CN101611210B - Intermetallic aluminide polycrystalline diamond compact (pdc) cutting elements - Google Patents

Intermetallic aluminide polycrystalline diamond compact (pdc) cutting elements Download PDF

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Publication number
CN101611210B
CN101611210B CN200880001859.7A CN200880001859A CN101611210B CN 101611210 B CN101611210 B CN 101611210B CN 200880001859 A CN200880001859 A CN 200880001859A CN 101611210 B CN101611210 B CN 101611210B
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aluminide
diamond
cutting
intermetallic
pdc
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CN101611210A (en
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Ww·金
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HOLEYBETON ENERGY SOURCE SERVICE CO
Halliburton Energy Services Inc
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HOLEYBETON ENERGY SOURCE SERVICE CO
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C26/00Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B10/00Drill bits
    • E21B10/46Drill bits characterised by wear resisting parts, e.g. diamond inserts
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B10/00Drill bits
    • E21B10/46Drill bits characterised by wear resisting parts, e.g. diamond inserts
    • E21B10/56Button-type inserts
    • E21B10/567Button-type inserts with preformed cutting elements mounted on a distinct support, e.g. polycrystalline inserts
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/963Surface properties, e.g. surface roughness

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Fluid Mechanics (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Physics & Mathematics (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Structural Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Metallurgy (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Earth Drilling (AREA)
  • Drilling Tools (AREA)
  • Catalysts (AREA)

Abstract

Machining and cutting tools including, but not limited to, rotary drill bits, mining tools, milling tools, wood shredders, reamers and wire dies formed with at least one substrate having a layer of polycrystalline diamond disposed thereon. The polycrystalline diamond layer may be generally described as a polycrystalline diamond compact (PDC) or PDC layer. The PDC may be formed by using an intermetallic aluminide catalyst. One example of such catalyst may include nickel aluminide used to form diamond to diamond bonds between adjacent diamond particles.

