CN101585611A - Industrial wastewater and municipal wastewater treatment method - Google Patents

Industrial wastewater and municipal wastewater treatment method Download PDF

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CN101585611A
CN101585611A CNA2009101433447A CN200910143344A CN101585611A CN 101585611 A CN101585611 A CN 101585611A CN A2009101433447 A CNA2009101433447 A CN A2009101433447A CN 200910143344 A CN200910143344 A CN 200910143344A CN 101585611 A CN101585611 A CN 101585611A
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water
treatment
sewage
filter
filtration
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CN101585611B (en
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程相武
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Beijing Xiangwu Technology Co Ltd
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Beijing Xiangwu Technology Co Ltd
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Abstract

The invention relates to an industrial wastewater and municipal wastewater processing method. The sewage treating apparatus comprises: TR1, TR2, TR3 and TR4 on-line water processor units which grind pulp in the pulping process and in the primary and second pulp washing process; a flocculating filtration apparatus, a mechanical filtration apparatus, a secondary filtration apparatus and a hyperfiltration apparatus which process the water in the bleaching and rinsing process; and a desalinisation processing apparatus TR5 which ensures the final desalinisation of the circulating water. The processing method changes the fluid form in the whole process after adding the flocculant in the wastewater. In the biochemical polymerization reaction and mechanical physical movement process, the polluting factors rapidly generate the flocculation dissociation in the flow process, thus making the tiny microparticle impurities generate the agglomerate which is convenient for filtration, hydrophilic and insoluble and dewatering the pollutant to be sorted into dry matters. The invention has the advantages of low equipment investment, no waste liquid discharge and remarkable economic benefit. The processed water is used in cycle. The invention is applied to paper-making pulping, municipal wastewater and industrial wastewater process.

Description

Trade effluent and municipal wastewater treatment method
The application divides an application, and the applying date of original application is: 2005.2.30, application number are: 200510003422.5, denomination of invention is: trade effluent and municipal wastewater treatment facility and processing method thereof.
Technical field
The invention belongs to water treatment field, be meant a kind of trade effluent and municipal wastewater treatment method especially.
Background technology
At present, the harm that the paper industry environmental pollution causes is fairly obvious, especially on the pulp production link of paper, because production technique such as the cooking process that adopts, oxidation style can produce a large amount of waste water in process of production.Adopt traditional waste water control method, the efficient of administering sewage is low; Water treating equipment are invested, working cost is big; The energy consumption height has caused many papermaking enterprises that factory effluent is discharged in river, river, the lake water steathily, has seriously polluted water resources, has polluted environment.In addition, the most of municipal effluent of China also directly discharges without effectively handling, and consequent water pollution has become serious environmental problem.
External many new technologies, novel process were introduced into China to nineteen ninety-five in 1975, all were applied in China municipal sewage plant as B method, oxidation ditch process, A/O technology, A2O method, SBR method.Simultaneously, more external advanced persons, the sewage disposal specific equipment has also entered the wastewater treatment in China industry market efficiently, as equipment such as grid maker, submersible pump, desanding device, mud scraper, aerator, gas blower, sludge pump, water extracter, biogas generator, methane boiler, sludge digestion stirring systems.
The municipal sewage plant that China built the eighties in the past is most of to adopt common aeration active sludge treatment process, because this technology is major objective to remove BOD and SS mainly, very low to the clearance of nitrogen phosphorus.
What China adopted more than 80% existing municipal sewage plant is activated sludge process, and all the other adopt one-level processing, enhanced primary processing, stabilization pond method and soil facture etc.
Along with the raising of China to the quality of water environment requirement, revised country " integrated wastewater discharge standard " is (GB8978-1996) also more and more tighter, particularly the requirement to water outlet nitrogen, phosphorus improves, and makes newly-built municipal sewage plant must consider effective removal problem of nitrogen phosphorus.Developed improvement A2O technology and returned sluge denitrification biological phosphate-eliminating technology thus, and begun in actual engineering, to use.Newly-built reaching in the technology that the municipal sewage plant adopted of building, various types of activated sludge processes still are main flow, account for more than 90%, all the other then reach the sewage treatment technologies such as the natural, ecological method of purification that combine with other treatment process for one-level processing, enhanced primary processing, stabilization pond method, biomembrance process.
The industrial sewage processing technological flow mainly comprises workshop sections such as aeration anaerobic treatment, precipitation process, aerobic treatment.Be major objective mainly to remove BOD and SS, but very low to the clearance of nitrogen, phosphorus.
The municipal wastewater processing technological flow mainly comprises workshop sections such as mechanical treatment, biochemical treatment (waterline), sludge treatment.The system that is made of mechanical treatment and biochemical treatment belongs to the second-stage treatment system, and its BOD5 and SS clearance can reach 90%~98%.Treatment effect between firsts and seconds is handled be commonly referred to as that enhanced primary is handled, one-level half is handled or not exclusively level handle, mainly contain high loading biological treatment and chemical method two big classes, BOD5 clearance 45%~75%.Second-stage treatment system with biological dephosphorize denitrification function is commonly referred to degree of depth second-stage treatment.In order to remove specific material, the treatment system that is provided with after second-stage treatment belongs to tertiary treatment, for example: chemical dephosphorization, flocculation filtration, charcoal absorption etc.
