CN101583699A - System for generating Brown gas and uses thereof - Google Patents

System for generating Brown gas and uses thereof Download PDF

Info

Publication number
CN101583699A
CN101583699A CNA2007800418504A CN200780041850A CN101583699A CN 101583699 A CN101583699 A CN 101583699A CN A2007800418504 A CNA2007800418504 A CN A2007800418504A CN 200780041850 A CN200780041850 A CN 200780041850A CN 101583699 A CN101583699 A CN 101583699A
Authority
CN
China
Prior art keywords
gas
blang
chamber
water
steam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2007800418504A
Other languages
Chinese (zh)
Inventor
莫祥谢·史蒂文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CN101583699A publication Critical patent/CN101583699A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/30Use of alternative fuels, e.g. biofuels

Abstract

A system for the generation, storage and use of Brown gas comprising at least one Brown gas generator (116), in communication with an electricity supply (104) and water supply (102); at least one first storage chamber (122), in fluid communication with the generator, for storing the Brown gas generated from said generator (116); and Brown gas application means (146, 200, 300) in communication with said at least one first storage chamber, wherein said generator and first storage chamber are located proximate the Brown gas application means. For example, the Brown gas may be used for the production of hot water (146), for the production of chilled water (200) and as fuel in an incineration unit (300).

