN101697940 B CN 101697940B CN 2009101938263 A CN2009101938263 A CN 2009101938263A CN 200910193826 A CN200910193826 A CN 200910193826A CN 101697940 B CN101697940 B CN 101697940B
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Abstract
The invention discloses a hair care composition containing the following ingredients, by weight percent, of: 0.2-10.0% of cationic surfactant, 0.1-15.0% of high melting-point aliphatic compound, 0.2-8.0% of lower alkylol and water as the balance. The invention further discloses a preparation method of the hair care composition. The hair care composition can ameliorate hair quality, care hair, endow wet hair with excellent spreadability and smoothness, enhance softness and lubrication of dry hair and lower production cost. The preparation method of the hair care composition leads the composition to higher yield stress, emulsion suspension ability and electrolyte resistance.
Description
Technical field
The present invention relates to filed of daily-use chemical industry, be specifically related to a kind of Haircare composition and preparation method thereof.
Background technology
Hair is body interior health status " indicating gage ".Modern's rhythm of life is accelerated, the change of living habit, and dietetic nutrition is unbalanced, environmental pollution, problem such as operating pressure is excessive all might have influence on the physiological situation of our skin of head.Our hair can be because bad diet, the mental status, health status, weather, the care method of hair, the care product of use etc. be former thereby variety of problems occurs, as alopecia, fuel-displaced, withered crude, the jag of the dandruff, hair, shortage gloss etc. are arranged.
At present; Developed the hair care composition of a lot of kinds on the market; The method that those skilled in the art use always is to use conditioner, like quaternary ammonium salt, cationic polymer, hard fat compounds of group, silicone compounds and some grease chemical compounds, and their mixture.These care compositions can provide various conditioning effects, send out and dried softness and the smooth feeling of sending out as wet.The method for preparing of known various hair care compositions is that aqueous carrier is heated to 70 ℃ to 85 ℃; With cationic surfactant, hard fat compounds of group, silicone compounds and the mixture heated to 70 such as grease that mix with it ℃ to 85 ℃, in this temperature range, with biphase mixing stirring or homogenize; Form emulsification system; Room temperature is reduced in stirring, and hard fat compounds of group, grease and silicone compounds are disperseed to form molecule usually, are stable in the middle of the thickness substrate.During use, these conditioners can provide the beneficial effect of conditioning hair.
Yet, the lower problem of prescription existence price ratio of above-mentioned hair care composition, and its preparation method still needs to promote, and to prepare the better Haircare composition of nursing efficacy, therefore is worth improving.
Summary of the invention
The objective of the invention is to be directed against the deficiency that exists in the existing Haircare composition, a kind of Haircare composition that can improve hair hair quality, hair conditioning is provided.
Another purpose of the present invention is to provide the method for preparing of above-mentioned Haircare composition.
The present invention is achieved according to following technical scheme:
Haircare composition of the present invention comprises following components in percentage by mass: cationic surfactant 0.05～10.0%, hard fat compounds of group 0.05～15.0%, lower alkyl alcohol 0.05～8.0%, surplus are water.
The component of Haircare composition of the present invention is preferred by mass percentage as follows: cationic surfactant 0.1～8.0%, hard fat compounds of group 0.5～8.0%, lower alkyl alcohol 0.2～5.0%, surplus are water.
Wherein, water is preferably deionized water.
Above-mentioned Haircare composition also can add silicone compounds and grease, and said silicon oxide compound accounts for 0.1～6.0% of compositions by mass percentage, and said grease accounts for 0.1～5.0% of compositions by mass percentage.
Wherein, said cationic surfactant is one or more the mixture in single long alkyl quaternary ammonium salts, two long alkyl quaternary ammonium salts, the three long alkyl quaternary ammonium saltss; Preferred single long alkyl quaternary ammonium salts, two long alkyl quaternary ammonium salts or its mixture; Wherein, single long alkyl quaternary ammonium salts accounts for 0.1 ~ 5.0% of compositions gross mass, preferred 1 ~ 3.5%; Two long alkyl quaternary ammonium saltss account for 0.05 ~ 3.0% of compositions gross mass, and preferred 0.3 ~ 1.5%; Three long alkyl quaternary ammonium saltss account for 0.05 ~ 2.0% of compositions gross mass, and preferred 0.1 ~ 1.0%.The structural formula of said single long alkyl quaternary ammonium salts, two long alkyl quaternary ammonium salts and three long alkyl quaternary ammonium saltss is following:
Wherein, have at least one to be selected from the fat base that contains 16～40 carbon atoms, fragrant fat or alkoxyl among R1, R2, R3, the R4, preferably contain the fat base of 16 ~ 26 carbon atoms, fragrant fat or alkoxyl, most preferably contain the fat base of 16～22 carbon atoms, fragrant fat or alkoxyl; Remaining is selected from aryl, alkoxyl or the alkylamidoalkyl with 1～6 carbon atom; X
-Be alkyl sulfate ion or the chloride ion that contains 1～4 carbon atom.