One-level biological treatment system is mainly desilting, oil removing, precipitation, and purpose is to remove suspended substance and small part CODcr, BOD5.Along with quantity of wastewater effluent increases day by day, the aggravation of water pollution, and the raising of emission standard, developing into two stage biological handles, on behalf of technology, it technologies such as the conventional oxidation pool, activated sludge process, biological filter, bio-contact oxidation are arranged, and mainly removes CODcr, BOD5, and part NH3-N.Along with deepening continuously of research work, people recognize the organic matter of being not only that causes pollution, and the ammonia of inorganic nature, phosphorus also are the major causes of body eutrophication.Therefore, more strict emission control standards has all been formulated in countries in the world, is removing the organic nutritive substances such as nitrogen, phosphorus of removing simultaneously.In order to adapt to this requirement, develop a collection of degree of depth second-stage treatment technology, or be called secondary half treatment process, mainly contain technologies such as oxidation ditch, integrated activated sludge processing, BAF, the Biostatic pool.
It all is the suspended biological facture that derives from from activated sludge process that current domestic popular sewage treatment process has these technologies such as common aeration (conventional activated sludge method), AB method, oxidation ditch process, SBR method, A2/O method, A/O method, UNITANK method.
1, common aeration (conventional activated sludge method): it is the technology that occurs the earliest, still has great vitality so far, and treatment effect is good, the sludge loading height, Chi Rong is long-pending little, and power consumption is economized, but common aeration does not possess the denitrogenation dephosphorizing function, only can satisfy BOD5, CODcr, three effluent index of SS.
2, SBR method (sequence batch (): generally form, rotate water inlet, aeration, precipitation, left-falling stroke water, leave standstill by one group of four pond.This technology is original treatment process, in modern technologies, can be regarded as anaerobism (dephosphorization), aerobic (remove BOD5 and nitrated), anoxic (denitrogenation), precipitation (removing SS) and combine in the pond, sedimentary mud is retained in the pond and saves mud and take out and rise reflow process.This method is applicable to that the water yield, water quality discharges uniform trade effluent, and can save equalizing tank, reduces investment outlay; But large-scale wastewater treatment plant there is not superiority.
3, oxidation ditch process: oxidation ditch is actually a kind of distortion of activated sludge process, because of the mixed solution of its waste water and active sludge constantly circulates in the channel of cyclic aeration tank, so the someone is called " circulated aeration tank " again.Original oxidation ditch belongs to extended aeration, does not establish primary sedimentation pond, and sewage reaches the nitrated stage, obtains corresponding aerobic treatment, measures less and slaking; Oxidation ditch is with changeing the brush surface aeration, and management is simple.Originally original oxidation ditch is discontinuous running, after develop into continuous operation, set up secondary sedimentation basins, aeration and depositing technology are separated, kinds of processes appears then: DE formula, DT formula, increased preposition anaerobic zone and rearmounted settling tank, return-flow system, and possessed the denitrogenation dephosphorizing function, but its power consumption is bigger, and running expense is higher.
4, A2/O method: the technology of the general denitrogenation dephosphorizing of using always is A2/O (anaerobism, anoxic, aerobic) method.Phosphorus discharges at anaerobic zone, absorbs at aerobic zone, reaches the dephosphorization purpose, and pollutent is removed COD and BOD in the oxidized degraded of aerobic zone; Under the effect of nitrifier, the ammonia nitrogen that organic oxygen transforms is converted into nitrous acid nitrogen and nitrate nitrogen in succession simultaneously; The macro-mixing liquid that contains nitrate nitrogen is back to the oxygen-starved area and carries out denitrification denitrogenation; But the sludge treatment workload is big in its mud reflux technique, and energy-saving effect is poor.
5, AB method: promptly adsorb and two sections biological treatments of biological degradation, generally do not establish preliminary sedimentation tank.The A section is the biological absorption phase of high loading, promptly makes full use of the microorganism (bacterium) in the sewage, is adsorbed as the main BOD of removal with biology, and its running status is with higher sludge loading removal organism more than 50% in short aeration time; The B section is property mud method operation routinely then, and sewage is after handling through the A section, and the BOD concentration that enter the B section this moment reduces significantly, and the time that reaches nitrated is shortened dramatically, and has also reduced the B section and has handled the volume of structures, but also reduced construction costs.Conventional AB method, the about 50-70% of TP clearance, the TN clearance is about 30-40%.The AB method is applicable to the processing high concentration organic sewage, and the BOD removal is worth about 300-350mg/L.
6, UNITANK method: this technology is a kind of novel process based on activated sludge process.Characteristics are that aeration and precipitation are formed one.This technology is divided into some lattice with the pond, head and end alternative aeration and precipitation; But this method does not possess the denitrogenation dephosphorizing function.
In a word, aforesaid method does not still fundamentally solve and administers effluent problem.
Summary of the invention
The objective of the invention is to overcome the deficiency in the background technology and the treatment process method of a kind of trade effluent and municipal wastewater is provided.
Technical scheme of the present invention is:
The water treating equipment of a kind of trade effluent and municipal wastewater, it comprises water treating equipment, be made up of flocculant concentration pump, flocculation filtration jar, mechanical filter, accurate filter, micro-filtrate membrane filtration device, pump and pipeline, it is characterized in that: the sewage that pulping process is produced is provided with above TR1, TR2, TR3, the TR4 water treating equipment unit of a cover at least; And TR5 is set is terminal water desalination treatment facility unit, finishes the sewage disposal in the pulping process.
Wherein, described TR1 water treating equipment unit is to be used for sewage disposal in the one-level pulp washing process, is made up of flocculant concentration pump, flocculation filtration jar, sewage jar, pump and pipeline; The sewage inlet of flocculation filtration jar is connected with the dosing mouth of flocculant concentration pump, the outlet of the quick concentrating and separating machine of one-level washing device; Clear water after handling is delivered to the clear water inlet of one-level washing device; Use for production cycle.
