CN101638532A - Water-solubility printing ink washing agent - Google Patents
Water-solubility printing ink washing agent Download PDFInfo
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- CN101638532A CN101638532A CN200910042379A CN200910042379A CN101638532A CN 101638532 A CN101638532 A CN 101638532A CN 200910042379 A CN200910042379 A CN 200910042379A CN 200910042379 A CN200910042379 A CN 200910042379A CN 101638532 A CN101638532 A CN 101638532A
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Abstract
A water-solubility printing ink washing agent comprises A component, B component and solvent according to weight ratio of 1: (1.5-2.5): (0.04-0.08), wherein raw materials of the A component are as follows according to weight parts: 12-15 parts of fatty alcohol-polyoxyethylene ether, 0.5-1 part of alkylphenol polyoxyethylene, 8-10 parts of aviation kerosene, 2-4 parts of dibutyl phthalate, 1-3 parts of butyl cellosolve, 1-2 parts of benzyl alcohol and 1-3 parts of butyl acetate; raw materials of the B component are as follows according to weight parts: 5-8 parts of sodium dodecyl benzene sulfonate, 1-2 parts of ethanolamine, 1-3 parts of diethanolamide, 0.5-1 part of urea, 0.5-1 part of sodium carbonate, 0.3-0.5 part of sodium silicate, and 45-55 parts of water. The preparation of the invention is simple, has simple and convenient manufacture, stable performance, safe usage, does not easily burn, does not corrode device and does not pollute the environment. The washing agent has good washing effect, is safe and non-toxic, has easily obtained and stored raw materials, has high stability, can be repeatedly used, and has wide market prospect.
Description
Technical field
The present invention relates to a kind of clean-out system that is used for printing-inks such as cleaning printing press tool, printing manuscript, forme, is a kind of water-solubility printing ink washing agent specifically.
Background technology
Be used for cleaning printing press tool, forme, printing manuscript in the Printing industry and wait the printing ink at black position, use gasoline, kerosene, alcohol, acetone and other organic solvent mostly, such clean-out system is inflammable, explosive, high volatility, contaminate environment, be detrimental to health, and easily causes dissolving, corrosion to being cleaned equipment surface.For overcoming the shortcoming of this type of conventional clean agent, people have developed multiple new type water-solubility printing ink washing agent, as: a kind of water soluble ink scavenger prescription and preparation technology (patent publication No.: CN 1287142A); A kind of water-solubility printing ink washing agent and preparation technology thereof (patent publication No.: CN 1438281A); A kind of detergent for ink (patent publication No.: CN 1563220A); Detergent for water-based print ink (patent publication No.: CN 1923918A); A kind of frosting detergent for ink and preparation method thereof (patent publication No.: CN 101050323A) etc.Along with the continuous appearance of various water soluble ink scavengers, people have also found the drawback of this type of clean-out system: the narrow application range that has, the etching apparatus that has, the injury skin that has, the performance gentleness that has but cleaning performance is not good enough, the prescription complexity that has, with high costs.Therefore, under the prerequisite that does not influence cleansing power, cheap, environmental friendliness, safe in utilization, extensive concern and research that clean-out system that technology is simple, non-volatile, flammable, not non-explosive more and more obtains people.
Summary of the invention
The purpose of this invention is to provide a kind of have the prescription manufacture craft simple, cleaning performance good, safe in utilization, nonflammable, the tractable water-solubility printing ink washing agent of raffinate.
Principle of the present invention is similar principle and the solubleness theory of mixing, by selecting polarity and the approaching solute component of printing-ink, and make the solubility parameter of solvent and solute approaching as far as possible, by adjusting component concentration, make clean-out system polarity as far as possible near printing ink polarity, thereby reach the purpose of removing printing ink to greatest extent.
Water-solubility printing ink washing agent provided by the invention, it is by A component, B component and solvent by weight ratio 1: (1.5～2.5): (0.04～0.08) is formed, and wherein the raw materials by weight portion of A component is counted: 12～15 parts of fatty alcohol-polyoxyethylene ether, 0.5～1 part of alkylphenol polyoxyethylene, 8～10 parts of aviation kerosenes, 2～4 parts of dibutyl phthalates, 1～3 part of butyl glycol ether, 1～2 part of phenylcarbinol, 1～3 part of butylacetate; The raw materials by weight portion of B component is counted: 5～8 parts of Sodium dodecylbenzene sulfonatees, 1～2 part of thanomin, 1～3 part of lauric acid amide of ethanol, 0.5～1 part in urea, 0.5～1 part in yellow soda ash, 0.3～0.5 part of water glass, 45～55 parts in water.