Description

Be used to produce the system and the application thereof of Blang's gas
Invention field
The present invention relates to a kind of application that is used to produce the system and the different purposes thereof of Blang's gas.
Background of invention
Sweet natural gas is generally used for family expenses and industrial purposes.Yet, act as a fuel the source to satisfy the needs that increase day by day to using Sweet natural gas, for example the worry of the heat supply of family and factory is increasing.Greenhouse discharge from combustion of natural gas comprises carbonic acid gas, sulfurous gas, nitrous oxide and water vapor.In fact, natural gas burning is considered to one of essential environmental factors of facilitating Global warming.The whole world that presents a contrast owing to the global shortage with natural gas supply needs to increase, and using another problem of Sweet natural gas is its secular economic feasibility, and availability.Other problem is that not all country all has the gas source of oneself, and therefore seriously depending on other country obtains Sweet natural gas.Also necessity exists a large amount of infrastructure networks to support supply, storage and the distribution of Sweet natural gas to the final user.Costliness is not only built and safeguarded to network at vast geographic exposure pipeline and final equipment, and be very easy to be subjected to external influence, for example the natural disaster or the threat of terrorism.
Propose several alternative fuel source and replaced Sweet natural gas.An example is to use sun power and is converted into feasible energy source.Another example is at US 4,081, the Blang's gas described in 656, and the content of this US 4,081,656 is combined in this by reference.Blang's gas is called as the energy source that is fit to that is used for pure industrial welding and cutting application.Particularly, US 4,081, and 656 have described that a kind of electrolysis by water produces oxygen and the method for the mixture of hydrogen.Product Blang gas has significant characteristic, high heating value for example, and can carry out the reactivity burning with selected metal and low pollution emission thing.
Several patents has been described the application of Blang's gas.For example, US 6,761, and 558 have described the heating installation that utilizes Blang's gas thermal response, and its content is combined in this by reference.It has further described the method for catching heat after Blang's gas is by hexane liquid from its reactivity burning.US 6,443, and 725 have described in the burner circulating combustion Blang gas method with heating heat production device, and its content is combined in this by reference.
Consider above-mentioned situation, in the current techniques developmental level, need reliable and safe system to supply family expenses and industrial energy as can be seen, thereby can satisfy the increase of energy requirement, and to the minimum that influences of environment.In addition, this explanation needs some row to have the new technology of these advantages.
For example, burning is usual way of eliminating pathogenic agent, virus and the toxic organic compound be present in most of families and the industrial waste.Yet conventional incinerator faces some problems more and more.For example a large amount of fuel of incineration plant consumption comes combustion waste.Fuel can comprise Sweet natural gas, propane or thin fuel oil.Because need increase and the whole world shortage of natural gas supply the whole world of Sweet natural gas, therefore traditional thermal incineration is for the very expensive means of waste treatment.In order to alleviate this influence, new incineration plant is positioned at from densely populated regional farther place, thereby causes the high transportation cost of refuse, fuel and other supply, because for the operation incineration plant, these all need through longer distance.
Another problem is owing to the incomplete combustion in the burning process of family and industrial waste dioxin and furans to be discharged in the atmosphere, causes the serious health threat to society.This has caused increasing from the pressure of environment, so that strict control and control have been forced in the treatment of wastes produced that produces dioxin and furans.Under the situation of high residence time of at least 2 seconds of the very chaotic mixing (utilizing forced ventilation) of refuse and stack gas, can in burning process, destroy De dioxin and furans in the combustion chamber effectively greater than 1200 ° combustion temperatures.Therefore, guarantee the perfect combustion of refuse and make that the minimized a kind of method of formation of De dioxin and furans is to improve the temperature of existing burning process with remarkable rising stove in the combustion processes, to improve efficiency of combustion.Yet this will cause the increase of running cost, and reason is that fuel combustion will increase.
Several alternative approach have been proposed to reach high temperature of combustion.An example is to change fluidized-bed propane incinerator into.Another example is to use the thermal plasma incinerator, and it is used to eliminate refuse with high energy, high-intensity plasma jet.Yet these methods can not directly be attached in the existing burning facility.Another kind method be utilize cheap, calorific value is high and have the alternative fuel source of minimum environmental influence.
In another example, airborne particulate matter emissions and flue gas emissions thing remain a general problem.Be known that extensively that also these discharges cause significant environment and health risk.These discharges may be produced by commercial run, coal combustion with from the burning facility of trash burning, and this only lists several.As the result of described effect (process), if be not discharged in the atmosphere under having situation about further handling, then the composition of discharge may be harmful to environment.
The existing measure of control and processing discharge and stack gas comprises the use of cyclone, electrostatic precipitator (ESP), settling pocket, wet scrubber and fabric filter system.Yet on big degree, these only help to reduce the particulate matter in discharge and the stack gas, and the composition of partially disposed stack gas and discharge.Therefore, when the discharge that will be somebody's turn to do " processing " and flue gas emissions were in atmosphere, discharge and stack gas still may contain might environmentally harmful composition.
For example, cyclone has low total particle collection effciency, particularly for the particle size that is lower than 10mm.Under the situation of ESP, although effective aspect processing discharge and stack gas, installation and maintenance is very expensive.They also need big installing space.And, in electromerism, may produce ozone by the electronegative electrode of ESP, this has increased environmental problem.Also may need the personnel of highly training to operate ESP.The fabric filter system also is expensive, and reason is when operating under surpassing about 290 ℃ temperature, needs the expensive refractory mineral or the fabric of metal.Also exist certain density some dust in the presence of unexpected Mars or flame, to explode and incendiary harm.
What address these problems under the circumstances, is favourable with the means with energy efficiency reliably on environment.
Summary of the invention
According to first aspect, the invention provides a kind of system that is used to produce, store and utilize Blang's gas, described system comprises:
-at least one Blang's gas generator, it is communicated with power supply and water source (water supply);
-at least one first storing chamber, it is communicated with the producer fluid, is used to store the Blang's gas that is produced by described producer; With
-Blang gas application apparatus, it is communicated with described at least one first storing chamber,
The wherein said producer and first storing chamber are positioned at the contiguous place (proximate) of Blang's gas application apparatus.
Should be understood that " contiguous place " relates to expection of the present invention and use.For example, the application of using at intra-building must limit " contiguous the locating " that falls into inside, mansion house, for example has the factory building of conventional boiler, regulates the installation of similar roof with industrial air or has the adjacent of external frame of the mansion of switch box.
For example in the housing development, " contiguous place " can be included in the central position in the housing development in different application.Itself and conventional energy are supplied with such as mains electricity relatively, are different, supply with by the energy of routine, can produce generating (generation) for several kilometers away from exploitation place.Therefore, therefore in this case, and at " remote " aspect generating and/or the storage, need the conventional energy resources of the basic Infrastructure that is used to distribute to supply with and compare, " contiguous place " is restricted in the available position, need not basic Infrastructure before the final assignment of purposes.Therefore, in the present invention, has the producer that is positioned at the contiguous place of Blang's gas application apparatus and the efficient that advantage is the raising system of first storing chamber.When comparing with the dependence exterior source of energy, this configuration also reduces the cost that is used to provide Infrastructure still less.
Shown that Blang's gas has high heating value when comparing with the Sweet natural gas of other form, and insignificant pollutant effulent.Therefore, it will be favourable using Blang's gas for family and industrial purposes.For example, the Blang's gas that produces can be used to provide pipeline gas, described pipeline gas be used for cooking with the space heating or be used for preparation technology industrial thermal treatment, be used to produce laundry, cleaning and flushing usefulness hot water, be used to produce the water coolant of space cooling usefulness, and be used to provide fuel that incinerator uses with decomposition rubbish, refuse and other family or industrial waste.
In second aspect, the invention provides a kind of boiler and burner device that is used to produce hot water, described boiler and burner device comprises:
-be used to receive first of feedwater enter the mouth;
-be used to receive second inlet from Blang's gas of Blang's gas generator; With
-be used to discharge the outlet of the hot water that is produced.
According to another embodiment, application apparatus can comprise that at least one is used to produce first Room of hot water, wherein obtained being used to heat the heat of described hot water by the burning of Blang's gas, and Blang's gas obtains from least one first storing chamber.Particularly, at least one first Room can be the boiler and burner device.At least one first Room can comprise:
-be used to receive first inlet from Blang's gas of at least one first storing chamber;
-be used to receive second of water enter the mouth;
-gas burner; With
-be used to discharge the outlet of the hot water that is produced,
Wherein the Blang's gas from first inlet can be burnt by gas burner, thereby heats the water from second inlet, and wherein the water that has heated can be discharged from outlet.
Being used to receive second of water enters the mouth and can be connected with the outlet of at least one heat exchanger that is accommodated at least one Blang's gas generator inside.
Being used to receive second of water enters the mouth and can also be connected with the outlet of at least one solar thermal collector.
Can settle at least one flash eliminator in the first inlet front.Flash eliminator can comprise and usually using on the supply line of volatilization gas such as hydrogen, acetylene and other fuel gas, is used to prevent that propagation of flame from arriving the device of supply source such as pressurization gas hold-up vessel or producer gas generator.For the present invention, flash eliminator can be installed on each different juncture (junction) of Blang's source of the gas, light the Blang's gas hold-up vessel that partly is filled with as the Liquefied Hydrocarbon of flame refrigerant conversely to prevent flame (flash).
At least one first Room can also comprise the reactive metal element.For example, the reactive metal element that can use at least one first Room can include but not limited to any in the following material: platinum, steel, nickel-chromium alloy or other high temperature nickel alloy.The reactive metal element can be the form of tool foraminous single curved surface or bi-curved housing on surface of shell, so that the contact area maximum between hardware and the Blang's gas flame.Nickel-chromium alloy can be in the form of nichrome wire.The reactive metal element can be arranged on the path of Blang's gas flame with the realization response burning, thereby further improve flame temperature in first Room.
System of the present invention can also comprise at least one second storing chamber that is used to store the hot water that is produced by at least one first Room.Therefore, at least one second storing chamber can be connected with the outlet of at least one first Room.The hot water that is produced can be stored in the storing chamber and heat to be used for space in the future, can use in laundry, cleaning and flushing.
According to another embodiment, application apparatus can also comprise that at least one is used to produce second Room of chilled water.Particularly, at least one second Room can be absorbefacient cooling arrangement.
At least one second Room can comprise:
-be used to receive first of absorption agent enter the mouth;
-be used to receive second of refrigeration agent enter the mouth;
-be used to receive the 3rd inlet of water coolant;
-be used to receive the 4th inlet of warm water;
-the first heat exchanger;
-the second heat exchanger;
-be used to discharge first of warm water export; And
-be used to discharge second outlet of the chilled water that produced,
Wherein the 3rd inlet can be connected with first heat exchanger with first outlet, and the 4th inlet can be connected with second heat exchanger with second outlet.
Absorption agent can be lithiumbromide (LiBr), ammonia (NH 3) or other absorption agent that is fit to such as siccative or dehumidizer, this will be clearly to those skilled in the art.Refrigeration agent can be a water.For purpose of the present invention, also can use other suitable refrigeration agent.
At least one second Room can utilize by the heat that hot water produced of heat exchanger operation from least the second storing chamber, perhaps direct the heat that burning produced by Blang's gas from least one first Room, so that refrigeration agent and absorption agent evaporation, thereby realize refrigeration cycle.As the result of refrigeration cycle, be cooled from the water of at least one second Room.The chilled water that produces can be stored at least one the 3rd storing chamber.Chilled water can be used for various application.For example, being used for the space cooling uses.Particularly, can flow in the air processor that comprises heat exchanger and gas blower, so that the space cooling to be provided from the chilled water of at least one the 3rd storing chamber.
According to another embodiment, application apparatus of the present invention can also comprise: at least one is used for the 3rd Room of combustion waste.Particularly, described at least one the 3rd Room is the incinerator device.At least one the 3rd Room can comprise:
-the combustion unit of combustion waste by burning Blang's gas;
-the first inlet is connected with combustion unit, is used to receive refuse;
-the second inlet is connected with combustion unit, is used to receive the Blang's gas from least one first storing chamber; With
-outlet is connected with combustion unit, is used to discharge the stack gas that is produced by combustion unit.
Refuse can be separated into solid and Liquid wastes.Refuse can be handled before being supplied to combustion unit, to reduce the water capacity in the refuse.
Can also comprise according to system of the present invention: be used to discharge the heat exchanger that the outlet of low temperature flue gas is connected.Alternatively, can comprise according to system of the present invention: wet scrubber, it is connected with the outlet that is connected to combustion unit, so that from the temperature quenching of the stack gas of outlet discharging, and/or removes particle and flying dust in the stack gas.Wet scrubber is to be used for flow of process air to remove the device of the flying dust more than the submicron.Wet scrubber can have a series of high volumetrical spray nozzles, to provide from the fast quench of the stack gas of outlet discharging.For example, stack gas can be quenched to 200 ℃ to 300 ℃.Can be suppressed at like this and form dioxin and furans in the atmosphere.Outlet can also be connected with air filter system.It is favourable having incinerator in system, thereby can handle deleterious refuse under situation about not stopping over, and has therefore avoided the noxious emission to environment.Incinerator can also be configured to the incinerator of refuse to energy (waste-to-energy), and the heat that reclaims trash burning thus is to produce steam or power.
According to second aspect, the invention provides the boiler and burner device that is used to produce hot water, described boiler and burner device comprises:
-be used to receive first of feedwater enter the mouth;
-be used to receive second inlet from Blang's gas of Blang's gas generator; With
-be used to discharge the outlet of the hot water that is produced,
Thereby the Blang's gas that wherein burns is to produce the heat that heated feed water produces hot water.
The outlet that is used to discharge the hot water that is produced can be connected with the hold-up vessel that is used to store the hot water that is produced.First inlet of boiler and burner device can be with the outlet of the outlet of first heat exchanger of Blang's gas generator, at least one solar thermal collector and/or the hold-up vessel that is used to store the hot water that is produced be connected.
In the third aspect, the invention provides a kind of system that is used to reclaim by the heat that burning produced of incendiary material, described system comprises:
-at least one Blang's gas generator, it is communicated with power supply and water source;
-at least one first storing chamber, it is communicated with the producer fluid, is used to store the Blang's gas that is produced by described producer;
-at least one combustion chamber, it is communicated with at least one first storing chamber, and described incendiary material is used to burn; With
-at least one hot extraction chamber, it is fit to receive the heat that burning produced by incendiary material by the combustion chamber,
Wherein the producer and first storing chamber are positioned at the contiguous place of combustion chamber and hot extraction chamber.
In fourth aspect, the invention provides a kind of method that is used to reclaim by the heat that burning produced of incendiary material, said method comprising the steps of:
-by burning Blang gas, at least one combustion chamber, incendiary material is burnt; And
-receive the stack gas that produces by the combustion chamber to reclaim heat wherein.
At least one Blang's gas generator is accepted electric power hydrolytic dissociation become oxygen and hydrogen in electrolytic process.At least one Blang's gas generator can comprise tank room.The miscellany of oxygen and hydrogen is transported at least one first storing chamber with pipe.At least one first storing chamber can contain the Liquefied Hydrocarbon that predetermined amount can be used as the flame refrigerant.For example, Liquefied Hydrocarbon can be selected from hexane, heptane, methyl alcohol, ethanol and their combinations.Liquefied Hydrocarbon can be remained on low temperature, for example in the temperature of the boiling point that is lower than hydrocarbon.It will be understood by those skilled in the art that the storing temp that is fit to, because these are contents of common sense to available hydrocarbon.For example, described temperature can be between 20 ℃ to 100 ℃.Particularly, described temperature can be between 10 ℃ to 20 ℃.Especially, when employed hydrocarbon was hexane, described temperature can be 20 ℃.Liquefied Hydrocarbon is as the catalyzer (catalyst) of the flame temperature that relaxes Blang's gas.Especially, Liquefied Hydrocarbon can be a hexane.