Described TR2 water treating equipment unit is to be used for sewage disposal in the secondary pulp washing process, is made up of flocculant concentration pump, flocculation filtration jar, mechanical filter, accurate filter, micro-filtrate membrane filtration device, pump and pipeline; The sewage inlet of flocculation filtration jar is connected with the dosing mouth of flocculant concentration pump, the outlet of the quick concentrating and separating machine of secondary washing device; The water of finishing after one-level is handled is delivered to by mechanical filter, accurate filter, micro-filtrate membrane filtration device, carried out two-stage ultrafiltering and handle, the water after two-stage ultrafiltering is handled is delivered to the water treatment of TR5 terminal.
Described TR3 water treating equipment unit is to be used for being made up of flocculant concentration pump, flocculation filtration jar, sewage jar, pump and pipeline floating bleach residue sewage disposal in the slurry process; The dosing mouth of the sewage inlet of flocculation filtration jar and flocculant concentration pump, the outlet of floating the quick concentrating and separating machine of slurry equipment are connected; Water after handling is delivered to the water treatment of TR5 terminal.
Described TR4 water treating equipment unit is to be used for residual bleaching liquor sewage disposal to after rinsing separates, is made up of flocculant concentration pump, flocculation filtration jar, mechanical filter, accurate filter, micro-filtrate membrane filtration device, pump and pipeline; The sewage inlet of flocculation filtration jar is connected with the dosing mouth of flocculant concentration pump, the outlet of residual bleaching liquor sewage; The water that outlet will be finished after one-level is handled is delivered to by mechanical filter, accurate filter, micro-filtrate membrane filtration device, carries out two-stage ultrafiltering and handles, and the water after two-stage ultrafiltering is handled can be delivered to the water treatment of TR5 terminal.
Described TR5 terminal water desalination treatment facility unit is the salt balance in being used for guaranteeing recycling after the water treatment, form by many groups sea water desaltination treatment unit, atomizing dry tower, water after TR2,3,4 water treatments inserts many group sea water desaltination treatment unit, atomizing dry tower desalting treatment unit, finish desalting treatment, finally obtain water purification.
A kind of trade effluent and municipal wastewater treatment method, it is with after adding flocculation agent in the sewage, whole flow process is in the change flow morphology, in biochemical polyreaction and the mechanical-physical moving process, pollution factor produces waddingization rapidly in flow process free, granulometric impurity tiny in the water can be generated to be convenient to filtering hydrophilic water-fast agglomerate material.Whole wadding generative process only needs very short time (generally being no more than 40 seconds), just 95% above pollution substance dehydration sub-argument can be become dry-matter.
Technology processing system of the present invention, it mainly comprises: barrier pre-treatment, equalizing tank, the mixing of multistage water, water quality adjusting system, dynamically flocculation, metal membrane filter unit, backwater treatment system.
The barrier pre-treatment: former water is introduced into thick barrier through conduit, is used for removing foreign material such as water hair, fiber, turns round normally to guarantee subsequent disposal safety.The barrier retaining power is strong, adopts full-automatic device, need not artificial periodic cleaning interception dirt.
Equalizing tank: because wastewater flow rate and enter the inhomogeneous of impurity in the discharge of wastewater process, making flow, concentration and the temperature of waste water has variation in a big way in round the clock.For guaranteeing water conditioning, be not subjected to the influence of waste water peak flow or change in concentration, so utilize regulating tank to come regulating pondage and water quality.In addition, waste water can neutralize in regulating tank, and the sewage of discharging is handled, and is used for homogenizing water quality, regulating pondage.With " building municipal sewage treatment design specifications " is foundation, and this pool volume plays homogenizing water quality, prevents sedimentary effect by handling water yield design.
Flocculation and line-blending: the core that the mixed stage of intelligence flocculation and pipeline has been concentrated the entire treatment processing method.Add intelligent flocculation agent in this technical process process, applied fluid dynamics, principle of electrophoresis by process synergic effects such as " compression double electric layer effect ", " charge neutrality ", " adsorption bridgings ", reach flocculating effect.
(1) compression double electric layer effect: adsorption layer and diffusion layer are collectively referred to as electrostatic double layer.Cation concentration reduces from inside to outside gradually in the electrostatic double layer, until with water in cation concentration about equally.Therefore, electrostatic double layer has certain thickness.Add a large amount of ionogen as Xiang Shuizhong, then its positive ion will be clamp-oned diffusion layer and make it attenuation; And then clamp-on adsorption layer, and the electronegativity on glue nuclear surface is reduced, this effect claims compression double electric layer.When electrostatic double layer is compressed, intergranular static is scolded and can will be reduced, and when the kinetic energy of reducing to less than the particle pedesis, particle is adsorption-condensation mutually just.
(2) charge neutrality effect: more than be cohesion between micelle of the same race, and the charge neutrality effect is meant that flocculation agent forms the micelle of positively charged in water, their can and water in electronegative micelle attract each other, thereby make electrical neutralization each other and condense.For this reason, require both quantities of electric charge will be about equally.
(3) adsorption bridging effect: some are the high-molecular coagulant adopting of linear structure, and after metal endures the class flocculation agent form linear high polymer in water, all can the strong adsorption colloidal particle.When the particulate of absorption when increasing, above-mentioned thread-like molecule can be crooked, distortion and becomes net, thereby play the effect of bridge formation, distance between particulate is shortened and bonds mutually, forms thick flocs unit gradually.
