CN101634108A - Resin finishing agent composition for purified cotton clothes and preparing method thereof - Google Patents
Resin finishing agent composition for purified cotton clothes and preparing method thereof Download PDFInfo
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- CN101634108A CN101634108A CN200910041388A CN200910041388A CN101634108A CN 101634108 A CN101634108 A CN 101634108A CN 200910041388 A CN200910041388 A CN 200910041388A CN 200910041388 A CN200910041388 A CN 200910041388A CN 101634108 A CN101634108 A CN 101634108A
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Abstract
The invention provides a resin finishing agent composition for purified cotton clothes and a preparing method thereof. The resin finishing agent composition is a multi-ingredient resin finishing agent prepared by using etherified modified glyoxal resin, vinol, a polyethylene softener, an organic siloxane softener, MgCl2.6H2O, water and the like as main parts. The resin finishing agent composition is used in three-dimensional cat whisker crumpling finishing of pure cotton clothes. Compared with the conventional resin finishing agent, the resin finishing agent composition of the invention simplifies production technology and reduces operation and technology difficulties; and after finishing, fabrics have strength retention of 65-75%, a wrinkle recover angle (WRA/degree) is greater than 254 degrees, and the cat whisker three-dimensional retention effect reaches four to five level.
Description
Technical field
The present invention relates to a kind of resin finishing agent composition and method of making the same.More particularly, the present invention relates to the textile clothes of a kind of textile printing and dyeing garment wash industry and crumple resin finishing agent composition and method of making the same in the arrangement with three-dimensional cat's whisker.
Background technology
Cellulose base fiber fabric is soft because of having, gloss is soft, warmth retention property good, strong to stand up to hard wear, absorption of perspiration is strong, advantage such as comfortable and easy to wear, in textiles, occupy an important position all the time, but cellulose base fiber fabric exist wrinkle resistance poor, need shortcoming such as flatiron after creasing easily, easily shrink, washing, make to be difficult to become high-grade product.In order to overcome the above-mentioned shortcoming of cellulose base fiber fabric, usually pure cotton fabric is carried out RESIN FINISH processing.
The suitability for industrialized production of cotton fabric RESIN FINISH has the history in more than 80 year, has experienced the developing stage of wrinkle resistant shiinkproof finish, " wash and wear " arrangement and durable press finish.It is perfect that production technology has become, and required resin finishing agent and auxiliary aid thereof be great variety of goods also, and COTTON FABRIC of producing and textile clothes can both satisfy user and market demands at aspects such as wearability and release formaldehydes.
In recent years, textile clothes particularly jeans are taken the style sudden change, have occurred and the antipodal fashion trend of conventional durable press finish---and solid crumples the cat's whisker arrangement.Put out clothes in order at positions such as the trouser legs of clothes, trousers bodies and taking the flat and circular natural wrinkle that produce in the process, and its wrinkle form stable got off, because of its shape such as cat's whisker, so claim that three-dimensional cat's whisker crumples arrangement, this style enjoys consumers in general to like because of its nature, novelty, fashion.Conventional resin finishing agent is used for the three-dimensional cat's whisker of textile clothes and crumples arrangement; need use simultaneously with catalyst, fiber strength protective agent, softener and wetting agent etc.; not only required auxiliary aid is wide in variety; and technical difficulty height, technology are complicated; cause the production technology poor reproducibility; fabric strength loss is big, the three-dimensional guarantor's type of cat's whisker and stretching rebound performance are poor, quality of production instability.
Summary of the invention
The purpose of this invention is to provide a kind of textile printing and dyeing industry garment wash and crumple resin finishing agent composition in the arrangement with the three-dimensional cat's whisker of textile clothes; to solve the above-mentioned problems in the prior art; with this resin finishing agent composition of the present invention textile clothes are carried out three-dimensional cat's whisker and crumple arrangement; do not need to add catalyst; the fiber strength protective agent; auxiliary aid such as softener and wetting agent; simplified production technology; reduced technical difficulty; it is little that clothes crumple arrangement back strength loss; cat's whisker stretching rebound performance and three-dimensional guarantor's type are effective; the technology favorable reproducibility, constant product quality.
Another object of the present invention provides a kind of preparation method of above-mentioned composition.