Described solvent is a propyl carbinol.
Described thanomin is Monoethanolamine MEA BASF, diethanolamine or trolamine.
The preparation method of this water-solubility printing ink washing agent, carry out as follows:
A, preparation A component: 8～10 parts of aviation kerosenes, 2～4 parts of dibutyl phthalates, 1～3 part of butyl glycol ether, 1～2 part of phenylcarbinol and butylacetate are mixed for 1～3 part form double solvents earlier, then 12～15 parts of fatty alcohol-polyoxyethylene ether and alkylphenol polyoxyethylene are added in the double solvents for 0.5～1 part, obtain transparent or semitransparent brown yellow solution A component after stirring;
B, preparation B component: earlier 5～8 parts of Sodium dodecylbenzene sulfonatees are joined in 45～55 parts in the water, add 0.3～0.5 part of 1～2 part of thanomin, 1～3 part of lauric acid amide of ethanol, 0.5～1 part in urea, 0.5～1 part in yellow soda ash and water glass then successively, obtain colourless after stirring or shallow yellow transparent solution B component;
C, the B component is joined in the A component, be stirred to two-phase and disperseed to form milk sap fully, add solvent, promptly, wherein the weight proportion of A component, B component and solvent is 1: (1.5～2.5): (0.04～0.08) behind restir 30～50min;
Above-mentionedly all carry out at normal temperatures and pressures.
The present invention can be widely used in the cleaning at all printing inking positions.This cleaning agent formula is simple, simple for production, stable performance, safe in utilization, nonflammable, not etching apparatus, non-environmental-pollution.Applicable to the printing ink of printing machinery (steel part, plastic component) clean, waste paper printing ink cleans, also be applicable to the cleaning operation workman on hand, the printing ink on the clothing etc.This clean-out system cleaning performance is good, and safety non-toxic, raw material are simple and easy to, and easily stores, and stability is high, and is repeatedly reusable, has vast market prospect.
Embodiment
The present invention will be further described below in conjunction with embodiment.
The preparation method of this water-solubility printing ink washing agent carries out as follows:
A, preparation A component: aviation kerosene 900g, dibutyl phthalate 300g, butyl glycol ether 200g, phenylcarbinol 150g and butylacetate 200g are mixed form double solvents earlier, then fatty alcohol-polyoxyethylene ether 1350g and alkylphenol polyoxyethylene 75g are added in the double solvents, obtain transparent or semitransparent brown yellow solution A component after stirring;
B, preparation B component: earlier Sodium dodecylbenzene sulfonate 65g is joined among the water 5000g, add trolamine 150g, lauric acid amide of ethanol 200g, urea 75g, yellow soda ash 75g and water glass 40g then successively, obtain colourless after stirring or shallow yellow transparent solution B component;
C, B component 100g is joined among the A component 200g, be stirred to two-phase and disperseed to form milk sap fully, add solvent, n-butanol 6g, promptly get the micro-emulsion type detergent for ink behind the restir 40min;
Above-mentionedly all carry out at normal temperatures and pressures.
Water dilution with 7～11 times of weight during use gets final product.
Performance test:
(1) stability experiment
Shelf-stability: product is statically placed in the test tube, sealing, normal temperature is preserved and was not seen layering in 700 days, and no floss is separated out.
Centrifugal test: placing supercentrifuge to rotate 15min down in 3000r/min in sample does not have demixing phenomenon.
(2) combustibility and viscosity experiment
Dip in l Water Paper or cotton with sample and be put in that sample does not fire on the burning things which may cause a fire disaster.
Measure its viscosity down in room temperature (25 ℃), with No. 2 rotors, rotating speed is 6r/min, and recording viscosity is 3.093PaS.