This flocculation agent has characteristics such as the preparation method is simple, nontoxic, consumption is few, raw material sources are extensive, be suitable for pH value a wider range and flocculating effect is good, medicament expense is low, and whole water treatment procedure is no more than one minute, has improved water treatment efficiency greatly.
Coarse filtration conservancy trash machine: adopt filtration unit cheaply, leach the floss and the water-fast large particulate matter that produce in the flocculation pipeline.
The smart filtration: the core technology of automatic cleaning strainer is a filter screen, and it has changed traditional filter structure, and filter screen is made the oblique net that tilts to rotate along filter cylinder, utilizes the scraper in the net to produce shearing force with the angle that oblique net forms again.Like this, whatsoever the dirt of type under the effect of shearing force, all can or not sticked on the net wall by chopping; Simultaneously, DA-W type automatic cleaning strainer at the another side of net inner cutter, also is provided with a brush in order to reach better cleaning performance, and along with the rotation of cutting knife, the residual spot that brush also will stick on the inwall is simultaneously cleaned out.
Can on the net wall, produce oil film when filtering oily liquid and stop up the problem of filter screen, on the scraper of automatic cleaning strainer, design a backwash device in order to solve.The principle of work of backwash device is: design a sewage draining exit again in the bottom of strainer, it communicates with the backwash device; And there is a Mgs to control at sewage draining exit.When sensor detecting when mesh is stopped up by oil stain, when starting the scraper rotation, the control valve of sewage draining exit is pressed the program behavior that setting means is carried out open closed, when the moment that control valve is opened, the pressure of pipeline is greater than the pressure of sewage draining exit, produce pressure difference, produce back suction power in the part of backwash device, thereby the oil film on the filter screen is sucked sewage draining exit.
Another design of automatic cleaning strainer is that its filter screen is not to make with dull and stereotyped, because the dull and stereotyped filter screen of making can increase the chance that dirt stops up filter screen, so each root of the filter screen of automatic cleaning strainer all is leg-of-mutton; Its inwall is level and smooth, help the cleaning of scraper and brush, and outer net is an opening triangular in shape, and the dirt that therefore is less than or equal to the filtering accuracy requirement can not be stuck on the filter screen, makes strainer remain good working order.
Another characteristics that automatic cleaning strainer is different from other automatic cleaning strainer are, control center of exterior design at machine, the user can be according to the variation that is filtered liquid (often changing as foreign material content), by switchboard the cleaning process of filter interior is adjusted, thereby guarantee that washing unit can rational and effective clean filter screen, really accomplish initiatively to clean.
The belt filter pressing dehydrator: the belt filter pressing dehydrator is to carry sludge blanket secretly by the strainer of two tensionings up and down, S-shaped process from the roll-in tube of a succession of regular arrangement, the tension force of dependence strainer itself forms squeezing and the shearing force to sludge blanket, capillary water in the sludge blanket is pushed out, obtain the higher mud cake of solid content, thereby realize sludge dewatering.
Sterilizing agent throwing device: be used for killing water bacterium, intestinal bacteria etc., guarantee that effluent quality reaches miscellaneous domestic water quality standard.At present, the domestic apparatus and method for that is used for water sterilization is a lot, as: chlorine dioxide generator, ozonizer, chlorine tablets do speculate, chlorine liquid is wet speculates etc.Sterilizing agent can adopt chlorine bleach liquor, solid chlorine tablets, Babysafe etc.
Water quality adjusting system: because wastewater flow rate and enter the ununiformity of impurity in the discharge of wastewater process, making flow, concentration and the temperature of waste water has variation in a big way in round the clock.For guaranteeing water conditioning system works better, be not subjected to the influence of waste water peak flow or change in concentration, so utilize regulating tank to come regulating pondage and water quality.In addition, waste water can neutralize in regulating tank and the sewage of discharging is carried out pre-treatment.
Processed water Processing intent The main component for the treatment of water Handle quantity m 3/ hour Treatment process Result
Sewage (it is acid that pH value is) Adjust water quality Slant acidity etc. 20-1100m 3 Water quality is adjusted agent Make water ph value be neutrality etc.
Add for the first time flocculation agent: add flocculation agent through adjusted sewage, sewage is carried out ionic adsorption handle, it is free to reach the water-soluble organic compound waddingization.
Processed water Processing intent The main component for the treatment of water Handle quantity m 3/ hour Treatment process Result
Through the adjusted sewage of water quality Make the water-soluble organic compound waddingization free Outstanding absurd creature such as organism and colloid 20-1100m 3 Add quick flocculating agent; Waddingization is free; The Ex-all fiber,
It is free that outstanding absurd creature produces waddingization rapidly Outstanding absurd creatures such as colloid, grey matter organic/inorganic substance
Coarse filtration for the first time: waste water promotes from regulating tank and through after the one-level flocculation, big floc sedimentation organic fibre throw out is fallen in coarse filtration.
Processed water Processing intent The main component for the treatment of water Handle quantity m 3/ hour Treatment process Result
Water after the adjustment waddingization Organic fibre is fallen in coarse filtration Organic coarse fiber, colloid etc. 20-1100m 3 Metal net device is handled The pollution substance coarse filtration
Metallic membrane is smart for the second time filters:
Water after the coarse filtration enters pipeline and begins to finish the smart filtration procedure of metallic membrane.
The metal membrane filter process: after adding flocculation agent for the first time, impurity is condensed into the granulated substance of hydrophilic insoluble in water in the water that is filtered, though this granulated substance is water insoluble, its filtration procedure has certain degree of difficulty, so be easy to filter stoppage.The core technology of this process metal film filter is a filter screen, and this metal membrane filter device not only can filter out by successfully that viscosity is high material, can also automatically dirt be discharged under non-maintaining situation.This metal membrane filter device utilizes the not viscosity of its metallic membrane, makes the surface of metallic membrane form one deck waste layer in filtration procedure, utilizes this waste layer with the slag filter residue again, to reach abundant filtering purpose.