The three-dimensional cat's whisker of resin finishing agent composition for purified cotton clothes of the present invention crumples the arrangement principle: the polyfunctional group macromolecule resin finishing agent that contains in the resin finishing agent composition produces hydrogen bond and frictional resistance with the amorphous region of cancellated pitch deposition at cellulose fibre; Simultaneously, the formation covalent cross-linking that reacts of the hydroxyl in resin macromolecule and the cellulose, thus change the rheological property of fiber, improved the recovery capability of deformation, reach the purpose that crumples the three-dimensional guarantor's type of cat's whisker.The resin finishing agent composition is crumpling when arrangement, and the etherification modified glyoxal resin in the resin finishing agent reacts with hydroxyl in the cellulose fibre under the effect of high temperature and catalyst, produces covalent cross-linking; Simultaneously high-molecular polyvinyl alcohol in the resin finishing agent composition and organosiloxane macromolecule also with fiber-reactive, and form the fine and close reticulated film of one deck, thereby reach the effect of crease-resistant guarantor's type of reinforced fiber and rebound performance at fiber surface.
Resin finishing agent composition for purified cotton clothes of the present invention, said composition is composed of the following components by weight percentage:
Etherification modified glyoxal resin 35.0%-60.0%
Polyvinyl alcohol 1.0%-8.0%
Polyethylene softener 5.0%-10.0%
Organosiloxane softener 1.0%-6.0%
MgCl
2·6H
2O?????????5.0％-20.0％
Penetrating agent JFC 0.0%-3.0%
Water 8.0%-50.0%
In above-mentioned resin finishing agent composition, etherification modified glyoxal resin is a crosslinking agent, can with cellulose fibre generation cross-linking reaction, make clothes crumple arrangement back cat's whisker form stable; Polyvinyl alcohol is a kind of macromolecule filming material, can form one deck macromolecule membrane at fiber surface, the morphological stability and the stretching resilience of wrinkle after the raising RESIN FINISH, and give certain washing fastness; The polyethylene softener can improve the tearing brute force after the textile resins arrangement, and gives fabric sofetening, plentiful feel; The organosiloxane softener can improve the thick and stiff shortcoming in textile resins arrangement back, and the feel of giving fabric sofetening is improved the fabric tearing brute force simultaneously; MgCl
26H
2O is the acid compound of diving, and the condition of cross-linking reaction is provided; Penetrating agent JFC can improve the wettability of fabrics energy, helps to improve resin and is evenly distributed on fabric.The above-mentioned percentage range of the combination of these components and each component, determine by a large amount of tests, combinations thereof and percentage range make that resin finishing agent composition of the present invention is used for that the three-dimensional cat's whisker of textile clothes crumples RESIN FINISH and has that technology is simple, technical difficulty is low, strength loss is little, stretching rebound performance height, three-dimensional guarantor's type are effective, the technology favorable reproducibility, constant product quality.
In above-mentioned resin finishing agent composition, the content of etherification modified glyoxal resin is preferably 40.0%-55.0%, and perhaps the content of polyvinyl alcohol is preferably 2.0%-5.0%, perhaps MgCl
26H
2O content is preferably 8.0%-12.0%.
Preparing resin finishing agent method for compositions of the present invention is made up of following steps successively:
A, in reactor, add entry and MgCl
26H
2O stirred 1 hour, formed solution;
B, polyvinyl alcohol is joined in the above-mentioned solution, ℃ stirred 5 hours heat temperature raising to 80～90;
C, this solution is cooled to 50 ℃;
D, add etherification modified glyoxal resin, polyethylene softener, water-soluble organic silicon oxygen alkane softener, ooze to this solution
Saturating agent JFC;
E, stirring 1 hour are finished product;
Above step is all carried out under normal pressure.
Resin finishing agent composition of the present invention can carry out three-dimensional cat's whisker to textile clothes with following method and crumple arrangement: clothes soak (70～80 ℃ of resin working solution (resin finishing agent composition 200g/L) → centrifugal dehydrations (liquid carrying rate 75～80%) → oven dry, (147～150 ℃ of typings are made → baked to 5～8min) → cat's whisker, 12～18min) → hot water wash (60 ℃, 10min) → oven dry.Three-dimensional cat's whisker rebound performance height, the three-dimensional guarantor's type that the processing and sorting of this resin finishing agent composition goes out is effective, strength loss is little, technology favorable reproducibility, constant product quality.
