CN101564218A - Printing rubber foxing and manufacture method thereof - Google Patents
Printing rubber foxing and manufacture method thereof Download PDFInfo
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- CN101564218A CN101564218A CNA2008100157394A CN200810015739A CN101564218A CN 101564218 A CN101564218 A CN 101564218A CN A2008100157394 A CNA2008100157394 A CN A2008100157394A CN 200810015739 A CN200810015739 A CN 200810015739A CN 101564218 A CN101564218 A CN 101564218A
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Abstract
The invention provides a printing rubber foxing belonging to the technical fields of printing on rubber and manufacture thereof. The printing rubber foxing comprises rubber foxings, a finishing agent for treating the rubber foxing, transfer paper, patterns printed on one surface of the transfer paper, a 3150 finishing agent for treating the transfer paper and an adhesive coated on the other surface of the transfer paper and one surface of the rubber foxing. The manufacture method of the printing rubber foxing comprises the following steps: (a), selecting the rubber foxings; (b), coating and treating the rubber foxings; (c), preparing the finishing agent to coat and treat the transfer paper; (d), preparing the adhesive to coat the transfer paper; (e), preparing the adhesive to coat the rubber foxing; and (f), heating and molding. The invention has the advantages of fugitive-resistant patterns, friction and high temperature resistance and high racking strength and viscosity holding power.
Description
Technical field
The present invention relates to a kind of printing rubber foxing and manufacture method thereof, belong to stamp and manufacturing technology field thereof on rubber.
Technical background
At present, for the footwear manufacturing, use leather to make usually, but some tourism and leisure footwear rubber material also commonly used makes, a gluing again corral bar on the footwear list especially plays effects such as fastening, protecting against shock, slip-off preventing.Along with the improvement of people, help to improve sight property and improve the desire to purchase of consuming and give various pattern less to these rubber foxings to the outward appearance of footwear.For this reason, China produces this pattern that exports and sell on market footwear are subjected to liking of consumers in general, embody the sales volume that has by force.Footwear have become one of daily wearing trimmings of people, also are products in one's favour in the footwear.Rubber phase has good temperature tolerance and tensile strength to leather, yet, there are a lot of technological difficulties at the stamp that with rubber is base material, so for highly difficult printing rubber technology China or to external import.But relative leather pattern-printing, this printing technique is simple, this on leather stamp do not have technical difficulty, and the domestic and international market uses already, it is to utilize conventional color printing equipment that needed pattern is printed thereon in a side of film, also is in daily use.But the deficiency that mainly has the following aspects with existing this technology stamp on rubber: 1, the retention time short, printing the pattern time just grown and faded, present the bald place of flecky void; 2, friction resistant not will often be walked owing to wear footwear, and bump is often arranged, and particularly just peels through the friction back; 3, be that temperature tolerance is very poor; 4, viscose glue is poor, peels off easily.Be existence, thereby restricted the impact that be extensive use of and suffer importing technology of printing rubber on article of footwear, limited the development of shoe industry on printing technique simultaneously owing to above-mentioned many defectives.
Summary of the invention
The objective of the invention is to overcome above weak point provides a kind of printing rubber foxing, this printing rubber foxing stamp exquisite pattern not fugitive color, friction resistant, high temperature resistant, peel strength is high and it is strong to hold viscosity.
The present invention also aims to provide the manufacture method of above-mentioned printing rubber foxing, so that this printing rubber foxing satisfies above-mentioned requirements.
The objective of the invention is to reach like this, a kind of printing rubber foxing, it comprises rubber foxing (1), be used to handle the inorganic agent (6) of rubber foxing (1) usefulness, specially print paper (2), be printed on the pattern (3) of special seal paper (2) one side surfaces, be used to handle 3150 inorganic agents (4) of special seal paper (2) and be coated on special seal paper (2) opposite side surface and the viscose glue (5) of rubber foxing (1) one side surface.
