CN101575185B - High-efficiency compound slag-grinding aid of beet waste mash compound and production method thereof - Google Patents

High-efficiency compound slag-grinding aid of beet waste mash compound and production method thereof Download PDF

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Publication number
CN101575185B
CN101575185B CN2009103034333A CN200910303433A CN101575185B CN 101575185 B CN101575185 B CN 101575185B CN 2009103034333 A CN2009103034333 A CN 2009103034333A CN 200910303433 A CN200910303433 A CN 200910303433A CN 101575185 B CN101575185 B CN 101575185B
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China
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parts
compound
waste mash
slag
beet waste
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Expired - Fee Related
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CN2009103034333A
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CN101575185A (en
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徐彬
蔡戈
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Xinjiang Western Blue Sky New Materials Co ltd
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Individual
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/18Waste materials; Refuse organic
    • C04B18/24Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork
    • C04B18/248Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork from specific plants, e.g. hemp fibres
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/026Comminuting, e.g. by grinding or breaking; Defibrillating fibres other than asbestos
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Botany (AREA)
  • Environmental & Geological Engineering (AREA)
  • Civil Engineering (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention relates to the technical field of building material manufacturing and sugar-making, and is a high-efficiency compound slag-grinding aid of beet waste mash compound and a production method thereof; the invention further comprises a using method of the high-efficiency compound slag-grinding aid of beet waste mash compound and application of beet waste mash in slag-grinding aid. The high-efficiency compound slag-grinding aid of beet waste mash compound contains beet waste mash compound, glycol, diglycol, triethanolamine and water. The invention not only uses industrial waste, reduces the cost of slag-grinding aid, but also adds 0.015-0.035% of the grinding aid in grinding process of the slag to increase the yield of slag grinder by 15%-30%; 0.015-0.035% of grinding aid is added under the condition of maintaining yield of the grinder so that the specific surface area of slag powder is increased by 7%-15%, thereby reaching to purpose of energy-saving and emission-reduction andgenerating economic benefit and social benefit.

