CN101597526B - 一种采收煤岩油气藏中的液体燃料的方法、产品及用途 - Google Patents
一种采收煤岩油气藏中的液体燃料的方法、产品及用途 Download PDFInfo
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- CN101597526B CN101597526B CN 200810114302 CN200810114302A CN101597526B CN 101597526 B CN101597526 B CN 101597526B CN 200810114302 CN200810114302 CN 200810114302 CN 200810114302 A CN200810114302 A CN 200810114302A CN 101597526 B CN101597526 B CN 101597526B
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- 239000003245 coal Substances 0.000 title claims abstract description 80
- 239000000446 fuel Substances 0.000 title claims abstract description 58
- 238000000034 method Methods 0.000 title claims abstract description 49
- 239000007788 liquid Substances 0.000 title claims abstract description 27
- 239000003921 oil Substances 0.000 claims abstract description 59
- 239000000295 fuel oil Substances 0.000 claims abstract description 15
- 238000004939 coking Methods 0.000 claims abstract description 14
- 238000007670 refining Methods 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000002817 coal dust Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 24
- 239000010742 number 1 fuel oil Substances 0.000 claims description 23
- 239000002802 bituminous coal Substances 0.000 claims description 20
- 229930195733 hydrocarbon Natural products 0.000 claims description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims description 13
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- 239000003077 lignite Substances 0.000 claims description 10
- 239000003318 humic coal Substances 0.000 claims description 5
- 238000001311 chemical methods and process Methods 0.000 claims description 4
- 230000003111 delayed effect Effects 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 9
- 239000000843 powder Substances 0.000 abstract 3
- 239000003250 coal slurry Substances 0.000 abstract 2
- 230000009466 transformation Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 17
- 239000003208 petroleum Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000010913 used oil Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000010779 crude oil Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000010430 carbonatite Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920002101 Chitin Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- BIVQBWSIGJFXLF-UHFFFAOYSA-N PPM-18 Chemical compound C=1C(=O)C2=CC=CC=C2C(=O)C=1NC(=O)C1=CC=CC=C1 BIVQBWSIGJFXLF-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000010763 heavy fuel oil Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000010117 shenhua Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000004079 vitrinite Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
6#燃料油 | 稠油 | |
密度,g/cm3 | 0.98(15℃) | 0.92(20℃) |
残碳,重% | 10.8 | 6.1 |
闪点,℃ | 87 | 122 |
倾点,℃ | -9 | -3 |
碳,重% | 86.4 | 85.9 |
氢,重% | 11.2 | 13.1 |
氧,重% | 0.3 | 0.2 |
氮,重% | 0.41 | 0.3 |
钠,ppm | 18 | / |
硫,重% | 2.4 | / |