Description

Intermetallic aluminide polycrystalline diamond composite sheet (PDC) cutting part
The cross reference of related application
The application is No.60/883 according to the application number that 35U.S.C § 119 (e) requires to submit on January 8th, 2007,938, denomination of invention is the rights and interests of the U.S. Provisional Application of " intermetallic aluminide polycrystalline diamond composite sheet (PDC) cutting part ".
Technical field
The present invention relates to rotary drilling-head and relevant cutting part, and relate more specifically to fixedly cutting teeth (cut ter) drill bit and relevant cutting part and/or insert (insert), be furnished with the hard layer of cutting material at least a portion of described cutting part and/or insert.
Background technology
The polycrystalline diamond composition is researched and developed by General Electric (General Electric) at first.The early literatures that uses the super-pressure forcing press to make this composition is the US Patent No. 3,141,746 of De Lai.In the document, De Lai has described gang's metal, and in polycrystalline diamond composites (sometimes being called as " polycrystalline diamond composite sheet ") manufacturing (PDC), described metal can be for providing diamond and diamond bonding catalyzer.The described metallic catalyst of De Lai comprises iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium, platinum, titanium, chromium, manganese and tantalum.Can be clearly in document as developing at PDC, General Electric continues test various metals catalyst combination during the twentieth century sixties and the seventies.Nickel, aluminium and their alloy have been used as the binder catalyst of cubic boron nitride (CBN) composite sheet and PDC.
At twentieth century the mid-80, comprise nickel aluminide (Ni 3Al) compound-material begins to obtain the business application between interior novel metal.Before twentieth century the mid-80, due to intrinsic fragility with less than the hardness of desired value, the nickel aluminide usually is considered to almost there is no commercial value.Add approximately 1% boron to make it stronger or harder and have better ductility when keeping high capacity of heat transfer in the process of preparation intermetallic nickel aluminide (INA).The crucial patent in this field is the people's such as Huang patent US4,478,791.
Wittmer and Filip have made the immediate development about the bonding diamond of intermetallic compound (IBD), as described in the U.S. Patent Application Publication 2006/0280638 announced on December 14th, 2006 and the international publication number WO2006/107628 that announced on October 12nd, 2006 by WIPO, the nickel aluminide is disclosed as the application of binder material in the bonding diamond of intermetallic (IBD) preparation.Their work and observed result have been further described in other two pieces of open source literatures " FinalTechnical Report; on December 31,1 day to 2004 March in 2004 " and " Final TechnicalReport, on September 30,1 day to 2005 January in 2005 " for the project of " Intermetallic-BondedDiamond Tools for Coal Mining " by name.
Wittmer and Filip prepare the IBD compound with several different methods, comprising: heating, vacuum/pressurized sintering and high temperature insostatic pressing (HIP) in the stove with continuous-flow argon gas.High temperature insostatic pressing (HIP) is known in the art and is the technique that is generally used for making the impregnated with diamond cutter head (segment) of rotary drilling-head and other downhole tool.Such cutter head typically can comprise copper/Ni binder be used for boning mixture of tungsten-carbide powder and tiny diamond particles.Importantly, should be noted that IBD compound by Wittmer and Filip exploitation does not relate to diamond bonding but form inside and have the metallic binder of diamond particles with diamond.
Wittmer and Filip have provided some advantages of their IBD compound.As if these compounds than using copper/nickel alloy or other metal to have a higher repellence to heat is deteriorated as the compound of cementing agent.In addition, use the nickel aluminide as if can postpone usually can occur the graphited tendency of diamond under the graphited higher temperature of diamond when using copper/Ni binder.
Summary of the invention
An aspect of of the present present invention can comprise the super-pressure manufacturing of polycrystalline diamond composites (PDC), uses intermetallic aluminide as catalyzer and uses the PDC of process generation thus to form cutting part or insert.For example, can will be connected to by the PDC that uses intermetallic aluminide to form as catalyzer the PDC cutting teeth that substrate is used with the preparation rotary drilling-head at least in part.
PDC cutting teeth adduction of the present invention instruction can be benefited from the high capacity of heat transfer of intermetallic aluminide, compares the existing catalyzer cobalt for example that is used to form PDC.High capacity of heat transfer can alleviate intermetallic aluminide and diamond may affecting of the difference between the coefficient of expansion separately.The high capacity of heat transfer of intermetallic aluminide can with above-mentioned PDC in diamond crystal synergy, on the bit that dissipates fast or cutting face by fricative heat.
PDC cutting teeth adduction instruction of the present invention can be benefited from the situation that higher than typical temperature and the graphited ability of delay diamond that has iron class workpiece intermetallic aluminide.Past is because therefore diamond known ineffectivity in this is used comes the machine iron type materials with the cubic boron nitride cutting teeth.The hardness of cubic boron nitride and abrasion resistance usually are not so good as diamond but are better than diamond in the iron type materials machine are used.Use intermetallic aluminide can overcome the inadequacy in the past of PDC as the performance of the PDC cutting teeth of catalyzer manufacturing, thereby the machine iron type materials also can provide the excellence with respect to the cutting teeth of being made by cubic boron nitride to substitute satisfactorily.
Use the IBD compound of nickel aluminide can cut iron type materials, for example casting pig, use the cutting face that this IBD compound forms to have very little wearing and tearing in long-time the use.Be known that in the machine iron type materials diamond and iron type materials chemically reactive and the frictional interface place between Diamond Cutting parts and iron type materials are rapidly from separating or graphitization.When being formed by natural diamond, diamond, impregnated with diamond and PDC in the cutting face, situation is like this.Obviously, the IBD compound that uses the nickel aluminide to make can not occur this cutting face from separating or relevant adamantine graphitization.Obviously, by using the nickel aluminide can effectively stop in the cutting iron type materials is used from separating adamantine heat and/or chemical process to form PDC as binder material.
Description of drawings
