CN101599314A - A kind of environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material - Google Patents
A kind of environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material Download PDFInfo
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- CN101599314A CN101599314A CNA2008100385615A CN200810038561A CN101599314A CN 101599314 A CN101599314 A CN 101599314A CN A2008100385615 A CNA2008100385615 A CN A2008100385615A CN 200810038561 A CN200810038561 A CN 200810038561A CN 101599314 A CN101599314 A CN 101599314A
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- flame retardant
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- thermoplastic polyurethane
- polyurethane elastomer
- cable material
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Abstract
The present invention relates to a kind of environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material, this CABLE MATERIALS comprises following component and content (weight portion): TPUE 100; Viscosity modifier 5-30; Fire retardant 15-40; Delustering agent 2-10; Antioxidant 0.5-5.0; Lubricant 1-5; Other auxiliary agent 1-8.Compared with prior art, environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material of the present invention has adopted advanced modification technology, solved the viscosity with temperature of TPU in course of processing characteristic jumpy, the processing temperature zone is brought up to about 30 ℃ by original about 5 ℃, make it more easy to control when producing, obtain the good surface of extruding, adopted high-quality environmental protection flame retardant compound system and advanced delustring technology simultaneously, the mute light effect of cloudy surface that has reached after UL94 V0 flame retardant rating and TPU extrude is good.
Description
Technical field
The present invention relates to CABLE MATERIALS, relate in particular to a kind of environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material.
Background technology
Environmentally-friendly flame retardant thermoplastic polyurethane elastomer (TPU) CABLE MATERIALS, be a kind ofly to have the characteristic of rubber and need not the crosslinked thermoplastic that can process repeatedly, it has fabulous toughness, resistance to wear, oil resistance, low temperature flexibility, elasticity, thermal stability and mechanical property, can be widely used in power source cable, communication cable, automobile cable, geographical exploration cable, shipboard cable and other spring wire, image and tone frequency channel wire or the like of requirement softness, wear-resisting, oil resistant etc.Particularly along with harsh day by day environmental requirement, the TPU material of environmental protection just progressively replaces a lot of materials such as PVC, rubber etc. on different cables, extreme environment is as towing, the cable that drags on ice and snow on the ground of rock in the open air, and TPU will demonstrate impayable advantage.
There is following difficult point in the technology of present environmentally-friendly flame retardant thermoplastic polyurethane elastomer (TPU) CABLE MATERIALS: 1. the processing temperature zone is very narrow, and is very responsive to temperature, is difficult to extrude; 2.TPU fusion drip phenomenon is serious when burning, reach very difficulty of high level anti-flammability; 3.TPU material behavior for being bright characteristic after extruding, and customer demand mostly is atomized surface effect greatly, delustring is very difficult.
Therefore, though TPU CABLE MATERIALS market demand heightens in recent years, but because the technical difficulty of environmentally-friendly flame retardant thermoplastic polyurethane elastomer (TPU) CABLE MATERIALS is very big at present, domestic still do not have a production firm, a large amount of demands relies on expensive imported product fully, makes production cost can not be in any more.
Summary of the invention
Purpose of the present invention is exactly to provide in order to overcome the defective that above-mentioned prior art exists that a kind of processing temperature zone is wide, the environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material of good flame retardation effect.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material is characterized in that, this CABLE MATERIALS comprises following component and content (weight portion):
TPUE 100;
Viscosity modifier 5-30;
Fire retardant 15-40;
Delustering agent 2-10;
Antioxidant 0.5-5.0;
Lubricant 1-5;
Other auxiliary agent 1-8.
Described TPUE comprises the ternary block polymer of vulcabond and macromolecular diol and butanediol.
The chemical type of described TPUE is a polyether-type, and hardness range is at shoreA70-90.
Described viscosity modifier comprises ethene and vinyl acetate copolymer, ethene and acrylate copolymer, ethene and hexene copolymer, ethylene-butylene copolymer.
Described fire retardant comprises bromide fire retardant, Sb system fire retardant, nitrogen flame retardant, phosphorus flame retardant, phosphor nitrogen combustion inhibitor, organic silicon fibre retardant.
