CN101611916A - A kind of food deoxidizing antistaling agent and using method and camellia seed kernel deoxidation preservation method - Google Patents
A kind of food deoxidizing antistaling agent and using method and camellia seed kernel deoxidation preservation method Download PDFInfo
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- CN101611916A CN101611916A CN200910062651A CN200910062651A CN101611916A CN 101611916 A CN101611916 A CN 101611916A CN 200910062651 A CN200910062651 A CN 200910062651A CN 200910062651 A CN200910062651 A CN 200910062651A CN 101611916 A CN101611916 A CN 101611916A
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Abstract
A kind of food deoxidizing antistaling agent and using method and camellia seed kernel deoxidation preservation method belong to the food additives field.The composition of each raw material and weight % are: ditert-butylhydro quinone 30%～40%, biphosphate are received powder 20%～30%, citric acid 15%～30%, active carbon 5%～35%.Its using method is: earlier the food deoxidizing antistaling agent is added water and be mixed into the aqueous solution; The aqueous solution with the food deoxidizing antistaling agent adds in the processed food of drying processing then, mixes, again with processed food drying.Preparation is convenient, and consumption is little, has no side effect, and is safe in utilization, and its using method is easy, good refreshing effect, and long fresh-keeping period, the time of deoxidation preservation is longer.Be particularly suitable for as the deoxidation behind grease class nuts such as shelled peanut, camellia seed kernel, pinenut and the dry fruit food drying fresh-keeping.
Description
Technical field
The present invention relates to a kind of additive and preservation method of food, be meant a kind of food deoxidizing antistaling agent and using method and camellia seed kernel deoxidation preservation method specifically.Belong to the food additives field.
Background technology
The tea oil that is extracted by tea seed is rich in necessary for human body 17 seed amino acids and zinc, selenium and other trace elements, and its quality surpasses the west first olive oil.The tea seed of China extensively exports to countries such as Japan, America and Europe.Because tea seed proportion is lighter, the oil-containing composition is relatively low, and vanning exports the cost of transportation height, and is wrapping because of tea seed has the tea shell, and quality is difficult to distinguish, so export volume is few.The camellia seed kernel that obtains after tea seed peeled off, volume is little, the oil content height, added value is higher, and the cost of outlet vanning is relatively low, has not only reduced cost of transportation, and has improved credit rating; Can increase export manufacturer through the income, also obtain foreign trader's welcome.But camellia seed kernel belongs to arbor seeds of trees benevolence, and processing easy oxidation of back camellia seed kernel and corresponding increase acid value make the black of camellia seed kernel, and quality reduces, and the acid value that causes being extracted in the tea oil improves, and quality reduces.The high added value foreign exchange earning that improves tea seed is caused very big restriction.Even adopt to improve packing, the mode of adding conventional antistaling agent is carried out fresh-keeping, and its fresh-keeping effect is still not ideal enough, and easily produces the problem that chemical addition agent exceeds standard.Chinese patent publication number: CN1197111A, open day: on October 28th, 1998, denomination of invention: " grease compounded oxidation resistance fresh keeping agent ", proposed with TBHQ, citric acid, the citric acid isopropyl ester is the compounded oxidation resistance fresh keeping agent of principal component, have good heat endurance and security, but this technical scheme makes an addition to mainly in the liquid fluid, can't be applied to the oxidation resistanct fresh-keeping of dry fruit food such as grease class nut.
Summary of the invention
First purpose of the present invention be overcome existing food preservative difficulty can satisfy dry fruit food the fresh-keeping requirement of deoxidation defective and deficiency, a kind of food deoxidizing antistaling agent is provided, its deoxidation good refreshing effect, health is had no side effect, raw material sources are extensive, cost of manufacture is low, and is applied widely.
Second purpose of the present invention provides a kind of using method and camellia seed kernel deoxidation preservation method of food deoxidizing antistaling agent, and its technology is simple, adds easy to usely, and deoxidizing antistaling agent adds evenly, and adhesion amount is little, and effect is lasting, and cost of manufacture is low.
