CN101585719A - 弱酸性高含量硼肥的制备方法 - Google Patents
弱酸性高含量硼肥的制备方法 Download PDFInfo
- Publication number
- CN101585719A CN101585719A CNA2009100626688A CN200910062668A CN101585719A CN 101585719 A CN101585719 A CN 101585719A CN A2009100626688 A CNA2009100626688 A CN A2009100626688A CN 200910062668 A CN200910062668 A CN 200910062668A CN 101585719 A CN101585719 A CN 101585719A
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- Prior art keywords
- boron fertilizer
- weak acid
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- acid high
- preparation
- Prior art date
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- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title claims abstract description 53
- 229910052796 boron Inorganic materials 0.000 title claims abstract description 53
- 239000003337 fertilizer Substances 0.000 title claims abstract description 41
- 239000002253 acid Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 230000018044 dehydration Effects 0.000 claims abstract description 12
- 238000006297 dehydration reaction Methods 0.000 claims abstract description 12
- XDVOLDOITVSJGL-UHFFFAOYSA-N 3,7-dihydroxy-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B(O)OB2OB(O)OB1O2 XDVOLDOITVSJGL-UHFFFAOYSA-N 0.000 claims abstract description 10
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 8
- 239000004327 boric acid Substances 0.000 claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 239000005864 Sulphur Substances 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 230000035764 nutrition Effects 0.000 claims description 2
- 235000016709 nutrition Nutrition 0.000 claims description 2
- 238000007873 sieving Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 238000004090 dissolution Methods 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- 208000005156 Dehydration Diseases 0.000 description 10
- 238000000034 method Methods 0.000 description 6
- 230000002378 acidificating effect Effects 0.000 description 4
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 1
- CDMADVZSLOHIFP-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 CDMADVZSLOHIFP-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- -1 this Chemical compound 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
- C01B35/10—Compounds containing boron and oxygen
- C01B35/1027—Oxides
- C01B35/1036—Boric anhydride
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
- C01B35/10—Compounds containing boron and oxygen
- C01B35/1045—Oxyacids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Fertilizers (AREA)
Abstract
本发明公开了一种弱酸性高含量硼肥的制备方法，包括下述步骤：将硼酸加温至180℃－200℃，保温20－30分钟，脱水后取出，得到焦硼酸；将所述焦硼酸冷却至40℃－60℃，然后进行粉碎、过筛，得到粉状的弱酸性高含量硼肥。本发明具有节能环保、生产成本低、溶解速度快、混配性好和纯硼含量更高的优点。