Description below reading in conjunction with the drawings can obtain understanding more comprehensively and more thoroughly of embodiment of the present invention and advantage thereof, and identical Reference numeral represents identical feature in the accompanying drawings, wherein:
Accompanying drawing 1 is the schematic diagram that shows an embodiment of aluminide PDC cutting part of the present invention or the instruction of cutting teeth adduction;
Accompanying drawing 2 is the schematic cross-sections that show another embodiment of aluminide PDC cutting part of the present invention or the instruction of cutting teeth adduction;
Accompanying drawing 3 is to show to use the intermetallic aluminide catalyzer by the schematic cross-section of the local detachment of the hard cutting material layer of diamond pellet particle shape one-tenth.
The specific embodiment
Be appreciated that the preferred embodiments of the invention and various advantage by reference accompanying drawing 1-3.In each accompanying drawing, same Reference numeral is used for same and corresponding key element.
The term that uses in the application " rotary drilling-head " can comprise polytype: rock bit (rollercone drill bit), rotation tapering drill bit (rotary come drill bit), fixed cutter drill bits (fixed cutter drill bit), drag bit (drag bit), matrix drill bits (matrixdrill bit) and can extend through in order to formation the PDC drill bit of the well of one or more down-hole formations.Rotary drilling-head and the associated components that forms according to instruction of the present invention can have many different design and structures.Cutting part of the present invention also can be used for reamer, near-bit reamer and other downhole tool relevant to forming well with blade adduction feature.
The term that uses in the application " cutting part " can comprise various types of composite sheet, cutting teeth and/or the insert that is applicable to various rotary drilling-heads.Term " cutting teeth " can include but not limited to: building up by welding tooth (face cutter), gauge cutting teeth (gage cutter), inner cutting teeth (innercutter), shoulder cutting teeth (shoulder cutter), active gauge cutting teeth and passive gauge cutting teeth.
Polycrystalline diamond composite sheet (PDC), PDC cutting teeth and PDC insert usually are used as the cutting part of rotary drilling-head.The polycrystalline diamond composite sheet also can be called as the PDC composite sheet.
Use for some, the cutting part that forms according to instruction of the present invention can comprise one or more by using the intermetallic aluminide catalyzer to be formed on suprabasil polycrystalline diamond layer.Sometimes described layer can be called " cutting lay " or " platform layer (table) ".According to instruction of the present invention, can form cutting lay according to many kind structures, shape and size.The example of described structure and shape can include but not limited to " cutting surface ", " cutting edge ", " cutting face " and " truncated sides ".
The term that uses in the present invention " cutting structure " can comprise the various combination and permutation of cutting part, cutting teeth, building up by welding tooth, gauge cutting teeth, collision braking device (impact arrestor), protector, blade and/or the other parts of following instrument, as rotary drilling-head, coring bit, reamer be used to form other downhole tool of well.Some fixed cutter drill bits can comprise one or more blades that extend from relevant drill body.Cutting part is arranged on other outside of outside or relevant to fixed cutter drill bits drill body of blade with the form of row usually.According to instruction of the present invention, can be formed for the various structures of blade and cutting teeth the cutting structure of fixed cutter drill bits.
One embodiment of the invention can be included in uses the nickel aluminide as catalyzer in PDC cutting teeth preparation process.The nickel aluminide is not the exemplary alloy of nickel and aluminium, and opposite nickel aluminide means and is Ni 3The good orderly crystalline compound of Al.It is a kind of in emerging intermetallic aluminide material family, and described intermetallic aluminide also comprises iron aluminide, cobalt aluminide, titanium aluminide, nickel-platinum aluminide, Ni-Ti aluminide, niobium aluminide, ruthenium aluminide, scandium aluminide and zirconium aluminide.This process can comprise that filling has the unit of WC substrate, described WC substrate includes a small amount of cobalt (2%-15%), cover end or the part of described substrate with the mixture that uses intermetallic nickel aluminide powder and diamond particles, the size range of described diamond particles is about 3-60 micron.Use the diamond particles of preferred 5-25 micron for some.
Gained PDC can have approximately 50% to 95% the diamond volume percentage that accounts for each PDC cumulative volume.Use for some, the diamond volume percentage of 75%-92% is preferred.Substrate with mixture of diamond particles and intermetallic aluminide can be placed in the conventional vessel relevant to making the PDC cutting teeth.Then, can be placed into the unit of filling in the super-pressure forcing press and improve lasting certain period of pressure and temperature, as what describe in detail in known in prior art and document.Result obtains being more suitable for than the PDC cutting teeth of prior art the PDC cutting teeth that high temperature is used and/or the machine of iron type materials is used.
Accompanying drawing 1 has shown a kind of cutting part, and it comprises substrate and be furnished with the PDC layer on an end of substrate.As previously mentioned, can use the intermetallic aluminide catalyzer to obtain this PDC layer.
Use for some, the wafer of intermetallic nickel aluminide can be placed between end and intermetallic nickel aluminide and diamond particles mixture of powders of substrate.Described wafer can serve as baffle element to prevent that cobalt moves to PDC in a large number from substrate in pressing cycle.If too many cobalt enters into PDC in processing procedure, may reduce by the advantage of using the intermetallic aluminide catalyzer to bring.
Accompanying drawing 2 has shown a kind of cutting part, and it comprises layer or the wafer of the intermetallic aluminide that is arranged between end of substrate and relevant PDC layer.As previously mentioned, can use intermetallic aluminide to form this PDC layer.The substrate that shows as accompanying drawing 1-2 can be formed by many kinds of materials, includes but not limited to tungsten carbide (WC).
Use the PDC cutting teeth that instruction of the present invention is made be specially adapted to rock-boring instrument, down-hole drilling and reaming tool, mining tool, iron class and nonferrous material machinery tools, wire drawing die, timber processing and be used for the diamond saw blade that rock gathers.
Although described the present invention and advantage thereof in detail, should be understood that, in the situation that do not deviate from the scope of the invention that purport of the present invention and following claim limit, can make multiple change, replacement and substitute.

