CN101560374B - Environment-friendly snowmelt agent - Google Patents

Environment-friendly snowmelt agent Download PDF

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Publication number
CN101560374B
CN101560374B CN2008100111070A CN200810011107A CN101560374B CN 101560374 B CN101560374 B CN 101560374B CN 2008100111070 A CN2008100111070 A CN 2008100111070A CN 200810011107 A CN200810011107 A CN 200810011107A CN 101560374 B CN101560374 B CN 101560374B
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agent
snow
growth
environment
calcium
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CN101560374A (en
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刘勇
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DANDONG ZHONGHE CHEMICAL PLANT
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DANDONG ZHONGHE CHEMICAL PLANT
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Abstract

The invention relates to an environment-friendly snowmelt agent which comprises the raw materials by weight percentage: 60 to 80 of tetrahydrate calcium nitrate, 8 to 15 of monohydrate calcium acetate, 4 to 7 of tetrahydrate magnesium acetate, 1 to 4 of potassium nitrate, 4 to 8 of potassium acetate, 2.5 to 5 of diammonium hydrogen phosphate and 0.5 to 1 of anticaking agent. The invention is harmless to the growth of plants, such as flowers, grasses, trees and crops, does not pollute fishes, does not damage the growth of the fishes, does not erode steel and fully achieves the snowmelt and environmental-protection requirements.