Described delustering agent is a silicon compound, comprises silicon dioxide etc.
Described antioxidant comprises Hinered phenols antioxidant, suffocated amine antioxidant, phosphite ester kind antioxidant.
Described lubricant comprises organo-silicic oil, PE wax, PP wax, aliphatic acid, soap.
Described other auxiliary agent comprises matal deactivator, light stabilizer, colouring agent.
Compared with prior art, environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material of the present invention has adopted advanced modification technology, solved the viscosity with temperature of TPU in course of processing characteristic jumpy, the processing temperature zone is brought up to about 30 ℃ by original about 5 ℃, make it more easy to control when producing, obtain the good surface of extruding, adopted high-quality environmental protection flame retardant compound system and advanced delustring technology simultaneously, the mute light effect of cloudy surface that has reached after UL94 V0 flame retardant rating and TPU extrude is good.
Embodiment
The invention will be further described below in conjunction with specific embodiment.
Embodiment 1～5, a kind of environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material, and its prescription is as follows:
In the foregoing description 1: described TPUE (TPU) is the ternary block polymer of vulcabond and macromolecular diol and butanediol, chemical type is a polyether-type, hardness range is at shoreA70-90, described viscosity modifier is ethene and vinyl acetate copolymer EVA, described fire retardant is bromide fire retardant TDE or deca-BDE, described delustering agent is a silicon dioxide, described antioxidant is Hinered phenols antioxidant antioxidant 1010 or antioxidant 1076, described lubricant is an organo-silicic oil silicone oil, and described other auxiliary agent is matal deactivator N-salicylidene-N ' salicylyl hydrazine (being called for short SSE), light stabilizer 2-hydroxyl-4-methoxy benzophenone (UV-9) and colorant pigment Huang 139 (weight ratio is 1: 1: 1).
In the foregoing description 2: described TPUE (TPU) is the ternary block polymer of vulcabond and macromolecular diol and butanediol, chemical type is a polyether-type, hardness range is at shoreA70-90, described viscosity modifier is ethene and methyl acrylate copolymer EMA, described fire retardant is Sb system fire retardant alchlor antimony or alchlor antimony, described delustering agent is a silicon dioxide, described antioxidant is suffocated amine antioxidant N, N '-six methine two-3 (3,5 di-t-butyls-4 hydroxy phenyl) propionamide (being called for short HBP), described lubricant is a PE wax, described other auxiliary agent is 1,2 pair of matal deactivator (2-(2-hydroxybenzoyl)) hydrazine (being called for short BHH), red 151 (weight ratio is 1: 2: 3) of light stabilizer benzotriazole UV-P and colorant pigment.
In the foregoing description 3: described TPUE (TPU) is the ternary block polymer of vulcabond and macromolecular diol and butanediol, chemical type is a polyether-type, hardness range is at shoreA70-90, described viscosity modifier is ethene and hexene copolymer, described fire retardant is a nitrogen flame retardant melamine cyanurate, described delustering agent is a silicon dioxide, described antioxidant is phosphite ester kind antioxidant three (nonyl is for phenyl) phosphite ester (being called for short TNP) or three (2, the 4-di-tert-butyl-phenyl) phosphite ester (being called for short TBP), described lubricant is a PP wax, described other auxiliary agent is N, the two hydrazines of N '-diethyl phthalidyl sulfo-dipropyl phthalidyl (being called for short DTD), red 242 (weight ratio is 3: 1: 1) of hindered amine light stabilizer and colorant pigment.
In the foregoing description 4: described TPUE (TPU) is the ternary block polymer of vulcabond and macromolecular diol and butanediol; chemical type is a polyether-type; hardness range is at shoreA70-90; described viscosity modifier is an ethylene-butylene copolymer; described fire retardant is phosphorus flame retardant tricresyl phosphate phenol or xylenylphosphate; described delustering agent is a silicon dioxide; described antioxidant is Hinered phenols antioxidant 2; the 6-di-tert-butyl-4-methy phenol; described lubricant is a stearic acid; described other auxiliary agent is matal deactivator N; N '-diacetyl adipyl base two hydrazides (being called for short DAD); light stabilizer 2,2 '-dihydroxy-4-methoxy benzophenone (UV-24) and colorant pigment orange 43 (weight ratio is 2: 4: 1).