Processed water Processing intent The main component for the treatment of water Handle quantity m 3/ hour Treatment process Result
The ion waddingization and free after water Filter out thick organic fibre Organic coarse fiber, colloid etc. 20-1100m 3 The microfiltration membrane device is handled Finishing the above pollution substance of 0.6mm leaches
The super smart filtration of metallic membrane for the third time: result reaches discharging standards GB35442001.
Processed water Processing intent The main component for the treatment of water Handle quantity m 3/ hour Treatment process Result
Liquid after filtering for the second time Purify raffinate; Reach the standard that recycles Outstanding absurd creatures such as thin organism and colloid 20-1100m 3 Adding quick flocculating agent makes outstanding absurd creature produce flocculation rapidly Reach discharging standards GB3544 2001
Sludge dewatering: can not directly discharge from metal membrane filter device sewage draining exit sludge discharged, therefore will discharge mud and concentrate, and be with the press dehydration, the comprehensive collection of this process using concentrates and dehydration is the equipment of one.This device processes ability: maximum 40m 3/ h or 360kgDS/h; Strainer is wide: 1.1 meters; Flocculation agent proportioning: 2.5 ‰-4 ‰; Excess sludge water ratio: 99.45%; Water ratio after the sludge dewatering:<75%.
Dynamically flocculation: add flocculation agent, it comprises organic cellulose, for example: W-Gum, sweet potato starch or straw pulp Mierocrystalline cellulose etc.; It is rendered to pass through high-speed motion in the sewage, the physics biochemical reaction takes place in moment, and with the flocculation of organic oxygen compound dynamic diffusion such as water-soluble robust fibre, grey body, pigment, colloid, flocculating rate is up to 99.7%, by the metal membrane filter technology, remove pollution substance again.
The metallic membrane unit: it is a metallic membrane specialty strainer, is a kind of metallic membrane that utilizes metallic character to produce.This film can will be filtered effective isolating while of medium and impurity, guarantee that filter screen is not blocked.In order to guarantee that this technology is brought into play more fully, be provided with washing unit in the inside of metal membrane filter device.
The present invention can dispose different water conditioner, flocculation agent according to the different dirty factor characteristics that causes, and makes the pollution factor instaneous polymerization become big floc sedimentation state, is convenient to extract; The present invention adopts the metallic membrane technology, carries out the serial cascade filtration and extracts, and reaches the pollution treatment purpose; Its tail water refluxes and designs, and not only can release rare and the reduction Pollutant levels, also can improve treatment effect, improves the effluent quality index; The present invention adopts the sewage isolation technique, replaces dewatered sludge to handle the suction mud equipment of workshop section with the most easy movable excavating pump.
The invention has the advantages that:
1, water treating equipment of the present invention are rational in infrastructure, and facility investment is few, reduced water treatment difficulty and fund input; Realize desanding, removed stone, removed colloid and removed ash content; Water after the processing can be recycled; Do not discharge waste liquid.
2, the present invention adopts totally-enclosed pipeline to be connected with each system purification unit, realizes the processing unit cleaner production, and construction investment and investment in land have been reduced in aeration tank that need not be big.
3, the water after water technology of the present invention is handled can be recycled and not efflux, and has thoroughly stopped secondary environmental pollution, and noiselessness, free from extraneous odour produce in system's operational process, and the water quality after the processing reaches national GB8978-1996 first discharge standard.
4, the present invention adopts string format cascade filtration structure formation.The characteristics of this kind structure formation are: simple in structure, be convenient to the construction.
5, according to examining report: the present invention monitors total row mouthful petroleum-type, sulfide etc., all reaches corresponding national standards.
The principal pollutant title COD cr BOD 5 SS PH
Unit Mg/L Mg/L Mg/L
After sewage quality is handled 80 70 70 6-9
Standard GB 3,544 2001 300 100 100 6-9
6, running expense of the present invention is low, and the reduced price of waste water per ton is low.
7, the present invention can be widely used in China's municipal effluent and industrial sewage, as industrial sewages such as power station, tannery, paper mill, petroleum chemical plant, pharmaceutical factory, garbage loading embeading factory, penetrating fluids; And to effective improvement in contaminated river and lake, its social benefit, economic benefit and obvious environment benefit.
Description of drawings
Fig. 1 is a water treating equipment embodiment skeleton diagram of the present invention.
Fig. 2 is TR1 water treating equipment unit skeleton diagram among the water treating equipment embodiment of the present invention.
Fig. 3 is TR2 water treating equipment unit skeleton diagram among the water treating equipment embodiment of the present invention.
Fig. 4 is TR3 water treating equipment unit skeleton diagram among the water treating equipment embodiment of the present invention.
Fig. 5 is TR4 water treating equipment unit skeleton diagram among the water treating equipment embodiment of the present invention.
Fig. 6 is TR5 terminal water desalination treatment facility unit skeleton diagram among the water treating equipment embodiment of the present invention.
Fig. 7 is a water treatment technological process skeleton diagram of the present invention.
Fig. 8 is filter bank technological process block-diagram in the water technology of the present invention.
Fig. 9 is metal membrane filter device structural representation in the water technology of the present invention.
Figure 10 is a water treatment erecting equipment process flow diagram of the present invention.
Embodiment
The present invention is further illustrated below in conjunction with drawings and Examples.