Above-mentioned single long alkyl quaternary ammonium salts is meant that one among R1 in the structural formula, R2, R3, the R4 is to be selected from the fat base that contains 12～40 carbon atoms, fragrant fat, alkoxyl or alkylamide, and remaining is selected from aryl, alkoxyl or the alkylamidoalkyl that contains 1～6 carbon atom; The mixture of one or more in preferred cetyl trimethyl ammonium Methylsulfate, cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium Methylsulfate, stearyl trimethyl ammonium chloride, mountain Yu base trimethyl ammonium Methylsulfate, mountain Yu base trimethyl ammonium chloride, the palmitamide oxypropyl trimethyl ammonium chloride; Most preferably mountain Yu base trimethyl ammonium chloride and stearyl trimethyl ammonium chloride.
Above-mentioned two long alkyl quaternary ammonium salts is meant that two among R1 in the structural formula, R2, R3, the R4 is to be selected from the fat base that contains 12～40 carbon atoms, fragrant fat, alkoxyl or alkylamide, and remaining is selected from aryl, alkoxyl or the alkylamidoalkyl that contains 1～6 carbon atom; The mixture of one or more in preferred two cetyl Dimethyl Ammonium Methylsulfates, two cetyl alkyl dimethyl ammonium chlorides, distearyl Dimethyl Ammonium Methylsulfate, VARISOFT TA100, two mountain Yu base Dimethyl Ammonium Methylsulfate, the two mountain Yu base alkyl dimethyl ammonium chloride; Two cetyl alkyl dimethyl ammonium chloride and VARISOFT TA100s most preferably.
Above-mentioned three long alkyl quaternary ammonium saltss are meant that three among R1 in the structural formula, R2, R3, the R4 are selected from the fat base that contains 12～40 carbon atoms, fragrant fat, alkoxyl or alkylamide, and remaining is selected from aryl, alkoxyl or the alkylamidoalkyl that contains 1～6 carbon atom; Preferred three spermaceti fat ylmethyl ammonium chloride.
Said hard fat compounds of group is one or more the mixture in aliphatic alcohol, fatty acid, fatty alcohol derivative, the derivative of fatty acid; Wherein, aliphatic alcohol is the alcohols that contains 12～40 carbon atoms, preferably contains the saturated straight or branched alcohol of 16～22 carbon atoms, most preferably is one or more the mixture in spermol, stearyl alcohol, the behenyl alcohol; Fatty acid is the acids that contains 12～40 carbon atoms, preferably contains the saturated or undersaturated straight or branched acid of 16～22 carbon atoms, most preferably is one or more the mixture in myristic acid, Palmic acid, stearic acid, the oleic acid.
Said lower alkyl alcohol is for containing the lower alkyl alcohol of 1 ~ 6 carbon atom, preferred alcohol, ethylene glycol, isopropyl alcohol, propylene glycol, glycerin, hexylene glycol, 1,3 butylene glycol, tetramethylolmethane, sorbitol.
Said silicone compounds comprises one or more the mixture in straight chain polydimethylsiloxane, amino polydimethylsiloxane, annular dimethyl polysiloxane, the phenyl polydimethylsiloxane; Said polydimethylsiloxane is the polydimethylsiloxane that viscosity is lower than 500000cst, preferably is lower than the polydimethylsiloxane of 100000cst.
Said grease comprises mineral oil, isopropyl myristate, isopropyl palmitate, the different monooctyl ester of myristic acid, iso-octyl palmitate, sad capric acid triglyceride, hydrogenated polydecene or maleic acid Semen Ricini grease.
The method for preparing of Haircare composition of the present invention comprises the steps:
(1) cationic surfactant, hard fat compounds of group, the pure and mild water of low alkyl group are mixed;
(2) under 45～70 ℃, said mixture is mixed stirring carry out homogenize, form lamellar gel matrix and get final product.
The method for preparing of Haircare composition of the present invention is preferably:
(1) deionized water is heated to 40～70 ℃;
(2) cationic surfactant, hard fat compounds of group, lower alkyl alcohol are mixed; Be heated to 60～80 ℃, wherein, the mass ratio of cationic surfactant and aliphatic compound is 1: 1～1: 6; Preferred 1: 1.5～1: 5, most preferably 1: 2～1: 4.5.
(3) deionized water of step (1) and the mixture of step (2) are mixed into system, middling speed stirs homogenize, when the viscosity of system significantly increases formation stratiform liquid crystal base, slowly stirs, and is cooled to below 50 ℃;
(4) add silicone compounds and grease, mix, be cooled to room temperature, promptly get with the layered liquid crystal substrate that step (3) obtains.