According to another embodiment, combustion waste at least one combustion chamber.At least one combustion chamber using Blang gas acts as a fuel.Blang's gas can be available from least one first storing chamber.Particularly, the combustion chamber can be an incinerator.The combustion chamber can be the combustion chamber of single-stage or multistage structure.At least one combustion chamber can comprise:
Make incendiary material incendiary combustion unit by burning Blang gas;
First inlet, it is connected with combustion unit, is used to receive incendiary material;
Second inlet, it is connected with combustion unit, is used to receive the Blang's gas from least one storing chamber; With
Outlet, it is connected with combustion unit, is used to discharge the stack gas that is produced by combustion unit.
Incendiary material can be refuse, junk and other family or industrial waste.The combustion chamber can also comprise and is used for the pretreatment unit that pre-treatment is supplied to the incendiary material before the combustion unit.Incendiary material can be separated into solid and liquid incendiary material.Can be with incendiary material classification material capable of circulation to remove, incombustible and deleterious incendiary material.Can be with incendiary material densification and/or drying, to reduce the water capacity in the incendiary material.
Incendiary material is burnt in combustion unit.Incendiary material is supplied to combustion unit by any suitable method.For example, can incendiary material be supplied to combustion unit by gravity or mechanism.Combustion unit can comprise Blang's air burner, so that thermal-flame is projected in the combustion unit, thereby incendiary material is burnt.Combustion unit can also comprise that the permission fresh air is supplied to the other inlet of combustion unit with the more perfect combustion of realization incendiary material.Combustion unit can have the lining that uses refractory material, to keep the high temperature of combustion unit inside.Incendiary incendiary material and empyreumatic incombustible material can be collected in combustion unit inside, and from combustion unit, remove to handle.Incendiary incendiary material and empyreumatic incombustible material can experience further be handled before being disposed.
Except that combustion unit, the combustion chamber can also comprise and reoxidizes the chamber.Reoxidize the chamber and can be and be used in flue gas emissions before the atmosphere device of the stack gas that is produced in the heat washing combustion unit.For example, can be oxidized in reoxidizing the chamber by the stack gas that burning produced of incendiary material in the combustion unit, stack gas is further decomposed or is oxidized to the form more harmless to environment.Reoxidizing the chamber can also utilize Blang's gas to carry out its operation.Therefore, reoxidize the chamber and can comprise Blang's air burner, stack gas is heated to suitable temperature.For example, to be heated the temperature that reaches can be the reduction reaction temperature of stack gas composition to stack gas.This temperature can be between 1000 ℃ and 2000 ℃.Particularly, this temperature can be between about 1000 ℃ and 1500 ℃.
In order further to reduce the discharging of nitrous oxide, the Blang's air burner that reoxidizes in the chamber can replace the miscellany of pure oxygen and Blang's gas fresh air to be used for burning.High nitrogen inclusion in fresh air can be reacted, and forming at high temperature may environmentally harmful oxynitride.
Reoxidize the chamber and can comprise mesh grid parts (mesh-grid block).Blang's gas flame in the mesh grid arrangements of components can being become make it and reoxidize the chamber directly contacts, to reach a high temperature.The mesh grid parts can be supported on the metal frame.The mesh grid parts can be the mesh grid parts of any suitable material.For example, the mesh grid parts can be made by platinum, stainless steel, nickel-chromium alloy or aluminium-Chrome metal powder.Can make the stack gas introduced from combustion unit through the red-hot mesh grid parts that heated to realize stack gas composition such as carbon monoxide, oxynitride and other particulate thermal chemical reaction the complete oxidation stack gas.Processed stack gas can be used for other application in the system of the present invention, further handles before perhaps in being discharged into atmosphere.
At the multistage structure of combustion chamber for example in the two-stage combustion chamber, incendiary material can be burnt in combustion unit under inadequate air conditions, comprise the stack gas of carbon dioxide, water vapor, CO (carbon monoxide converter) gas, hydrogen and hydrocarbon compound gas with generation.Then, can be with stack gas with pipe-line transportation to reoxidizing the chamber.Reoxidize the chamber and can provide competent air, and the oxygen enrichment state, with the composition of further oxidation stack gas.
Transport out from combustion unit with pipeline in order to ensure the stack gas that will be produced, the combustion unit and the chamber of reoxidizing are maintained under the suitable negative pressure.For example, pressure can be-50Pa.Can keep negative pressure by vacuum fan being installed in the outlet of combustion unit.
As mentioned above, the burning of the incendiary material in the combustion chamber produces stack gas.Heat from stack gas is used to intrasystem other purposes.For example, the stack gas that produces can be piped at least one hot extraction chamber.Particularly, at least one hot extraction chamber can be steam generating plant or moisture eliminator.
Steam generating plant can be used to produce steam, makes to be used to produce the heat of steam by obtaining from the combustion chamber with the stack gas of pipe-line transportation to steam generating plant.Can use any suitable steam generating plant.Steam generating plant can be designed to accept to be no more than the stack gas of preset temperature, and allow stack gas to enter with the volumetric flow rate of minimum.In this case, gas blower can be installed in the inlet of steam generating plant,, and improve the volumetric flow rate of the stack gas of introducing with the temperature of stack gas that reduce to introduce.For example, steam generating plant can be in the form of metal tube counterflow heat exchanger steam generating plant.At least one hot extraction chamber can comprise:
-water inlet;
-be used to receive the waste gas inlet of the stack gas that produces by combustion unit;
-be used to discharge first outlet of the steam that produced, and
-be used to discharge second of stack gas export,
Make by from the stack gas heating of waste gas inlet water, thereby produce steam from water inlet, and discharged steam from first outlet wherein, and from second outlet, discharge stack gas.Therefore, the waste gas inlet of at least one hot extraction chamber can be connected with the outlet of at least one combustion chamber.
The feedwater that enters hot extraction chamber can be obtained by intrasystem water source.Feedwater in hot extraction chamber absorbs the heat of the stack gas of free combustion chamber generation, to form steam.Steam can rise to dry drum, with further heating under high pressure, thereby produces superheated vapour.
Feedwater at least one hot extraction chamber can be carried out preheating in the combustion chamber.For example, water service pipe can lead to the roof and spread (run) along combustion chamber wall, makes exposed tube in the heat of the stack gas of coming free combustion chamber to produce or the heat of inside, combustion chamber.Feedwater at pipe interior can be by convection current and radiant heat heating.Can be controlled at the volumetric flow rate of the feedwater in the pipeline, it is about below 90 ℃ to make water be heated to.The service pump of heating can be delivered at least one hot extraction chamber to produce steam then.
According to another embodiment, system of the present invention can also comprise the generating device that is communicated with at least one first Room.Generating can comprise with device:
-at least one steam turbine, it is fit to receive the steam that is produced by at least one first Room;
-at least one generator, it is communicated with at least one steam turbine, is used to produce electric power; With
-be used to discharge the device of the electric power that produces by generator.
From at least one hot extraction chamber for example the steam of steam generating plant make turbine operation, thereby produce mechanical energy, this mechanical energy is converted to electric energy at least one producer, thereby produces electric power, and the electric power that is wherein produced is released.Can use any suitable steam turbine.For example, steam turbine can be single-stage or multistage steam turbine.Can pass through the supply of Controlling System steam regulation or superheated vapour to steam turbine.For example, enter the flow of the feedwater of steam generating plant by change, can steam regulation to the supply of steam turbine.
The electric power that is produced can be supplied to Blang's gas generator and/or electrical network that at least one produces Blang's gas.Therefore, an advantage of system of the present invention is: by producing electric power by steam, can reduce the dependence to external power source.
Described system can also comprise the heat exchanger that is communicated with at least one steam turbine.Particularly, heat exchanger can be a refrigerating unit.Heat exchanger can comprise:
-be used for from the steam-in of steam turbine reception steam; With
-water out,
The steam that receives from the steam-in of heat exchanger cooling wherein, thus make vapor condensation, and producing water, and wherein water discharges from water out.The water that discharges from heat exchanger can recirculation in system.For example, can use the water that from heat exchanger, discharges as the feedwater that enters steam generating plant.
Heat exchanger can also be communicated with at least one hot extraction chamber.Particularly, when steam turbine reaches maximum capacity, can be with the steam that in steam generating plant, produces with pipe-line transportation to heat exchanger, to be cooled to water.Therefore, heat exchanger can comprise second inlet, and this second inlet is suitable for receiving the steam that is produced by at least one hot extraction chamber when steam turbine reaches its maximum capacity.
According to another embodiment, at least one hot extraction chamber can comprise moisture eliminator, and described moisture eliminator was used for dry this incendiary material before incendiary material burns in the combustion chamber.For example, at least one hot extraction chamber can be the part as the pretreatment unit of above-mentioned combustion chamber.Particularly, before incendiary material was burnt in combustion unit, moisture eliminator had reduced the water capacity of this incendiary material.Be used for to obtain by the stack gas of from the combustion chamber, discharging in the heat of at least one hot extraction chamber drying and burning material.Therefore, in the future the stack gas of auto-combustion chamber with pipe-line transportation to moisture eliminator.Can also with from the stack gas of steam generating plant with pipe-line transportation to the moisture eliminator that is used for the drying and burning material.The exsiccant incendiary material is supplied to the combustion chamber to burn in the combustion chamber.
System of the present invention can also comprise be used for after-treatment device that stack gas was handled before it is discharged into atmosphere.Therefore, can be delivered to after-treatment device with the stack gas of pipeline auto-combustion in the future chamber, moisture eliminator and/or steam generating plant.After-treatment device can comprise that at least one reoxidizes chamber, wet scrubber and/or expander.Reoxidize the chamber, for example aforesaid chamber that reoxidizes, heat washing stack gas by burning Blang's gas.Wet scrubber is to be used for flow of process air to remove the device of the flying dust more than the submicron.Wet scrubber can have a series of high volumetrical spray nozzle, so that the fast quench to the stack gas of discharging from outlet to be provided.For example, stack gas can be quenched to 200 ℃ to 300 ℃.This can be suppressed at the formation again of Da gas Zhong dioxin and furans.Outlet also can be connected with air filter system.Expander has reduced from the temperature of the stack gas of outlet discharging, and/or removes particle and flying dust in the stack gas.
According to second aspect, the invention provides the method for a kind of recovery by the heat of the burning generation of incendiary material, described method comprises the steps:
In at least one combustion chamber, make the incendiary material burning by burning Blang gas; And
The stack gas that reception is produced by the combustion chamber is to reclaim heat wherein.
Described method can also be included in the boiler step that produces steam, and the heat that wherein is used to produce steam can be obtained by the stack gas that the combustion chamber produces.Steam can be supplied to the steam turbine that is communicated with the generator that is used for generating electricity.
Described method can also comprise the steps: to be dried before incendiary material burns at least one combustion chamber, the feasible heat that obtains being used for the drying and burning material from the stack gas that produces by the combustion chamber.
In aspect the 5th, the invention provides a kind of assembly that is discharged into atmosphere stack gas before that is used to handle, described assembly comprises:
-at least one is used to receive and the treatment chamber of heating flue gas;
-Blang's the gas that is used to burn is used for the device of the heat of heating flue gas with supply; And
-be used to discharge the part of the stack gas that has heated.
In aspect the 6th, the invention provides a kind of method that is discharged into atmosphere stack gas before that is used for handling, said method comprising the steps of:
-stack gas is provided at least one treatment chamber;
-Blang's gas is provided to the device of the Blang's gas that is used to burn; With
-by burning Blang gas stack gas is heated to preset temperature.
The device of Blang's gas of being used to burn can be Blang's air burner.For purpose of the present invention, can use any suitable Blang's air burner.Blang's air burner can project thermal-flame in the treatment chamber with heating flue gas.Treatment chamber can also comprise that other inlet is supplied to treatment chamber to allow fresh air.Treatment chamber can be supplied to competent air and oxygen enrichment state, with further oxidation stack gas composition.Treatment chamber can have the lining that uses refractory material, to keep the high temperature of inner treatment chamber.When heating flue gas, can be in treatment chamber oxidation stack gas, with further stack gas is decomposed or be oxidized to may be more harmless to environment form.For example, stack gas can be heated to suitable temperature.Stack gas can be heated to ignition temperature.Stack gas is heated the temperature that reaches can be greater than 700 ℃.Particularly, stack gas can be heated to the temperature between 800 ℃ to 1600 ℃.
Assembly can also be included at least one member of at least one inner treatment chamber, wherein near the bigger heating efficiency of heating flue gas realization stack gas at least one member.For example, at least one member can comprise net, Steel Wool, rod, metal sheet or their combination.Member can be made by any suitable material.Particularly, member comprises the mesh grid parts, and wherein the mesh grid parts are contained at least one treatment chamber.The mesh grid parts can be made by platinum, steel, nickel-chromium alloy, aluminium-Chrome metal powder or their combination.Can settle member make its directly with project treatment chamber in Blang's gas flame contact to reach a high temperature.Member can be supported on the bracing or strutting arrangement.For example, the mesh grid parts can be supported on the metal frame.For better heating efficient, can make the member of stack gas of introducing treatment chamber by having heated.Particularly, can make the red-hot mesh grid parts of stack gas by having heated of introducing, react such as carbon monoxide, oxynitride and other particulate heat-chemistry to realize the stack gas composition in the complete oxidation stack gas.Processed stack gas can be used for other purposes or be further processed before being discharged into atmosphere.
Can comprise one or more treatment chambers in the assembly.For example, 1,2,3,4,5 or 6 treatment chamber can be arranged.Particularly, 3 treatment chambers are arranged.Advantage with a plurality of treatment chambers is the residence time increase of heated stack gas, therefore can realize the complete oxidation of stack gas composition.When existing more than 1 treatment chamber, the possible mode of settling treatment chamber is that series connection is settled, and makes stack gas pass through each in 3 treatment chambers successively.
The stack gas that has heated can be used for other purposes.Therefore, assembly may further include the hot extraction chamber that is fit to receive from the stack gas that has heated of at least one treatment chamber.Particularly, hot extraction chamber can comprise steam generating plant.Also more especially, hot extraction chamber comprises steam boiler plant.
Hot extraction chamber can comprise the steam generating plant that is used to produce steam, makes to be used for producing the heat of steam by obtaining from the gas of heating flue that at least one treatment chamber is delivered to steam generating plant with pipeline.Can use any suitable steam generating plant.For example, steam generating plant can be in the form of metal tube or board-like counterflow heat exchanger steam generating plant.Hot extraction chamber can comprise:
-water inlet;
-vapour outlet; With
-flue gas outlet,
Described hot extraction chamber is positioned to and allows stack gas to add hot water to produce steam.Particularly, heat by stack gas, thereby produce steam and wherein steam and stack gas are discharged respectively from vapour outlet and flue gas outlet from least one treatment unit from the water of water inlet.
Can obtain the feedwater enter steam generating plant from the water source.Feedwater in steam generating plant absorbs the heat of the stack gas of free at least one treatment chamber generation, to form steam.Steam can rise to dry drum, with further heating under high pressure, thereby produces superheated vapour.Feedwater to steam generating plant can be heated in advance.For example, water service pipe can lead to the roof and spread along the wall of at least one treatment chamber, makes exposed tube in from the heat of the stack gas that is supplied to one or more treatment chambers or the heat of one or more inner treatment chamber.Feedwater at pipe interior can be by convection current and radiant heat heating.Can be controlled at the volumetric flow rate of the feedwater in the pipeline, it is about below 90 ℃ to make water be heated to.The service pump that has heated can be delivered to steam generating plant then to produce steam.
According to another embodiment, assembly may further include the generating device that is communicated with hot extraction chamber.This generating can comprise with device:
-at least one steam turbine, it is fit to receive the steam that is produced by hot extraction chamber;
-at least one generator, it is communicated with at least one steam turbine to produce electric power; With
-be used to discharge the device of the electric power that produces by generator.
Come the self-heating extraction chamber particularly the steam of steam generating plant make turbine operation, thereby produce mechanical energy, this mechanical energy is converted to electric energy at least one generator, from producing electric power, and the electric power that is wherein produced is released.Can use any suitable steam turbine.For example, steam turbine can be single-stage or multistage steam turbine.Can pass through the supply of Controlling System steam regulation or superheated vapour to steam turbine.For example, can enter the flow of the feedwater of steam generating plant by change, steam regulation is to the supply of steam turbine.The electric power that is produced can be supplied to electrical network.Electric power can be used for intrasystem other purposes.Therefore, one of advantage of system of the present invention is can reduce the dependence to external power source by producing electric power by steam.