Description

High-efficiency compound slag-grinding aid of beet waste mash compound and production method thereof
The present invention relates to the technical field of material of construction manufacturing and sugaring, be a kind of high-efficiency compound slag-grinding aid of beet waste mash compound and production method thereof, also comprise using method and the application of beet waste mash in slag grinding aid of high-efficiency compound slag-grinding aid of beet waste mash compound.
Background technology
Slag is a large amount of a kind of industrial residues that produce in steel manufacture process, and it is levigate rear as cement mixture or the existing history for many years of concrete admixture.Be milled down to specific surface area 〉=420m after slag drying 2The micro mist of/kg is prepared burden, and can significantly improve cement and concrete performance.But the grindability of slag is very poor, and not only production efficiency is low but also energy consumption is huge to cause the production of slag powders.Therefore, the mill efficiency of raising slag is significant for energy-saving and emission-reduction.
Beet waste mash be in the beet sugar manufacture process a large amount of produce take organism as main nontoxic harmful waste liquid.At present the useless mash resource utilization mode of beet sugar is mainly that agriculture is filled with method, rushed grey method, oxidation pond process, method of enrichment process alcohol slops and manufacture order cell protein and Yeast protein.
After the beet waste mash agriculture is filled with, the soil salinization increases the weight of, and suppresses the mineralising of the soil organism and total oxygen, and available phosphorus content significantly descends, and effectively zinc, manganese, iron level obviously increase.Dirty filling makes wheat yield, sewage mix filling and also makes the vegetables underproduction.
Oxidation pond process mainly utilizes microorganism and aquatic organism to come digestion of organic matter, although this method less investment, working cost is low, simple to operate, needs the pond capacity large, and floor space is large, treating processes severe contamination air and underground water.
Method of enrichment process alcohol slops be waste liquid after neutralization, precipitation process, by evaporation concentration repeatedly, then drying is made dry powder.Dry powder is made cement water reducing agent or fertilizer raw material.This method evaporation concentration, dry steam consumption is high and the product that reclaims is limited as the water reducer consumption, makes the fertilizer output value low.Because investment is large, energy consumption and working cost are high, and the amount of circulating funds used is large, and built method of enrichment manufacturer mostly can't continue to produce at present.
Summary of the invention
The invention provides a kind of high-efficiency compound slag-grinding aid of beet waste mash compound and production method thereof, it has overcome the deficiency of prior art, the beet waste mash that utilizes sugar industry to produce in a large number and be difficult to process is as one of raw material, not only reduced cost but also turned waste into wealth, utilize this high-efficiency compound slag-grinding aid of beet waste mash compound that the slag mill output is significantly improved, thereby improved economic benefit and realized the effect of energy-saving and emission-reduction.
One of technical scheme of invention is achieved like this: a kind of high-efficiency compound slag-grinding aid of beet waste mash compound, and it contains by parts by weight of raw materials: the beet waste mash compound of 15 parts to 25 parts, the ethylene glycol of 1 part to 3 parts, the glycol ether of 8 parts to 15 parts, the trolamine of 23 parts to 42 parts, the water of 15 parts to 53 parts; Wherein: this beet waste mash compound contains by parts by weight of raw materials: the beet waste mash of 55 parts to 80 parts, the urea of 5 parts to 8 parts, the Sodium sulfate anhydrous.min(99) of 1 part to 2 parts and the water of 10 parts to 39 parts.
The below is further optimization and/or the selection to one of technique scheme:
Above-mentioned beet waste mash compound obtains in the steps below: at first reacted 15 hours to 17 hours at the temperature of 80 ℃ to 95 ℃ after beet waste mash, urea, Sodium sulfate anhydrous.min(99) and the water mixing with requirement, next obtains beet waste mash compound after being cooled to normal temperature and filtering out solid residue.
Be warmed up to 80 ℃ to 95 ℃ after beet waste mash, urea, Sodium sulfate anhydrous.min(99) and water mixing with above-mentioned requirement in 15 minutes to 30 minutes.
Being cooled to normal temperature after above-mentioned reaction falls solid residue with 200 purpose screen filtrations and obtains beet waste mash compound.
Two of technical scheme of the present invention is achieved like this: the production method of above-mentioned high-efficiency compound slag-grinding aid of beet waste mash compound is carried out in the steps below: beet waste mash compound, ethylene glycol, glycol ether, trolamine, the water of requirement fully are mixed to get high-efficiency compound slag-grinding aid of beet waste mash compound.
Three of technical scheme of the present invention is achieved like this: the using method of above-mentioned high-efficiency compound slag-grinding aid of beet waste mash compound is characterized in that adding the weight percent of expecting total amount to add 0.015% to 0.035% high-efficiency compound slag-grinding aid of beet waste mash compound by the slag grinding machine.
Four of technical scheme of the present invention is achieved like this: the application of beet waste mash in slag grinding aid.
The present invention not only takes full advantage of trade waste, has reduced the cost of slag grinding aid, and adds this kind grinding aid of 0.015% to 0.035% can make the slag mill hourly output improve 15% to 30% in the grinding process of slag; Add this kind grinding aid of 0.015% to 0.035% in the situation that keep the original unit-hour output of grinding machine, can make the specific surface area of slag powders improve 7% to 15%.This had both reached the purpose of energy-saving and emission-reduction, had produced again good economic benefit and social benefit.
Embodiment
The present invention is not subjected to the restriction of following embodiment, can determine concrete embodiment according to technical scheme and the practical situation of the invention described above.
Below in conjunction with embodiment, the present invention is done further discussion:
Embodiment 1, and this beet waste mash compound contains by parts by weight of raw materials: the beet waste mash of 55 parts, the urea of 5 parts, the Sodium sulfate anhydrous.min(99) of 1 part and the water of 10 parts.
