CN101573315B - 长链聚亚甲基卤调聚物 - Google Patents

长链聚亚甲基卤调聚物 Download PDF

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Publication number
CN101573315B
CN101573315B CN2007800487504A CN200780048750A CN101573315B CN 101573315 B CN101573315 B CN 101573315B CN 2007800487504 A CN2007800487504 A CN 2007800487504A CN 200780048750 A CN200780048750 A CN 200780048750A CN 101573315 B CN101573315 B CN 101573315B
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fluorine
composition according
group
perfluoroalkyl
hydrogen
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Expired - Fee Related
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Chinese (zh)
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CN101573315A (zh
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乔治·G·I·莫尔
杨宇
理查德·M·弗林
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/26Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/272Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions
    • C07C17/275Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions of hydrocarbons and halogenated hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C19/00Acyclic saturated compounds containing halogen atoms
    • C07C19/08Acyclic saturated compounds containing halogen atoms containing fluorine
    • C07C19/14Acyclic saturated compounds containing halogen atoms containing fluorine and bromine
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C19/00Acyclic saturated compounds containing halogen atoms
    • C07C19/08Acyclic saturated compounds containing halogen atoms containing fluorine
    • C07C19/16Acyclic saturated compounds containing halogen atoms containing fluorine and iodine
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/78Halides of sulfonic acids
    • C07C309/79Halides of sulfonic acids having halosulfonyl groups bound to acyclic carbon atoms
    • C07C309/82Halides of sulfonic acids having halosulfonyl groups bound to acyclic carbon atoms of a carbon skeleton substituted by singly-bound oxygen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/01Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms
    • C07C311/02Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C311/09Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton the carbon skeleton being further substituted by at least two halogen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00Ethers; Compounds having groups, groups or groups
    • C07C43/02Ethers
    • C07C43/03Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04Saturated ethers
    • C07C43/12Saturated ethers containing halogen
    • C07C43/126Saturated ethers containing halogen having more than one ether bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/62Halogen-containing esters
    • C07C69/63Halogen-containing esters of saturated acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F120/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F120/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F120/10Esters
    • C08F120/22Esters containing halogen
    • C08F120/24Esters containing halogen containing perhaloalkyl radicals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F120/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F120/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F120/10Esters
    • C08F120/34Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C08F120/36Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/22Esters containing halogen
    • C08F220/24Esters containing halogen containing perhaloalkyl radicals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/10Acylation
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/12Hydrolysis
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/14Esterification
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805Compounds having only one group containing active hydrogen
    • C08G18/288Compounds containing at least one heteroatom other than oxygen or nitrogen
    • C08G18/2885Compounds containing at least one heteroatom other than oxygen or nitrogen containing halogen atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/256Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/3154Of fluorinated addition polymer from unsaturated monomers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Textile Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
CN2007800487504A 2006-12-29 2007-12-27 长链聚亚甲基卤调聚物 Expired - Fee Related CN101573315B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US88281006P 2006-12-29 2006-12-29
US88279806P 2006-12-29 2006-12-29
US60/882,798 2006-12-29
US60/882,810 2006-12-29
PCT/US2007/088903 WO2008083199A1 (en) 2006-12-29 2007-12-27 Long-chain polymethylene halide telomers

Publications (2)

Publication Number Publication Date
CN101573315A CN101573315A (zh) 2009-11-04
CN101573315B true CN101573315B (zh) 2013-05-29

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US (2) US7893186B2 (enExample)
EP (1) EP2109596B1 (enExample)
JP (1) JP5543215B2 (enExample)
CN (1) CN101573315B (enExample)
AT (1) ATE467611T1 (enExample)
DE (1) DE602007006557D1 (enExample)
WO (2) WO2008083199A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8729138B2 (en) 2010-03-25 2014-05-20 E I Du Pont De Nemours And Company Mixture of polyfluoroalkylsulfonamido alkyl amines