In the foregoing description 5: described TPUE (TPU) is the ternary block polymer of vulcabond and macromolecular diol and butanediol, chemical type is a polyether-type, hardness range is at shoreA70-90, described viscosity modifier is ethene and ethyl acrylate copolymer EEA, described fire retardant is organic silicon fibre retardant SFR100 (General Electric Apparatus Co.'s production) or phosphor nitrogen combustion inhibitor N, N '-piperazine two (neopentyl glycol) phosphoramidate, described delustering agent is a silicon dioxide, described antioxidant is suffocated amine antioxidant 4,4 ' two uncle's octyl diphenylamines (being called for short DOD), described lubricant is zinc stearate or barium stearate, described other auxiliary agent is matal deactivator N-salicylidene-N ' salicylyl hydrazine (being called for short SSE), light stabilizer 2 (2-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl)-5-chlorinated benzotriazole (UV-328) and colorant pigment indigo plant 60 (weight ratio is 1: 1: 2).
The performance index of environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material of the present invention are as follows:
Claims (9)
1. an environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material is characterized in that, this CABLE MATERIALS comprises following component and content (weight portion):
TPUE 100;
Viscosity modifier 5-30;
Fire retardant 15-40;
Delustering agent 2-10;
Antioxidant 0.5-5.0;
Lubricant 1-5;
Other auxiliary agent 1-8.
2. a kind of environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material according to claim 1 is characterized in that described TPUE comprises the ternary block polymer of vulcabond and macromolecular diol and butanediol.
3. a kind of environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material according to claim 1 is characterized in that the chemical type of described TPUE is a polyether-type, and hardness range is at shoreA70-90.
4. a kind of environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material according to claim 1, it is characterized in that described viscosity modifier comprises ethene and vinyl acetate copolymer, ethene and acrylate copolymer, ethene and hexene copolymer, ethylene-butylene copolymer.
5. a kind of environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material according to claim 1 is characterized in that, described fire retardant comprises bromide fire retardant, Sb system fire retardant, nitrogen flame retardant, phosphorus flame retardant, phosphor nitrogen combustion inhibitor, organic silicon fibre retardant.
6. a kind of environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material according to claim 1 is characterized in that described delustering agent is a silicon compound, comprises silicon dioxide etc.
7. a kind of environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material according to claim 1 is characterized in that described antioxidant comprises Hinered phenols antioxidant, suffocated amine antioxidant, phosphite ester kind antioxidant.
8. a kind of environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material according to claim 1 is characterized in that, described lubricant comprises organo-silicic oil, PE wax, PP wax, aliphatic acid, soap.
9. a kind of environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material according to claim 1 is characterized in that, described other auxiliary agent comprises matal deactivator, light stabilizer, colouring agent.
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| CN2008100385615A CN101599314B (en) | 2008-06-05 | 2008-06-05 | Environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material |
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| CN2008100385615A CN101599314B (en) | 2008-06-05 | 2008-06-05 | Environmentally-friendly flame retardant thermoplastic polyurethane elastomer cable material |