The technical solution of first purpose of the present invention is: a kind of food deoxidizing antistaling agent, the composition of each raw material and weight % are: ditert-butylhydro quinone 30%～40%, biphosphate is received powder 20%～30%, citric acid 15%～30%, active carbon 5%～35%.
The composition of described raw material and weight % are: ditert-butylhydro quinone 36%, biphosphate are received powder 23%, citric acid 18%, active carbon 23%.
The composition of described raw material and weight % are: ditert-butylhydro quinone 40%, biphosphate are received powder 29%, citric acid 26%, active carbon 5%.
The fineness of described active carbon is 100～200 orders.
The technical solution of second purpose of the present invention is: a kind of using method of food deoxidizing antistaling agent: earlier the food deoxidizing antistaling agent is added water and be mixed into the aqueous solution; The aqueous solution with the food deoxidizing antistaling agent adds in the processed food of drying processing then, mixes, again with processed food drying.
The present invention further proposes a kind of camellia seed kernel deoxidation preservation method, may further comprise the steps:
A. take by weighing the food deoxidizing antistaling agent by 0.02%～0.05% of green oil tea seed kernel weight, mix after adding water by 200%～500% of food deoxidizing antistaling agent weight;
B. the green oil tea seed kernel is sent into drying room, start air-heater, at 45 ℃～55 ℃ hot down baking green oil tea seed kernels, make the water content of green oil tea seed kernel reduce to 15%～13%, food deoxidizing antistaling agent liquid after dissolving from the air inlet dropping of air-heater then, after being added dropwise to complete, heat baking camellia seed kernel to its water content reduces to 11%～12% again, camellia seed kernel is sent drying room, get final product after the cooling.
Among the described step B, the green oil tea seed kernel sent into drying room after, be coated with cotton or chemical fabric on camellia seed kernel material surface towards drying room hot-blast outlet one side.
Among the described step B, the air inlet of air-heater is provided with the dropping liquid sebific duct, the other end of dropping liquid sebific duct is communicated with the bottom of food deoxidizing antistaling agent liquid container, and the dropping liquid sebific duct is provided with volume control device, and the rate of addition of described dropping liquid sebific duct is 1～5 liter/hour.
In the food deoxidizing antistaling agent of the present invention, ditert-butylhydro quinone (TBHQ) is a kind of oil-soluble inhibitor, mainly be to reach antioxidation, and have the effect of fresh-keeping mildew-resistant concurrently by the terminating chain transmission, safe, Heat stability is good, be widely used in edible oil and fat, can stop or postpone Oxidation of Fat and Oils and go bad, but have certain acute toxicity and chronic carcinogenesis, its addition should strictly limit, and the maximum use amount of national standard TBHQ is 0.2g/kg.
Sodium hydrogen phosphate (DSP) chemical formula: Na
2HPO
4.12H
2O another name: disodium, molecular weight: 358.0.Wherein 12 water things of sodium hydrogen phosphate are the white crystals body, relative density 1.52, and easy-weathering, 35 ℃ of fusions also lose 5 crystallizations water, become anhydride in the time of 100 ℃, become sodium pyrophosphate in the time of 250 ℃; Anhydride is a white powder, easily deliquescence; The two is all soluble in water, and the aqueous solution is alkalescent, is insoluble to alcohol.In food industry, be used to make baking powder, make quality improver, emulsifying agent, nutrition fortifier, fermentation assistant, binding agent.