Prepare Haircare composition through method for preparing of the present invention, can make it form laminated crystalline substrate closely, this laminated crystalline substrate has higher yield stress, and plays the effect of conditioning hair.
Compared with prior art, the present invention has following beneficial effect:
Haircare composition of the present invention can improve hair quality, makes wet sending out have good spreadability and smooth feeling, improves and does pliability and the lubricity of sending out.The method for preparing of Haircare composition of the present invention has reduced production cost, has improved the viscosity (yield stress) of compositions, makes the suspending power of compositions and salt-tolerant trait stronger.
The specific embodiment
Below just embodiment come further to explain the present invention, but embodiment does not do any qualification to the present invention.
Each embodiment set of dispense ratio of table 1
The result of use of table 2 Haircare composition of the present invention
| Evaluation index | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Smear spreadability | 4.7 | 4.6 | 4.8 | 4.7 | 4.7 |
| The wet smooth feeling of sending out | 4.6 | 4.6 | 4.7 | 4.5 | 4.6 |
| Wet Comb is rational | 4.6 | 4.6 | 4.7 | 4.5 | 4.5 |
| Hair drying comb is rational | 4.6 | 4.5 | 4.7 | 4.5 | 4.5 |
| Do and send out lubricity | 4.5 | 4.5 | 4.5 | 4.4 | 4.4 |
| Do and send out pliability | 4.5 | 4.5 | 4.6 | 4.5 | 4.5 |
Evaluating result:
Standards of grading: 4.5～5.0 minutes: outstanding; 3.5～4.5 minutes: good; 2.5～3.5 minutes: general; 1.5～2.5 minutes: relatively poor; 1～1.5 minute: very poor.
In the table 2, each index is by the average mark after the evaluation group assessment of specialty.
Show by above result: embodiment 1～5 smear spreadability, the wet smooth feeling, cardability, the hair drying comb rational faculty, lubricity, pliability sent out all reaches outstanding or good grade.Thereby compositions of the present invention has wet the sending out of improvement and has good spreadability and smooth feeling, improves dried pliability and lubricity.
Claims (1)
1. Haircare composition is characterized in that said composition comprises following components in percentage by mass:
Mountain Yu base trimethyl ammonium chloride 2%, three cetyl ammonio methacrylate 0.3%, spermol 3%; Stearyl alcohol 3%, tetramethylolmethane 1%, glycerin 1%; Polydimethylsiloxane 1% encircles five polydimethylsiloxane 1%, maleic acid Semen Ricini grease 0.3%; Essence 0.35%, antiseptic 0.1%, surplus is a deionized water;
Or stearyl trimethyl ammonium chloride 1%, two cetyl trimethyl oronain 1%, three cetyl ammonio methacrylates 0.5%, spermol 2.5%; Stearyl alcohol 2.5%, behenyl alcohol 0.5%, tetramethylolmethane 0.5%, sorbitol 1.5%; Polydimethylsiloxane 2% encircles five polydimethylsiloxane 1.5%, maleic acid Semen Ricini grease 0.3%; Essence 0.35%, antiseptic 0.1%, surplus is a deionized water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101938263A CN101697940B (en) | 2009-11-10 | 2009-11-10 | Hair care composition and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101938263A CN101697940B (en) | 2009-11-10 | 2009-11-10 | Hair care composition and preparation method thereof |
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| Publication Number | Publication Date |
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| CN101697940A CN101697940A (en) | 2010-04-28 |
| CN101697940B true CN101697940B (en) | 2012-11-21 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102670422B (en) * | 2011-03-08 | 2016-07-20 | 花王株式会社 | Hair cosmetic composition |
| CN104887580B (en) * | 2015-06-09 | 2017-12-15 | 广东丸美生物技术股份有限公司 | It is a kind of to wash shield composition with scalp anti-aging function |
| FR3064476B1 (en) * | 2017-03-31 | 2020-10-23 | Oreal | COSMETIC TREATMENT PROCESS FOR KERATINIC FIBERS INCLUDING THE APPLICATION OF A BASE COMPOSITION AND OF A COMPOSITION INCLUDING A CATIONIC SURFACTANT |
| CN107468532A (en) * | 2017-08-04 | 2017-12-15 | 澳宝化妆品（惠州）有限公司 | A kind of translucent Haircare composition |
| CN114748369B (en) * | 2022-04-14 | 2023-11-03 | 上海蜂花日用品有限公司 | High-smoothness easy-carding type silicon-free hair conditioner and preparation method thereof |
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Application publication date: 20100428 Assignee: Zhaoqing Dicai Daily Chemical Science and Technology Co., Ltd. Assignor: Guangzhou Decolor Cosmetic Co., Ltd. Contract record no.: 2014440000135 Denomination of invention: Hair care composition and preparation method thereof Granted publication date: 20121121 License type: Exclusive License Record date: 20140331 |
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