The specific embodiment
Further specify the present invention below by embodiment and Comparative Examples.In the following Examples and Comparative Examples, with the loss of ultimate strength retention rate (%) expression fabric strength, this numerical value is big more, illustrates that the fabric strength loss is little; With fabric pincher recovery angle (WRA/ °) expression fabric resilience energy, this numerical value is big more, illustrates that fabric resilience can be high more; Represent to crumple the three-dimensional guarantor's type of cat's whisker effect with 1～5, this numerical value is big more, and it is good more that expression crumples the three-dimensional guarantor's type of cat's whisker effect.
Embodiment 1
At normal temperatures and pressures, in reactor, add entry and MgCl by each component of appointment in the following table 1 respectively
26H
2O, stirred 1 hour, form solution, polyvinyl alcohol is joined in the above-mentioned solution, heat temperature raising to 80～90 ℃ stirring 5 hours, this solution is cooled to 50 ℃, adds methyl-etherified hydroxymethyl-2 dihydroxy-ethylene urea resin, polyethylene softener, water-soluble organic silicon oxygen alkane softener, penetrating agent JFC, continue to stir after 1 hour and make the resin finishing agent composition to this solution.Adopt following method that the resin finishing agent composition is carried out three-dimensional cat's whisker to textile clothes and crumple arrangement: clothes soak (70～80 ℃ of resin working solution (resin finishing agent composition 200g/L) → centrifugal dehydrations (liquid carrying rate 75～80%) → oven dry, (147～150 ℃ of typings are made → baked to 5～8min) → cat's whisker, 12～18min) → hot water wash (60 ℃, 10min) → oven dry.Then, test ultimate strength retention rate (%), fabric pincher recovery angle (WRA/ °) and three-dimensional guarantor's type effect of textile clothes arrangement back cat's whisker, in table 1, listed test result.
Embodiment 2
Repeat the method for embodiment 1 by each constituent content of appointment in the following table 1, but replace methyl-etherified hydroxymethyl-2 dihydroxy-ethylene urea resin, ether hydroxymethyl-2 dihydroxy-ethylene urea resin, polyvinyl alcohol, MgCl with ether hydroxymethyl-2 dihydroxy-ethylene urea resin
26H
2O content adopts preferable range, has listed test result in the table 1.
Embodiment 3
Repeat the method for embodiment 1 by each constituent content of appointment in the following table 1, but replace methyl-etherified hydroxymethyl-2 dihydroxy-ethylene urea resin, ether hydroxymethyl-2 dihydroxy-ethylene urea resin, polyvinyl alcohol, MgCl with ether hydroxymethyl-2 dihydroxy-ethylene urea resin
26H
2O content adopts preferable range, has listed test result in the table 1.
Embodiment 4
Repeat the method for embodiment 1 by each constituent content of appointment in the following table 1, but the ether hydroxymethyl-2 dihydroxy-ethylene urea resin with the inferior ethylene urea modification of ring replaces methyl-etherified hydroxymethyl-2 dihydroxy-ethylene urea resin, but etherification modified glyoxal resin, polyvinyl alcohol adopt preferable range, MgCl
26H
2O content does not adopt preferable range, has listed test result in the table 1.
Comparative Examples 1
At normal temperatures and pressures, by each constituent content of appointment in the following table 1 in reactor with methyl-etherified hydroxymethyl-2 dihydroxy-ethylene urea resin, polyvinyl alcohol, polyethylene softener, water-soluble organic silicon oxygen alkane softener, penetrating agent JFC, MgCl
26H
2O and water adding are blended directly in together, stir 1 hour, and heat temperature raising to 80～90 ℃ stirring is 5 hours then, and this solution is cooled to 50 ℃, continues to stir after 1 hour and makes slight white mucus shape resin finishing agent composition.Adopt following method that the resin finishing agent composition is carried out three-dimensional cat's whisker to textile clothes and crumple arrangement: clothes soak (70～80 ℃ of resin working solution (resin finishing agent composition 200g/L) → centrifugal dehydrations (liquid carrying rate 75～80%) → oven dry, (147～150 ℃ of typings are made → baked to 5～8min) → cat's whisker, 12～18min) → hot water wash (60 ℃, 10min) → oven dry.Then, test ultimate strength retention rate (%), fabric pincher recovery angle (WRA/ °) and three-dimensional guarantor's type effect of textile clothes arrangement back cat's whisker, in table 1, listed test result.