Citric acid is first acid in the organic acid, because the performance of physical property, chemical property, derivative is to be widely used in the most important organic acids of industry such as food, medicine, daily use chemicals.Because citric acid has gentle frank tart flavour, generally is used for the manufacturing of food such as various beverages, carbonated drink, grape wine, candy, dessert, biscuit, canned fruit juice, dairy products.A part crystallization water citric acid also can be used as the antioxidant of edible oil mainly as the acidic flavouring agent of cold drink, fruit juice, jam, fruit drops and can etc.Improve the sensory properties of food simultaneously, whet the appetite and promote digesting and assimilating of calcium in the body, phosphorus substance.Anhydrous citric acid is used for solid beverage in a large number.The common use of citric acid and ditert-butylhydro quinone can strengthen the oxidation resistance of ditert-butylhydro quinone.
Active carbon is an a kind of class microcrystalline carbon materials of being made by carbonaceous material, and outward appearance is black, the prosperity of internal void structure, big, the high adsorption capacity of specific area.The invisible micropore of a large amount of naked eyes is arranged in the absorbent charcoal material, have a kind of effect of " physical absorption " and " chemisorbed " strongly.
Food deoxidizing antistaling agent of the present invention need add water and mix the back use.
By technique scheme, the invention has the beneficial effects as follows: 1. food deoxidizing antistaling agent of the present invention has adopted ditert-butylhydro quinone and has been used citric acid and biphosphate is received, and oxidation resistance is strong, helps promoting the quality and the quality of food.2. the present invention utilizes ditert-butylhydro quinone, biphosphate to receive and the characteristic of citric acid water dissolubility, Heat stability is good, the characteristic good with the active carbon physical adsorbability, it is modulated into the aqueous solution, after the active carbon physical absorption, together dry with food, its oxidation resistanct fresh-keeping material is attached to the surface of food, and consumption is few, the deoxidation good refreshing effect.3. through water-soluble and dry, active carbon inside is adsorbed with the oxidation resistanct fresh-keeping material, and attached to the surface of food, the drying that both can keep food, can improve the adhesive rate of deoxidation preservation liquid again at food surface, it is water-soluble to make ditert-butylhydro quinone, citric acid and the biphosphate of active carbon inside receive composition when absorbing the water in air molecule, can continue to bring into play the oxidation resistanct fresh-keeping effect, and the time of deoxidation preservation is longer.4. deoxidizing antistaling agent preparation of the present invention is convenient, and consumption is little, has no side effect, safe in utilization, its using method is easy, good refreshing effect, long fresh-keeping period is particularly suitable for as the deoxidation behind grease class nuts such as shelled peanut, camellia seed kernel, pinenut and the dry fruit food drying fresh-keeping.
The specific embodiment
The present invention is described in further detail below in conjunction with specific embodiment.
A kind of food deoxidizing antistaling agent of the present invention, the content of described raw material each component is: ditert-butylhydro quinone 30%～40%, biphosphate receive 20%～30%, citric acid 15%～30%, active carbon 5%～35%.Wherein, the fineness of described active carbon is 100～200 orders.Wherein biphosphate is received the requirement that should meet HG2920-2000 (food-grade).
The consumption of described ditert-butylhydro quinone is 30%～40%, and less than 30%, fresh-keeping effect reduces, and greater than 40%, the risk of edible safety increases.
The consumption that described biphosphate is received is 20%～30%, and is less than 20%, not obvious to the protective effect that reduces food acid value and outward appearance; the effect of quality improving is relatively poor; greater than 30%, influence original local flavor of food and color and luster easily, also be unfavorable for adjusting the acid-base value of deoxidizing antistaling agent.
The consumption of described citric acid is 15%～30%, and is less than 15%, not obvious to the catalysis and the palingenesis of ditert-butylhydro quinone, make its oxidation resistance be difficult to give full play to, greater than 30%, can increase the acid value of food, also be unfavorable for adjusting the acid-base value of deoxidizing antistaling agent.
The consumption of described active carbon is 5%～35%, less than 5%, entrained oxidation resistanct fresh-keeping material very little, food surface to adhere to density lower, be unfavorable for the formation of fresh-keeping anti-oxidant aspect, greater than 35%, easily form dust.