Water treating equipment of the present invention comprise: flocculation agent storage tank, flocculation filtration jar, mechanical filter, accurate filter, micro-filtrate membrane filtration device, pump and pipeline.
With the sewage disposal that produces in the pulping and papermaking processes is example.
As shown in Figure 1, the present invention includes: one-level washing device 1, secondary washing device 2, float slurry equipment 3, float slurry raffinate equipment 4; And be connected with online water treating equipment unit TR1, TR2, TR3, TR4 respectively; Water treating equipment unit TR2, TR3, TR4 are connected with terminal water desalination treatment facility unit TR5 respectively; And the output terminal of terminal water desalination treatment facility unit TR5 respectively with one-level washing device 1, secondary washing device 2, float equipment slurry 3, float slurry raffinate equipment 4 and be connected; Wherein, the output terminal of water treating equipment unit TR1 is connected with one-level washing device 1; Finish sewage disposal in the pulping process with circulation.
As shown in Figure 2, water treating equipment unit TR1 is that it is made up of flocculant concentration pump 101, flocculation filtration jar 102, sewage jar 103, pump and pipeline to the sewage disposal in one-level washing device 1 workshop section's process.Wherein, the sewage inlet of flocculation filtration jar 102 is connected with the dosing mouth of flocculant concentration pump 101, the delivery port of one-level washing device 1; And the output terminal of flocculation filtration jar 102 is connected with sewage jar 103, and clear water is after treatment delivered to the clear water inlet of one-level washing device 1 again, to recycle.
As shown in Figure 3, water treating equipment unit TR3 is used for to floating the sewage disposal of bleach residue in slurry equipment 3 processes, and it is made up of flocculant concentration pump 301, flocculation filtration jar 302, sewage jar 303, pump and pipeline.Wherein, the dosing mouth of the sewage inlet of flocculation filtration jar 302 and flocculant concentration pump 301, the delivery port that floats slurry equipment 3 are connected; And the output terminal of flocculation filtration jar 302 is connected with sewage jar 303, and water is after treatment delivered to terminal water desalination treatment facility unit TR5 again and carried out the terminal water treatment.
As shown in Figure 4, water treating equipment unit TR2 is to the sewage disposal in secondary washing device 2 processes, and it is made up of flocculant concentration pump 201, flocculation filtration jar 202, mechanical filter 203, accurate filter 204, micro-filtrate membrane filtration device 205, pump and pipeline.Wherein, the sewage inlet of flocculation filtration jar 202 is connected with the dosing mouth of flocculant concentration pump 201, the delivery port of secondary washing device 2; Water after finishing one-level and handle via flocculation filtration jar 202 is delivered to via mechanical filter 203, accurate filter 204, micro-filtrate membrane filtration device 205 and is carried out the two-stage ultrafiltering water treatment; Deliver to terminal water desalination treatment facility unit TR5 again through the water after the two-stage ultrafiltering water treatment and carry out the terminal water treatment.
As shown in Figure 5, water treating equipment unit TR4 starches the residual bleaching liquor sewage disposal after separating in the raffinate equipment 4 to floating, and it is made up of flocculant concentration pump 401, flocculation filtration jar 402, mechanical filter 403, accurate filter 404, micro-filtrate membrane filtration device 405, pump and pipeline.Wherein, the dosing mouth of the sewage inlet of flocculation filtration jar 402 and flocculant concentration pump 401, the sewage outlet that floats slurry raffinate equipment 4 are connected; Finish water after one-level is handled through flocculation filtration jar 402, deliver to mechanical filter 403, accurate filter 404, micro-filtrate membrane filtration device 405 again and carry out the two-stage ultrafiltering water treatment; Deliver to terminal water desalination treatment facility unit TR5 again through the water after the two-stage ultrafiltering processing and carry out the terminal water treatment.
As shown in Figure 6, terminal water desalination treatment facility unit TR5 is the salt balance in being used for guaranteeing recycling after the water treatment, and it is made up of many groups sea water desaltination treatment unit 501, atomizing dry tower 502.Water after water treating equipment unit TR2, TR3, TR4 water treatment, by pipeline enter many group sea water desaltination treatment unit 501, atomizing dry tower 502 carries out desalting treatment; After finishing desalting treatment, finally obtain water purification 503 and dry Industrial Salt 504.
Isolated flocculated sludge after online water treating equipment unit TR1, TR2, TR3, TR4 handle is delivered to the flocculation slag bath by the road, can be used as organic fertilizer.
What technical scheme of the present invention related to is the production unit of Industrial Wastewater Treatment during pulping and paper-making is produced.In concrete enforcement, can be according to practical situation, with the integral part of the present invention as new production line; Also can be with the present invention as former online transformation of building the production line water treating equipment.