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5543215B2 (ja) * 2006-12-29 2014-07-09 スリーエム イノベイティブ プロパティズ カンパニー 長鎖ポリメチレンハロゲン化物テロマー類
CN101993338B (zh) * 2009-08-24 2014-12-17 中化蓝天集团有限公司 六氟丙烯二聚体的分离提纯方法
US9168408B2 (en) 2010-03-25 2015-10-27 The Chemours Company Fc, Llc Surfactant composition from polyfluoroalkylsulfonamido alkyl amines
US8779196B2 (en) * 2010-03-25 2014-07-15 E I Du Pont De Nemours And Company Polyfluoroalkylsulfonamido alkyl halide intermediate
CN103347842B (zh) 2010-12-17 2016-09-28 3M创新有限公司 部分氟化的亚磺酸单体和它们的盐
CN103261242B (zh) * 2010-12-17 2016-05-04 3M创新有限公司 包含含有亚磺酸根的分子的含氟聚合物
WO2015050928A1 (en) 2013-10-04 2015-04-09 3M Innovative Properties Company Fluoroalkyl silicone compositions
EP3052509A1 (en) 2013-10-04 2016-08-10 3M Innovative Properties Company Fluoroalkylsilanes and coatings therefrom
JP2017517587A (ja) 2014-03-31 2017-06-29 スリーエム イノベイティブ プロパティズ カンパニー フルオロアルキルシリコーン
US9994676B2 (en) 2014-06-23 2018-06-12 3M Innovative Properties Company Silicon-containing polymer and method of making a silicon-containing polymer
WO2021049455A1 (ja) * 2019-09-12 2021-03-18 Agc株式会社 含フッ素化合物の製造方法及び共重合体の製造方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3016407A (en) * 1960-09-21 1962-01-09 Du Pont Telomers from ch=ch and icf2cf2i
US3514487A (en) * 1967-04-25 1970-05-26 Allied Chem Telomers and process for the preparation thereof
GB1415245A (en) * 1972-04-17 1975-11-26 Kali Chemie Ag Method of producing fluoralkyl-iodide telomers