Cleaning experiment:
Detersive efficiency of the present invention is measured with mass analysis: printing ink is applied on the aluminum laminate film of certain mass, dries under the state of nature.Aluminum laminate film is placed the beaker that fills clean-out system, and after soaking 5min, 5min vibrates at the uniform velocity again.Take out plate, dry, weigh.Detersive efficiency calculates with following formula.
Detersive efficiency=(W
1-W
2)/(W
1-W
0) * 100%
W in the formula
1---wash the quality of header board, g
W
2---wash the quality of back plate, g
W
0---tabula rasa quality, g
(1) iron and steel, plastics substrate oil the China ink cleaning experiment
This 10 times of dilute with water of prescription is scrubbed with hairbrush after the metal of printing ink or plastic component soak 5～10min scribbling, and cleaning efficiency reaches 100%.Reusable more than 25 times.
(2) printing equipment residual ink cleaning experiment
Be used for printing ink residual on the cleaning of graphic arts equipment behind 8 times of the dilute with waters, clean-out system is sprayed onto on the roller that desire cleans, and the turning handle clean-out system by roller is transported on the inking device, to be cleaned dose with the abundant mixing of printing ink after, wipe printing ink off with scraper, realize cleaning purpose; Perhaps clean-out system is poured on the cloth, uses cloth
Wash the parts that are stained with printing ink, clean with clear water again.
(3) printing manuscript deinking experiment
Behind 10 times of the dilute with waters, will print manuscript and be immersed in the emulsion, and just brush gently and can very fast printing-ink on the paper be cleaned up with hairbrush behind the 30min, papery will not be had influence substantially.
Claims (4)
1, a kind of water-solubility printing ink washing agent, it is characterized in that it is by A component, B component and solvent by weight ratio 1: (1.5～2.5): (0.04～0.08) is formed, and wherein the raw materials by weight portion of A component is counted: 12～15 parts of fatty alcohol-polyoxyethylene ether, 0.5～1 part of alkylphenol polyoxyethylene, 8～10 parts of aviation kerosenes, 2～4 parts of dibutyl phthalates, 1～3 part of butyl glycol ether, 1～2 part of phenylcarbinol, 1～3 part of butylacetate; The raw materials by weight portion of B component is counted: 5～8 parts of Sodium dodecylbenzene sulfonatees, 1～2 part of thanomin, 1～3 part of lauric acid amide of ethanol, 0.5～1 part in urea, 0.5～1 part in yellow soda ash, 0.3～0.5 part of water glass, 45～55 parts in water.
2, water-solubility printing ink washing agent according to claim 1 is characterized in that described solvent is a propyl carbinol.
3, water-solubility printing ink washing agent according to claim 1 is characterized in that described thanomin is Monoethanolamine MEA BASF, diethanolamine or trolamine.
4, the preparation method of the described water-solubility printing ink washing agent of claim 1 is characterized in that it is to carry out as follows:
A, preparation A component: 8～10 parts of aviation kerosenes, 2～4 parts of dibutyl phthalates, 1～3 part of butyl glycol ether, 1～2 part of phenylcarbinol and butylacetate are mixed for 1～3 part form double solvents earlier, then 12～15 parts of fatty alcohol-polyoxyethylene ether and alkylphenol polyoxyethylene are added in the double solvents for 0.5～1 part, obtain transparent or semitransparent brown yellow solution A component after stirring;
B, preparation B component: earlier 5～8 parts of Sodium dodecylbenzene sulfonatees are joined in 45～55 parts in the water, add 0.3～0.5 part of 1～2 part of thanomin, 1～3 part of lauric acid amide of ethanol, 0.5～1 part in urea, 0.5～1 part in yellow soda ash and water glass then successively, obtain colourless after stirring or shallow yellow transparent solution B component;