Embodiment 2, and this beet waste mash compound contains by parts by weight of raw materials: the beet waste mash of 55 parts, the urea of 8 parts, the Sodium sulfate anhydrous.min(99) of 1 part and the water of 39 parts.
Embodiment 3, and this beet waste mash compound contains by parts by weight of raw materials: the beet waste mash of 55 parts, the urea of 5 parts, the Sodium sulfate anhydrous.min(99) of 2 parts and the water of 10 parts.
Embodiment 4, and this beet waste mash compound contains by parts by weight of raw materials: the beet waste mash of 55 parts, the urea of 8 parts, the Sodium sulfate anhydrous.min(99) of 2 parts and the water of 39 parts.
Embodiment 5, and this beet waste mash compound contains by parts by weight of raw materials: the beet waste mash of 80 parts, the urea of 8 parts, the Sodium sulfate anhydrous.min(99) of 1 part and the water of 39 parts.
Embodiment 6, and this beet waste mash compound contains by parts by weight of raw materials: the beet waste mash of 80 parts, the urea of 5 parts, the Sodium sulfate anhydrous.min(99) of 2 parts and the water of 10 parts.
Embodiment 7, and this beet waste mash compound contains by parts by weight of raw materials: the beet waste mash of 80 parts, the urea of 8 parts, the Sodium sulfate anhydrous.min(99) of 1 part and the water of 39 parts.
Embodiment 8, and this beet waste mash compound contains by parts by weight of raw materials: the beet waste mash of 80 parts, the urea of 8 parts, the Sodium sulfate anhydrous.min(99) of 2 parts and the water of 39 parts.
Embodiment 9, and this beet waste mash compound contains by parts by weight of raw materials: the beet waste mash of 68 parts, 7 parts urea, 1.5 parts Sodium sulfate anhydrous.min(99) and: the water of 25 parts.
Embodiment 10, and this beet waste mash compound contains by parts by weight of raw materials: the beet waste mash of 55 parts to 80 parts, 5 parts to 8 parts urea, 1 part to 2 parts Sodium sulfate anhydrous.min(99) and: the water of 10 parts to 39 parts.
Above-described embodiment 1 to 10 obtains by following production method: at first reacted 15 hours to 17 hours at the temperature of 80 ℃ to 95 ℃ after beet waste mash, urea, Sodium sulfate anhydrous.min(99) and the water mixing with requirement, next obtains beet waste mash compound after being cooled to normal temperature and filtering out solid residue.Wherein: be preferably in and be warmed up to 80 ℃ to 95 ℃ in 15 minutes to 30 minutes, be preferably in and be cooled to normal temperature after reaction and fall solid residue with 200 purpose screen filtrations and obtain beet waste mash compound.
Embodiment 11, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: the beet waste mash compound of 15 parts to 25 parts, the ethylene glycol of 1 part to 3 parts, the glycol ether of 8 parts to 15 parts, the trolamine of 23 parts to 42 parts, the water of 15 parts to 53 parts.
Embodiment 11, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: the beet waste mash compound of 15 parts, the ethylene glycol of 1 part, the glycol ether of 8 parts, the trolamine of 23 parts, the water of 15 parts.
Embodiment 12, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: the beet waste mash compound of 15 parts, the ethylene glycol of 3 parts, the glycol ether of 8 parts, the trolamine of 42 parts, the water of 15 parts.
Embodiment 13, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: the beet waste mash compound of 15 parts, the ethylene glycol of 1 part, the glycol ether of 15 parts, the trolamine of 23 parts, the water of 53 parts.
Embodiment 14, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: the beet waste mash compound of 15 parts, the ethylene glycol of 3 parts, the glycol ether of 15 parts, the trolamine of 42 parts, the water of 53 parts.
Embodiment 15, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: the beet waste mash compound of 25 parts, the ethylene glycol of 3 parts, the glycol ether of 15 parts, the trolamine of 42 parts, the water of 53 parts.
Embodiment 16, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: the beet waste mash compound of 25 parts, the ethylene glycol of 1 part, the glycol ether of 15 parts, the trolamine of 23 parts, the water of 53 parts.
Embodiment 17, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: the beet waste mash compound of 25 parts, the ethylene glycol of 1 part, the glycol ether of 8 parts, the trolamine of 42 parts, the water of 15 parts.
Embodiment 18, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: the beet waste mash compound of 25 parts, the ethylene glycol of 3 parts, the glycol ether of 8 parts, the trolamine of 23 parts, the water of 15 parts.
Embodiment 19, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: the beet waste mash compound of 20 parts, the ethylene glycol of 2 parts, the glycol ether of 11 parts, the trolamine of 32 parts, the water of 34 parts.
Embodiment 20, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: the beet waste mash compound of 15 parts to 25 parts, the ethylene glycol of 1 part to 3 parts, the glycol ether of 8 parts to 15 parts, the trolamine of 23 parts to 42 parts, the water of 15 parts to 53 parts.
Above-described embodiment 11 to 20 obtains by following production method: beet waste mash compound, ethylene glycol, glycol ether, trolamine, the water of requirement fully are mixed to get high-efficiency compound slag-grinding aid of beet waste mash compound.
Embodiment 21, and the using method of this high-efficiency compound slag-grinding aid of beet waste mash compound is to add the weight percent of expecting total amount to add 0.015% to 0.035% high-efficiency compound slag-grinding aid of beet waste mash compound by the slag grinding machine.
Test is learnt to gained high-efficiency compound slag-grinding aid of beet waste mash compound of the present invention: add this kind grinding aid of 0.015% to 0.035% can make the slag mill hourly output improve 15% to 30% in the grinding process of slag; Add this kind grinding aid of 0.015% to 0.035% in the situation that keep the original unit-hour output of grinding machine, can make the specific surface area of slag powders improve 7% to 15%.This all reaches the purpose of energy-saving and emission-reduction, and produces good economic benefit and social benefit.
The concerned countries standard that the present invention relates to is as follows:
GB 175-1999 silicate cement, ordinary Portland cement.
The GB/T 1345-1991 cement fineness method of inspection (80 μ m sieve sieve formula).
GB/T 8074-1987 Method of determination for specific surface of cement Bo Shi method.
GB/T 17671-1999 Test method for strength of hydraulic cement mortar (ISO method).
JC/T 667-2004 cement grinding aid.
GB/T18046-2008 is used for the GBFS of cement and concrete.