Assembly may further include the heat exchanger that is communicated with at least one steam turbine.Particularly, heat exchanger can be a refrigerating unit.Heat exchanger can comprise:
-be used to receive first inlet from the steam of steam turbine; And
-water out,
Wherein heat exchanger can make vapor condensation, and with generation water, and wherein water discharges from outlet.The water that discharges from heat exchanger can recirculation in assembly.For example, can use the water that from heat exchanger, discharges as the feedwater that enters steam generating plant.Therefore, the water out of heat exchanger can be connected with the water inlet of hot extraction chamber.
Heat exchanger can also be communicated with hot extraction chamber.Particularly, when steam turbine reached maximum capacity, the steam that produces in the steam generating plant of hot extraction chamber can be with pipe-line transportation to heat exchanger, to be cooled to water.Therefore, heat exchanger can comprise second inlet that receives when being adapted at steam turbine reaches its maximum capacity by the steam that hot extraction chamber produced.
Assembly of the present invention can also comprise after-treatment device, is used for further handling before stack gas is discharged into atmosphere stack gas.For example, after-treatment device can be a wash.Wash can comprise the device that is used to wash stack gas.Wash is fit to receive from the stack gas of the part that is used to discharge the stack gas that has heated and/or the stack gas of coming the flue gas outlet of self-heating extraction chamber.Particularly, the device that is used to wash stack gas is a washer.Can use any suitable washer.For example, washer can be wet scrubber, venturi scrubber, impingement plate scrubber or tower spray scrubber.The device that is used to wash stack gas can comprise gravity settling chamber and mechanical collection device.
Importantly be used to wash stack gas device can with from the particle transfer of stack gas to liquid stream, to be reduced in the particulate amount in the stack gas.Reduced like this in amount the particulate matter in the stack gas before flue gas emissions is in the atmosphere.It is the above particulate matters of about 3 μ m that the device that is used to wash stack gas can remove mean diameter.The device that is used to wash stack gas can be collected simultaneously from the particulate matter and the gaseous pollutant of stack gas.Can remove gas by absorption or chemical reaction.For example, in washer, make the stack gas contact drop that is rich in particle, the liquid vortex sheet (sheet) on packing material by force or from the hydrofluidic of plate.For example, the particle wet scrubber ability of removing particle from air-flow depends on following variable:
The size of-particle, i.e. aerodynamic diameter;
The speed of-particle; And/or
-drop, vortex sheet or effusive speed.
The device that is used to wash stack gas may further include prefilter or final strainer, further to remove the particulate matter of stack gas inside.For example, prefilter can be installed in the upstream that the washer of the particulate matter with bigger mean diameter is caught in expection.Although washer itself also can be removed this bigger particulate matter, before air communication is crossed washer, remove bigger particle and can make washer sharper and concentrate on effectively on the particulate matter with littler mean diameter.Final strainer can be installed in the downstream of washer.Final strainer expection is captured in the particle that is not removed in the washing process.
Wet scrubber can come flow of process air by the flying dust of removing more than the submicron from air-flow.Except that remove particulate matter from air-flow, wet scrubber also can make the stack gas quenching fast.For example, wet scrubber can have a series of high volumetrical spray nozzles, so that the fast quench of stack gas to be provided.
Wash may further include and is used to cool off the device that is discharged into atmosphere stack gas before.Can use any suitable device that is used for cooling stack gas.For example, the device that is used for cooling stack gas is an expander.The device that is used for cooling stack gas can be with flue gas cools to the temperature that is lower than 300 ℃.The advantage of the flue gas cools before being discharged in the atmosphere is: can be suppressed at like this and form dioxin and furans in the atmosphere again.Being used for the refrigerative device can be connected with air filter system, further to remove particle and the flying dust in the stack gas.
According to second aspect, the invention provides a kind of method that is discharged into atmosphere stack gas before that is used for handling, said method comprising the steps of:
-stack gas is provided at least one treatment chamber;
-Blang's gas is provided to the device of the Blang's gas that is used to burn; With
-by burning Blang gas stack gas is heated to preset temperature.
Heating steps can be included in heating flue gas under the existence of at least one member that is used to realize higher heating efficiency.Preset temperature can be higher than 700 ℃.The device of Blang's gas of being used to burn can be Blang's air burner.
According to a specific embodiment, stack gas is provided to 3 treatment chambers, stack gas is passed through each in 3 treatment chambers successively.Particularly, described method can may further comprise the steps:
-stack gas is provided to first treatment chamber;
-by burning Blang gas, in first treatment chamber, stack gas is heated to first preset temperature;
-will be delivered to second treatment chamber from the stack gas that has heated of first treatment chamber with pipeline;
-by burning Blang gas, in second treatment chamber, stack gas is heated to second preset temperature;
-will be delivered to the 3rd treatment chamber from the stack gas that has heated of second treatment chamber with pipeline; And
-by burning Blang gas, in the 3rd treatment chamber, stack gas is heated to the 3rd preset temperature.
For example, first preset temperature can be about 800 ℃.Second preset temperature can be about 1000 ℃.The 3rd preset temperature can be higher than 1200 ℃.Particularly, the 3rd preset temperature can be about 1600 ℃.
Described method may further include the step that produces steam in hot extraction chamber, wherein is used to produce the stack gas acquisition of heat from having heated of steam.The steam that is produced can be supplied to the steam turbine that is communicated with the generator that is used for generating electricity.
Described method can also comprise the step of the stack gas that further processing has been heated.For example, described method can may further comprise the steps:
-the stack gas that heated in the device washing that is used for washing stack gas; And/or
-the stack gas that heated in the device cooling that is used for cooling stack gas.
Can be with flue gas cools to the temperature that is fit to.For example, with flue gas cools to the temperature that is lower than 300 ℃.
The accompanying drawing summary
Suitable is to further describe the present invention with reference to the accompanying drawings, and this accompanying drawing shows possible configuration of the present invention.The present invention can have other configuration, so the singularity of accompanying drawing is not intended to restriction the present invention.
Fig. 1 is the synoptic diagram according to the system of one embodiment of the invention.
Fig. 2 is the synoptic diagram according to the absorptivity water cooler of another embodiment of the present invention.
Fig. 3 is the incinerator schematic representation of apparatus according to another embodiment of the present invention.
Fig. 4 is according to another embodiment of the present invention, is used for pipe-line transportation to Blang's gas of multilayer building and hot water and the synoptic diagram of part generation, storage and the delivery system of water coolant.
Fig. 5 is the synoptic diagram according to the system of another embodiment of the present invention.
Fig. 6 is according to another embodiment of the present invention, is used to the synoptic diagram of system of the heat of the stack gas that the free combustion chamber produced.
Fig. 7 is according to another embodiment of the present invention, be used to the stack gas that the free combustion chamber produced heat the synoptic diagram of system.
Fig. 8 is the synoptic diagram according to the assembly of another embodiment of the present invention.
Detailed Description Of The Invention
Fig. 1 has shown the part of the independent system of one embodiment of the invention.Particularly, Fig. 1 has shown the generation of Blang's gas and the use in the boiler and burner device of Blang's gas in independent system.Blang's gas produces in Blang's gas generator 116, and Blang's gas generator 116 is to be described in United States Patent (USP) 4,081, a kind of form in 656.Producer 116 can comprise tank room.Power supply 104 is connected with control panel 106, and these control panel 106 monitoring and red-tape operati parameter are supplied with (electricity supply) such as the electric power that arrives producer 116 via electric wire 114.Also settled water source 102.Water source 102 can be the form of water tank., and filtering RO water is stored in the RO water pot 110 by reverse osmosis (RO) water filter 108 from the water at water source 102.Will be to producer 116 by pump 112 from the water supply of RO water pot 110.
Therefore, producer 116 absorbs RO power and water power with oxygen and the hydrogen of dissociating out in electrolytic process.Via pipeline 121, with the mixture of the oxygen that produced and hydrogen with pipe-line transportation to Blang's gas hold-up vessel 122.Producer 116 also comprises heat exchanger 118.The direct by product of electrolytic process is the heat that becomes its composition from hydrolytic dissociation.Heat exchanger 118 is water-cooleds.Water 102 is supplied to heat exchanger 118 via pipeline 152 from the water source.Subsequently, preheating water is come out with pipe-line transportation from heat exchanger 118 by pipeline 154.
Blang's gas hold-up vessel 122 is partially filled Liquefied Hydrocarbon.In this case, Liquefied Hydrocarbon is a hexane 124.Also provide hexane hold-up vessel 126.To be pumped to Blang's gas hold-up vessel 122 by pump 127 from the hexane 124 of hexane hold-up vessel 126.The mixture of oxygen and hydrogen mixes with hexane vapor 124, to form Blang's gas 120.Blang's gas hold-up vessel 122 also is equipped with safety valve 128.
Control panel 106 also monitor and control other operating parameters such as 116 the RO water supply from RO water pot 110 to producer, to the hexane 124 of Blang's gas hold-up vessel 122 supply with, in the service temperature of producer 116 and Blang's gas hold-up vessel 122 gas inside pressure, producer 116 and from the flow of the mixture of the oxygen of producer 116 and hydrogen.
Blang's gas 120 from Blang's gas hold-up vessel 122 directly can be supplied to the final user via piping network 130.Pipeline can be equipped with at least one vacuum breaker 132, only carries out in one direction to guarantee gas flow.Pipeline 130 also comprises pressure-regulator 133, control valve 134 and flash eliminator 136.Except that Blang's gas 120 directly being supplied to the final user, Blang's gas 120 can also be supplied to boiler and burner device 146 to produce hot water.
Particularly, Blang's gas 120 is supplied to the burner 148 of boiler and burner device 146 by pipeline 138.Pipeline 138 comprises vacuum breaker 140, pressure-regulator 141, control valve 142 and flash eliminator 144.Burner 148 is standard industry gas burners, and it has the device that is used for gas and lights, is used for flame profile and the device of pattern control and the device of flame detection.Burner 148 carries out work with Blang's gas 120, and has electric motor driven gas blower, gas supply electromagnetic valve and gas jet.Burner 148 is configured to produce the flame of temperature up to 1000 ℃.Burner 148 projects flame in the boiler.
Boiler 150 is to have the spatial cylindrical structure that holds festoon (end show) in it, and described festoon is used to store and is supplied to boiler 150 so that it is heated to produce the feedwater of hot water.In addition,, have the layer of the reactive metal element on the path of the flame that is placed on burning Blang gas 120, burn to realize the reactivity that helps further to improve flame temperature in boiler 150 inside.The hot gas that is produced by the burning of the Blang's gas 120 in burner 148 contacts with restraining, and therefore, has heated the feedwater in pipeline.In order to keep the combustion heat as much as possible, the outside of boiler 150 is coated in the insulation material layer.Utilize the incendiary heat of Blang's gas 120 in burner 148 to heat the feedwater that is supplied to boiler 150, to produce hot water.
The feedwater of arriving boiler 150 is from three sources.At first, as make up water from water source 102.Along pipeline 156 water pump is delivered to boiler by pump 158.The second, the preheating water in pipeline 154 that gives off as the heat exchanger from Blang's gas generator 116 118.The 3rd, as the preheating water in pipeline 157 that from least one solar thermal collector 159, gives off.At least one solar thermal collector 159 absorbs from the water at water source 102 and discharging preheating water, and this preheating water is supplied in the boiler and burner device 146 via pipeline 157.Particularly, will be pumped to boiler and burner device 146 from the water combination of pipeline 154,156 and 157 and by pump 158.The hot water that is produced by boiler 150 can be used for space heating, cleaning and flushing purposes.Before Jiang Shui is used for space heating, cleaning and flushing purposes, can be according to purposes, the hot water that boiler 150 can be produced mixes via the agitator valve with the water from water source 102, to reach about 50 ℃ to 70 ℃ temperature.Can be in hot water storing tank with the hot water storage that produced.
Fig. 2 has shown the other device that is included in the system of the present invention.Particularly, Fig. 2 has shown the configuration of absorptivity water cooler 200.Absorptivity water cooler 200 produces the chilled water that can be used for space cooling purposes.Absorptivity water cooler 200 is divided into four parts: condenser 202, producer 204, vaporizer 206 and resorber 208.200 pairs in absorptivity water cooler is working with the thermochemical process that absorbs its heat on every side near the vacuum-evaporation refrigeration agent.
Vaporizer 206 and resorber 208 parts are maintained at the condition near vacuum.Particularly, as follows: as vaporizer 206 to be remained under the vacuum state, to be implemented in the evaporation under the low temperature more in the condition of vaporizer 206.For example, pressure can be about 1kPa, and temperature can be about 4 ℃.Absorptivity water cooler 200 quilts flow from heat exchanger 205 heating of the hot water of hot-water cylinder 201.In addition, in order to compensate heat, it can be positioned near the burner 148 of boiler and burner device 146.Lithiumbromide (LiBr) 210, absorption agent and water 212, refrigeration agent are supplied to the producer part 204 of absorptivity water cooler 200.Make water evaporates in the LiBr solution 210 in the producer part 204 by the heat that hot water produced that produces by boiler and burner device 146 or from the incendiary heat of Blang's gas 120 by burner 148.The refrigerant vapour of water vapor 214 forms is recycled in the condenser portion 202, and discharges latent heat to the water coolant 242 in the heat exchanger in the condenser portion 202 216.In this process, refrigeration agent water 212 is got back in water vapor 214 condensations.
The pipeline 218 that refrigeration agent water 212 is flowed through and comprised expansion valve 220 is to form refrigeration agent spraying 222 in evaporator section 206.To be sprayed onto from the water of spraying 222 in the own water coolant tube bank 224 in the evaporator section 206.The dense LiBr 230 that is absorbed in the device part 208 from spraying 222 water partly absorbs, and partly is collected in 223 of evaporator section 206, and gets back to condenser portion 202 by means of pump 238 via pipeline 218 recirculation.The temperature cooling of the water of refrigeration agent spraying 222, so the water of refrigeration agent spraying 222 absorbs the heat of the warm water 246 in the water-cooled tube 224 of controlling oneself, and evaporation (under vacuum).Therefore, will be water coolant discharging from water-cooled tube 224.The dense LiBr 230 that the refrigerant vapour that produces in this process is absorbed in the device part 208 absorbs.When vaporizer 206 and resorber 208 interconnected, this rapid absorption of refrigerant vapour produced vacuum states at vaporizer 206.Especially, there is the pump (not shown) that is connected with resorber 208 with vaporizer 206.Pump produces subatmospheric 1.0% high vacuum.In producer part 204, produce dense LiBr.When the moisture content in LiBr solution evaporates, form dense LiBr in producer part 204.Dense LiBr flows to resorber part 208 via the pipeline 226 that comprises expansion valve 228, to form LiBr spraying 230.Collect from the LiBr of LiBr spraying 230 in the bottom of resorber part 208, with when it makes up with the refrigerant vapour that comes flash-pot 206, form the pond of the LiBr solution 232 of dilution, it is cycled back to LiBr pond 210 in the producer part 204 by pump 236.LiBr spraying 230 is sprayed onto LiBr on the heat exchanger 215 in the resorber part 208.Heat exchanger 215 has temperature and is about 25 ℃ water coolant 240, this water coolant 240 is supplied to the heat exchanger from cooling tower 250, the water 242 that simultaneous temperature is high slightly discharges from heat exchanger 215, and is supplied to the heat exchanger 216 in the condenser portion 202.Therefore, after the heat that absorbs from the refrigerant vapour in the condenser portion 202 214, high-temperature water 244 discharges from heat exchanger 216, and is supplied to cooling tower 250.
With the water coolant 248 usefulness pipe-line transportation that produce in the evaporator section 206 to hold-up vessel or directly with pipe-line transportation to the final user to be used for various uses, such as space cooling purposes.For example, water coolant 248 can flow to the air processor (heat exchanger with gas blower) of each family so that cooling purposes in space to be provided.
System of the present invention also comprises incinerator device 300.The configuration of incinerator device 300 is presented among Fig. 3.Particularly, incinerator device 300 utilizes the Blang's gas 120 that is produced by Blang's gas generator 116 to act as a fuel.300 oxidations of incinerator device are at the family and the industrial waste of system for field.Incinerator device 300 carries out work with Blang's gas 120, and this Blang's gas 120 is obtained by Blang's gas hold-up vessel 122.By piping network 302 with Blang's gas 120 from hold-up vessel 122 usefulness pipe-line transportation to the combustion chamber 312 and reoxidize chamber 314.Piping network 302 also comprises pressure-regulator 304, at the vacuum breaker 303 in the exit of Blang's gas hold-up vessel 122 and multiport valve (multivalve) 306 Blang's air-flow 120 be separated into combustion chamber 312 and reoxidize in the chamber 314.Uniform outlet Blang gas 120 pressure in pressure-regulator 304 controls and the maintenance piping network 302.Combustion chamber 312 and reoxidize in the chamber 314 each Blang's air burner 313 and 315 are equipped with respectively.Blang's air burner 313 and 315 is the standard industry gas burners with device of the device that is used for gas and lights, the device that is used for flame profile and pattern control and flame detection.Blang's air burner 313 and 315 carries out work with Blang's gas 120, and has electric motor driven gas blower, gas supply electromagnetic valve and gas jet.Burner 313 and 315 is formed at combustion chamber 312 and reoxidizes and produces the flame of temperature up to 1500 ℃ in the chamber 314.Also with flash eliminator 308 and 310 and control valve 305 and 307 be placed in combustion chamber 312 respectively and reoxidize the inlet separately of chamber 314.
