CN104004330A - High weather resistant, halogen-free and flame retardant PC/ABS alloy material special for outdoor telecommunication box and preparation method thereof - Google Patents
High weather resistant, halogen-free and flame retardant PC/ABS alloy material special for outdoor telecommunication box and preparation method thereof Download PDFInfo
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/72—Measuring, controlling or regulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7461—Combinations of dissimilar mixers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92904—Die; Nozzle zone
Abstract
The invention discloses a high weather resistant, halogen-free and flame retardant PC/ABS (polycarbonate/acrylonitrile-butadiene-styrene) alloy material special for an outdoor telecommunication box and a preparation method thereof. The PC/ABS alloy material is prepared from the following raw materials by weight percentage: 60%-80% of polycarbonate resin; 0.1%-10% of acrylonitrile-butadiene-styrene resin; 0.1%-5% of a compatibilizer; 2%-10% of triphenyl phosphate; 2%-10% of resorcinol (diphenyl phosphate); 0.1%-1% of an anti-dripping agent; 0.1%-2% of a light stabilizer; and 0.1%-2% of assistants. According to the invention, the PC and ABS resin with good weather resistance are adopted as the matrix, and through synergy of the compatilizer, the halogen-free flame retardants and the light stabilizer, the halogen-free and flame retardant PC/ABS alloy material with high heat resistance and high performance can be obtained, and can be widely used in the communications industry, the automobile industry, building materials, decoration materials, cables and the electrical industry. The preparation method of the alloy material adopts existing equipment, is simple to operate, and is suitable for industrialized production.
Description
Technical field
The invention belongs to chemical field, relate in particular to a kind of alloy material, be specifically related to the special high Weather resistant halogen-free flame retardant PC/ABS alloy material of a kind of electrical outdoor mailbox and preparation method.
Background technology
Polycarbonate (PC) and acrylonitrile-butadiene-styrene copolymer (ABS) blend are by a certain percentage made to PC/ABS alloy, it is suitability for industrialized production the earliest, the most ripe at present, most widely used general, a kind of PC modified product of output maximum, comprehensively both premium propertiess of such alloy: can improve on the one hand thermotolerance, shock resistance and the tensile property of ABS, replace ABS for high-performance field; Can reduce on the other hand cost and the melt viscosity of PC, improve its processing characteristics, reduce goods internal stress and the susceptibility of shock strength to products thickness, be the comprehensive polymer alloy of a kind of performance.
It is the application of fire retardation PC/ABS alloy in a lot of industries that the Rolls that European Union puts into effect for 2003 and two instruction cloth of WEEE have limited halogen, particularly the American-European restriction that computer casing material fire retardant is used in recent years.Therefore, research and development efficient and environment-friendly type halogen-free flame retardant PC/ABS alloy day by day becomes the focus of flame retardant area research.
The communicating appliance of flame-proof environmental protection, due to PC/ABS good electrical insulating property, is widely used in the field of telecommunication devices of communicating by letter, especially electrical outdoor mailbox material; But because this material is life-time service out of doors, this just requires material require to have extraordinary weather resistance, and the fire-retardant V-2 of PC resin could meet V-0 but PC/ABS alloy material must add external fire retardant.It is the application of fire retardation PC/ABS alloy in a lot of industries that the Rolls that European Union puts into effect for 2003 and two instruction cloth of WEEE have limited halogen.In ABS resin, divinyl component contains two keys, easy molecular scission under long-term illumination condition, and weathering resistance is poor.While causing light PC/ABS product to use out of doors, there is variable color risk, affect product appearance.And the adding of halogen-free flame retardants, weathering process that again can accelerated material, causes bad impact to the weather resistance of material.Therefore, research and develop weather-proof high performance halogen-free flame-retardant PC/ABS alloy and day by day become the focus of flame retardant area research.Especially outdoor product, for example: telecommunications, the outdoor case such as movement; Due to the long-term effect in illumination, this just requires material must have excellent weather resistance, so it is significant to develop a kind of weather-proof high performance halogen-free flame-retardant PC/ABS alloy material.