The using method of a kind of food deoxidizing antistaling agent of the present invention: earlier the food deoxidizing antistaling agent is added water and be mixed into the aqueous solution; The aqueous solution with the food deoxidizing antistaling agent adds in the processed food of drying processing then, mixes, again with processed food drying.
Camellia seed kernel deoxidation preservation method of the present invention may further comprise the steps:
A. take by weighing the food deoxidizing antistaling agent by 0.02%～0.05% of green oil tea seed kernel weight, mix after adding water by 200%～500% of food deoxidizing antistaling agent weight;
B. the green oil tea seed kernel is sent into drying room, start air-heater, at 45 ℃～55 ℃ hot down baking green oil tea seed kernels, make the water content of green oil tea seed kernel reduce to 15%～13%, food deoxidizing antistaling agent liquid after dissolving from the air inlet dropping of air-heater then, after being added dropwise to complete, heat baking camellia seed kernel to its water content reduces to 11%～12% again, camellia seed kernel is sent drying room, get final product after the cooling.Described air-heater is the power-equipment that hot blast is provided to drying room, the air inlet of air-heater is the cool air inlet that leads to atmosphere, the air outlet of air-heater is the hot air outlet that leads to drying room, cold air enters air-heater by air inlet, by being blown into the drying room from air outlet through blower fan, hot blast is discharged the hot-blast outlet of drying room heating back from drying room through heater heating back.After food deoxidizing antistaling agent liquid splashes into the air inlet of air-heater, be inhaled into heater with cold air, through flashing to gas and active carbon dust after the heating, be blown on drying room and the surface from air outlet by blower fan again attached to camellia seed kernel, form the fresh-keeping layer of deoxidation.
For making food deoxidizing antistaling agent gas in the hot blast more attached on the camellia seed kernel surface, can be in described step B, after the green oil tea seed kernel sent into drying room, be coated with cotton or chemical fabric on camellia seed kernel material surface towards drying room hot-blast outlet one side.Flow velocity during with reduction hot blast process camellia seed kernel increases the blast of hot blast to the camellia seed kernel particle, to improve the adhesive rate of food deoxidizing antistaling agent at the camellia seed kernel particle surface.
Among the described step B, the air inlet of air-heater is provided with the dropping liquid sebific duct, the other end of dropping liquid sebific duct is communicated with the bottom of food deoxidizing antistaling agent liquid container, and the dropping liquid sebific duct is provided with volume control device, and the rate of addition of described dropping liquid sebific duct is 1～5 liter/hour.Described dropping liquid sebific duct can be the structure the same with medical vein point drip apparatus with volume control device, quantitatively flows into the air inlet of air-heater continuously to guarantee dropping liquid.
Embodiment 1
Get 500 kilograms in fresh shelled peanut, fry and do its appearance moisture content; Get ditert-butylhydro quinone 4 gram, biphosphate is received 2.9 grams, citric acid 2.6 grams, fineness 100 purpose active carbons 0.5 gram, be mixed with the food deoxidizing antistaling agents of 10 grams, add water 100 gram and be mixed into the aqueous solution, then the food deoxidizing antistaling agent aqueous solution is added in the fresh shelled peanut after the stir-fry, mix, again the moisture content of shelled peanut appearance is fried and done, after the spreading for cooling that takes the dish out of the pot, in storage below 30 ℃, check the shelled peanut bright in color as before after half a year, do not detect and produce mildew and rotten shelled peanut particle.
Embodiment 2
Get 500 kilograms of fresh sunflower seeds, go into pot and fry to medium well; Get ditert-butylhydro quinone 3.5 grams, biphosphate receive 2.8 the gram, citric acid 2.2 grams, fineness 150 purpose active carbons 2.5 grams, be mixed with the food deoxidizing antistaling agents of 10 grams, add water 150 gram and be mixed into the aqueous solution, then the food deoxidizing antistaling agent aqueous solution is added in the sunflower seeds after the stir-fry, mix, again sunflower seeds is fried, after the spreading for cooling that takes the dish out of the pot, in storage below 30 ℃, check the sunflower seeds color and luster as before after half a year, the seed shell is clear-cut, the palatable crisp of its seed benevolence food, flavor delicate fragrance, free from extraneous odour, and do not detect the sunflower seeds particle that produces mildew and go bad.