Incinerator device 300 also comprises pretreatment unit 316 and 318.Pretreatment unit 316 is used for pre-treatment solid waste, and pretreatment unit 318 is used for pre-treatment liquid refuse.Pretreatment unit 316 comprises collection device 320, separator 322 and moisture eliminator 324.Collection device 320 is collected solid waste, and separator 322 sorting refuses.Can be by artificial separation person via vision means physical separation solid waste, to remove glass, gravel, metal and other block object.The water capacity of refuse is lowered in the moisture eliminator 324 that adds hot waste.Add hot waste by tube bank.Tube bank has steam by beam tube with heating tube bundle, therefore adds hot waste.The refuse of self-desiccation device 324 is supplied in the combustion chamber 312 in the future then.Similarly, for the pre-treatment of Liquid wastes, the vaporizer 330 of in pretreatment unit 318, settling the collection device 326 be used for collecting Liquid wastes, removing the strainer 328 of mud and from mud, remove moisture content from Liquid wastes.Strainer 328 can be any suitable strainer.For example, strainer can be fabric or film filter.Alternatively, can also use pressure filter or centrifugal filter.The pretreatment process that is used for Liquid wastes can comprise the solid-water separation that filters out mud from former water.Mud can be collected at the vaporizer that is used for dewatering.Then, filtered former water carries out chemical treatment before can be in being discharged into water exhaust system.Then the refuse of handling is supplied in the combustion chamber 312.
Combustion chamber 312 is heated by the burning of Blang's gas 120, and to reach 1500 ℃ temperature at the most, this temperature is higher than the flash-point of most solid refuse.In case from the burning of refuse and Blang's gas 120, combustion chamber 312 reaches about 1000 ℃ temperature, Blang's air burner 313 just quits work.Only 312 temperature drops to when being lower than 1000 ℃ and just refires Blang's air burner 313 in the combustion chamber.312 inside, combustion chamber itself can also have heat exchanger 338.Heat exchanger 338 can make the recovery of heat maximization.For example, contained recirculated water absorbs the combustion heat from combustion chamber 312 in the tube bank of heat exchanger 338, and in refuse moisture eliminator 324 place's release of heat, at this, heat can be used for removing the moisture of solid waste.Comprise also that in incinerator device 300 recycle system is to provide feedwater to the heat exchanger in the incinerator device 300.The recycle system comprises multiport valve 348,350,352, steam slurry tank 344, pump 346 and piping network 342.
The stack gas 332 that produces owing to the burning of refuse in combustion chamber 312 is supplied to and reoxidizes in the chamber 314, to decompose any refuse that remains in the stack gas 332 fully by further oxidation organic materials and other hazardous material.
Because the burning of stack gas 332 and Blang's gas 120 is by the aid burning of burner 315, remain on temperature more than 1000 ℃ with reoxidizing chamber 314.Reoxidize chamber 314 and be equipped with the device of supplying with fresh air, this fresh air is used for the oxygen-enriched combusting of stack gas 332.Reoxidize the chamber by burner 315 heating, to reach about 1000 ℃ temperature, that is, the stack gas composition is such as carbon monoxide (CO), hydrogen (H 2) and methane (CH 3) auto ignition temp.Reach about 1000 ℃ temperature in case reoxidize chamber 314 from the aid burning of the burning of stack gas 332 and Blang's gas 120, burner 315 just quits work.When the temperature that reoxidizes chamber 314 drops to when being lower than 1000 ℃, the burner 315 Blang's gas 120 that takes fire.Reoxidize chamber 314 and also be equipped with the mesh grid parts 311 that are supported on the metal frame that reoxidizes 314 inside, chamber.The perforation mesh grid parts 311 of hypersynchronous can be made by platinum, steel, nickel-chromium alloy or other nickelalloy.The hole of mesh grid parts 311 can have any suitable shape, such as square, trilateral or Polygons.The multilayered structure that mesh grid parts 311 can be configured to interlock so that with the exposure maximization of the Blang's gas flame that contacts and burner 315 is produced of the stack gas of introducing 332.
The flow direction of stack gas 332 and Blang's gas flame of being produced by burner 315 is such with respect to the orientation of mesh grid parts 311: make them be perpendicular to one another or be parallel to each other.Mesh grid parts 311 be positioned to the Blang's gas flame that produces by burner 315 in line.Guiding is passed mesh grid parts 311 from the stack gas 332 of combustion chamber 312.In case directly be exposed to the Blang's gas flame that is produced by burner 315, mesh grid parts 311 are just luminous, and be able to and the temperature of stack gas 332 reactions introduced.In this process, the stack gas composition is such as carbon monoxide (CO), hydrogen (H 2) and other hydrocarbon gas compound be oxidized to the form more harmless to environment, such as carbonic acid gas (CO 2), water and other more innocuous gas.
Before being discharged in the atmosphere, from the chamber 334 of the gained stack gas 335 that reoxidizes chamber 314 by comprising wet scrubber 336 as waste gas 340.Wet scrubber 336 is handled resulting stack gas 335 to remove the flying dust more than the submicron.Wet scrubber 336 can have a series of high volumetrical spray nozzles, is rapidly quenched to about 200 ℃ to 300 ℃ temperature so that stack gas 335 to be provided before it is released as waste gas 340, forms dioxin and furans in the atmosphere again to be suppressed at.Feedwater to wet scrubber 336 is obtained by water source 102.334 waste gas 340 that discharge can be connected with air filter system from the chamber.
Fig. 4 has shown the example of configuration of each device of aforesaid system.Particularly, Fig. 4 has shown how the device such as Blang's gas generator 116, boiler and burner device 146, absorptivity water cooler 200 and incinerator device 300 and so on can use in independent system, to produce Blang's gas, store Blang's gas and to carry the Blang's gas that is used for various uses in tier building.
Fig. 5 has shown the general independent system of one embodiment of the invention.Particularly, Fig. 5 has shown the generation of Blang's gas, and the use of Blang's gas in the combustion chamber of independent system.Blang's gas results from Blang's gas and produces in the system 1113, and wherein Blang's gas generation system 1113 comprises Blang's gas generator 1114, heat exchanger 1116 and Blang's gas hold-up vessel 1122.Particularly, Blang's gas produces in Blang's gas generator 1114, and described Blang's gas generator 1114 is to be described in United States Patent (USP) 4,081, a kind of form in 656.Producer 1114 can comprise tank room.Power supply 1104 is connected to control panel 1106, and these control panel 1106 monitoring and red-tape operati parameter are such as supplying with via electric wire 1112 to the electric power of producer 1114.Also settled water source 1102.Water source 1102 can be the form of water tank.By pump 1110, make water from water source 1102 by reverse osmosis (RO) water filter 1108, and with filtered RO water supply to the tank room of producer 1114.
Therefore, producer 1114 absorbs RO power and water power with oxygen and the hydrogen of dissociating out in electrolytic process.With the miscellany of the oxygen that produces and hydrogen via pipeline 1121 usefulness pipe-line transportation to Blang's gas hold-up vessel 1122.Blang's gas produces system 1113 and also comprises heat exchanger 1116.The direct by product of electrolytic process is from the heat of hydrolytic dissociation for its composition.Heat exchanger 1116 is water-cooleds.Water coolant is circulated to heat exchanger 1116 from cooling tower 1118 via pipeline 1117.Subsequently, warm water is gone out with pipe-line transportation from heat exchanger 1116 by pipeline 1119, and turn back to cooling tower 1118.
Blang's gas hold-up vessel 1122 partly is full of Liquefied Hydrocarbon.In this case, Liquefied Hydrocarbon is a hexane 1124.Also settle hexane hold-up vessel 1126.To be pumped to Blang's gas hold-up vessel 1122 from the hexane 1124 of hexane hold-up vessel 1126 by the pump (not shown).The miscellany of oxygen and hydrogen mixes with hexane vapor to form Blang's gas 1120.Blang's gas hold-up vessel 1122 further is equipped with safety valve 1128.Safety valve is to be set to open under certain stress level to prevent that container or intrasystem pressure from reaching the valve of dangerous level.
Blang's gas from Blang's gas hold-up vessel 1122 directly can be supplied in the combustion chamber 1142 via piping network 1130.The pipeline of piping network 1130 can be equipped with at least one vacuum breaker 1132, only carries out in one direction to guarantee flowing of Blang's gas 1120.Piping network 1130 also comprises at least one pressure-regulator 1134, at least one control valve 1136 and at least one flash eliminator 1138.Pressure-regulator is to be used to control and to keep the exit gas pressure of tubing system to install uniformly, and flash eliminator is the device that prevents from via " backfire " of the external flame of the spit cock of opening.
Particularly, by pumping network 1130, Blang's gas 1120 is supplied at least one burner 1140 of combustion chamber 1142.Burner 1140 is standard industry gas burners, and it has the device that is used for gas and lights, is used for flame profile and the device of pattern control and the device of flame detection.Burner 1140 carries out work with Blang's gas 1120, and has electric motor driven gas blower, gas supply electromagnetic valve and gas jet.Burner 1140 is configured to produce temperature greater than 1200 ℃ flame.Burner 1140 can be positioned at a side of combustion chamber 1142, and flame is projected in the combustion chamber 1142.When combustion waste in combustion chamber 1142, produce stack gas.As described in detail later, can be used for generating from the heat of stack gas.
Fig. 6 has shown the configuration of system of the present invention, and wherein the heat of the stack gas of free combustion chamber 1142 generations in the future is used for various other purposes.Comprise single-stage combustion unit 1142a in the combustion chamber shown in Fig. 6.Combustion unit 1142a uses the Blang's gas 1120 that is produced by Blang's gas generation system 1113 to act as a fuel so that the incendiary material burning.Incendiary material can be a refuse, and it can comprise family and industrial waste.As above Fig. 5 is described, by piping network 1130, will produce Blang's gas 1120 pipe-line transportation of system 1113 to combustion unit 1142a from Blang's gas.The even outlet Blang atmospheric pressure of combustion unit 1142a is controlled and kept being applicable to pressure-regulator 1134 in piping network 1130.For example, gaseous tension can be about 11 inches water (promptly about 2738Pa).
The inwall of combustion unit 1142a is lined with refractory material, being tolerated in the combustion heat of combustion unit 1142a inside, and the structure of protection combustion unit 1142a.For example, refractory material can comprise hard, the heat-stable material that can work in sour environment.The example of refractory material includes but not limited to aluminum oxide, silicon carbide, fireclay, brick and silicon-dioxide.Via in the side of combustion unit 1142a or the hole of bottom, compressed-air actuated intermittent jet is supplied to combustion unit 1142a.Pressurized air is used for improving at combustion unit 1142a treats that the incendiary refuse mixes with the turbulent flow of air.Compressed-air actuated intermittent jet helps to prevent with the obstruction of compressed air-feed to the hole of combustion unit 1142a.In the grid (not shown) of the bottom of combustion unit 1142a with drying solid refuse and dust separation.Bottom dust 1201 from the trash burning among the combustion unit 1142a is collected to handle via the funnel (not shown) bottom combustion unit 1142a.
As the result of combustion waste in combustion unit 1142a, produce stack gas 1202.With some stack gases 1202 from combustion unit 1142a through pipe-line transportation to water pipe steam boiler 1204.By pump 1212 water pump is delivered in the steam boiler 1204.In steam boiler 1204, water is at pipeline 1206 internal recycle, described pipeline 1206 by from combustion unit 1142a through stack gas 1202 indirect heating of pipe-line transportation to steam boiler 1204.For example, stack gas can be in 900 ℃.Because the water-filling pipe 1206 that is included in the steam boiler 1204 is exposed to high-temperature flue gas 1202, so the rising of the temperature of the water in the pipeline 1206, and because thermosyphon effect, hot water rises to the dry drum 1208 in the steam boiler 1204.Produce steam 1214 by the hot water in the stack gas 1202 further heating steam drums 1208.Steam 1214 is extracted out from the top of dry drum 1208, and chosen wantonly further heating in the superheater (not shown), to produce superheated vapour.Then via passage 1228a with stack gas 1202 usefulness pipe-line transportation to after-treatment device 1230, so that the stack gas 1202 before being discharged into as waste gas 1236 in the atmosphere is handled.Be described in more detail below after-treatment device 1230.
Then steam 1214 or superheated vapour are used to drive steam turbine 1216.For example, superheated vapour can be in more than 390 ℃.Steam turbine 1216 can be single-stage or multistage steam turbine.Steam turbine 1216 is connected with the generator 1220 that is used to generate electricity by axle 1218.Steam 1214 is clung to (2.3 * 10 about 23 6Pa) be supplied to steam turbine 1216 under the high pressure.Steam turbine 1216 rotations, thus also rotation of axle 1218 caused.As the result of axle 1218 rotations, the magnet that comprises in generator 1220 also rotates.Magnet has the line of coiling around it.Magnet rotation along with in generator 1220 inside produces electric current in lead 9 (wire).Generator 1220 is converted to electric energy with mechanical energy.The power transmission that will produce by generator 1220 is used to regulate Blang's gas and produces the electrical installation of system 1113 for the voltage and current that produces Blang's gas 1120 and use to a series of then, perhaps transfer to the electrical network that is positioned at internal system, promptly be used for the power supply 1104 of system.
Then, will guide to heat exchanger 1222 by the steam 1214 or the superheated vapour of steam turbine 1216.Steam 1214 is cooled off in heat exchanger 1222, to be condensed into water.By pump 1212 condensate pump is sent back to the pipeline 1206 of steam boiler 1204 then, to absorb heat from stack gas 1202 to produce steam 1214.By piping network 1224,1102 obtain the inflow heat exchanger 1222 to cool off from the steam 1214 of steam turbine 1216 or the feedwater of superheated vapour from the water source.Heat exchanger 1222 also cools off excessive superheated vapour or excessive steam 1214.When steam turbine 1216 reached its maximum capacity and can not absorb steam 1214 or superheated vapour again, steam 1214 was considered to excessive.When this thing happens, excess steam 1214 or excessive superheated vapour are guided to heat exchanger 1222 via by-pass line 1226.As mentioned above, excess steam 1214 and excessive superheated vapour are cooled off in heat exchanger 1222 and be condensed into water.By pump 1212 water pump is sent back to the pipeline 1206 of steam boiler 1204 then, to absorb heat from stack gas 1202 to produce steam 1214.
Combustion chamber 1142 also comprises pretreatment unit 1242.Particularly, pretreatment unit 1242 is used for pre-treatment solid waste.Pretreatment unit 1242 comprises moisture eliminator, is used for being supplied to the water capacity that combustion unit 1142a reduces refuse before burning at refuse.Add hot waste by the tube bank 1243 that is present in the moisture eliminator.Tube bank 1243 has the stack gas 1202 through the pipeline of the tube bank that externally adds hot waste.Particularly, the pipeline of tube bank 1243 is highly conductive.In the future some stack gases 1202 of auto-combustion device 1142a via passage 1229 usefulness pipe-line transportation to restraining 1243.Also will be from the stack gas 1202 usefulness pipe-line transportation of steam boiler 1204 to restraining 1243 via passage 1228b.Then will be through tube bank 1243 stack gas 1202 usefulness pipe-line transportation to after-treatment device 1230 via passage 1244, before being rejected in atmosphere with the form of waste gas 1236 stack gas 1202, this stack gas 1202 is handled.Following more detailed description after-treatment device 1230.
Respectively via passage 1228a and 1244, will be from the stack gas 1202 usefulness pipe-line transportation of steam boiler 1204 and pretreatment unit 1242 to after-treatment device 1230.After-treatment device 1230 comprises wet scrubber 1232 and expander 1234.To in wet scrubber 1232, wash from the stack gas 1202 of steam boiler 1204 and pretreatment unit 1242.Wet scrubber 1232 is to be chemical wet scrubber.For example, the pharmaceutical chemicals that in chemical wet scrubber, uses can be by calcium hydroxide or sodium hydroxide form water-soluble serous.Wet scrubber 1232 can be the closure member with chamber of a plurality of interconnection.Each chamber can be formed by perforation plate, to slow down the flux (passage) through the stack gas 1202 of wet scrubber 1232.Wet scrubber 1232 is handled stack gas 1202 to remove flying dust, dust and the particle more than the submicron.Wet scrubber 1232 can have a series of highly compressed fluid injection nozzles.For example, fluid can be that basic solution is such as sodium hydroxide or calcium hydroxide.In the basic solution and may be tart stack gas 1202.Basic solution is also washed flying dust and big particle in the stack gas 1202 off.
, then half stack gas of handling 1202 is cleaned at the expander 1234 that is used for fast quench by after the wet scrubber 1232 in stack gas 1202.Expander 1234 has the spray nozzle of a series of heavy body, to be provided at stack gas 1202 with before the release of waste gas 1236 forms, stack gas 1202 is rapidly quenched to about 200 ℃ to 300 ℃ temperature, forms dioxin and furans in the atmosphere again thereby be suppressed at.Quenching also reduces the smell of half stack gas of handling 1202.Feedwater 1102 acquisitions to expander 1234 from the water source.Via piping network 1238, be pumped to expander 1234 by pump 1239 from the water at water source 1102.Before being recycled the spray nozzle of getting back to wet scrubber 1232 by pump 1233, collect in after-treatment device 1230 bottoms contain flying dust and big particulate fluid can pass through filter system.With uniform interval, the fluid in the bottom of after-treatment device 1230 can be discharged into treatment unit 1240, at this with its chemical treatment.The fluid re-circulation of chemical treatment can be got back to wet scrubber 1232 or be discharged in the water exhaust system.
Randomly, before being discharged into atmosphere, the waste gas 1236 that discharges from expander 1234 can be connected with air filter system, with further processing.Waste gas 1236 can also comprise saturated water vapor.Therefore, the pneumatic outlet that vaporizer can be installed in expander 1234 to be removing the saturated vapo(u)r in the waste gas 1236, thereby prevents to form in atmosphere plume.As a further alternative, processed stack gas 1202 also can be passed through gas filter system before being discharged into atmosphere, to remove the particle of submicron-scale.