Claims (14)

1. cutting part comprises:
Substrate with first end, be furnished with one deck polycrystalline diamond composite sheet at least on it, described polycrystalline diamond composite sheet is partly by forming diamond and diamond is bonding forms between adjacent diamond particles as catalyzer with intermetallic aluminide; With
Be arranged in the first end of described substrate and the layer of the intermetallic aluminide between the described polycrystalline diamond of one deck at least composite sheet.
2. cutting part as claimed in claim 1, wherein said intermetallic aluminide catalyzer comprises the nickel aluminide.
3. cutting part as claimed in claim 1, wherein said intermetallic aluminide catalyzer chosen from Fe aluminide, cobalt aluminide, titanium aluminide, nickel-platinum aluminide, Ni-Ti aluminide, niobium aluminide, ruthenium aluminide, scandium aluminide and zirconium aluminide.
4. cutting part as described in any one in claim 1-3, the layer of wherein said intermetallic aluminide is intermetallic nickel aluminide.
5. cutting part as claimed in claim 1, also comprise: a plurality of void spaces that form between by diamond and the bonding and mutual bonding adjacent diamond particles of diamond, wherein intermetallic aluminide is arranged in the void space that forms between adjacent diamond particles.
6. cutting part as described in any one in claim 1-3, these parts are for the fixing insert of cutting teeth rotary drilling-head.
7. downhole tool, described downhole tool is rotary drilling-head, reamer, Tapper or coring bit, the part of downhole tool as described in wherein cutting part as described in claim 1-6 any one consists of.
8. downhole tool as claimed in claim 7, wherein said reamer is near-bit reamer.
9. instrument, described instrument is mining tool, the machinery tools that are used for the cutting iron type materials, the machinery tools that are used for the cutting nonferrous material, be used for the machinery tools of converted timber and other fibrous material or be used for the saw blade of cutting building stones, described instrument comprises on its at least a portion as the described cutting part of claim 1-6 any one.
10. instrument as claimed in claim 9, wherein said instrument are the saw blades for cutting limestone or granite.
11. be used for forming at down-hole formation the rotary drilling-head of well, comprise:
Drill body, it has to be connected to an end of drill string;
Be arranged in a plurality of as the described cutting part of claim 1-6 any one on the drill body outside.
12. rotary drilling-head as claimed in claim 11, wherein at least one substrate has the circular cross-section of being roughly.
13. rotary drilling-head as claimed in claim 11, wherein at least one substrate has the noncircular cross section of being roughly.
14. drill bit as claimed in claim 11, wherein:
Described drill bit has the bit face profile of the back taper structure relative with a described end of drill body;
The opening that forms in drill body, it is next to the reverse taper portion of bit face profile;
Described drill bit also comprises the cylinder that extends from substrate; And
Described cylinder is arranged in the described opening of drill body, together with the described layer of polycrystalline diamond composite sheet in order to act on the earth formation material contiguous with the reverse taper portion of bit face profile.
CN200880001859.7A 2007-01-08 2008-01-07 Intermetallic aluminide polycrystalline diamond compact (pdc) cutting elements Expired - Fee Related CN101611210B (en)

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US88393807P 2007-01-08 2007-01-08
US60/883,938 2007-01-08
PCT/US2008/050402 WO2008086284A2 (en) 2007-01-08 2008-01-07 Intermetallic aluminide polycrystalline diamond compact (pdc) cutting elements

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CN101611210B true CN101611210B (en) 2013-05-15

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WO2008086284A3 (en) 2008-10-30
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CA2674469A1 (en) 2008-07-17

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