Embodiment 3
Get 20000 kilograms of green oil tea seed kernels, the green oil tea seed kernel is sent into drying room, the top of drying room is a hot-blast outlet, surface coverage cotton or chemical fabric above the camellia seed kernel material, start air-heater, at 50 ℃ of hot down baking green oil tea seed kernels, make the water content of green oil tea seed kernel reduce to 15%～13% by about 20%; Press ditert-butylhydro quinone 36%, biphosphate receives 23%, citric acid 18%, and fineness 150 purpose active carbons 23% are mixed with the 1000 food deoxidizing antistaling agents that restrain, and add water 4000 grams and are mixed into the aqueous solution; The air inlet of air-heater is provided with the dropping liquid sebific duct, make the liquid droping port of dropping liquid sebific duct be positioned at the pipeline of air inlet, the other end of dropping liquid sebific duct is communicated with the bottom of food deoxidizing antistaling agent liquid container, adopt food deoxidizing antistaling agent liquid after the dropping liquid sebific duct drips dissolving from the air inlet of air-heater, rate of addition is 5 liters/hour, after being added dropwise to complete, heat baking camellia seed kernel is about 8～9 hours again, reduce to 11%～12% to its water content, to satisfy the water content requirement of outlet camellia seed kernel, camellia seed kernel is sent drying room, get final product after the cooling.In storage below 30 ℃, check the camellia seed kernel color and luster as before after half a year, there is not the blackout phenomenon, do not detect and produce mildew and rotten camellia seed kernel particle, the outgoing quality grade of its camellia seed kernel can improve 1 to 2 grade, obviously improves through neat benefit.
Embodiment 4
Get 20000 kilograms of green oil tea seed kernels, the green oil tea seed kernel is sent into drying room, the top of drying room is a hot-blast outlet, surface coverage cotton or chemical fabric above the camellia seed kernel material, start air-heater, heat baking green oil tea seed kernels are about 40 hours under 50 ℃, make the water content of green oil tea seed kernel reduce to 15%～13% by about 20%; Press ditert-butylhydro quinone 38%, biphosphate receives 20%, citric acid 15%, and fineness 200 purpose active carbons 27% are mixed with the 600 food deoxidizing antistaling agents that restrain, and add water 2400 grams and are mixed into the aqueous solution; The air inlet of air-heater is provided with the dropping liquid sebific duct, make the liquid droping port of dropping liquid sebific duct be positioned at the pipeline of air inlet, the other end of dropping liquid sebific duct is communicated with the bottom of food deoxidizing antistaling agent liquid container, adopt food deoxidizing antistaling agent liquid after the dropping liquid sebific duct drips dissolving from the air inlet of air-heater, rate of addition is 2 liters/hour, after being added dropwise to complete, heat baking camellia seed kernel is about 8～9 hours again, reduce to 11%～12% to its water content, to satisfy the water content requirement of outlet camellia seed kernel, camellia seed kernel is sent drying room, get final product after the cooling.In storage below 30 ℃, check the camellia seed kernel color and luster as before after half a year, there is not the blackout phenomenon, do not detect and produce mildew and rotten camellia seed kernel particle, the outgoing quality grade of its camellia seed kernel can improve 1 to 2 grade, obviously improves through neat benefit.
Claims (8)
1. food deoxidizing antistaling agent is characterized in that the composition of each raw material and weight % are: ditert-butylhydro quinone 30%～40%, biphosphate are received powder 20%～30%, citric acid 15%～30%, active carbon 5%～35%.
2. a kind of food deoxidizing antistaling agent according to claim 1 is characterized in that: the composition of described each raw material and weight % are: ditert-butylhydro quinone 36%, biphosphate are received powder 23%, citric acid 18%, active carbon 23%.