Summary of the invention
The object of the present invention is to provide the special high Weather resistant halogen-free flame retardant PC/ABS alloy material of a kind of electrical outdoor mailbox and preparation method, the special high Weather resistant halogen-free flame retardant alloy material of described this electrical outdoor mailbox and preparation method will solve PC/ABS alloy material weathering resistance of the prior art and the not good technical problem of flame retardant effect.
The special high Weather resistant halogen-free flame retardant PC/ABS alloy material of electrical outdoor mailbox of the present invention, made by the raw material of following mass percent:
Further, described PC resin is the weather-proof good polycarbonate trade mark, is 5g/10min～25g/10min at 300 DEG C, melting index when load 1.2Kg; Concrete, the PC1250Z100, the PC1225Z100 etc. that change into as Supreme Being people.
Further, in described acrylonitrile-butadiene-styrene copolymer resin, described divinyl quality percentage composition is between 18-20%.Concrete, described ABS is the good trade mark of weathering resistance (being the trade mark that butadiene content is lower).As the ABS PA-758 of strange U.S..
Further, described compatilizer is selected from styrene butadiene thermoplasticelastomer, methyl methacrylate-divinyl-styrene copolymer, any one in polyester elastomer, polyolefin elastomer or MBS (terpolymer of methyl methacrylate (M)-divinyl (B)-vinylbenzene (S)).
Further, the acid number (mgKOH/g)≤0.10 of described triphenylphosphate (TPP), quality percentage composition %>99.0.
Further, described Resorcinol (diphenyl phosphoester) (RDP) in, described phenol content (ppm)≤500, fusing point (DEG C) >=90.
Further, described anti-dripping agent is modified polytetrafluoroethylparticles particles, makes PFOA, NP content reduce to minimum, meets stricter environmental protection standard.Concrete, as
sN3307.Described modified polytetrafluoroethylparticles particles is elite ST-AN coating material, has excellent consistency with PC and ABS engineering plastics.
Further, described photostabilizer is UV-5411.UV-3450, UV-531, two or more in AO-2777.
Further, described processing aid comprises primary antioxidant, auxiliary antioxidant, internal lubricant and external lubricant; Described primary antioxidant is β-(3,5-di-tert-butyl-hydroxy phenyl) the positive octadecanol ester of propionic acid, four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, two (2,4-di-tert-butyl-phenyl) tetramethylolmethane or 2,6 ditertiary butyl p cresol; Described auxiliary antioxidant is the two stearic alcohol esters of three (2,4-di-tert-butyl-phenyl) phosphorous acid ester, sulfo-three propionic acid two lauryls or thio-2 acid; Described internal lubricant is E wax, calcium stearate or PE wax; Described external lubricant is one or more in silicone master batch, silicone powder, pentaerythritol stearate.
The present invention also provides the preparation method of the above-mentioned special high Weather resistant halogen-free flame retardant PC/ABS alloy material of a kind of electrical outdoor mailbox, comprises the following steps:
After being mixed, raw material joins extruding pelletization in twin screw extruder, twin screw extruder is respectively to the temperature of head by feed zone: 160 DEG C ± 10 DEG C, 200 DEG C ± 10 DEG C, 260 DEG C ± 10 DEG C, 260 DEG C ± 10 DEG C, 255 DEG C ± 10 DEG C, 250 DEG C ± 10 DEG C, 250 DEG C ± 10 DEG C, 250 DEG C ± 10 DEG C, 250 DEG C ± 10 DEG C, and die head: 260 DEG C ± 10 DEG C;
Then through water-cooled, pelletizing and dry, obtain the special high Weather resistant halogen-free flame retardant PC/ABS alloy material of a kind of electrical outdoor mailbox.