As shown in Figure 7, water treatment technological process of the present invention comprises:
The sewage A that 1), will handle sends into water quality adjusting system B;
2), in water quality adjusting system B, add to adjust agent B1, regulating pondage and water quality are carried out pre-treatment to sewage;
3) G that dynamically flocculates handles: add flocculation agent, it comprises organic cellulose: W-Gum, sweet potato starch or straw pulp Mierocrystalline cellulose, and with the flocculation of organic oxygen compound dynamic diffusion such as water-soluble robust fibre, grey body, pigment, colloid, flocculating rate is up to 99.7%;
4), carry out filtration treatment:
The first road coarse filtration: handle by coarse filtration unit C, filter out the organic fibre throw out;
The second road metallic membrane is smart to be filtered: D1 filters by the metal membrane filter unit, removes pollution substance;
The super smart filtration of the 3rd road metallic membrane: filter by metal membrane filter unit D2 again, remove pollution substance, reach discharging standards GB3544 2001;
Water A ' up to standard can reuse after the super smart filtration of metallic membrane; After backwater treatment system F1 and backwater secondary treatment system F2 were passed through in the water outlet of press filtration unit E, refluxing entered water quality adjusting system B;
5), enter press filtration unit E and carry out sludge dewatering: can not directly discharge from metal membrane filter device sewage draining exit sludge discharged, therefore will discharge mud concentrates, and be with the press dehydration, adopt comprehensive collection to concentrate and dewater to be the equipment of one, its processing power: maximum 40m 3/ h or 360kgDS/h; Strainer is wide: 1.1 meters; Flocculation agent proportioning: 2.5 ‰-4 ‰; Excess sludge water ratio: 99.45%; Water ratio after the sludge dewatering:<75%;
6) enter backwater treatment system F1, again, backwater secondary treatment system F2 carries out circular treatment, finish entire sewage and handle.
As shown in Figure 8, the filter bank flow process comprises in the water technology of the present invention:
1), below standard water is sent into intelligent flocculation system G and carried out dynamic flocculation treatment: add flocculating agent B 1, it comprises organic cellulose: W-Gum, sweet potato starch or straw pulp Mierocrystalline cellulose, with the flocculation of organic oxygen compound dynamic diffusion such as water-soluble robust fibre, grey body, pigment, colloid, flocculating rate is up to 99.7%;
2), the water after will flocculating enters metal membrane filter device D11, D22 again by pipeline and pump H, filters out organic fibre throw out and pollution substance; Reuse water up to standard is put back to production line I carry out reuse;
3), enter the press filtration unit E that slags tap and carry out sludge dewatering.
The structural representation of the metal membrane filter device among the present invention, as shown in Figure 9, wherein: 5, import and export the position flange; 6, import and export the position pipe; 7, metal membrane filter device shell; 8, filter screen; 9, brush; 10, sewage draining exit position pipe; 11, sewage draining exit position flange; 12, motor; 13, metal membrane filter device main body loam cake flange; 14, bolt * nut; 15, flange intermediate washer; 16, metal membrane filter device main flange; N1, import; N2, outlet; N3, sewage draining exit; N4, venting port.
As shown in figure 10, water treatment erecting equipment of the present invention technical process comprises:
The sewage A that 1), will handle is by pipeline and be pumped into treatment system;
2), in pipeline, add adjustment agent B1 by adding pharmacy K;
3), thick barrier pre-treatment: sewage A enters thick barrier L by the road, enters settling pit M again;
4) add flocculation agent G1 by adding pharmacy K in pipeline, it comprises organic cellulose: W-Gum, sweet potato starch or straw pulp Mierocrystalline cellulose, and with the flocculation of organic oxygen compound dynamic diffusion such as water-soluble robust fibre, grey body, pigment, colloid, flocculating rate is up to 99.7%;
5), before the coarse filtration unit metering outfit T is set;
6), carry out filtration treatment simultaneously by two cover filter banks: it comprises: the first road coarse filtration unit C1, the second road fine filter group D1, the 3rd road super fine filter group D2 filter out the organic fibre throw out, the removal pollution substance;
7) the mud W after, filter bank is handled goes into sewage recycling and utilizes production line to handle; The water outlet of super fine filter group D2 enters clean water basin Q;
8), tail water A ' up to standard after treatment can carry out qualified discharge;
9), mud W enters sludge treatment workshop W1 and carries out sludge dewatering treatment: its processing power: maximum 40m 3/ h or 360kgDS/h; Strainer is wide: 1.1 meters; Flocculation agent proportioning: 2.5 ‰-4 ‰; Excess sludge water ratio: 99.45%; Water ratio after the sludge dewatering:<75%;
10), in the W1 of sludge treatment workshop, the sewage of deviating from from mud enters the coarse filtration unit once more and carries out circular treatment, finishes the entire sewage treating processes.

Claims (4)

1, the sewage treatment process method of a kind of trade effluent and municipal wastewater, it is characterized in that: it comprises:
1), the sewage that will handle (A) is sent into water quality adjusting system B;
2), in water quality adjusting system (B), add to adjust agent (B1), regulating pondage and water quality are carried out pre-treatment to sewage;
3) dynamically flocculate (G) handle: add flocculation agent, it comprises organic cellulose: W-Gum, sweet potato starch or straw pulp Mierocrystalline cellulose, with the flocculation of organic oxygen compound dynamic diffusion such as water-soluble robust fibre, grey body, pigment, colloid, flocculating rate is up to 99.7%;
4), carry out filtration treatment:
The first road coarse filtration: handle by coarse filtration unit (C), filter out the organic fibre throw out;
The second road metallic membrane is smart to be filtered: (D1) filters by the metal membrane filter unit, removes pollution substance;
The super smart filtration of the 3rd road metallic membrane: filter by metal membrane filter unit (D2) again, remove pollution substance;
Water A ' up to standard can reuse after the super smart filtration of metallic membrane; After backwater treatment system F1 and backwater secondary treatment system F2 were passed through in the water outlet of press filtration unit E, refluxing entered water quality adjusting system B;
5), enter press filtration unit (E) and carry out sludge dewatering: can not directly discharge from metal membrane filter device sewage draining exit sludge discharged, therefore will discharge mud concentrates, and be with the press dehydration, adopt comprehensive collection to concentrate and dewater to be the equipment of one, its processing power: maximum 40m 3/ h or 360kgDS/h; Strainer is wide: 1.1 meters; Flocculation agent proportioning: 2.5 ‰-4 ‰; Excess sludge water ratio: 99.45%; Water ratio after the sludge dewatering:<75%;
6) enter backwater treatment system (F1), again, backwater secondary treatment system (F2) carries out circular treatment, finish entire sewage and handle.