Family Cites Families (80)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US305055A (en) * 1884-09-16 Quartz-crushing machine
BE463774A (enExample) * 1942-04-10
US2440801A (en) 1942-06-17 1948-05-04 Du Pont Process of reacting hydrogen chloride with olefinic compounds, and product
BE464314A (enExample) 1943-01-01
US2519983A (en) * 1948-11-29 1950-08-22 Minnesota Mining & Mfg Electrochemical process of making fluorine-containing carbon compounds
US2567011A (en) * 1949-01-10 1951-09-04 Minnesota Mining & Mfg Fluorocarbon acids and derivatives
US2642416A (en) * 1950-05-26 1953-06-16 Minnesota Mining & Mfg Fluorinated acrylates and polymers
US2592069A (en) 1951-03-05 1952-04-08 Minnesota Mining & Mfg Fluorocarbon vinyl esters and polymers
US2662835A (en) 1951-04-06 1953-12-15 Minnesota Mining & Mfg Chromium coordination complexes of saturated perfluoro-monocarboxylic acids and articles coated therewith
US2693458A (en) 1952-07-18 1954-11-02 Minnesota Mining & Mfg Chromium complexes of fluorocarbon acids
US2732398A (en) * 1953-01-29 1956-01-24 cafiicfzsojk
DE1074267B (de) 1953-04-06 1960-01-28 Minnesota Mining and Manufac turing Company St Paul Mmn (V St A) Verfahren zur Herstellung von fluorhaltigen Telomeren
US2727923A (en) * 1953-07-17 1955-12-20 Minnesota Mining & Mfg Perfluoro quaternary ammonium compounds
US2764602A (en) 1954-04-21 1956-09-25 Minnesota Mining & Mfg Quaternary ammonium alkylperfluoroamides
US2764603A (en) * 1954-04-21 1956-09-25 Minnesota Mining & Mfg Alkylaminoalkyl-perfluoroamides
US2759019A (en) 1954-08-09 1956-08-14 Minnesota Mining & Mfg Perfluoro amine compounds and quaternary derivatives
US2809990A (en) * 1955-12-29 1957-10-15 Minnesota Mining & Mfg Fluorocarbon acids and derivatives
US2803615A (en) 1956-01-23 1957-08-20 Minnesota Mining & Mfg Fluorocarbon acrylate and methacrylate esters and polymers
US2803656A (en) 1956-01-23 1957-08-20 Minnesota Mining & Mfg Fluorocarbonsulfonamidoalkanols and sulfates thereof
US2846472A (en) * 1956-06-29 1958-08-05 Minnesota Mining & Mfg Process for making organic sulfonyl fluorides
US3171861A (en) * 1957-06-11 1965-03-02 Minnesota Mining & Mfg Fluorinated aliphatic alcohols
US2915554A (en) 1957-07-23 1959-12-01 Minnesota Mining & Mfg Non-ionic surfactant derivatives of perfluoro alkane-sulfonamides
US3102103A (en) 1957-08-09 1963-08-27 Minnesota Mining & Mfg Perfluoroalkyl acrylate polymers and process of producing a latex thereof
US3050555A (en) 1958-09-19 1962-08-21 Minnesota Mining & Mfg Ethylene telomers
NL123950C (enExample) * 1959-08-10
US3055953A (en) * 1960-06-17 1962-09-25 Du Pont Ethylene telomers and process of preparing same
US3094547A (en) * 1961-02-06 1963-06-18 Minnesota Mining & Mfg Perfluoroalkylsulfonamidoalkyl esters of phosphorus acids
US3145222A (en) * 1961-02-23 1964-08-18 Du Pont Addition of polyfluoroalkyl iodides to unsaturated compounds and products produced thereby
US3106407A (en) * 1961-05-02 1963-10-08 Virdean R Mattingly Packing ring with anti-extrusion end rings
US3398182A (en) * 1962-06-22 1968-08-20 Minnesota Mining & Mfg Fluorocarbon urethane compounds
GB1102903A (en) 1964-02-24 1968-02-14 Daikin Ind Ltd Fluoro alkyl-containing compounds and water- and oil-repellent compositions containing them
US3818074A (en) 1965-03-01 1974-06-18 Minnesota Mining & Mfg Fluorinated esters
US3341497A (en) 1966-01-21 1967-09-12 Minnesota Mining & Mfg Organic solvent soluble perfluorocarbon copolymers
GB1215861A (en) 1967-02-09 1970-12-16 Minnesota Mining & Mfg Cleanable stain-resistant fabrics or fibers and polymers therefor
US3573332A (en) * 1968-07-19 1971-03-30 Union Oil Co Preparation of aliphatic acids and esters
US3842019A (en) * 1969-04-04 1974-10-15 Minnesota Mining & Mfg Use of sulfonic acid salts in cationic polymerization
US3641171A (en) * 1969-06-11 1972-02-08 Shell Oil Co Ethylene telomerization
US3592866A (en) * 1969-06-11 1971-07-13 Shell Oil Co Alpha-olefin production
US3562156A (en) 1969-06-12 1971-02-09 Minnesota Mining & Mfg Fire extinguishing composition comprising a fluoroaliphatic surfactant and a fluorine-free surfactant
US4058573A (en) * 1971-07-02 1977-11-15 Ciba-Geigy Corporation Process for the addition of gaseous non-halogenated olefins and acetylenes to perfluoroalkyl iodides
US3916053A (en) 1971-09-12 1975-10-28 Minnesota Mining & Mfg Carpet treating and treated carpet
US3787351A (en) 1972-02-28 1974-01-22 Minnesota Mining & Mfg Use of soluble fluoroaliphatic oligomers in resin composite articles
US4024178A (en) 1972-03-06 1977-05-17 Minnesota Mining And Manufacturing Company Fluoroaliphatic radical containing carbodiimides
CH587381B5 (enExample) 1972-03-06 1977-04-29 Minnesota Mining & Mfg
US4043923A (en) * 1974-02-26 1977-08-23 Minnesota Mining And Manufacturing Company Textile treatment composition
US4147851A (en) 1978-06-13 1979-04-03 E. I. Du Pont De Nemours And Company Fluorine-containing oil- and water-repellant copolymers
US4264484A (en) 1979-01-24 1981-04-28 Minnesota Mining And Manufacturing Company Carpet treatment
US4359096A (en) * 1980-04-28 1982-11-16 Minnesota Mining And Manufacturing Company Aqueous film-forming foam fire extinguisher