The present invention and prior art are compared, and its effect is actively with obvious.The PC resin that the present invention adopts is 5g/10min～25g/10min at 300 DEG C, melting index when load 1.2Kg, as PC L-1250Z100 and PC L-1225Z100.ABS resin adopts the trade mark of butadiene content in 18%-20% left and right, for example, and strange beautiful ABS PA-758.These two kinds of fundamental components are weather-proof good polycarbonate trades mark.The present invention uses the synergistic flame retardant combination of RDP and TPP, to a certain degree can reduce fire retardant cost and can improve again impact and mobility, and fire retardant is dropped to minimum on the impact of weathering resistance.RDP in addition, has good processibility, the unique advantage such as self-extinguishing energy and good compatibility; By the synergistic effect of fire retardant, can reduce the usage quantity of fire retardant, the mechanics and the heat-drawn wire that maintain material are had to good effect, for material out of doors, place that especially temperature is higher is used that has brought may.Anti-dripping agent of the present invention is special modified polytetrafluoroethylparticles particles, adopts elite ST-AN coating material and PC and ABS engineering plastics to have excellent consistency, and PFOA, NP content reduce to minimum, meets stricter environmental protection standard.As
sN3307 can play the effect of a part of anti-drippage simultaneously, has again some wear-resisting effects; Antidrip agent mainly uses needing fire retardant not reach in the plastic material of V0 level, can prevent from melting and drips and improve flame retardant properties, can reach equally the requirement of UL V-0 in the time reducing the consumption of fire retardant, reduces costs simultaneously, strengthens product competitiveness.The present invention selects the synergy of several different weather-proof auxiliary agents, farthest improve the weathering resistance of halogen-free flame retardant PC/ABS alloy material, because this material must be taken into account PC, ABS and fire retardant, the weather resistance of the factors such as compatilizer, use the conventional on the market weather-proof auxiliary agent of 1-2 kind to be difficult to reach good weather-proof effect, therefore present method is passed through great many of experiments, find out being used in conjunction with between several weather-proof auxiliary agents with good synergy, make halogen-free flame retardant PC/ABS alloy material there is excellent weather-proof effect, be particularly suitable for being applicable to outdoor goods.The special high Weather resistant halogen-free flame retardant alloy material height of electrical outdoor mailbox of the present invention is heat-resisting, weather-proof, the performance of highly effective flame-retardant, and with low cost, handling ease.The present invention can adopt existing installation, simple to operate, is suitable for suitability for industrialized production.
The most important utilization of a kind of special high Weather resistant halogen-free flame retardant PC/ABS alloy material of electrical outdoor mailbox of the present invention is communications industry, especially the shell of outdoor communication case, the while also can provide for the open air use of automobile industry, material of construction, finishing material, cable and electrical apparatus industry a kind of solution of excellence certainly.
Embodiment
Embodiment 1-5 and comparative example 1
Table 1 starting material component proportion (embodiments of the invention)
The above embodiments and comparative example all adopt following method preparation:
The preparation method of the special high Weather resistant halogen-free flame retardant PC/ABS alloy material of a kind of electrical outdoor mailbox of the present invention, comprises the following steps:
After being mixed, raw material joins extruding pelletization in twin screw extruder, twin screw extruder is respectively to the temperature of head by feed zone: 160 DEG C ± 10 DEG C, 200 DEG C ± 10 DEG C, 260 DEG C ± 10 DEG C, 260 DEG C ± 10 DEG C, 255 DEG C ± 10 DEG C, 250 DEG C ± 10 DEG C, 250 DEG C ± 10 DEG C, 250 DEG C ± 10 DEG C, 250 DEG C ± 10 DEG C, and die head: 260 DEG C ± 10 DEG C;
Then through water-cooled, pelletizing and dry, obtain the special high Weather resistant halogen-free flame retardant PC/ABS alloy material of a kind of electrical outdoor mailbox.
Electrical outdoor mailbox proprietary material, due to life-time service out of doors, just must make material there is well heat-resisting and light aging resisting property, and the resistance toheat that adds membership reduction material of halogen-free flame retardants, this just requires us on material foundation formula, to increase the content of the good PC resin of thermotolerance, so that material has excellent weather resistance, and by the adding of several different light aging resisting auxiliary agents, can comprehensively improve the weathering resistance of material.Whether this patent experiment, by contrasting raw-material weathering resistance, add ultraviolet-resistant aid, and add the difference of ultraviolet-resistant aid kind, finds the best special halogen-free flame retardant PC/ABS of the outdoor telecommunications alloy material of effect.