2, sewage treatment process method according to claim 1, it is characterized in that: the filter bank flow process comprises:
1), below standard water is sent into intelligent flocculation system (G) and carried out dynamic flocculation treatment: add flocculation agent (B1), it comprises organic cellulose: W-Gum, sweet potato starch or straw pulp Mierocrystalline cellulose, with the flocculation of organic oxygen compound dynamic diffusion such as water-soluble robust fibre, grey body, pigment, colloid, flocculating rate is up to 99.7%;
2), the water after will flocculating enters metal membrane filter device (D11), (D22) again by pipeline and pump (H), filters out organic fibre throw out and pollution substance; Reuse water up to standard is put back to production line I carry out reuse;
3), enter the press filtration unit (E) of slagging tap and carry out sludge dewatering.
3, sewage treatment process method according to claim 1 and 2, it is characterized in that: the smart filtration of described metallic membrane comprises: the water after the coarse filtration enters pipeline and begins to finish metal membrane filter, and it is the granulated substance that impurity is condensed into hydrophilic insoluble in water in the water that is filtered of flocculation agent; Though this granulated substance is water insoluble, its filtration procedure has certain degree of difficulty, is easy to the metal membrane filter device is stopped up; The core technology of this metal membrane filter device is a filter screen, and this metal membrane filter device not only can filter out by successfully that viscosity is high material, can also automatically dirt be excreted under non-maintaining situation; This metal membrane filter device utilizes the not viscosity of its metallic membrane, makes the surface of metallic membrane form one deck waste layer in filtration procedure, utilizes this waste layer with the slag filter residue again, reaches abundant filtering purpose.
4, the sewage disposal device mounting process of a kind of trade effluent and municipal wastewater, it is characterized in that: it comprises:
1), the sewage that will handle (A) is by pipeline and be pumped into treatment system;
2), in pipeline, add adjustment agent (B1) by adding pharmacy (K);
3), thick barrier pre-treatment: sewage A enters thick barrier L by the road, enters settling pit M again;
4) add flocculation agent (G1) by adding pharmacy K in pipeline, it comprises organic cellulose: W-Gum, sweet potato starch or straw pulp Mierocrystalline cellulose; With the flocculation of organic oxygen compound dynamic diffusion such as water-soluble robust fibre, grey body, pigment, colloid, flocculating rate is up to 99.7%;
5), control the content of flocculation agent by metering outfit (T); Sewage quantity by metering outfit (T ') control coarse filtration unit;
6), carry out filtration treatment simultaneously by two cover filter banks: it comprises: the first road coarse filtration unit (C1), the second road fine filter group (D1), the super fine filter group in the 3rd road (D2) filter out the organic fibre throw out, the removal pollution substance;
7) (W goes into sewage recycling and utilizes production line to handle the mud after, filter bank is handled; The water outlet of super fine filter group D2 enters clean water basin Q;
8), tail water up to standard after treatment (A ') can carry out qualified discharge;
9), mud (W) enters sludge treatment workshop (W1) and carries out sludge dewatering treatment: its processing power: maximum 40m 3/ h or 360kgDS/h; Strainer is wide: 1.1 meters; Flocculation agent proportioning: 2.5 ‰-4 ‰; Excess sludge water ratio: 99.45%; Water ratio after the sludge dewatering:<75%;
10), in sludge treatment workshop (W1), the sewage of deviating from from mud enters the coarse filtration unit once more and carries out circular treatment, finishes the entire sewage treating processes.
CN2009101433447A 2004-12-30 2005-12-30 Industrial wastewater and municipal wastewater treatment method Expired - Fee Related CN101585611B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102260012A (en) * 2011-05-19 2011-11-30 河海大学 Riverbank-type tail water treatment system
CN105174550A (en) * 2015-10-09 2015-12-23 中林联盟(北京)科技发展有限公司 Segmented wastewater treatment process
CN112870803A (en) * 2021-03-08 2021-06-01 湖南金龙智造科技股份有限公司 Intelligent grating for sewage filtration, grating cleaning device and pollutant cleaning method
CN113072285A (en) * 2021-04-22 2021-07-06 泉州市程远环保工程有限公司 Sludge concentration and dehydration integrated treatment process
CN113952785A (en) * 2021-11-24 2022-01-21 深圳市福昌发电路板有限公司 Sewage treatment system for manufacturing decorative printing paper

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102260012A (en) * 2011-05-19 2011-11-30 河海大学 Riverbank-type tail water treatment system
CN102260012B (en) * 2011-05-19 2012-09-05 河海大学 Riverbank-type tail water treatment system
CN105174550A (en) * 2015-10-09 2015-12-23 中林联盟(北京)科技发展有限公司 Segmented wastewater treatment process
CN112870803A (en) * 2021-03-08 2021-06-01 湖南金龙智造科技股份有限公司 Intelligent grating for sewage filtration, grating cleaning device and pollutant cleaning method
CN112870803B (en) * 2021-03-08 2024-04-23 湖南金龙智造科技股份有限公司 Intelligent sewage filtering grid, grid cleaning device and pollutant cleaning method
CN113072285A (en) * 2021-04-22 2021-07-06 泉州市程远环保工程有限公司 Sludge concentration and dehydration integrated treatment process
CN113952785A (en) * 2021-11-24 2022-01-21 深圳市福昌发电路板有限公司 Sewage treatment system for manufacturing decorative printing paper

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