In various other purposes, use the other configuration of system of the present invention of the heat of the stack gas that free combustion chamber 1142 produces to be presented among Fig. 7.Except combustion chamber 1142, the system of Fig. 6 is identical with the system of Fig. 7 basically.The combustion chamber 1142 that is presented among Fig. 7 comprises the two-stage combustion chamber.Particularly, the combustion chamber 1142 of Fig. 7 comprises combustion unit 1142a and reoxidizes chamber 1302.Reoxidizing chamber 1302 can be that heat reoxidizes the chamber.As combustion unit 1142a, reoxidize chamber 1302 and also use the Blang's gas 1120 that produces by Blang's gas generation system 1113 to act as a fuel.Therefore, by piping network 1130 Blang's gas 1120 is produced system's 1113 pipe-line transportation to reoxidizing chamber 1302 from Blang's gas.Piping network 1130 can comprise that multiport valve 1303 reaches combustion unit 1142a and reoxidizes in the chamber 1302 with the flow point with Blang's gas 1120.Piping network 1130 also comprises vacuum breaker 1304, pressure-regulator 1306, control valve 1308 and flash eliminator 1310.Even Blang's atmospheric pressure in pressure-regulator 1306 controls and the maintenance piping network 1130.
Reoxidize chamber 1302 and be equipped with Blang's air burner 1312.Blang's air burner 1312 is standard industry gas burners, and it has the device that is used for gas and lights, is used for flame profile and the device of pattern control and the device of flame detection.Blang's air burner 1312 carries out work with Blang's gas 1120, and has electric motor driven gas blower, gas supply electromagnetic valve and gas jet.Blang's air burner 1312 can be formed to reoxidize in the chamber 1302 and produce temperature greater than 1200 ℃ flame.Particularly, will reoxidize the temperature that chamber 1302 is maintained at about 1000 ℃, promptly the stack gas composition is such as carbon monoxide (CO), hydrogen (H 2) and methane (CH 4) reduction reaction temperature.
When beginning to burn (burning) process, combustion unit 1142a and the Blang's air burner 1140 and 1312 that the reoxidizes chamber 1302 Blang's gas 1120 that burns respectively is with heating flame device 1142a with reoxidize the furnace space of 1302 inside, chamber.The flow and the incendiary time length of control Blang gas 1120 are to reach preset temperature in combustion unit 1142a.Typically, do not having under the situation of refuse, combustion unit 1142a can reach and be higher than 1000 ℃ temperature.In burning process, the exsiccant refuse is supplied to combustion unit 1142a consistently, with its burning.Under stable status, under the situation of constant supply refuse, combustion unit 1142a can reach and be higher than 1200 ℃ temperature.In combustion processes, produce and be rich in carbon monoxide, hydrocarbon gas compound and produce nitrogen oxide (NO x) stack gas.The stack gas 1202 that produces is delivered to reoxidizes chamber 1302 with further processing.Reoxidize structure that chamber 1302 can have an elongation to allow in Schwellenwert perfect combustion stack gas 1202 in 2 seconds the residence time.Alternatively, reoxidizing chamber 1302 can be made by plural bogey similar or heteroid interconnection, with by increasing the exposure duration of handling stack gas 1202, handles stack gas 1202 more completely.
Reoxidize chamber 1302 and be equipped with the mesh grid parts 1313 that are supported on the metal frame that reoxidizes 1302 inside, chamber.The perforation mesh grid parts 1313 of hypersynchronous can be made by platinum, steel, nickel-chromium alloy or nickelalloy.Mesh grid parts 1313 react energetically with Blang's gas flame that Blang's air burner 1312 is produced, to reach a high temperature reoxidizing 1302 inside, chamber.The hole of mesh grid parts 1313 can have any suitable shape such as square, trilateral or Polygons.Particularly, the multilayered structure that mesh grid parts 1313 can be configured to interlock so that with the exposure maximization of the Blang's gas flame that contacts and Blang's air burner 1312 is produced of the stack gas of introducing 1202.
The flow direction of flue gas stream and Blang's gas flame of being produced by Blang's air burner 1312 is such with respect to the orientation of mesh grid parts 1313: they are perpendicular to one another or are parallel to each other.Mesh grid parts 311 are positioned to Blang's gas flame of being produced with Blang's air burner 1312 in line.Guiding is passed mesh grid parts 1313 from the stack gas 1202 of combustion unit 1142a.When directly being exposed to the Blang's gas flame that is produced by Blang's air burner 1312, mesh grid parts 1313 are luminous, and are able to and the temperature of stack gas 1202 reactions introduced.In this process, the stack gas composition is such as CO, H 2Be oxidized to the form more harmless with other hydrocarbon gas compound, such as carbonic acid gas (CO to environment 2), water and other more innocuous gas.Particularly, oxygen further with Blang's gas 1120 in H-H reaction before, nitrogenous stack gas 1202 is reduced to elemental composition, i.e. nitrogen and oxygen, thereby produce nitrogen steam and water vapour.
As shown in last Fig. 6, will guide to steam boiler 1204 with pipeline from the part of the stack gas 1314 that reoxidizes chamber 1302, be used to produce steam (or superheated vapour), generate electricity to drive steam turbine 1216 and generator 1220.Also will be from a part of pipe-line transportation of the stack gas 1314 that reoxidizes chamber 1302 to restraining 1243, with the refuse in the dry pretreatment unit 1242 via passage 1315.
In whole burning process, combustion unit 1142a and reoxidize chamber 1302 and be maintained at negative pressure guaranteeing producing suitable draft, and makes stack gas 1202 from combustion unit 1142a with reoxidize chamber 1302 and flow to steam boiler 1204 and pretreatment unit 1242.For example, pressure can be pact-50Pa.Can realize via vacuum fan at combustion unit 1142a and the negative pressure that reoxidizes in the chamber 1302, described vacuum fan be installed in combustion unit 1142a flue gas emissions end (under the situation of the system shown in Fig. 6), reoxidizing the flue gas emissions end (under the situation of the system shown in Fig. 7) of chamber 1302 or at the exhaust side of after-treatment device 1230.
Fig. 8 has shown the general assembly of one embodiment of the invention.Particularly, Fig. 8 has shown before will be from the flue gas emissions of stack gas ejector discharging to atmosphere the processing to this stack gas.Will be from stack gas 2103 usefulness pipe-line transportation to the first treatment chambers 2104 of stack gas ejector 2102.Stack gas ejector 2102 can be any system of discharging stack gas.For example, stack gas ejector 2102 can be incinerator, coal-fired stove etc.Stack gas 2103 can be rich in carbon monoxide, hydrocarbon gas compound and nitrogen oxide (NO x).Stack gas 2103 typically has about temperature more than 300 ℃.In first treatment chamber 2104, stack gas 2103 is further heated.For example, stack gas 2103 is further heated to about 800 ℃ in first treatment chamber 2104.The stack gas 2103 that will heat with pipeline is delivered to second treatment chamber 2106 with further heating then.For example, can in second treatment chamber 2106, stack gas 2103 be heated to about 1000 ℃ temperature.From the stack gas that has heated 2103 usefulness pipe-line transportation to the three treatment chambers 2108 of second treatment chamber 2106 to be heated to temperature greater than 1200 ℃.Particularly, the temperature in the 3rd treatment chamber 2108 is about 1600 ℃.
By burning Blang gas, stack gas 2103 is heated in first treatment chamber 2104, second treatment chamber 2106 and the 3rd treatment chamber 2108.Can produce Blang's gas in Blang's gas generator, this Blang's gas generator is to be described in United States Patent (USP) 4,081, a kind of form in 656.By piping network 2112, Blang's gas can directly be supplied to treatment chamber 2104,2106 and 2108 from Blang's gas hold-up vessel 2110.Blang's gas hold-up vessel 2110 can be equipped with safety valve 2111.Safety valve is to be set at certain stress level to open to prevent to reach at container or intrasystem pressure the valve of dangerous level.Piping network 2112 can be equipped with at least one vacuum breaker 2114.Piping network 2112 may further include multiport valve 2116 Blang's air-flow is separated in each treatment chamber 2104,2106 and 2108.For example, Blang's air-flow can be separated, and by piping network 2118,2120 and 2122, Blang's gas is supplied to first treatment chamber 2104, second treatment chamber 2106 and the 3rd treatment chamber 2108 with respectively.Each piping network 2118,2120,2122 can comprise at least one pressure-regulator 2124,2132,2140, at least one control valve 2126,2134,2142 and at least one flash eliminator 2128,2136,2144 respectively.Pressure-regulator is to be used to control and to keep the exit gas pressure of tubing system to install uniformly, and flash eliminator is to prevent the device of external flame via the spit cock of opening " backfire ".Pressure-regulator 2124,2132 and 2140 is controlled respectively and is kept being applicable to the treatment chamber 2104,2106 of piping network 118,2120 and 2122 and 2108 even outlet Blang atmospheric pressure.For example, gaseous tension can be about 11 inches water (that is about 2738Pa).
Particularly, respectively Blang's gas is supplied to the burner 2130,2138 and 2146 of first treatment chamber 2104, second treatment chamber 2106 and the 3rd treatment chamber 2108. Burner 2130,2138 and 2146 is standard industry burners, and it has the device that is used for gas and lights, is used for flame profile and the device of pattern control and the device of flame detection.Burner 2130,2138 and 2146 carries out work with Blang's gas, and has electric motor driven gas blower, gas supply electromagnetic valve and gas jet.Burner 2130,2138 and 2146 can be configured to produce temperature greater than 1200 ℃ flame.Burner 2130,2138 and 2146 can be set to make flame to be projected in treatment chamber 2104,2106 and 2108 respectively.
Blang's air burner 2130,2138 and 2146 is configured to respectively to produce the flame of about 800 ℃, 1000 ℃ of temperature and 1200 ℃ in first treatment chamber 2104, second treatment chamber 2106 and the 3rd treatment chamber 2108.Particularly, the stack gas composition is such as carbon monoxide (CO), hydrogen (H 2) and methane (CH 4) auto ignition temp between about 800 ℃ and 1600 ℃.In case reach required temperature in treatment chamber 2104,2106 and 2108 from the aid burning of the burning of stack gas 2103 and Blang's gas, Blang's air burner 2130,2138 and 2146 is with regard to shut-down operation.When the temperature of first treatment chamber 2104, second treatment chamber 2106 and the 3rd treatment chamber 2108 drops to respectively when being lower than 800 ℃, 1000 ℃ and 1200 ℃, Blang's air burner 2130,2138 and 2146 Blang's gas that takes fire.When the beginning treating processes, Blang's air burner 2130,2138 and 2146 is lighted Blang's gas to heat the furnace space in first treatment chamber 2104, second treatment chamber 2106 and the 3rd treatment chamber 2108 inside respectively.The flow of control Blang gas and duration of combustion are to reach preset temperature in each of treatment chamber 2104,2106 and 2108.
First treatment chamber, 2104, the second treatment chambers 2106 and the 3rd treatment chamber 2108 can have elongated structure to allow in 2 seconds residence time perfect combustion stack gas 2103 of Schwellenwert.Alternatively, in first treatment chamber 2104, second treatment chamber 2106 and the 3rd treatment chamber 2108 each can be made by plural bogey similar or heteroid interconnection, handles stack gas 2103 more fully to reach by the exposure duration that increases processing stack gas 2103.In first treatment chamber 2104, second treatment chamber 2106 and the 3rd treatment chamber 2108 at least one can further be equipped with mesh grid parts (not shown).
The mesh grid parts can be supported at least one the metal frame of inside in first treatment chamber 2104, second treatment chamber 2106 and the 3rd treatment chamber 2108.The perforation mesh grid parts of hypersynchronous can be made by platinum, steel, nickel-chromium alloy, nickelalloy or their combination.Mesh grid parts 1313 react energetically with Blang's gas flame that Blang's air burner 2130,2138 and 2146 is produced, to reach a high temperature in first treatment chamber 2104, second treatment chamber 2106 and the 3rd treatment chamber 2108 inside.The hole of mesh grid parts can have any suitable shape and size.For example, the shape in the hole of mesh grid parts can be square, trilateral or Polygons.Particularly, the mesh grid parts can be configured to interlock, multilayered structure so that with the Blang's gas flame that contacts and Blang's air burner 2130,2138 and 2146 is produced of the stack gas of introducing 2103 in the exposure maximization.
The direction of Blang's gas flame that flue gas stream and Blang's air burner 2130,2138 and 2146 are produced is such with respect to the orientation of mesh grid parts, and promptly they are perpendicular to one another or are parallel to each other.The mesh grid parts are positioned to Blang's gas flame of being produced with Blang's air burner 2130,2138 and 2146 in line.Guiding is passed mesh grid parts in first treatment chamber 2104, second treatment chamber 2106 or the 3rd treatment chamber 2108 respectively from the stack gas 2103 of stack gas ejector 2102, first treatment chamber 2104 or second treatment chamber 2106.By directly being exposed in Blang's gas flame that Blang's air burner 2130,2138 and 2146 produced, the heating of mesh grid parts, and be able to and the temperature of stack gas 2103 reactions introduced.In this process, the stack gas composition is such as CO, H 2Be oxidized to the form more harmless with other hydrocarbon gas compound, such as carbonic acid gas (CO to environment 2), water and other more innocuous gas.Particularly, with Blang's gas in H-H reaction before, nitrogenous stack gas 2103 dissociates into elemental composition, thereby produces nitrogen.
Can with from the stack gas that has heated 2103 of each first treatment chamber 2104, second treatment chamber 2106 and the 3rd treatment chamber 2108 some with pipe-line transportation to after-treatment device.After-treatment device can be following wash in greater detail 2176.Alternatively, will from treatment chamber particularly some in the stack gas that has heated of the 3rd treatment chamber 2108 with pipe-line transportation to water pipe steam boiler 2148.By pump 2170 water pump is delivered to steam boiler 2148.In steam boiler 2148, water circulates in pipeline 2150, and it is externally heated from the stack gas that has heated 2103 that the 3rd treatment chamber 2108 is delivered to steam boiler 2148 with pipeline.Because the water fill pipe 2150 that comprises in steam boiler 2148 is exposed in the high-temperature flue gas 2103, therefore the temperature of the water in pipeline 2150 rises, thereby produce steam 2154, described then steam 2154 rises to the dry drum 2152 in the steam boiler 2148.Steam 2154 is extracted out from the top of dry drum 2152, and chosen wantonly further heating in the superheater (not shown), to produce superheated vapour.Then with stack gas 2103 usefulness pipe-line transportation to after-treatment device, so that stack gas 2103 was handled before being discharged in the atmosphere as waste gas 2194.This after-treatment device can be a wash 2176, below it is described in more detail.
Then steam 2154 or superheated vapour are used to drive steam turbine 2156.For example, superheated vapour can be in more than 250 ℃.Steam turbine 2156 can be single-stage or multistage steam turbine.Steam turbine 2156 is connected to the generator 2158 that is used to generate electricity by axle 2160.Steam 154 under high pressure is supplied to steam turbine 2156.Steam turbine 2156 rotations, thus also rotation of axle 2160 caused.As the result of the rotation of axle 2160, the magnet that comprises in generator 2158 also rotates.Magnet has the lead that is coiled in around it.Magnet rotation along with in generator 2158 inside produces electric current in lead.Generator 2158 is converted to electric energy with mechanical energy.The power transmission that will produce by generator 2158 is to electrical network 2168 then.
To guide to heat exchanger 2166 through the steam 2154 or the superheated vapour of steam turbine 2156 then.Steam 2154 is cooled off in heat exchanger 2166, to be condensed into water.By pump 2170 condensate pump is sent back to the pipeline 2150 of steam boiler 2148 then, to absorb heat from stack gas 2103 to produce steam 2154.By piping network 2174,2172 obtain inflow heat exchanger 2166 with the feedwater of cooling from the superheated vapour of steam turbine 2156 from the water source.Heat exchanger 2166 also cools off excessive superheated vapour or excessive steam 2154.When steam turbine 2156 reached its maximum capacity and can not absorb steam 2154 or superheated vapour again, steam 2154 was considered to excessive.When this thing happens, excess steam 2154 or excessive superheated vapour are guided to heat exchanger 2166 via by-pass line 2162.As mentioned above, excess steam 2154 and excessive superheated vapour are cooled off in heat exchanger 2166 and be condensed into water.By pump 2170 water pump is sent back to the pipeline 2150 of steam boiler 2148 then, be used to absorb heat from stack gas 2103 to produce steam 2154.
Will be from the stack gas 2103 usefulness pipe-line transportation of steam boiler 2148, first treatment chamber 2104, second treatment chamber 2106 and/or the 3rd treatment chamber 2108 to wash 2176.Wash 2176 comprises wet scrubber 2178 and expander 2188.To in wet scrubber 2178, clean from the stack gas 103 of steam boiler 2148, first treatment chamber 2104, second treatment chamber 2106 and/or the 3rd treatment chamber 2108.Wet scrubber 2178 can be chemical wet scrubber.Wet scrubber 2178 can be the closure member with chamber of a plurality of interconnection.Each chamber can be formed by perforation plate, to slow down the flux by the stack gas 2103 of wet scrubber 2178.Wet scrubber 2178 is handled stack gas 2103 to remove flying dust, dust and the particle more than the submicron.Wet scrubber 2178 can have a series of highly compressed fluid injection nozzles 2180.For example, fluid can be that alkaline fluids is such as sodium hydroxide or calcium hydroxide.In the alkaline fluids and may be tart stack gas 2103.Alkaline fluids is also washed flying dust and big particle in the stack gas 2103 off.
, then half stack gas of handling 2103 is cleaned at the expander 2188 that is used for fast quench by after the wet scrubber 2178 in stack gas 2103.Expander 2188 has the spray nozzle 2190 of a series of heavy body, before stack gas 2103 is released in the atmosphere as waste gas 2194, to make this stack gas be rapidly quenched to about 200 ℃ to 300 ℃ temperature, form dioxin and furans in the atmosphere again thereby be suppressed at.Quenching also reduces the smell of half stack gas of handling 2103.Acquire the feedwater of expander 2188 by water source 2172.Via piping network 2196, will deliver to expander 2188 from the water pump at water source 2172 by pump 2192.Before being recycled the spray nozzle 2180 of getting back to wet scrubber 2178 by pump 2184, collect in wash 2176 bottoms contain flying dust and big particulate fluid 2182 can pass through filter system.With uniform interval, the fluid 2182 in wash 2176 bottoms can be discharged into treatment unit 2186, at this with its chemical treatment.The fluid re-circulation of chemical treatment can be got back to wet scrubber 2178 or be discharged in the water exhaust system.
Randomly, the waste gas 2194 that discharges from wash 2176 can be connected to air filter system, further handles before it being discharged into again atmosphere.Waste gas 2194 can also comprise saturated water vapor.Therefore, the pneumatic outlet that vaporizer can be installed in wash 2176 to be removing the saturated vapo(u)r in the waste gas 2194, thereby prevents to form in the atmosphere plume.As a further alternative, treated stack gas 2103 also can be before being discharged into atmosphere by gas filter system to remove the particle of submicron-scale.
In the entire treatment process, first treatment chamber 2104, second treatment chamber 2106 and the 3rd treatment chamber 2108 are maintained at negative pressure to guarantee producing suitable draft, are used to make stack gas 2103 from treatment chamber 2104,2106 and 2108 flowing to steam boiler 2148 and wash 2176.For example, pressure can be pact-50Pa.Negative pressure in first treatment chamber 2104, second treatment chamber 2106 and the 3rd treatment chamber 2108 can realize via vacuum fan, described vacuum fan is installed in the flue gas emissions end of first treatment chamber 2104, second treatment chamber 2106 and the 3rd treatment chamber 2108, perhaps at the exhaust side of wash 2176.