Rubber foxing of the present invention (1) is to be made by the raw material of following weight ratio: 19 parts in butadiene-styrene rubber, 21.9 parts of natural rubbers, 3.75 parts in zinc oxide, 0.4 part of stearic acid, 0.86 part in age resistor, 0.86 part in sulphur, 0.58 part in daylight age resistor, 0.10 part of promoter (M), 0.55 part of promoter (DM), 0.04 part of promoter (TS), 8.68 parts of white carbons, 14.9 parts of bonding reinforcing agents, 10.9 parts in calcium carbonate, 16.57 parts of titanium dioxides, 0.82 part of dispersant, 0.01 part in ultramarine, 0.02 part of pigment.
Inorganic agent of the present invention (4) is to be made by the raw material of following weight ratio: 2.5 parts of natural rubbers, 15 parts of blowing agents, 57.5 parts in acetone, 15 parts of toluene, 5.0 parts of curing agents, 2.5 parts of hexamethylene copper.
Viscose glue of the present invention (5) is to be made by the raw material of following weight ratio: 12.87 parts of natural rubbers, 0.62 part in zinc oxide, 0.13 part of stearic acid, 0.25 part of bloom inhibitor, 1.0 parts of softening agents, vulcanization accelerator 0.02-0.30 part, 3.82 parts of white carbons, 0.32 part of bonding reinforcing agent, 0.38 part of dispersant, 80.1 parts of hexamethylene copper.
The manufacture method of printing rubber foxing of the present invention, it comprises the steps:
(a). choose high temperature resistant, free of pinholes, level and smooth rubber foxing (1);
(b). after with toluene above-mentioned rubber foxing (1) brushing being handled earlier, handle with the brushing of MEK inorganic agent again, place air dry;
(c). with weight portion is after special seal paper (2) brushing that 2.5 parts of natural rubbers, 15 parts of blowing agents, 57.5 parts in acetone, 15 parts of toluene, 5.0 parts of curing agents, 2.5 parts of inorganic agents that are mixed with of hexamethylene copper (4) will be printed on pattern (3) is handled well, to place air dry;
(d). with weight ratio part is that 12.87 parts of natural rubbers, 0.62 part in zinc oxide, 0.13 part of stearic acid, 0.25 part of bloom inhibitor, 1.0 parts of softening agents, vulcanization accelerator 0.02-0.30 part, 3.82 parts of white carbons, 0.32 part of bonding reinforcing agent, 0.38 part of dispersant, 80.1 parts of viscose glues that are mixed with of hexamethylene copper (5) are coated on special seal paper (2) surface that is printed on pattern (3) after above-mentioned the handling well, mechanical drying, bake out temperature are controlled at 20 degree-30 degree;
(e). with weight ratio part is that 12.87 parts of natural rubbers, 0.62 part in zinc oxide, 0.13 part of stearic acid, 0.25 part of bloom inhibitor, 1.0 parts of softening agents, vulcanization accelerator 0.02-0.30 part, 3.82 parts of white carbons, 0.32 part of bonding reinforcing agent, 0.38 part of dispersant, 80.1 parts of viscose glues that are mixed with of hexamethylene copper (5) are coated on rubber foxing (1) surface after above-mentioned the handling well, mechanical drying, bake out temperature are controlled at 20 degree-30 degree;
(f). prevent that temperature is controlled at 140 degree-150 degree into the vulcanizing tank moulding of heating with above-mentioned rubber foxing (1) that is coated with viscose glue (5) and the special seal paper (2) that is coated with viscose glue (5) are bonding mutually.
Printing rubber foxing provided by the present invention and manufacture method thereof have pattern not fugitive color, friction resistant, high temperature resistant, peel strength is high and it is strong to hold viscosity.
Description of drawings
Fig. 1 is the schematic diagram of printing rubber foxing of the present invention.