Comparative Examples 2
At normal temperatures and pressures, by each constituent content of appointment in the following table 1 in reactor with ether hydroxymethyl-2 dihydroxy-ethylene urea resin, polyethylene softener, water-soluble organic silicon oxygen alkane softener, penetrating agent JFC, MgCl
26H
2O and water adding are blended directly in together, stir and make slight white mucus shape resin finishing agent composition after 1 hour.Adopt following method that the resin finishing agent composition is carried out three-dimensional cat's whisker to textile clothes and crumple arrangement: clothes soak (70～80 ℃ of resin working solution (resin finishing agent composition 200g/L) → centrifugal dehydrations (liquid carrying rate 75～80%) → oven dry, (147～150 ℃ of typings are made → baked to 5～8min) → cat's whisker, 12～18min) → hot water wash (60 ℃, 10min) → oven dry.Then, test ultimate strength retention rate (%), fabric pincher recovery angle (WRA/ °) and three-dimensional guarantor's type effect of textile clothes arrangement back cat's whisker, in table 1, listed test result.
Comparative Examples 3
At normal temperatures and pressures, in reactor, will encircle ether hydroxymethyl-2 dihydroxy-ethylene urea resin, the MgCl of inferior ethylene urea modification by each constituent content of appointment in the following table 1
26H
2O, penetrating agent JFC and water adding are blended directly in together, stir and make slight yellow mucus shape resin finishing agent composition after 1 hour.Adopt following method that the resin finishing agent composition is carried out three-dimensional cat's whisker to textile clothes and crumple arrangement: clothes soak (70～80 ℃ of resin working solution (resin finishing agent composition 200g/L) → centrifugal dehydrations (liquid carrying rate 75～80%) → oven dry, (147～150 ℃ of typings are made → baked to 5～8min) → cat's whisker, 12～18min) → hot water wash (60 ℃, 10min) → oven dry.Then, test ultimate strength retention rate (%), fabric pincher recovery angle (WRA/ °) and three-dimensional guarantor's type effect of textile clothes arrangement back cat's whisker, in table 1, listed test result.
The test data explanation of ultimate strength retention rate (%), fabric pincher recovery angle (WRA/ °) and three-dimensional guarantor's type effect of textile clothes arrangement back cat's whisker in each embodiment and the Comparative Examples in the following table 1, no matter on single performance, still on combination property, resin finishing agent composition of the present invention all is better than the resin finishing agent composition of Comparative Examples significantly.
Table 1
| Each constituent content (weight portion) and solid crumple the cat's whisker performance | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative Examples 1 | Comparative Examples 2 | Comparative Examples 3 |
| Etherification modified glyoxal resin | ??35 | ??45 | ??50 | ??55 | ??45 | ??50 | ??60 |
| Polyvinyl alcohol | ??1 | ??3 | ??2 | ??4 | ??2 | ||
| The polyethylene softener | ??5 | ??7 | ??10 | ??7 | ??5 | ||
| The organosiloxane softener | ??2 | ??3 | ??5 | ??3 | ??3 | ||
| ??MgCl 2·6H 2O | ??6 | ??10 | ??10 | ??15 | ??6 | ??10 | ??12 |
| Penetrating agent JFC | ??0.5 | ??1 | ??1 | ??2 | ??1 | ??1 | ??2 |
| Water | ??50.5 | ??41 | ??27 | ??9 | ??32 | ??31 | ??26 |
| Ultimate strength retention rate (%) | ??72 | ??70 | ??68 | ??65 | ??58 | ??56 | ??52 |
| Fabric pincher recovery angle (WRA/ °) | ??248 | ??255 | ??262 | ??252 | ??220 | ??225 | ??228 |
| The three-dimensional guarantor's type of cat's whisker effect | ??4 | ??5 | ??5 | ??5 | ??3 | ??3 | ??3 |
Claims (10)
1, a kind of resin finishing agent composition for purified cotton clothes is by etherification modified glyoxal resin, polyvinyl alcohol, polyethylene softener, organosiloxane softener, MgCl
26H
2Compositions such as O, penetrating agent JFC, water, form as following weight percent:
Etherification modified glyoxal resin 35.0%-60.0%
Polyvinyl alcohol 1.0%-8.0%
Polyethylene softener 5.0%-10.0%
Organosiloxane softener 1.0%-6.0%
MgCl
2·6H
2O???????????5.0％-20.0％
Penetrating agent JFC 0.0%-3.0%
Water 8.0%-50.0%.