Claims (7)

1. a high-efficiency compound slag-grinding aid of beet waste mash compound, is characterized in that containing by parts by weight of raw materials: the beet waste mash compound of 15 parts to 25 parts, the ethylene glycol of 1 part to 3 parts, the glycol ether of 8 parts to 15 parts, the trolamine of 23 parts to 42 parts, the water of 15 parts to 53 parts; Wherein: this beet waste mash compound contains by parts by weight of raw materials: the beet waste mash of 55 parts to 80 parts, the urea of 5 parts to 8 parts, the Sodium sulfate anhydrous.min(99) of 1 part to 2 parts and the water of 10 parts to 39 parts; Wherein, this beet waste mash compound obtains in the steps below: at first reacted 15 hours to 17 hours at the temperature of 80 ℃ to 95 ℃ after beet waste mash, urea, Sodium sulfate anhydrous.min(99) and the water mixing with requirement, next obtains beet waste mash compound after being cooled to normal temperature and filtering out solid residue.
2. high-efficiency compound slag-grinding aid of beet waste mash compound according to claim 1, is characterized in that being warmed up to 80 ℃ to 95 ℃ after beet waste mash, urea, Sodium sulfate anhydrous.min(99) and the water mixing with requirement in 15 minutes to 30 minutes.
3. high-efficiency compound slag-grinding aid of beet waste mash compound according to claim 1 and 2 is characterized in that being cooled to after reaction normal temperature and falls solid residue with 200 purpose screen filtrations and obtain beet waste mash compound.
4. the production method of a high-efficiency compound slag-grinding aid of beet waste mash compound according to claim 1 and 2, is characterized in that carrying out in the steps below: beet waste mash compound, ethylene glycol, glycol ether, trolamine, the water of requirement fully are mixed to get high-efficiency compound slag-grinding aid of beet waste mash compound.
5. the production method of a high-efficiency compound slag-grinding aid of beet waste mash compound according to claim 3, is characterized in that carrying out in the steps below: beet waste mash compound, ethylene glycol, glycol ether, trolamine, the water of requirement fully are mixed to get high-efficiency compound slag-grinding aid of beet waste mash compound.
6. the using method of a high-efficiency compound slag-grinding aid of beet waste mash compound according to claim 1 and 2, is characterized in that adding the weight percent of expecting total amount to add 0.015% to 0.035% high-efficiency compound slag-grinding aid of beet waste mash compound by the slag grinding machine.
7. the using method of a high-efficiency compound slag-grinding aid of beet waste mash compound according to claim 3, is characterized in that adding the weight percent of expecting total amount to add 0.015% to 0.035% high-efficiency compound slag-grinding aid of beet waste mash compound by the slag grinding machine.
CN2009103034333A 2009-06-19 2009-06-19 High-efficiency compound slag-grinding aid of beet waste mash compound and production method thereof Expired - Fee Related CN101575185B (en)

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Families Citing this family (4)

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Publication number Priority date Publication date Assignee Title
CN102249586A (en) * 2011-05-13 2011-11-23 洛阳万顺建材有限公司 Grinding-assistant reinforcing agent for mineral powder
CN104045253B (en) * 2013-03-13 2016-05-18 同济大学 A kind of slag additive and its production and use
CN106186780B (en) * 2016-07-05 2020-05-05 湖北鑫统领万象科技有限公司 Grinding aid for improving compatibility of cement and water reducing agent
CN106396453B (en) * 2016-08-31 2019-01-18 武汉理工大学 A kind of modified granite powder as additive and preparation method thereof

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CN1451624A (en) * 2002-04-19 2003-10-29 尹小林 Industrial waste residue activating grinding aid

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CN1451624A (en) * 2002-04-19 2003-10-29 尹小林 Industrial waste residue activating grinding aid

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