Specific embodiment
As shown in the figure, rubber foxing of the present invention (1) is to be 19 parts in butadiene-styrene rubber by weight ratio, 21.9 parts of natural rubbers, 3.75 parts in zinc oxide, 0.4 part of stearic acid, 0.86 part in age resistor, 0.86 part in sulphur, 0.58 part in daylight age resistor, 0.10 part of promoter (M), 0.55 part of promoter (DM), 0.04 part of promoter (TS), 8.68 parts of white carbons, 14.9 parts of bonding reinforcing agents, 10.9 parts in calcium carbonate, 16.57 parts of titanium dioxides, 0.82 part of dispersant, 0.01 part in ultramarine, 0.02 part of pigment, obtain by commercially available, it is mixed with the mixer stirring make rubber foxing (1) with excellent high-temperature stability and good smoothness and free of pinholes.The pattern of on rubber foxing (1), printing (3) can be the cartoon pattern, also can be the takes landscape pattern, can also be animal, literal, letter or their combination etc.Inorganic agent of the present invention (4) is by 2.5 parts of weight ratio natural rubbers, 15 parts of blowing agents, 57.5 parts in acetone, 15 parts of toluene, 5.0 parts of curing agents, 2.5 parts of hexamethylene copper, it is mixed to stir mutually make.Viscose glue of the present invention (5) is by 12.87 parts of weight ratio natural rubbers, 0.62 part in zinc oxide, 0.13 part of stearic acid, 0.25 part of bloom inhibitor, 1.0 parts of softening agents, vulcanization accelerator 0.02-0.30 part, 3.82 parts of white carbons, 0.32 part of bonding reinforcing agent, 0.38 part of dispersant, 80.1 parts of hexamethylene copper, it is mixed to stir mutually make.
The manufacture method of printing rubber foxing of the present invention can be given explanation by following examples.
Embodiment 1:
(a). choose high temperature resistant, free of pinholes, level and smooth rubber foxing (1);
(b). after with toluene above-mentioned rubber foxing (1) brushing being handled earlier, handle with the brushing of MEK inorganic agent again, place air dry;
(c). with weight portion is after special seal paper (2) brushing that 2.5 parts of natural rubbers, 15 parts of blowing agents, 57.5 parts in acetone, 15 parts of toluene, 5.0 parts of curing agents, 2.5 parts of inorganic agents that are mixed with of hexamethylene copper (4) will be printed on pattern (3) is handled well, to place air dry;
(d). with weight ratio part is that 12.87 parts of natural rubbers, 0.62 part in zinc oxide, 0.13 part of stearic acid, 0.25 part of bloom inhibitor, 1.0 parts of softening agents, vulcanization accelerator 0.02-0.30 part, 3.82 parts of white carbons, 0.32 part of bonding reinforcing agent, 0.38 part of dispersant, 80.1 parts of viscose glues that are mixed with of hexamethylene copper (5) are coated on special seal paper (2) surface that is printed on pattern (3) after above-mentioned the handling well, mechanical drying, bake out temperature are controlled at 20 degree;
(e). with weight ratio part is that 12.87 parts of natural rubbers, 0.62 part in zinc oxide, 0.13 part of stearic acid, 0.25 part of bloom inhibitor, 1.0 parts of softening agents, vulcanization accelerator 0.02-0.30 part, 3.82 parts of white carbons, 0.32 part of bonding reinforcing agent, 0.38 part of dispersant, 80.1 parts of viscose glues that are mixed with of hexamethylene copper (5) are coated on rubber foxing (1) surface after above-mentioned the handling well, mechanical drying, bake out temperature are controlled at 20 degree;
(f). prevent that temperature is controlled at 140 degree into the vulcanizing tank moulding of heating with above-mentioned rubber foxing (1) that is coated with viscose glue (5) and the special seal paper (2) that is coated with viscose glue (5) are bonding mutually.
Embodiment 2:
Step (d) pigment is got blueness, and 0.19 part of bake out temperature of vulcanization accelerator is controlled at 25 degree; 0.19 part of step (e) vulcanization accelerator, bake out temperature are controlled at 25 degree; Step (f) temperature is controlled at 145 degree; All the other are with embodiment 1, and the pattern of gained (3) is blue, and its properties of product are by shown in the following table.