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| CN101599314A true CN101599314A (en) | 2009-12-09 |
| CN101599314B CN101599314B (en) | 2011-07-20 |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382411A (en) * | 2010-08-30 | 2012-03-21 | 浙江万马电缆股份有限公司 | Twisting-resistant flexible cable sheath material for wind power generation, as well as preparation method and application thereof |
| CN102812523A (en) * | 2011-03-25 | 2012-12-05 | 富士高分子工业株式会社 | Wire array rubber connector and method for producing the same |
| CN103087505A (en) * | 2012-12-21 | 2013-05-08 | 安徽科聚新材料有限公司 | Thermoplastic polyurethane elastomer material and preparation method thereof |
| CN103483805A (en) * | 2013-09-08 | 2014-01-01 | 安徽万博电缆材料有限公司 | Formula of environment-friendly cable insulation layer material |
| CN103525076A (en) * | 2013-10-12 | 2014-01-22 | 绿宝电缆（集团）有限公司 | Halogen-free low-smoke flame-retardant TPE cable material |
| CN103540075A (en) * | 2012-07-18 | 2014-01-29 | 苏州朗创化工有限公司 | Highly flame-retardant TPE (Thermoplastic Polyurethane Elastomer) material |
| CN103756283A (en) * | 2013-12-31 | 2014-04-30 | 上海至正道化高分子材料有限公司 | Low-smoke halogen-free flame retardant oil-resistance super-soft elastomer cable material and preparation method thereof |
| CN103881360A (en) * | 2014-02-14 | 2014-06-25 | 安徽旺达铜业发展有限公司 | Thermoplastic polyurethane elastomer cable sheath material and preparation method thereof |
| CN104231220A (en) * | 2014-09-18 | 2014-12-24 | 东莞市吉鑫高分子科技有限公司 | Anti-yellowing transparent TPU (thermoplastic polyurethane) elastomer and preparation method thereof |
| CN104871255A (en) * | 2012-12-18 | 2015-08-26 | 帝斯曼知识产权资产管理有限公司 | The invention relates to an electrical cable comprising a cable cover |
| CN106366635A (en) * | 2016-08-31 | 2017-02-01 | 苏州亨利通信材料有限公司 | Easy-processing halogen-free flame retardant TPU elastomer and preparation method thereof |
| CN107882988A (en) * | 2016-09-23 | 2018-04-06 | 成都九十度工业产品设计有限公司 | A kind of elastane |
| CN108102210A (en) * | 2018-02-07 | 2018-06-01 | 合肥安力电力工程有限公司 | A kind of Environment-friendlyflame-retardant flame-retardant cable material and preparation method thereof |
| CN109036707A (en) * | 2018-07-02 | 2018-12-18 | 安徽坤和电气有限公司 | The preparation method of anti-corrosion cable |
| CN109280358A (en) * | 2018-09-10 | 2019-01-29 | 河北邦泰氨纶科技有限公司 | A kind of flame-proof thermoplastic polyurethane composition |
| CN110144112A (en) * | 2019-05-13 | 2019-08-20 | 浙江万马聚力新材料科技有限公司 | Halogen-free cable material and preparation method thereof and cable comprising the halogen-free cable material |
| CN112375371A (en) * | 2020-10-16 | 2021-02-19 | 深圳市沃尔核材股份有限公司 | TPU (thermoplastic polyurethane) sheath material for charging cable and preparation and application thereof |
| CN115215995A (en) * | 2022-08-19 | 2022-10-21 | 东莞理工学院 | Phosphorus-nitrogen-containing hindered phenol-based flame retardant and preparation method and application thereof |
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| CN2893872Y (en) * | 2006-03-05 | 2007-04-25 | 江苏亨通电力电缆有限公司 | Polyurethane insulation and shield sleeve flame resisting moving power supply soft cable |
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Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382411B (en) * | 2010-08-30 | 2012-11-28 | 浙江万马电缆股份有限公司 | Twisting-resistant flexible cable sheath material for wind power generation, as well as preparation method and application thereof |
| CN102382411A (en) * | 2010-08-30 | 2012-03-21 | 浙江万马电缆股份有限公司 | Twisting-resistant flexible cable sheath material for wind power generation, as well as preparation method and application thereof |
| CN102812523B (en) * | 2011-03-25 | 2014-09-10 | 富士高分子工业株式会社 | Wire array rubber connector and method for producing the same |
| CN102812523A (en) * | 2011-03-25 | 2012-12-05 | 富士高分子工业株式会社 | Wire array rubber connector and method for producing the same |