C, the B component is joined in the A component, be stirred to two-phase and disperseed to form milk sap fully, add solvent, promptly, wherein the weight proportion of A component, B component and solvent is 1: (1.5～2.5): (0.04～0.08) behind restir 30～50min;
Above-mentionedly all carry out at normal temperatures and pressures.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2009100423791A CN101638532B (en) | 2009-08-29 | 2009-08-29 | Water-solubility printing ink washing agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100423791A CN101638532B (en) | 2009-08-29 | 2009-08-29 | Water-solubility printing ink washing agent |
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| CN101638532A true CN101638532A (en) | 2010-02-03 |
| CN101638532B CN101638532B (en) | 2011-07-20 |
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|---|---|---|---|
| CN2009100423791A Expired - Fee Related CN101638532B (en) | 2009-08-29 | 2009-08-29 | Water-solubility printing ink washing agent |
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Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102850838A (en) * | 2011-06-29 | 2013-01-02 | 东友精细化工有限公司 | Intaglio washing solution composition used for offset printing and washing method using the same |
| CN103525164A (en) * | 2013-10-23 | 2014-01-22 | 合肥环照高分子材料厂 | Novel detergent for printing ink and preparation method of detergent |
| CN103525169A (en) * | 2013-10-23 | 2014-01-22 | 合肥环照高分子材料厂 | Cleaning agent for cleaning printing ink and preparation method thereof |
| CN103525162A (en) * | 2013-10-23 | 2014-01-22 | 合肥环照高分子材料厂 | Safe environment-friendly ink detergent and preparation method thereof |
| CN103525167A (en) * | 2013-10-23 | 2014-01-22 | 合肥环照高分子材料厂 | Novel detergent for printing ink as well as preparation method thereof |
| CN103540185A (en) * | 2013-10-23 | 2014-01-29 | 合肥环照高分子材料厂 | Special-effect printing ink cleaning agent and preparation method thereof |
| CN103602137A (en) * | 2013-11-19 | 2014-02-26 | 安徽本色印刷有限公司 | Novel printing ink cleaning agent and preparation method thereof |
| CN103613980A (en) * | 2013-10-28 | 2014-03-05 | 安徽拓普森电池有限责任公司 | Cleaning agent for cleaning printing machine ink and preparation method thereof |
| CN103613979A (en) * | 2013-10-28 | 2014-03-05 | 安徽拓普森电池有限责任公司 | Ink cleaning agent and preparation method thereof |
| CN103613983A (en) * | 2013-10-28 | 2014-03-05 | 安徽拓普森电池有限责任公司 | Novel cleaning agent for printing ink and preparation method thereof |
| CN103613982A (en) * | 2013-10-28 | 2014-03-05 | 安徽拓普森电池有限责任公司 | Cleaning agent for cleaning printing ink and preparation method thereof |
| CN103613978A (en) * | 2013-10-28 | 2014-03-05 | 安徽拓普森电池有限责任公司 | Ink cleaning agent with no damage to equipment and preparation method thereof |
| CN103613977A (en) * | 2013-10-20 | 2014-03-05 | 安徽美翔塑业有限公司 | Printing ink detergent |
| CN103709818A (en) * | 2013-12-17 | 2014-04-09 | 湖南城市学院 | Water-based deinking agent of smart phone glass |
| CN103725440A (en) * | 2013-12-31 | 2014-04-16 | 中国船舶重工集团公司第七一八研究所 | Cleaning agent for automobile |
| CN103865317A (en) * | 2014-02-27 | 2014-06-18 | 安徽颍美彩印包装有限公司 | Printing ink cleaning agent and preparation method thereof |
| CN104371416A (en) * | 2014-11-28 | 2015-02-25 | 卢家雄 | Paint cleaning agent |
| CN104830141A (en) * | 2015-04-30 | 2015-08-12 | 南京信息工程大学 | Microemulsion printing ink cleaner and preparation method thereof |
| CN105861175A (en) * | 2016-05-04 | 2016-08-17 | 芜湖真空科技有限公司 | Efficient coating device cleaning agent and preparation method thereof |
| CN103613978B (en) * | 2013-10-28 | 2016-11-30 | 肖晓梅 | A kind of detergent for ink undamaged to equipment and preparation method thereof |
| CN107858037A (en) * | 2017-11-02 | 2018-03-30 | 中国标准化研究院 | A kind of O/W micro-emulsion types printing-ink environment-friendly cleaning agent |