Embodiment 3:
With step (d) pigment extracting yellow, 0.30 part of vulcanization accelerator, bake out temperature are controlled at 30 degree; 0.30 part of step (e) vulcanization accelerator, bake out temperature are controlled at 30 degree; Step (f) temperature is controlled at 150 degree; All the other are with embodiment 1, and the pattern of gained (3) is yellow, and its properties of product are by shown in the following table.
In addition, the present invention does not mean that by schematic diagram and specification and limits to, can change to some extent under the prerequisite that does not break away from design aim.
The performance of printing rubber foxing of the present invention
| Item compared | | Embodiment | 1 | |
|
|
| Friction resistant | Laterally | N/CM | 100/2.5 | 200/3.5 | 300/4.5 | |
| High temperature resistant | Degree/hour | 100/ hour | 80/ hour | 60/ hour | ||
| Peel strength | Laterally | N/CM | 9.2/2.5 | 11.3/3.5 | 15.8/4 | |
| Hold viscosity | Hour/mm | 38 | 34 | 31 | ||
| The pattern | Level | 5 | 5 | 5 |
Claims (5)
1, a kind of printing rubber foxing, it is characterized in that it comprises rubber foxing (1), be used to handle the inorganic agent (6) of rubber foxing (1) usefulness, specially print paper (2), be printed on the pattern (3) of special seal paper (2) one side surfaces, be used to handle 3150 inorganic agents (4) of special seal paper (2) and be coated on special seal paper (2) opposite side surface and the viscose glue (5) of rubber foxing (1) one side surface.
2, printing rubber foxing according to claim 1 and manufacture craft thereof is characterized in that described rubber foxing (1) is to be made by the raw material of following weight ratio: 19 parts in butadiene-styrene rubber, 21.9 parts of natural rubbers, 3.75 parts in zinc oxide, 0.4 part of stearic acid, 0.86 part in age resistor, 0.86 part in sulphur, 0.58 part in daylight age resistor, 0.10 part of promoter (M), 0.55 part of promoter (DM), 0.04 part of promoter (TS), 8.68 parts of white carbons, 14.9 parts of bonding reinforcing agents, 10.9 parts in calcium carbonate, 16.57 parts of titanium dioxides, 0.82 part of dispersant, 0.01 part in ultramarine, 0.02 part of pigment.
3, printing rubber foxing according to claim 1 is characterized in that described inorganic agent (4) is to be made by the raw material of following weight ratio: 2.5 parts of natural rubbers, 15 parts of blowing agents, 57.5 parts in acetone, 15 parts of toluene, 5.0 parts of curing agents, 2.5 parts of hexamethylene copper.
4, printing rubber foxing according to claim 1 is characterized in that described viscose glue (5) is to be made by the raw material of following weight ratio: 12.87 parts of natural rubbers, 0.62 part in zinc oxide, 0.13 part of stearic acid, 0.25 part of bloom inhibitor, 1.0 parts of softening agents, vulcanization accelerator 0.02-0.30 part, 3.82 parts of white carbons, 0.32 part of bonding reinforcing agent, 0.38 part of dispersant, 80.1 parts of hexamethylene copper.