3. a kind of food deoxidizing antistaling agent according to claim 1 is characterized in that: the composition of described raw material and weight % are: ditert-butylhydro quinone 40%, biphosphate are received powder 29%, citric acid 26%, active carbon 5%.
4. according to each described a kind of food deoxidizing antistaling agent among the claim 1-3, it is characterized in that: the fineness of described active carbon is 100～200 orders.
5. the using method of each described a kind of food deoxidizing antistaling agent among the claim 1-4 is characterized in that may further comprise the steps: earlier the food deoxidizing antistaling agent is added water and be mixed into the aqueous solution; The aqueous solution with the food deoxidizing antistaling agent adds in the processed food of drying processing then, mixes, again with processed food drying.
6. use the camellia seed kernel deoxidation preservation method of each described a kind of food deoxidizing antistaling agent among the claim 1-4, it is characterized in that may further comprise the steps:
A. take by weighing the food deoxidizing antistaling agent by 0.02%～0.05% of green oil tea seed kernel weight, mix after adding water by 200%～500% of food deoxidizing antistaling agent weight;
B. the green oil tea seed kernel is sent into drying room, start air-heater, at 45 ℃～55 ℃ hot down baking green oil tea seed kernels, make the water content of green oil tea seed kernel reduce to 15%～13%, food deoxidizing antistaling agent liquid after dissolving from the air inlet dropping of air-heater then, after being added dropwise to complete, heat baking camellia seed kernel to its water content reduces to 11%～12% again, camellia seed kernel is sent drying room, get final product after the cooling.
7. camellia seed kernel deoxidation preservation method according to claim 6 is characterized in that: among the described step B, the green oil tea seed kernel sent into drying room after, be coated with cotton or chemical fabric on camellia seed kernel material surface towards drying room hot-blast outlet one side.
8. camellia seed kernel deoxidation preservation method according to claim 6, it is characterized in that: among the described step B, the air inlet of air-heater is provided with the dropping liquid sebific duct, the other end of dropping liquid sebific duct is communicated with the bottom of food deoxidizing antistaling agent liquid container, the dropping liquid sebific duct is provided with volume control device, and the rate of addition of described dropping liquid sebific duct is 1～5 liter/hour.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102652572A (en) * | 2012-05-17 | 2012-09-05 | 青岛宝泉花生制品有限公司 | Production method of peanuts wrapped with honey |
| CN105219173A (en) * | 2015-10-29 | 2016-01-06 | 苏州市灵通玻璃制品有限公司 | A kind of protection liquid for glass and using method thereof |
| CN105852008A (en) * | 2016-04-07 | 2016-08-17 | 浙江农林大学 | Processing method of torreya grandis |
| CN106900847A (en) * | 2017-03-14 | 2017-06-30 | 吉首大学 | The packed preservation method of camellia seed kernel |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1197111A (en) * | 1998-05-20 | 1998-10-28 | 卢少鹏 | Grease compounded oxidation resistance fresh keeping agent |
-
2009
- 2009-06-10 CN CN2009100626512A patent/CN101611916B/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102652572A (en) * | 2012-05-17 | 2012-09-05 | 青岛宝泉花生制品有限公司 | Production method of peanuts wrapped with honey |
| CN105219173A (en) * | 2015-10-29 | 2016-01-06 | 苏州市灵通玻璃制品有限公司 | A kind of protection liquid for glass and using method thereof |
| CN105852008A (en) * | 2016-04-07 | 2016-08-17 | 浙江农林大学 | Processing method of torreya grandis |
| CN106900847A (en) * | 2017-03-14 | 2017-06-30 | 吉首大学 | The packed preservation method of camellia seed kernel |
| CN106900847B (en) * | 2017-03-14 | 2020-05-19 | 吉首大学 | Bagged fresh-keeping method for camellia seed kernels |
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