钒,ppm | 269 | / |
铝,ppm | 10 | / |
硅,ppm | 13 | / |
芳香度 | 24 | / |
粘度,mm2/s, | 0.355(50℃) | 3.2(80℃) |
含水量,重% | 0.4 | 0.3 |
灰分,重% | 0.054 | 0.2 |
实施例1 | 实施例2 | 实施例3 | |
煤 | 褐煤A | 烟煤B | 烟煤C |
油 | 6#燃料油 | 6#燃料油 | 6#燃料油 |
煤/油比 | 0.6∶1 | 0.7∶1 | 0.5∶1 |
溶解后的油煤浆 | |||
热值,千焦/千克 | 39417 | 40337 | 41883 |
粘度,mm2/s,100℃ | 41.2 | 14.6 | 7.5 |
石油化工行业燃料油标准SH/T 0356-1996 | |||
6号 | 5号重 | 5号轻 | |
粘度,mm2/s,100℃ | |||
不小于 | 15.0 | 9.0 | 5.0 |
不大于 | 50.0 | 14.9 | 8.9 |
灰分,重%不大于 | - | 0.15 | 0.15 |
实施例4 | 实施例5 | 实施例6 | |
煤 | 褐煤A | 烟煤D | 烟煤E |
油 | 6#燃料油 | 6#燃料油 | 稠油 |
煤/油比 | 0.51∶1 | 0.7∶1 | 0.8∶1 |
焦化产物 | |||
水分,重% | 4.0 | 3.6 | 3.2 |
裂解气,重% | 11.3 | 2.5 | 8.4 |
焦化油,重% | 48.5 | 46.3 | 51.2 |
焦,重% | 36.3 | 47.6 | 37.2 |
Claims (13)
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CN 200810114302 CN101597526B (zh) | 2008-06-02 | 2008-06-02 | 一种采收煤岩油气藏中的液体燃料的方法、产品及用途 |
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CN 200810114302 CN101597526B (zh) | 2008-06-02 | 2008-06-02 | 一种采收煤岩油气藏中的液体燃料的方法、产品及用途 |
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CN101597526A CN101597526A (zh) | 2009-12-09 |
CN101597526B true CN101597526B (zh) | 2013-03-27 |
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Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107446632B (zh) * | 2017-09-20 | 2019-05-17 | 深圳瑞科天启科技有限公司 | 一种提高液体燃料或气体燃料能量密度的方法 |
CN110144249B (zh) * | 2019-05-16 | 2021-08-13 | 煤炭科学技术研究院有限公司 | 高匹配性油煤浆的配制方法 |
CN110437874B (zh) * | 2019-08-07 | 2020-10-02 | 北京中科诚毅科技发展有限公司 | 一种加氢混合物配制工艺 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1179464A (zh) * | 1996-10-16 | 1998-04-22 | 杨国光 | 油水煤浆组合物燃料及其生产方法 |
CN1236806A (zh) * | 1999-03-03 | 1999-12-01 | 苏宏文 | 水油煤浆及其生产方法 |
CN1354227A (zh) * | 2000-11-20 | 2002-06-19 | 中国科学院理化技术研究所 | 由煤炭、水、油组成的油基三元混合燃料 |
CN1389547A (zh) * | 2001-06-05 | 2003-01-08 | 中国矿业大学 | 油基煤浆燃料及制备工艺 |
CN1958754A (zh) * | 2006-08-24 | 2007-05-09 | 辽河石油勘探局 | 利用煤粉柴油油浆为原料的工业锅炉液体燃料及其制备方法 |
CN101092578A (zh) * | 2006-06-21 | 2007-12-26 | 颜春夏 | 高热值复合燃料及其制造方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1236024C (zh) * | 2003-10-15 | 2006-01-11 | 王逢旦 | 一种生产水煤浆或油煤浆的设备及其生产方法 |
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- 2008-06-02 CN CN 200810114302 patent/CN101597526B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1179464A (zh) * | 1996-10-16 | 1998-04-22 | 杨国光 | 油水煤浆组合物燃料及其生产方法 |
CN1236806A (zh) * | 1999-03-03 | 1999-12-01 | 苏宏文 | 水油煤浆及其生产方法 |
CN1354227A (zh) * | 2000-11-20 | 2002-06-19 | 中国科学院理化技术研究所 | 由煤炭、水、油组成的油基三元混合燃料 |
CN1389547A (zh) * | 2001-06-05 | 2003-01-08 | 中国矿业大学 | 油基煤浆燃料及制备工艺 |
CN101092578A (zh) * | 2006-06-21 | 2007-12-26 | 颜春夏 | 高热值复合燃料及其制造方法 |
CN1958754A (zh) * | 2006-08-24 | 2007-05-09 | 辽河石油勘探局 | 利用煤粉柴油油浆为原料的工业锅炉液体燃料及其制备方法 |
Non-Patent Citations (1)
Title |
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吴秀章等.煤炭直接液化起始溶剂油的研究.《石油炼制与化工》.2007,第38卷(第8期),第19-22页. * |
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