5, the manufacture method of printing rubber foxing according to claim 1 is characterized in that it comprises the steps:
(a). choose high temperature resistant, free of pinholes, level and smooth rubber foxing (1);
(b). after with toluene above-mentioned rubber foxing (1) brushing being handled earlier, handle with the brushing of MEK inorganic agent again, place air dry;
(c). with weight portion is after special seal paper (2) brushing that 2.5 parts of natural rubbers, 15 parts of blowing agents, 57.5 parts in acetone, 15 parts of toluene, 5.0 parts of curing agents, 2.5 parts of inorganic agents that are mixed with of hexamethylene copper (4) will be printed on pattern (3) is handled well, to place air dry;
(d). with weight ratio part is that 12.87 parts of natural rubbers, 0.62 part in zinc oxide, 0.13 part of stearic acid, 0.25 part of bloom inhibitor, 1.0 parts of softening agents, vulcanization accelerator 0.02-0.30 part, 3.82 parts of white carbons, 0.32 part of bonding reinforcing agent, 0.38 part of dispersant, 80.1 parts of viscose glues that are mixed with of hexamethylene copper (5) are coated on special seal paper (2) surface that is printed on pattern (3) after above-mentioned the handling well, mechanical drying, bake out temperature are controlled at 20 degree-30 degree;
(e). with weight ratio part is that 12.87 parts of natural rubbers, 0.62 part in zinc oxide, 0.13 part of stearic acid, 0.25 part of bloom inhibitor, 1.0 parts of softening agents, vulcanization accelerator 0.02-0.30 part, 3.82 parts of white carbons, 0.32 part of bonding reinforcing agent, 0.38 part of dispersant, 80.1 parts of viscose glues that are mixed with of hexamethylene copper (5) are coated on rubber foxing (1) surface after above-mentioned the handling well, mechanical drying, bake out temperature are controlled at 20 degree-30 degree;
(f). prevent that temperature is controlled at 140 degree-150 degree into the vulcanizing tank moulding of heating with above-mentioned rubber foxing (1) that is coated with viscose glue (5) and the special seal paper (2) that is coated with viscose glue (5) are bonding mutually.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008100157394A CN101564218A (en) | 2008-04-26 | 2008-04-26 | Printing rubber foxing and manufacture method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008100157394A CN101564218A (en) | 2008-04-26 | 2008-04-26 | Printing rubber foxing and manufacture method thereof |
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| Publication Number | Publication Date |
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| CN101564218A true CN101564218A (en) | 2009-10-28 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNA2008100157394A Pending CN101564218A (en) | 2008-04-26 | 2008-04-26 | Printing rubber foxing and manufacture method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103637462A (en) * | 2013-11-20 | 2014-03-19 | 中国人民解放军总后勤部军需装备研究所 | Protection rubber shoes used for industrial and mining enterprises |
| CN104277266A (en) * | 2014-10-30 | 2015-01-14 | 际华三五三七制鞋有限责任公司 | Master batching process of calendaring grass green rubber foxing glue for liberation shoes |
| CN104311901A (en) * | 2014-10-30 | 2015-01-28 | 际华三五三七制鞋有限责任公司 | Plastifying process for calendering type grass green rubber foxing rubber for liberation shoes |
| CN107011557A (en) * | 2017-05-05 | 2017-08-04 | 常州卓源橡胶制品有限公司 | A kind of preparation method of rubber pange calico paper |
| CN114786517A (en) * | 2019-12-16 | 2022-07-22 | 全星有限合伙公司 | Component with embedded particles and method of making the same |
-
2008
- 2008-04-26 CN CNA2008100157394A patent/CN101564218A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103637462A (en) * | 2013-11-20 | 2014-03-19 | 中国人民解放军总后勤部军需装备研究所 | Protection rubber shoes used for industrial and mining enterprises |
| CN103637462B (en) * | 2013-11-20 | 2016-04-06 | 中国人民解放军总后勤部军需装备研究所 | A kind of industrial and mining enterprises protection rubber overshoes |
| CN104277266A (en) * | 2014-10-30 | 2015-01-14 | 际华三五三七制鞋有限责任公司 | Master batching process of calendaring grass green rubber foxing glue for liberation shoes |
| CN104311901A (en) * | 2014-10-30 | 2015-01-28 | 际华三五三七制鞋有限责任公司 | Plastifying process for calendering type grass green rubber foxing rubber for liberation shoes |
| CN104277266B (en) * | 2014-10-30 | 2016-05-25 | 际华三五三七制鞋有限责任公司 | Female sweetening process of calendering type grass green rubber hold-down calendering glue for liberation footwear |
| CN107011557A (en) * | 2017-05-05 | 2017-08-04 | 常州卓源橡胶制品有限公司 | A kind of preparation method of rubber pange calico paper |
| CN114786517A (en) * | 2019-12-16 | 2022-07-22 | 全星有限合伙公司 | Component with embedded particles and method of making the same |
| US12004602B2 (en) | 2019-12-16 | 2024-06-11 | Converse Inc. | Components with embedded particles and methods of making same |
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Open date: 20091028 |