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| CN1359990A (en) * | 2000-12-22 | 2002-07-24 | 武汉现代工业技术研究院 | Efficient detergent for print ink |
| CN101434764B (en) * | 2007-11-15 | 2010-12-01 | 中国石油化工股份有限公司 | Printing ink cleaning agent |
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Cited By (26)
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|---|---|---|---|---|
| CN102850838A (en) * | 2011-06-29 | 2013-01-02 | 东友精细化工有限公司 | Intaglio washing solution composition used for offset printing and washing method using the same |
| CN102850838B (en) * | 2011-06-29 | 2016-01-13 | 东友精细化工有限公司 | Offset printing intaglio plate cleaning liquid composition and the washing methods using said composition |
| CN103613977A (en) * | 2013-10-20 | 2014-03-05 | 安徽美翔塑业有限公司 | Printing ink detergent |
| CN103525164A (en) * | 2013-10-23 | 2014-01-22 | 合肥环照高分子材料厂 | Novel detergent for printing ink and preparation method of detergent |
| CN103525167A (en) * | 2013-10-23 | 2014-01-22 | 合肥环照高分子材料厂 | Novel detergent for printing ink as well as preparation method thereof |
| CN103540185A (en) * | 2013-10-23 | 2014-01-29 | 合肥环照高分子材料厂 | Special-effect printing ink cleaning agent and preparation method thereof |
| CN103525169A (en) * | 2013-10-23 | 2014-01-22 | 合肥环照高分子材料厂 | Cleaning agent for cleaning printing ink and preparation method thereof |
| CN103540185B (en) * | 2013-10-23 | 2016-03-30 | 合肥环照高分子材料厂 | A kind of specific ink cleaning agent and preparation method thereof |
| CN103525162A (en) * | 2013-10-23 | 2014-01-22 | 合肥环照高分子材料厂 | Safe environment-friendly ink detergent and preparation method thereof |
| CN103613979A (en) * | 2013-10-28 | 2014-03-05 | 安徽拓普森电池有限责任公司 | Ink cleaning agent and preparation method thereof |
| CN103613978A (en) * | 2013-10-28 | 2014-03-05 | 安徽拓普森电池有限责任公司 | Ink cleaning agent with no damage to equipment and preparation method thereof |
| CN103613978B (en) * | 2013-10-28 | 2016-11-30 | 肖晓梅 | A kind of detergent for ink undamaged to equipment and preparation method thereof |
| CN103613982A (en) * | 2013-10-28 | 2014-03-05 | 安徽拓普森电池有限责任公司 | Cleaning agent for cleaning printing ink and preparation method thereof |
| CN103613979B (en) * | 2013-10-28 | 2016-11-30 | 潘剑利 | A kind of detergent for ink and preparation method thereof |
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| CN103613980A (en) * | 2013-10-28 | 2014-03-05 | 安徽拓普森电池有限责任公司 | Cleaning agent for cleaning printing machine ink and preparation method thereof |
| CN103602137A (en) * | 2013-11-19 | 2014-02-26 | 安徽本色印刷有限公司 | Novel printing ink cleaning agent and preparation method thereof |
| CN103602137B (en) * | 2013-11-19 | 2016-05-25 | 安徽本色印刷有限公司 | Printing ink cleaning agent of a kind of novelty and preparation method thereof |
| CN103709818A (en) * | 2013-12-17 | 2014-04-09 | 湖南城市学院 | Water-based deinking agent of smart phone glass |
| CN103725440A (en) * | 2013-12-31 | 2014-04-16 | 中国船舶重工集团公司第七一八研究所 | Cleaning agent for automobile |
| CN103865317A (en) * | 2014-02-27 | 2014-06-18 | 安徽颍美彩印包装有限公司 | Printing ink cleaning agent and preparation method thereof |
| CN103865317B (en) * | 2014-02-27 | 2016-04-27 | 安徽颍美彩印包装有限公司 | A kind of printing ink washing agent and preparation method thereof |
| CN104371416A (en) * | 2014-11-28 | 2015-02-25 | 卢家雄 | Paint cleaning agent |
| CN104830141A (en) * | 2015-04-30 | 2015-08-12 | 南京信息工程大学 | Microemulsion printing ink cleaner and preparation method thereof |
| CN105861175A (en) * | 2016-05-04 | 2016-08-17 | 芜湖真空科技有限公司 | Efficient coating device cleaning agent and preparation method thereof |
| CN107858037A (en) * | 2017-11-02 | 2018-03-30 | 中国标准化研究院 | A kind of O/W micro-emulsion types printing-ink environment-friendly cleaning agent |
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