Composition properties test result in table 2 embodiment and comparative example
By the alloy material contrast in PC/ABS alloy material of the present invention and comparative example, can find out from table 1 and table 2, because formula system is substantially identical, adopt single TPP fire retardant (for example: embodiment 2), flame retardant effect is poor; And use general PC (for example: embodiment 3) and the ABS trade mark (for example: embodiment 4) instead, effect aspect weathering resistance will be worse than and use the better matrix trade mark of weathering resistance, and the most frequently used single weather-proof auxiliary agent (for example: embodiment 5 and 6) in use market, due to the impact of fire retardant, the weather resistance of material is poor, aberration and inapplicable being more or less the same, and can reach extraordinary weather-proof effect by being used in conjunction with of multiple weather-proof auxiliary agent, only have the aberration minimum of embodiment 1, also mean that the weathering resistance of embodiment 1 is best.
The experimental result data of most critical is exactly the value of chromatism of illumination supporting.Test result shows, embodiment 1 is best, and the general aberration of customer requirement is below 5.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (8)
1. the special high Weather resistant halogen-free flame retardant PC/ABS alloy material of electrical outdoor mailbox, is characterized in that being made up of the raw material of following mass percent:
2. the special high Weather resistant halogen-free flame retardant PC/ABS alloy material of electrical outdoor mailbox according to claim 1, is characterized in that: the resin that it is 5g/10min～25g/10min that described polycarbonate resin is selected at 300 DEG C, melting index when load 1.2Kg.
3. the special high Weather resistant halogen-free flame retardant PC/ABS alloy material of electrical outdoor mailbox according to claim 1, it is characterized in that: in described acrylonitrile-butadiene-styrene copolymer resin, the quality percentage composition of described divinyl item is between 18-20%.
4. the special high Weather resistant halogen-free flame retardant PC/ABS alloy material of electrical outdoor mailbox according to claim 1, is characterized in that: described compatilizer is for being selected from any one in the terpolymer of styrene butadiene thermoplasticelastomer or methyl methacrylate-divinyl-styrene copolymer or polyester elastomer or polyolefin elastomer or MBS.
5. the special high Weather resistant halogen-free flame retardant PC/ABS alloy material of electrical outdoor mailbox according to claim 1, is characterized in that: the polytetrafluoroethylene granule that described anti-dripping agent is modification.
6. the special high Weather resistant halogen-free flame retardant PC/ABS alloy material of electrical outdoor mailbox according to claim 1, is characterized in that: described photostabilizer is selected from UV-5411.UV-3450 UV-531, the two or more combination in AO-2777.
7. the special high Weather resistant halogen-free flame retardant PC/ABS alloy material of electrical outdoor mailbox according to claim 1, it is characterized in that: described auxiliary agent comprises primary antioxidant, auxiliary antioxidant, internal lubricant and external lubricant, described primary antioxidant is β-(3,5-di-tert-butyl-hydroxy phenyl) the positive octadecanol ester of propionic acid or four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester or two (2,4-di-tert-butyl-phenyl) any one in tetramethylolmethane or 2,6 ditertiary butyl p cresol; Described auxiliary antioxidant is any one in three (2,4-di-tert-butyl-phenyl) phosphorous acid esters or sulfo-three propionic acid two lauryls or the two stearic alcohol esters of thio-2 acid; Described internal lubricant is E wax, calcium stearate or PE wax; Described external lubricant is one or more the combination in silicone master batch or silicone powder or pentaerythritol stearate.