2, according to the described resin finishing agent composition for purified cotton clothes of claim 1, it is characterized in that: etherification modified glyoxal resin is etherification modified hydroxymethyl-2 dihydroxy-ethylene urea resin.
3, according to the described resin finishing agent composition for purified cotton clothes of claim 2, it is characterized in that: etherification modified glyoxal resin is the hydroxymethyl-2 dihydroxy-ethylene urea resin reactive resin that etherificate got in 1～3 hour under pH value 1.5～5.5,35～65 ℃ of conditions of temperature, and etherifying agent is an alcohols material: a kind of in methyl alcohol, ethanol, propyl alcohol, butanols, ethylene glycol, propylene glycol, butanediol, polyethylene glycol, the diethylene glycol (DEG).
4, according to claim 1,2 or 3 described resin finishing agent composition for purified cotton clothes, it is characterized in that: etherification modified glyoxal resin is the reactive resin that etherification modified hydroxymethyl-2 dihydroxy-ethylene urea resin got with the inferior ethylene urea reaction of ring under pH value 4.5～7.5,45～55 ℃ of conditions of temperature in 1～2 hour.
5, according to the described resin finishing agent composition for purified cotton clothes of claim 1, it is characterized in that: the organosiloxane softener is a kind of in amino-polyether modified silicone oil, the epoxidized polyether modified silicon oil.
6, according to the described resin finishing agent composition for purified cotton clothes of claim 1, wherein, the content of etherification modified glyoxal resin is 40.0%～55.0%.
7, according to the described resin finishing agent composition for purified cotton clothes of claim 1, wherein, the content of polyvinyl alcohol is 2.0%～5.0%.
8, according to the described resin finishing agent composition for purified cotton clothes of claim 1, wherein, MgCl
26H
2The content of O is 8.0%～12.0%, more than each component sum be 100%.
9, the described resin finishing agent method for compositions of preparation claim 1 is characterized in that the preparation method of this resin finishing agent may further comprise the steps:
A, in reactor, add entry and MgCl
26H
2O stirred 1 hour, formed solution;
B, polyvinyl alcohol is joined in the above-mentioned solution, ℃ stirred 5 hours heat temperature raising to 80～90;
C, this solution is cooled to 50 ℃;
D, add etherification modified glyoxal resin, polyethylene softener, water-soluble organic silicon oxygen alkane softener, penetrating agent JFC to this solution;
E, stirring 1 hour are finished product.
Above step is all carried out under normal pressure.
10, according to the described resin finishing agent composition for purified cotton clothes of claim 1, fabric strength conservation rate after the said composition arrangement is 65～75%, creasy recovery angle (WRA/ °) is greater than 245 °, and the three-dimensional guarantor's type of cat's whisker effect reaches 4～5 grades, and has following physicochemical property:
1. outward appearance: slight white mucus;
2. pH value: 5.0-7.0;
3. solid content: 25.0-40.0%;
4. free formaldehyde :≤0.2%;
5. water-soluble: soluble in water.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100413889A CN101634108B (en) | 2009-07-24 | 2009-07-24 | Resin finishing agent composition for purified cotton clothes and preparing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100413889A CN101634108B (en) | 2009-07-24 | 2009-07-24 | Resin finishing agent composition for purified cotton clothes and preparing method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN101634108A true CN101634108A (en) | 2010-01-27 |
| CN101634108B CN101634108B (en) | 2012-04-18 |
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Cited By (12)
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|---|---|---|---|---|
| CN102286883A (en) * | 2011-06-23 | 2011-12-21 | 安徽大学 | Preparation method of composite resin finishing agent for hair interlining |