Claims (88)

1. system that is used to produce, store and utilize Blang's gas, described system comprises:
-at least one Blang's gas generator, it is communicated with power supply and water source;
-at least one first storing chamber, it is communicated with described producer fluid, is used to store the Blang's gas that is produced by described producer; With
-Blang gas application apparatus, it is communicated with described at least one first storing chamber,
The wherein said producer and first storing chamber are positioned at the contiguous place of described Blang's gas application apparatus.
2. system according to claim 1, wherein said at least one first hold-up vessel accommodates the Liquefied Hydrocarbon of predetermined amount.
3. system according to claim 2, wherein said Liquefied Hydrocarbon is selected from: hexane, heptane, methyl alcohol and ethanol.
4. according to each described system in preceding claim, wherein said application apparatus comprises that at least one is used to produce first Room of hot water, wherein obtain being used to heat the heat of described hot water, and described Blang's gas obtains from described at least one first storing chamber by the burning of Blang's gas.
5. system according to claim 4, wherein said at least one first Room is the boiler and burner device.
6. according to claim 4 or the described system of claim 5, wherein said at least one first Room comprises:
-the first inlet is used to receive the Blang's gas from described at least one first storing chamber;
-the second inlet is used to receive water;
-gas burner; With
-outlet is used to discharge the hot water that is produced,
Wherein burn from Blang's gas of described first inlet, thereby heat the water that enters the mouth from described second, and the water that wherein will heat discharges from described outlet by described gas burner.
7. system according to claim 6, wherein said second inlet that is used to receive water is connected with the outlet of at least one heat exchanger that is accommodated in described at least one Blang's gas generator inside.
8. according to claim 6 or the described system of claim 7, described system also is included at least one flash eliminator of the described first inlet front.
9. according to each described system in the claim 4 to 8, wherein said at least one first Room comprises the reactive metal element.
10. system according to claim 9, wherein said reactive metal element is selected from platinum, steel, nickel-chromium alloy or high temperature nickel alloy.
11. according to each described system in the claim 4 to 10, described system also comprises at least one second storing chamber that is used to store described hot water.
12. system according to claim 11, wherein said at least one second storing chamber is connected with the described outlet of described at least one first Room.
13. according to each described system in preceding claim, wherein said application apparatus also comprises at least one second Room that is used to produce chilled water.
14. system according to claim 13, wherein said at least one second Room is absorbefacient cooling arrangement.
15. according to claim 13 or the described system of claim 14, wherein said at least one second Room comprises:
-the first inlet is used to receive absorption agent;
-the second inlet is used to receive refrigeration agent;
-Di three inlets are used to receive water coolant;
-Di four inlets are used to receive warm water;
-the first heat exchanger;
-the second heat exchanger;
-the first outlet is used to discharge warm water; And
-the second outlet is used to discharge the chilled water that is produced,
Wherein said the 3rd inlet is connected with described first heat exchanger with first outlet, and described the 4th inlet is connected with described second heat exchanger with second outlet.
16. system according to claim 15, wherein said absorption agent is selected from lithiumbromide (LiBr) and ammonia (NH 3).
17. according to claim 15 or the described system of claim 16, wherein said refrigeration agent is a water.
18. according to each described system in the claim 15 to 17, wherein said the 4th inlet is connected with described at least one second storing chamber.
19. according to each described system in the claim 13 to 18, described system also comprises at least one the 3rd storing chamber that is used to store chilled water.
20. according to each described system in preceding claim, wherein said application apparatus also comprises at least one the 3rd Room that is used for combustion waste.
21. system according to claim 20, wherein said at least one the 3rd Room comprises:
-combustion unit, it is combustion waste by burning Blang's gas;
-the first inlet, it is connected with described combustion unit, is used to receive refuse;
-the second inlet, it is connected with described combustion unit, is used to receive the Blang's gas from least one first storing chamber; With
-outlet, it is connected with described combustion unit, is used to discharge the stack gas that is produced by described combustion unit.
22. system according to claim 21, described system also are included at least one flash eliminator of the described first inlet front.
23. according to claim 21 or the described system of claim 22, described system also comprises the heat exchanger that is connected with the described outlet that is used to discharge stack gas.
24. a boiler and burner device that is used to produce hot water, described boiler and burner device comprises:
-the first inlet is used for receiving feedwater;
-the second inlet is used to receive the Blang's gas from Blang's gas generator; With
-outlet is used to discharge the hot water of generation,
Wherein burn described Blang's gas to produce heat, and described heat heats described feedwater to produce hot water.
25. boiler and burner device according to claim 24, the described outlet that wherein is used to discharge the hot water that is produced is connected with the hold-up vessel that is used to store the hot water that is produced.
26. boiler and burner device according to claim 25, wherein the outlet of the outlet of first inlet and first heat exchanger of described Blang's gas generator, at least one solar thermal collector and/or the be used to hold-up vessel that stores the hot water that is produced is connected.
27. a system that is used to reclaim by the heat that burning produced of incendiary material, described system comprises:
-at least one Blang's gas generator, it is communicated with power supply and water source;
-at least one first storing chamber, it is communicated with described producer fluid, is used to store Blang's gas that described producer produces; With
-at least one combustion chamber, it is communicated with at least one first storing chamber, and described incendiary material is used to burn; With
-at least one hot extraction chamber, it is fit to receive the heat that produces via described combustion chamber from the burning of described incendiary material,
The wherein said producer and first storing chamber are positioned at the contiguous place of described combustion chamber and described hot extraction chamber.
28. system according to claim 27, wherein said at least one combustion chamber comprises:
-combustion unit, it is used for by the described Blang's gas that the burns described incendiary material that burns;
-the first inlet, it is connected with described combustion unit, is used to receive described incendiary material;
-the second inlet, it is connected with described combustion unit, is used to receive the Blang's gas from described at least one first storing chamber; With
-outlet, it is connected with described combustion unit, is used to discharge the stack gas that is produced by described combustion unit.
29. according to claim 27 or the described system of claim 28, wherein said incendiary material is a refuse.
30. according to claim 28 or the described system of claim 29, wherein said at least one hot extraction chamber is the steam generating plant that is used to produce steam, makes the heat be used to produce described steam be obtained by the stack gas that described combustion unit produces.
31. according to each described system in the claim 28 to 30, wherein said at least one hot extraction chamber comprises:
-water inlet;
-waste gas inlet is used to receive the stack gas that is produced by described combustion unit;
-the first outlet is used to discharge the steam of generation, and
-the second outlet is used to discharge stack gas,
Make by from the stack gas heating of described waste gas inlet water, thereby produce steam from described water inlet, and wherein from the described steam of the described first outlet discharging, and from the described stack gas of the described second outlet discharging.
32. system according to claim 31, the described waste gas inlet of wherein said at least one hot extraction chamber is connected with the outlet of described at least one combustion chamber.
33. according to each described system in the claim 27 to 32, described system also comprises the generating device that is communicated with described at least one hot extraction chamber.
34. system according to claim 33, wherein said generating comprises with device:
-at least one steam turbine, it is fit to receive the steam that is produced by described at least one hot extraction chamber;
-at least one generator, it is communicated with at least one steam turbine, is used to produce electric power; With
-be used to discharge the device of the electric power that produces by described generator.
35. system according to claim 34, wherein said at least one steam turbine is single-stage or multistage steam turbine.
36., wherein the electric power that is produced is supplied to described at least one Blang's gas generator and/or electrical network according to each described system in the claim 33 to 35.
37. according to each described system in the claim 34 to 36, described system also comprises the heat exchanger that is communicated with described at least one steam turbine and described at least one hot extraction chamber.
38. according to the described system of claim 37, wherein said heat exchanger comprises:
-steam-in is used to receive the steam from described steam turbine; With
-water out,
The steam that wherein said heat exchanger cooling receives from described steam-in, thus make described vapor condensation with generation water, and wherein discharge described water from described water out.
39. according to the described system of claim 38, wherein said heat exchanger also comprises: second inlet, the steam that produces by described at least one hot extraction chamber when described second inlet is fit to be received in described steam turbine and reaches its maximum capacity.
40. according to claim 38 or the described system of claim 39, the water out of wherein said heat exchanger is connected with the water inlet of described at least one hot extraction chamber.
41. according to each described system in the claim 27 to 40, wherein said at least one hot extraction chamber comprises moisture eliminator, described moisture eliminator is used for described incendiary material dry before it is burnt in described combustion chamber.
42. according to the described system of claim 41, the heat that wherein is used for dry described incendiary material is obtained by the stack gas of discharging from described combustion unit.
43. according to claim 41 or the described system of claim 42, wherein the incendiary material of exsiccant from described moisture eliminator burns in described at least one combustion chamber.
44. a method that is used to reclaim by the heat that burning produced of incendiary material said method comprising the steps of:
-by burning Blang gas, at least one combustion chamber, make the incendiary material burning; And
-receive the stack gas that produces by the combustion chamber to reclaim heat wherein.
45. according to the described method of claim 44, described method is further comprising the steps of:
Produce steam in boiler, the heat that wherein is used to produce described steam is obtained by the stack gas that produces from described combustion chamber.
46. according to the described method of claim 45, wherein said method is further comprising the steps of:
-described the steam that will produce is supplied at least one steam turbine; With
-generator that is communicated with described at least one steam turbine is provided, be used to produce electric power.
47., wherein the electric power that is produced is supplied to described at least one Blang's gas generator and/or electrical network according to the described method of claim 46.
48. according to claim 46 or the described method of claim 47, wherein said at least one steam turbine is single-stage or multistage steam turbine.
49. according to the described method of claim 44, described method is further comprising the steps of: incendiary material is dried before burning at least one combustion chamber, makes the stack gas by the generation of described combustion chamber obtain being used to heat the heat of described incendiary material.
50. according to the described method of claim 49, wherein the exsiccant incendiary material burns in described at least one combustion chamber.
51. one kind is used for handling the assembly that is discharged into atmosphere stack gas before, described assembly comprises:
-at least one treatment chamber is used for receiving and heating described stack gas;
The device of-Blang's the gas that is used to burn is used to heat the heat of described stack gas with supply; And
Be used to discharge the part of the stack gas that has heated.
52. according to the described assembly of claim 51, described assembly also is included at least one member of described at least one inner treatment chamber, wherein heating flue gas has been realized the bigger heating efficiency of described stack gas near described at least one member.
53. according to the described assembly of claim 52, wherein said at least one member comprises the mesh grid parts, wherein said mesh grid parts are contained in described at least one inner treatment chamber.
54. according to the described assembly of claim 53, wherein said mesh grid parts are made by platinum, steel, nickel-chromium alloy, aluminium-Chrome metal powder or their combination.
55. according to each described assembly in the claim 51 to 54, the device of the wherein said Blang's gas that is used to burn is Blang's air burner.
56. according to each described assembly in the claim 51 to 55, wherein said at least one treatment chamber is heated above 500 ℃ temperature.
57. according to the described assembly of claim 56, wherein said at least one treatment chamber is heated to the temperature between 800 ℃ to 1600 ℃.
58. according to each described assembly in the claim 51 to 57, wherein said assembly comprises 3 treatment chambers, described 3 treatment chambers are set up, and make described stack gas pass through each in described 3 treatment chambers successively.
59. according to each described assembly in the claim 51 to 58, described assembly also comprises the hot extraction chamber of the stack gas that suitable reception has been heated.
60. according to the described assembly of claim 59, wherein said hot extraction chamber comprises the steam generating plant that is used to produce steam, the feasible heat that obtains being used to produce steam from the described stack gas that has heated.
61. according to claim 59 or the described assembly of claim 60, wherein said hot extraction chamber comprises:
-water inlet;
-vapour outlet; With
-flue gas outlet,
Described hot extraction chamber is positioned to and allows described stack gas to add hot water to produce steam.
62. according to each described assembly in the claim 51 to 61, described assembly also comprises the generating device that is communicated with described hot extraction chamber.
63. according to the described assembly of claim 62, wherein said generating comprises with device:
-at least one steam turbine, it is fit to receive the steam that is produced by described hot extraction chamber;
-at least one generator, it is communicated with described at least one steam turbine, is used to produce electric power; With
-be used to discharge the device of the electric power that produces by described generator.
64. according to the described assembly of claim 63, wherein said at least one steam turbine is single-stage or multistage steam turbine.
65. according to each described assembly in the claim 62 to 64, wherein the electric power that is produced is fed into electrical network.
66. according to each described assembly in the claim 63 to 65, described assembly also comprises the heat exchanger that is communicated with described at least one steam turbine and described hot extraction chamber.
67. according to the described assembly of claim 66, wherein said heat exchanger comprises:
-the first inlet is used to receive the steam from described steam turbine; And
-water out,
Wherein said heat exchanger can make vapor condensation with generation water, and wherein discharges described water from described water out.
68. according to the described assembly of claim 67, wherein said heat exchanger also comprises second inlet, the steam that is produced by described hot extraction chamber when described second inlet is fit to be received in described steam turbine and reaches its maximum capacity.
69. according to claim 67 or the described assembly of claim 68, the water out of wherein said heat exchanger is connected with the water inlet of described hot extraction chamber.
70. according to each described assembly in the claim 51 to 69, described assembly also comprises wash, described wash comprises the device that is used to wash stack gas, and wherein said wash be fit to receive the stack gas from the flue gas outlet of part that is used to discharge the described stack gas that has heated and/or described hot extraction chamber.
71. according to the described assembly of claim 70, the wherein said device that is used to wash stack gas is a washer.
72. according to the described assembly of claim 71, wherein said washer is selected from wet scrubber, venturi scrubber, impingement plate scrubber and tower spray scrubber.
73. according to each described assembly in the claim 70 to 72, wherein said wash also comprises and is used for cooling off the device that is discharged into the stack gas before the atmosphere.
74. according to the described assembly of claim 73, the wherein said device that is used for cooling stack gas is an expander.
75. according to claim 73 or the described assembly of claim 74, the wherein said device that is used for cooling stack gas with described flue gas cools to the temperature that is lower than 300 ℃.
76. one kind is used to handle the method that is discharged into atmosphere stack gas before, said method comprising the steps of:
-stack gas is provided at least one treatment chamber;
-Blang's gas is provided to the device of the Blang's gas that is used to burn; With
-described Blang's gas is heated to preset temperature with described stack gas by burning.
77. according to the described method of claim 76, the existence that wherein said heating steps is included at least one member that is used to realize higher heating efficiency is the described stack gas of heating down.
78. according to claim 76 or the described method of claim 77, the device of the wherein said Blang's gas that is used to burn is Blang's air burner.
79. according to each described method in the claim 76 to 78, wherein said preset temperature is higher than 700 ℃.
80. according to each described method in the claim 76 to 79, wherein described stack gas is provided to 3 treatment chambers, described stack gas is passed through each in described 3 treatment chambers successively.
81. 0 described method according to Claim 8, described method is further comprising the steps of:
-described stack gas is provided to first treatment chamber;
-by the described Blang's gas of burning, the described stack gas in first treatment chamber is heated to first preset temperature;
-will be delivered to second treatment chamber from the stack gas that has heated of described first treatment chamber with pipeline;
-by the described Blang's gas of burning, the described stack gas in second treatment chamber is heated to second preset temperature;
-will be delivered to the 3rd treatment chamber from the stack gas that has heated of described second treatment chamber with pipeline; And
-by the described Blang's gas of burning, the described stack gas in the 3rd treatment chamber is heated to the 3rd preset temperature.
82. 1 described method according to Claim 8, wherein said first preset temperature is about 800 ℃.
83. according to Claim 81 or the described method of claim 82, wherein described two preset temperatures are about 1000 ℃.
84. each described method in 1 to 83 according to Claim 8, wherein said the 3rd preset temperature is higher than 1200 ℃.
85. according to each described method in the claim 76 to 84, described method also is included in the step that produces steam in the hot extraction chamber, wherein obtains being used to produce the heat of described steam from the stack gas that has heated.
86. 5 described methods according to Claim 8, described method is further comprising the steps of:
-steam that produces is supplied at least one steam turbine; With
-generator that is communicated with described at least one steam turbine is provided, be used to produce electric power.
87. according to each described method in the claim 76 to 86, described method is further comprising the steps of:
-in the described stack gas that has heated of device washing that is used for washing stack gas; And/or
-be used for the described stack gas that has heated of device cooling of cooling stack gas.
88. 7 described methods according to Claim 8, wherein with described flue gas cools to the temperature that is lower than 300 ℃.
CNA2007800418504A 2006-09-13 2007-09-13 System for generating Brown gas and uses thereof Pending CN101583699A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
SG200606177-4A SG141247A1 (en) 2006-09-13 2006-09-13 System for generating brown gas and uses thereof
SG2006061774 2006-09-13
SG2007024425 2007-04-04