Description
技术领域
本发明涉属于硼肥的制备方法，特别是一种呈弱酸性且纯硼含量高的硼肥的制备方法。
背景技术
现有硼肥的纯硼含量通常＜20％，称为低含量硼肥，一般用于基施，即土壤根施，纯硼含量＞20％的硼肥即为高含量硼肥，一般用于叶面喷施。目前国内外高含量硼肥均是采用十水硼砂为原料，经350℃-450℃高温脱水制成，其理论上的纯硼含量为21.48％，实际纯硼含量为20％-21％，存在以下不足：1、由于生产过程繁琐复杂，耗能大，使得生产成本较高；2、由于所得硼肥呈碱性，因此，其溶解速度慢，并且混配性较差；3、纯硼含量无法进一步提高。
发明内容
本发明的目的是针对上述问题提供一种弱酸性高含量硼肥的制备方法。
本发明的制备方法包括下述步骤：
(1)将硼酸加温至180℃-200℃，保温20-30分钟，脱水后取出，得到焦硼酸；
(2)将所述焦硼酸冷却至40℃-60℃，然后进行粉碎、过筛，得到粉状的弱酸性高含量硼肥。
在上述技术方案中，所述粉碎操作采用高速粉碎机或气流粉碎机，所述过筛操作采用100-200目的筛网。
在上述技术方案中，所述弱酸性高含量硼肥中可加入氮、磷、钾、镁、硫、锰、锌、铜、铁、钼营养元素的一种或多种专用肥。
在上述技术方案中，所述弱酸性高含量硼肥中可加入杀菌剂。
在上述技术方案中，所述弱酸性高含量硼肥中可加入杀虫剂。
上述技术方案中，采用呈弱酸性的硼酸为原料，经180℃-200℃高温脱水得到呈弱酸性的焦硼酸，其理论上的纯硼含量为27.5％，实际纯硼含量可达22.5％-23.5％。如果提高硼酸的脱水温度，超过200℃甚至更高，则可得到硼酸酐，其理论上的纯硼含量达到31.05％，但由于硼酸酐的物理性状呈玻璃块状，根本无法制成硼肥，因此，尽管其纯硼含量更高，也不能作为硼肥使用。也正因为如此，本发明将硼酸的脱水温度设定为180℃-200℃，这样，既可将硼酸脱水加工成为硼肥，又能使硼肥的纯硼含量达到一个较高的水平。
本发明的制备方法具有以下优点：1、由于脱水温度与现有硼肥制备方法相比相对较低，因此，节能环保，并且还由于缩短了生产时间，使得生产成本低；2、由于所得硼肥呈弱酸性，因此，其溶解速度快，并且混配性好；3、纯硼含量更高，可达22.5％-23.5％。
具体实施方式
下面结合实施例进一步说明本发明。
实施例1：以硼酸为原料，按下述步骤操作：
(1)将100公斤硼酸置于普通干烤箱内加温至180℃，保温20-30分钟，脱水后取出，得到焦硼酸；
(2)将所述焦硼酸冷却至40℃-60℃，然后采用3000转/分钟的高速粉碎机或气流粉碎机进行粉碎，采用100-200目的筛网过筛，得到90公斤粉状的弱酸性高含量硼肥，其纯硼含量为22.7％。
上述冷却后的焦硼酸也可先制成液体，然后采用高温喷雾法制成粉状的弱酸性高含量硼肥。
实施例2：脱水温度为190℃，其它同实施例1，得到的弱酸性高含量硼肥的纯硼含量为23.1％。
实施例3：脱水温度为200℃，其它同实施例1，得到的弱酸性高含量硼肥的纯硼含量为23.6％。
本发明可在生产过程中添加氮、磷、钾、镁、硫、锰、锌、铜、铁、钼等营养元素中的一种或多种专用肥，以及杀菌剂、杀虫剂，也可以在使用时将本发明产品与其他叶面肥、农药、杀菌剂、杀虫剂进行混合。
Claims (5)
1、一种弱酸性高含量硼肥的制备方法，其特征在于包括下述步骤：
(1)将硼酸加温至180℃-200℃，保温20-30分钟，脱水后取出，得到焦硼酸；
(2)将所述焦硼酸冷却至40℃-60℃，然后进行粉碎、过筛，得到粉状的弱酸性高含量硼肥。
2、如权利要求1所述的弱酸性高含量硼肥的制备方法，其特征在于：所述粉碎操作采用高速粉碎机或气流粉碎机，所述过筛操作采用100-200目的筛网。
3、如权利要求1或2所述的弱酸性高含量硼肥的制备方法，其特征在于：所述弱酸性高含量硼肥中可加入氮、磷、钾、镁、硫、锰、锌、铜、铁、钼营养元素的一种或多种专用肥。
4、如权利要求1或2所述的弱酸性高含量硼肥的制备方法，其特征在于：所述弱酸性高含量硼肥中可加入杀菌剂。
5、如权利要求1或2所述的弱酸性高含量硼肥的制备方法，其特征在于：所述弱酸性高含量硼肥中可加入杀虫剂。
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100626688A CN101585719B (zh) | 2009-06-16 | 2009-06-16 | 弱酸性高含量硼肥的制备方法 |
| RU2012101230/13A RU2501773C2 (ru) | 2009-06-16 | 2010-06-12 | Способ получения слабокислого удобрения с высоким содержанием бора |
| PCT/CN2010/073869 WO2010145515A1 (zh) | 2009-06-16 | 2010-06-12 | 弱酸性高含量硼肥的制备方法 |
| US13/327,724 US8946120B2 (en) | 2009-06-16 | 2011-12-15 | Method for preparing boron fertilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100626688A CN101585719B (zh) | 2009-06-16 | 2009-06-16 | 弱酸性高含量硼肥的制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101585719A true CN101585719A (zh) | 2009-11-25 |
| CN101585719B CN101585719B (zh) | 2010-12-29 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100626688A Expired - Fee Related CN101585719B (zh) | 2009-06-16 | 2009-06-16 | 弱酸性高含量硼肥的制备方法 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US8946120B2 (zh) |