US4484990A (en) 1980-06-16 1984-11-27 Minnesota Mining And Manufacturing Company Mist suppressant for solvent extraction metal electrowinning
US4401780A (en) 1982-02-03 1983-08-30 Minnesota Mining And Manufacturing Company Textile treatments
US4529658A (en) * 1982-10-13 1985-07-16 Minnesota Mining And Manufacturing Company Fluorochemical copolymers and ovenable paperboard and textile fibers treated therewith
US4540497A (en) 1982-11-09 1985-09-10 Minnesota Mining And Manufacturing Company Fluoroaliphatic radical-containing, substituted guanidines and fibrous substrates treated therewith
US4716208A (en) 1984-02-13 1987-12-29 E. I. Du Pont De Nemours And Company Fluorine-containing copolymers
US4668406A (en) * 1984-04-02 1987-05-26 Minnesota Mining And Manufacturing Company Fluorochemical biuret compositions and fibrous substrates treated therewith
US4606737A (en) 1984-06-26 1986-08-19 Minnesota Mining And Manufacturing Company Fluorochemical allophanate compositions and fibrous substrates treated therewith
US4564561A (en) 1985-03-27 1986-01-14 E. I. Du Pont De Nemours And Company Fluorine-containing polymer compositions and their preparation
US5025052A (en) 1986-09-12 1991-06-18 Minnesota Mining And Manufacturing Company Fluorochemical oxazolidinones
DE4025154A1 (de) * 1990-08-08 1992-02-13 Max Planck Gesellschaft Fotochemische herstellung von halogenverbindungen
US5276175A (en) 1991-04-02 1994-01-04 Minnesota Mining And Manufacturing Company Isocyanate derivatives comprising flourochemical oligomers
US5271806A (en) * 1991-04-17 1993-12-21 Minnesota Mining And Manufacturing Company Method for sizing paper
DE4143390A1 (en) 1991-04-26 1993-04-01 Fluorine contg. (co)polymers, useful for water- and oil repellent treatment of substrates
US5244951A (en) 1991-05-02 1993-09-14 Minnesota Mining And Manufacturing Company Durably hydrophilic, thermoplastic fiber
CA2071596A1 (en) 1991-07-10 1993-01-11 Frederick E. Behr Perfluoroalkyl halides and derivatives
US6048952A (en) 1991-07-10 2000-04-11 3M Innovative Properties Company Perfluoroalkyl halides and derivatives
US5207996A (en) 1991-10-10 1993-05-04 Minnesota Mining And Manufacturing Company Acid leaching of copper ore heap with fluoroaliphatic surfactant
US5451622A (en) * 1992-09-30 1995-09-19 Minnesota Mining And Manufacturing Company Composition comprising thermoplastic polymer and fluorochemical piperazine compound
US5380778A (en) 1992-09-30 1995-01-10 Minnesota Mining And Manufacturing Company Fluorochemical aminoalcohols
JPH06145687A (ja) 1992-11-06 1994-05-27 Sony Corp 潤滑剤及びその潤滑剤を保有する磁気記録媒体
US5390778A (en) * 1994-01-25 1995-02-21 U.S. Natural Resources, Inc. Apparatus for even ending lumber
US5468353A (en) * 1994-05-05 1995-11-21 Minnesota Mining And Manufacturing Company Mist suppressant for solvent extraction metal electrowinning
US5459212A (en) * 1994-05-26 1995-10-17 E. I. Du Pont De Nemours And Company Carbon based initiators for polymerization and telomerization of vinyl monomers
US5612431A (en) * 1994-09-21 1997-03-18 Minnesota Mining And Manufacturing Company Leaching of precious metal ore with fluoroaliphatic surfactant
US5725789A (en) 1995-03-31 1998-03-10 Minnesota Mining And Manufacturing Company Aqueous oil and water repellent compositions
US5641844A (en) 1995-12-13 1997-06-24 W. L. Gore & Associates, Inc. Polymers with crystallizable fluoropolymers
US5744201A (en) * 1996-07-23 1998-04-28 Minnesota Mining And Manufacturing Company Method for treating carpet using PH adjustment
US6326447B1 (en) * 1998-06-19 2001-12-04 E. I. Du Pont De Nemours And Company Polymeric compositions for soil release on fabrics
US6824882B2 (en) * 2002-05-31 2004-11-30 3M Innovative Properties Company Fluorinated phosphonic acids
US20050119430A1 (en) 2003-12-02 2005-06-02 Chung-Shan Institute Of Science & Technology Process for preparing a water- and oil-repellent agent of aqueous dispersion type
US8889230B2 (en) * 2006-08-31 2014-11-18 3M Innovative Properties Company Side chain fluorochemicals with crystallizable spacer groups
JP5543215B2 (ja) 2006-12-29 2014-07-09 スリーエム イノベイティブ プロパティズ カンパニー 長鎖ポリメチレンハロゲン化物テロマー類

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3016407A (en) * 1960-09-21 1962-01-09 Du Pont Telomers from ch=ch and icf2cf2i
US3514487A (en) * 1967-04-25 1970-05-26 Allied Chem Telomers and process for the preparation thereof
GB1415245A (en) * 1972-04-17 1975-11-26 Kali Chemie Ag Method of producing fluoralkyl-iodide telomers

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8729138B2 (en) 2010-03-25 2014-05-20 E I Du Pont De Nemours And Company Mixture of polyfluoroalkylsulfonamido alkyl amines

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US20090312517A1 (en) 2009-12-17
ATE467611T1 (de) 2010-05-15
DE602007006557D1 (de) 2010-06-24
CN101573315A (zh) 2009-11-04
JP2010514906A (ja) 2010-05-06
WO2008083199A1 (en) 2008-07-10
EP2109596B1 (en) 2010-05-12
EP2109596A1 (en) 2009-10-21
US7893186B2 (en) 2011-02-22
WO2008083201A1 (en) 2008-07-10
JP5543215B2 (ja) 2014-07-09
US8236425B2 (en) 2012-08-07

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