8. the preparation method of the special high Weather resistant halogen-free flame retardant PC/ABS alloy material of electrical outdoor mailbox claimed in claim 1, comprises the following steps:
First after raw material being mixed, join extruding pelletization in twin screw extruder, twin screw extruder is respectively to the temperature of head by feed zone: 160 DEG C ± 10 DEG C, 200 DEG C ± 10 DEG C, 260 DEG C ± 10 DEG C, 260 DEG C ± 10 DEG C, 255 DEG C ± 10 DEG C, 250 DEG C ± 10 DEG C, 250 DEG C ± 10 DEG C, 250 DEG C ± 10 DEG C, 250 DEG C ± 10 DEG C, and die head: 260 DEG C ± 10 DEG C;
Then through water-cooled, pelletizing and dry, obtain the special high Weather resistant halogen-free flame retardant alloy material of electrical outdoor mailbox.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104262925A (en) * | 2014-09-10 | 2015-01-07 | 苏州云舒新材料科技有限公司 | Anti-aging polycarbonate composition and preparation method thereof |
| CN104893271A (en) * | 2015-05-27 | 2015-09-09 | 金发科技股份有限公司 | Polycarbonate composition and preparation method thereof |
| CN105001612A (en) * | 2015-08-04 | 2015-10-28 | 苏州博云塑业有限公司 | Highlight halogen-free flame-retardant PC/ABS composite material for electric appliance shell |
| CN105802173A (en) * | 2014-12-30 | 2016-07-27 | 上海俊尓新材料有限公司 | Extinction halogen-free flame retardant PC/ABS alloy material and preparation method thereof |
| CN106633744A (en) * | 2015-10-28 | 2017-05-10 | 东莞市宇捷实业投资有限公司 | PC light diffusion material |
| CN110408154A (en) * | 2019-08-19 | 2019-11-05 | 南京天诗实验微粉有限公司 | A kind of modified ptfe anti-dripping agent and preparation method thereof |
| CN111074096A (en) * | 2019-12-31 | 2020-04-28 | 江苏拓展新材料科技有限公司 | Corrosion-resistant alloy material and preparation method thereof |
| CN112694738A (en) * | 2020-12-31 | 2021-04-23 | 珠海格力新材料有限公司 | PC/ABS composite material and preparation method and application thereof |
| CN114539758A (en) * | 2022-03-15 | 2022-05-27 | 山东合创宏新材料科技有限公司 | Halogen-free flame-retardant PC/ABS composite material and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103073869A (en) * | 2013-01-25 | 2013-05-01 | 上海俊尔新材料有限公司 | High-wall-thickness and high-impact-strength halogen-free and flame-retardant PC/ABS alloy material |
-
2014
- 2014-04-22 CN CN201410163526.1A patent/CN104004330A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103073869A (en) * | 2013-01-25 | 2013-05-01 | 上海俊尔新材料有限公司 | High-wall-thickness and high-impact-strength halogen-free and flame-retardant PC/ABS alloy material |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104262925A (en) * | 2014-09-10 | 2015-01-07 | 苏州云舒新材料科技有限公司 | Anti-aging polycarbonate composition and preparation method thereof |
| CN105802173A (en) * | 2014-12-30 | 2016-07-27 | 上海俊尓新材料有限公司 | Extinction halogen-free flame retardant PC/ABS alloy material and preparation method thereof |
| CN105802173B (en) * | 2014-12-30 | 2017-10-31 | 上海俊尓新材料有限公司 | A kind of delustring halogen-free flame retardant PC/ABS alloy material and preparation method thereof |
| CN104893271A (en) * | 2015-05-27 | 2015-09-09 | 金发科技股份有限公司 | Polycarbonate composition and preparation method thereof |
| CN105001612A (en) * | 2015-08-04 | 2015-10-28 | 苏州博云塑业有限公司 | Highlight halogen-free flame-retardant PC/ABS composite material for electric appliance shell |
| CN106633744A (en) * | 2015-10-28 | 2017-05-10 | 东莞市宇捷实业投资有限公司 | PC light diffusion material |
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| CN111074096A (en) * | 2019-12-31 | 2020-04-28 | 江苏拓展新材料科技有限公司 | Corrosion-resistant alloy material and preparation method thereof |
| CN112694738A (en) * | 2020-12-31 | 2021-04-23 | 珠海格力新材料有限公司 | PC/ABS composite material and preparation method and application thereof |
| CN114539758A (en) * | 2022-03-15 | 2022-05-27 | 山东合创宏新材料科技有限公司 | Halogen-free flame-retardant PC/ABS composite material and preparation method thereof |
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Application publication date: 20140827 |