| US9160094B2 (en) | 2011-03-25 | 2015-10-13 | Fuji Polymer Industries Co., Ltd. | Wire array rubber connector and method for producing the same |
| CN103540075A (en) * | 2012-07-18 | 2014-01-29 | 苏州朗创化工有限公司 | Highly flame-retardant TPE (Thermoplastic Polyurethane Elastomer) material |
| CN104871255A (en) * | 2012-12-18 | 2015-08-26 | 帝斯曼知识产权资产管理有限公司 | The invention relates to an electrical cable comprising a cable cover |
| CN103087505A (en) * | 2012-12-21 | 2013-05-08 | 安徽科聚新材料有限公司 | Thermoplastic polyurethane elastomer material and preparation method thereof |
| CN103483805B (en) * | 2013-09-08 | 2015-09-16 | 安徽万博电缆材料有限公司 | A kind of formula of environment-friendlycable cable insulation layer material |
| CN103483805A (en) * | 2013-09-08 | 2014-01-01 | 安徽万博电缆材料有限公司 | Formula of environment-friendly cable insulation layer material |
| CN103525076A (en) * | 2013-10-12 | 2014-01-22 | 绿宝电缆（集团）有限公司 | Halogen-free low-smoke flame-retardant TPE cable material |
| CN103525076B (en) * | 2013-10-12 | 2016-03-02 | 绿宝电缆（集团）有限公司 | A kind of Halogen-free low-smoke flame-retardant TPE cable material |
| CN103756283A (en) * | 2013-12-31 | 2014-04-30 | 上海至正道化高分子材料有限公司 | Low-smoke halogen-free flame retardant oil-resistance super-soft elastomer cable material and preparation method thereof |
| CN103881360A (en) * | 2014-02-14 | 2014-06-25 | 安徽旺达铜业发展有限公司 | Thermoplastic polyurethane elastomer cable sheath material and preparation method thereof |
| CN104231220A (en) * | 2014-09-18 | 2014-12-24 | 东莞市吉鑫高分子科技有限公司 | Anti-yellowing transparent TPU (thermoplastic polyurethane) elastomer and preparation method thereof |
| CN106366635A (en) * | 2016-08-31 | 2017-02-01 | 苏州亨利通信材料有限公司 | Easy-processing halogen-free flame retardant TPU elastomer and preparation method thereof |
| CN107882988A (en) * | 2016-09-23 | 2018-04-06 | 成都九十度工业产品设计有限公司 | A kind of elastane |
| CN108102210A (en) * | 2018-02-07 | 2018-06-01 | 合肥安力电力工程有限公司 | A kind of Environment-friendlyflame-retardant flame-retardant cable material and preparation method thereof |
| CN109036707A (en) * | 2018-07-02 | 2018-12-18 | 安徽坤和电气有限公司 | The preparation method of anti-corrosion cable |
| CN109280358A (en) * | 2018-09-10 | 2019-01-29 | 河北邦泰氨纶科技有限公司 | A kind of flame-proof thermoplastic polyurethane composition |
| CN110144112A (en) * | 2019-05-13 | 2019-08-20 | 浙江万马聚力新材料科技有限公司 | Halogen-free cable material and preparation method thereof and cable comprising the halogen-free cable material |
| CN110144112B (en) * | 2019-05-13 | 2021-11-23 | 浙江万马聚力新材料科技有限公司 | Halogen-free cable material, preparation method thereof and cable containing halogen-free cable material |
| CN112375371A (en) * | 2020-10-16 | 2021-02-19 | 深圳市沃尔核材股份有限公司 | TPU (thermoplastic polyurethane) sheath material for charging cable and preparation and application thereof |
| CN115215995A (en) * | 2022-08-19 | 2022-10-21 | 东莞理工学院 | Phosphorus-nitrogen-containing hindered phenol-based flame retardant and preparation method and application thereof |
| CN115215995B (en) * | 2022-08-19 | 2023-07-18 | 东莞理工学院 | Hindered phenol-based flame retardant containing phosphorus and nitrogen as well as preparation method and application thereof |
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| CN101599314B (en) | 2011-07-20 |
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Address after: 200331, 1-6, 599 Willow Road, Shanghai, Putuo District Patentee after: Shanghai Sirui Technology Co., Ltd. Address before: 200331, 1-6, 599 Willow Road, Shanghai, Putuo District Patentee before: Shanghai Surrey Polymers Co., Ltd. |
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Effective date of registration: 20190201 Address after: No. 599 Liuyuan Road, Putuo District, Shanghai, 2003 Patentee after: Shanghai Sri Cable New Material Technology Co., Ltd. Address before: Building No.1-6, 599 Liuyuan Road, Putuo District, Shanghai, 2003 Patentee before: Shanghai Sirui Technology Co., Ltd. |