| CN (1) | CN101585719B (zh) |
| RU (1) | RU2501773C2 (zh) |
| WO (1) | WO2010145515A1 (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010145515A1 (zh) * | 2009-06-16 | 2010-12-23 | 武汉飞喜乐农业科技有限公司 | 弱酸性高含量硼肥的制备方法 |
| CN102503656A (zh) * | 2011-10-11 | 2012-06-20 | 石河子大学 | 一种水溶性高效硼肥的生产方法 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101792336B (zh) * | 2010-02-10 | 2012-08-29 | 武汉飞喜乐农业科技有限公司 | 近中性高含量硼肥及其制备方法 |
| US8801827B2 (en) | 2012-10-22 | 2014-08-12 | Tiger-Sul Products (Canada) Co. | Fertilizer composition containing sulfur and boron |
| WO2022221270A1 (en) * | 2021-04-12 | 2022-10-20 | Edaphix, LLC | Environmentally friendly compositions and methods of their use for promoting the growth of turfgrass over weeds |
| WO2024059123A1 (en) * | 2022-09-14 | 2024-03-21 | U.S. Borax, Inc. | Fertiliser product |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5651949A (en) * | 1993-11-24 | 1997-07-29 | U.S. Borax Inc. | Production of boric oxide |
| US5928672A (en) * | 1996-03-28 | 1999-07-27 | Hammons; Barry D. | Polyborate composition |
| RU2108994C1 (ru) * | 1996-12-25 | 1998-04-20 | Нина Михайловна Дятлова | Способ получения удобрения |
| CN101050133A (zh) * | 2007-03-29 | 2007-10-10 | 武汉富强科技发展有限责任公司 | 聚合硼酸铵叶面肥及其制备方法 |
| CN101269996B (zh) * | 2008-05-08 | 2012-08-22 | 爱沃(北京)农业技术有限公司 | 一种水溶性硼肥及其制备方法 |
| CN101585719B (zh) * | 2009-06-16 | 2010-12-29 | 武汉飞喜乐农业科技有限公司 | 弱酸性高含量硼肥的制备方法 |
-
2009
- 2009-06-16 CN CN2009100626688A patent/CN101585719B/zh not_active Expired - Fee Related
-
2010
- 2010-06-12 RU RU2012101230/13A patent/RU2501773C2/ru not_active IP Right Cessation
- 2010-06-12 WO PCT/CN2010/073869 patent/WO2010145515A1/zh active Application Filing
-
2011
- 2011-12-15 US US13/327,724 patent/US8946120B2/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010145515A1 (zh) * | 2009-06-16 | 2010-12-23 | 武汉飞喜乐农业科技有限公司 | 弱酸性高含量硼肥的制备方法 |
| US20120088666A1 (en) * | 2009-06-16 | 2012-04-12 | Lin Gan | Method for preparing boron fertilizer |
| US8946120B2 (en) * | 2009-06-16 | 2015-02-03 | Wuhan Fishery Agricultural Science and Technology Co., Ltd. | Method for preparing boron fertilizer |
| CN102503656A (zh) * | 2011-10-11 | 2012-06-20 | 石河子大学 | 一种水溶性高效硼肥的生产方法 |
| CN102503656B (zh) * | 2011-10-11 | 2013-07-24 | 石河子大学 | 一种水溶性高效硼肥的生产方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US8946120B2 (en) | 2015-02-03 |
| WO2010145515A1 (zh) | 2010-12-23 |
| US20120088666A1 (en) | 2012-04-12 |
| RU2012101230A (ru) | 2013-07-27 |
| CN101585719B (zh) | 2010-12-29 |
| RU2501773C2 (ru) | 2013-12-20 |
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