Publications (1)

Publication Number Publication Date
CN101583699A true CN101583699A (en) 2009-11-18

Family

ID=39321369

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA2007800418504A Pending CN101583699A (en) 2006-09-13 2007-09-13 System for generating Brown gas and uses thereof

Country Status (2)

Country Link
CN (1) CN101583699A (en)
SG (1) SG141247A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105297071A (en) * 2015-10-29 2016-02-03 鹤山市嘉德环保科技有限公司 High-energy gas
CN108350836A (en) * 2015-07-29 2018-07-31 燃料节省有限公司 The method of marine propuision system and operating ship propulsion system

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108350836A (en) * 2015-07-29 2018-07-31 燃料节省有限公司 The method of marine propuision system and operating ship propulsion system
CN108350836B (en) * 2015-07-29 2020-09-22 燃料节省有限公司 Ship propulsion system and method of operating a ship propulsion system
CN105297071A (en) * 2015-10-29 2016-02-03 鹤山市嘉德环保科技有限公司 High-energy gas

Also Published As

Publication number Publication date
SG141247A1 (en) 2008-04-28

Similar Documents

Publication Publication Date Title
US20100206248A1 (en) System for generating brown gas and uses thereof
CN105090997B (en) A kind of highly concentrated brine waste, waste residue low-cost processes method and its device
CN110036238B (en) Method and system for improving boiler effectiveness
US20080257236A1 (en) Smokeless furnace
CN101724728B (en) Waste heat recovery and bag-type dust removal system
JPH09512626A (en) Fuel gas purification apparatus and method for thermoelectric generator unit
CN107166977A (en) A kind of closed vessel furnace furnace gas is reclaimed and cleaning treatment system
RU2632293C1 (en) Device for processing rubber waste
CN105987376B (en) A kind of fuel clean combustion and the combustion apparatus of purification discharge
CN109579022A (en) A kind of multi-functional straight tube radioactive waste control oxygen incinerator and incinerating method
CN203330097U (en) Integrated treatment and utilization device for hazardous decoction dreg wastes
CN108194931A (en) Industrial waste plasma handling system
US5078752A (en) Coal gas productions coal-based combined cycle power production
KR101666501B1 (en) Dry distillation type pyrolysis system of waste electric wire and communication line
CN204573999U (en) The combustion apparatus of fuel clean combustion and emission abatement
CN110081445A (en) A kind of liquid hazardous waste burn system and its burning process
CN207132737U (en) A kind of closed vessel furnace furnace gas recovery and cleaning treatment system
CN101583699A (en) System for generating Brown gas and uses thereof
WO2012110760A1 (en) Ammonia stripper
RU2425289C1 (en) Flame neutraliser of industrial wastes
CN105546552B (en) Resinae dangerous waste fluid bed high temperature incineration purifying integration device and method
CN204853508U (en) High enriched salt waste water, low -cost processing apparatus of waste residue of containing
CN201697133U (en) Garbage incinerator
CN103614509A (en) Carbon steel converter dry cloth bag dust removal process and device capable of recovering waste heat in whole process
CN102304603A (en) Waste heat recovery and bag-type dust removal system

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20091118