| CN102926146A (en) * | 2011-08-08 | 2013-02-13 | 广东群豪服饰有限公司 | Method for performing crease-resistant finishing on cotton textile fabrics or garments |
| CN103255617A (en) * | 2013-05-15 | 2013-08-21 | 江苏格玛斯特种织物有限公司 | Velvet fabric after-finishing auxiliary |
| CN103334302A (en) * | 2013-07-25 | 2013-10-02 | 赵玉英 | Finishing agent for clothes and preparation method |
| CN103469577A (en) * | 2013-10-08 | 2013-12-25 | 江门市宝发纺织服饰制造有限公司 | Stiffening agent used for crease finishing of jean clothes |
| CN105133315A (en) * | 2015-09-21 | 2015-12-09 | 宁波雅戈尔科技有限公司 | Finishing agent composition for cotton-silk fabrics and processing method of cotton-silk easy-care shirt |
| CN105133344A (en) * | 2015-09-21 | 2015-12-09 | 宁波雅戈尔科技有限公司 | Finishing agent composition for flax fabrics and processing method of flax easy-care shirt |
| CN105713162A (en) * | 2015-09-30 | 2016-06-29 | 齐齐哈尔大学 | 1,2-Propylene glycol etherification modified DMDHEU resin and synthetic method thereof |
| CN106868871A (en) * | 2017-02-09 | 2017-06-20 | 常熟市欣鑫经纬编有限公司 | Super-soft fiber cellulose fiber fabric postfinishing process |
| CN108797124A (en) * | 2018-07-02 | 2018-11-13 | 安徽职业技术学院 | A kind of textile clothes crease proofing agent and its finishing technique |
| CN111826958A (en) * | 2020-07-30 | 2020-10-27 | 鲁丰织染有限公司 | Finishing method for improving recovery angle of resin finishing crease |
| CN114790660A (en) * | 2021-12-27 | 2022-07-26 | 辽东学院 | Method for preparing functional textile by using natural plants |
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- 2009-07-24 CN CN2009100413889A patent/CN101634108B/en not_active Expired - Fee Related
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| CN102286883B (en) * | 2011-06-23 | 2012-11-28 | 安徽大学 | Preparation method of composite resin finishing agent for hair interlining |
| CN102286883A (en) * | 2011-06-23 | 2011-12-21 | 安徽大学 | Preparation method of composite resin finishing agent for hair interlining |
| CN102926146B (en) * | 2011-08-08 | 2015-04-15 | 广东群豪服饰有限公司 | Method for performing crease-resistant finishing on cotton textile fabrics or garments |
| CN102926146A (en) * | 2011-08-08 | 2013-02-13 | 广东群豪服饰有限公司 | Method for performing crease-resistant finishing on cotton textile fabrics or garments |
| CN103255617A (en) * | 2013-05-15 | 2013-08-21 | 江苏格玛斯特种织物有限公司 | Velvet fabric after-finishing auxiliary |
| CN103334302B (en) * | 2013-07-25 | 2015-11-04 | 赵玉英 | A kind of clothing finishing agent and preparation method |
| CN103334302A (en) * | 2013-07-25 | 2013-10-02 | 赵玉英 | Finishing agent for clothes and preparation method |
| CN103469577A (en) * | 2013-10-08 | 2013-12-25 | 江门市宝发纺织服饰制造有限公司 | Stiffening agent used for crease finishing of jean clothes |
| CN103469577B (en) * | 2013-10-08 | 2015-04-29 | 江门市宝发纺织服饰制造有限公司 | Stiffening agent used for crease finishing of jean clothes |
| CN105133315A (en) * | 2015-09-21 | 2015-12-09 | 宁波雅戈尔科技有限公司 | Finishing agent composition for cotton-silk fabrics and processing method of cotton-silk easy-care shirt |
| CN105133344A (en) * | 2015-09-21 | 2015-12-09 | 宁波雅戈尔科技有限公司 | Finishing agent composition for flax fabrics and processing method of flax easy-care shirt |
| CN105713162A (en) * | 2015-09-30 | 2016-06-29 | 齐齐哈尔大学 | 1,2-Propylene glycol etherification modified DMDHEU resin and synthetic method thereof |
| CN105713162B (en) * | 2015-09-30 | 2018-01-09 | 齐齐哈尔大学 | 1,2 propane diols are etherified modified DMDHEU resin and its synthetic method |
| CN106868871A (en) * | 2017-02-09 | 2017-06-20 | 常熟市欣鑫经纬编有限公司 | Super-soft fiber cellulose fiber fabric postfinishing process |
| CN108797124A (en) * | 2018-07-02 | 2018-11-13 | 安徽职业技术学院 | A kind of textile clothes crease proofing agent and its finishing technique |
| CN111826958A (en) * | 2020-07-30 | 2020-10-27 | 鲁丰织染有限公司 | Finishing method for improving recovery angle of resin finishing crease |
| CN114790660A (en) * | 2021-12-27 | 2022-07-26 | 辽东学院 | Method for preparing functional textile by using natural plants |
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