Description

Environment-friendly snowmelt agent
Technical field
What the present invention relates to is Snow Agent.Environment-friendly snowmelt agent particularly.
Background technology
The prior art Snow Agent mainly is that employing sodium-chlor is main raw material.Though reached the purpose of snow removing, corrodibility is big, not only can cause the heavy corrosion to highway, bridge, motor vehicle and traffic route facility; Reduce work-ing life; And cause damage for the flowers, plants and trees of highway both sides, and cause salinization to soil, cause environmental pollution.
For reaching the environmental protection purpose some improvement technology is arranged also, as the disclosed Snow Agent of CN200610046356 patented claim be with at least two kinds in nitrocalcite, calcium chloride, magnesium chloride, sodium-chlor, five kinds of raw materials of Losantin with Starso, Sodium orthomolybdate, tsp, Sodium Benzoate, borax, Sodium Nitrite, Efficacious Disinfeitant, benzotriazole at least the 1-2 kind constitute.The disclosed Snow Agent of CN200310107207 patented claim consists of: magnesium nitrate 20-30%, nitrocalcite 20-30%, saltpetre 10-20%, salt of wormwood 5-10%, solidifying agent 0.5-1.0%, CH (NH) 230-50%.
Summary of the invention
The purpose of this invention is to provide a kind of non-corrosiveness, harmless to soil, can promote the environment-friendly snowmelt agent of plant-growth.
Raw material of the present invention consists of weight ratio: 4 water nitrocalcite 60-80, a water acetic acid calcium 8-15,4 water acetic acid magnesium 4-7, saltpetre 1-4, Potassium ethanoate 4-8, Secondary ammonium phosphate 2.5-5, anti-caking agent (lime carbonate) 0.5-1.
The effect of each raw material
1,4 water nitrocalcite: be the main salt of Snow Agent, fusing point is low, and moisture absorption is extremely strong, and snow melt speed is fast.4 water nitrocalcite contain nitrogen and two kinds of nutritive elements of calcium; On agricultural, be used as the readily avaiable fertilizer of acid soil; The characteristics of replenishing the calcium, mending nitrogen are arranged fast, and the unique combination of its nitric nitrogen and hundred-percent water-soluble calcium provides unexistent character of many other chemical fertilizer and advantage; Nitrocalcite is one of chemical fertilizer of current market most worthy, so Snow Agent master salt adopts nitrocalcite can not work the mischief to farm crop.
2, a water acetic acid calcium: be auxiliary salt, suction lake property level is strong, can absorb a large amount of moisture content, quickens the snow melt of nitrocalcite.One water acetic acid calcium can resolve into ionized calcium and acetate ion, and sterilization, antiinflammation are arranged, and acetate is nontoxic.Calcium acetate always as sequestrant, presses down toxic agent in foodstuffs industry, stablizer, and buffer reagent and sweetener use, and have no side effect.
3,4 water acetic acid magnesium: fusing point is low, can promote to avenge quick liquefy.Can be used for drink additive.Human body and environment are had no side effect.
4, saltpetre: in Snow Agent, regulate the snow melt speed of other salt, keep the stabilization of Snow Agent.Saltpetre is 100% plant nutrient fertilizer.
5, Potassium ethanoate: moisture absorption is extremely strong, melts with snow the efficient height, and dissolved degree of separating is 1.3 times of water.
6, Secondary ammonium phosphate: soluble in water, the aqueous solution is alkalescence, and the pH value of adjustable Snow Agent keeps Snow Agent to dissolve back PH6.5-7.5.The Secondary ammonium phosphate chemical is more stable, contains needed phosphorus of plant-growth and nitrogen element, is the quick-acting nitrogen of a kind of high density, phosphorus composite fertilizer.Be suitable for various types of edaphic conditions, also be used for medicine, sugaring, fodder additives in the rice field of breeding fish, apply Secondary ammonium phosphate, and be not only harmless to fish, and help the growth of fish.
Employed proportioning raw material does not contain poisonous, objectionable impurities in the Snow Agent of the present invention in sum, to the human non-toxic evil, to soil and yet toxicological harmless effect of plant; And be a kind of available fertilizer, be the indispensable chemical fertilizer of plant-growth, crop growth there is promoter action; To animal toxicological harmless effect, snow melt flows into rivers, farmland, and fish growth is not had overslaugh and murder by poisoning; Road, bridge, steel are not had corrosion, fully reach snow melt and environmental-protection function.
Embodiment
Embodiment:
See example table proportioning raw materials, weight ratio
Title Prescription 1 Prescription 2 Prescription 3 Prescription 4 Prescription 5 Prescription 6
4 water nitrocalcite 65 64 70 75 80 60
One water acetic acid calcium 14 13 12 10 8 15
4 water acetic acid magnesium 6 7 6 7 4 7
Potassium ethanoate 8 7 5 8 4 8
Saltpetre 3 4 2 3 1 4
Secondary ammonium phosphate 3 4.5 4 4 2.5 5
Anti-hard caking agent 1 0.5 1 1 0.5 1
Add up to 100 100 100 100 100 100
Prescription 1,2,6 effects are the same basically.Prescription 3,4,5 effects are the same basically.
Overall formulation analysis, difference is not obvious, has all reached the basic effect of deciding.
This product be with Natural manganese dioxide, quicklime, salt of wormwood, liquefied ammonia be raw material and nitric acid acetic acid and phosphatase reaction generate nitrocalcite, saltpetre, calcium acetate, magnesium acetate, Potassium ethanoate, Secondary ammonium phosphate.
Nitric acid calcium salt, potassium salt, magnesium acetate, calcium acetate, Potassium ethanoate, Secondary ammonium phosphate are conventional working method in process of production, and these salts deliquescence in air is all more intense.Because the moisture absorption of these salts is extremely strong, so the Snow Agent that is made into these salts, its effect meets or exceeds the snow melt effect of sodium-chlor type Snow Agent.
Table 1: corrodibility simultaneous test, temperature 15--18 ℃
Figure GSB00000735884800041
Table 2: the test contrast of effect garlic bolt, shallot, temperature 15-18 ℃
Figure GSB00000735884800042
Table 3: the test contrast of effect rhododendron:
Figure GSB00000735884800051
flowerpot, temperature 15-18 ℃
Figure GSB00000735884800052
Table 4: to the simultaneous test of fish infringements: temperature 15-18 ℃
Figure GSB00000735884800053
Figure GSB00000735884800061
Table 5: snowfield pavement snow melting test contrast
Figure GSB00000735884800062
To sum up experiment contrast can find out that through table 1 test the sodium-chlor Snow Agent is serious to steel corrosion, and this Snow Agent does not have corrosive nature basically to iron and steel, can not cause corrosion to cement pavement.
Can find out that from table 2 test contrast the sodium-chlor Snow Agent has harm to vegetables, flowers and fruits, and this Snow Agent is safe from harm not only, can also promote plant-growth.
Can find out that from table 3 test contrast sodium-chlor has harm to tree crop, and this Snow Agent can also promote the growth of flowers and plants.
Can find out that from table 4 this Snow Agent does not have harm to fish.
Can find out that from watch 5 this Snow Agent snow melt speed is fast.
So this Snow Agent is harmless to plant, flowers, plants and trees, crop growth, to fish pollution-free with the infringement growth, iron and steel is not had corrosion, fully reach snow melt and environmental requirement.

Claims (1)

1. environment-friendly snowmelt agent is characterized in that raw material consists of weight ratio: 4 water nitrocalcite 60-80, a water acetic acid calcium 8-15,4 water acetic acid magnesium 4-7, saltpetre 1-4, Potassium ethanoate 4-8, Secondary ammonium phosphate 2.5-5, anti-caking agent 0.5-1;
The anti-caking agent is a lime carbonate.
CN2008100111070A 2008-04-16 2008-04-16 Environment-friendly snowmelt agent Expired - Fee Related CN101560374B (en)

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CN101560374B true CN101560374B (en) 2012-05-23

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Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101717616B (en) * 2009-11-17 2011-09-21 许庆华 Production process of rapid attapulgite ice and snow melting agent
CN101781547B (en) * 2009-12-08 2011-09-21 许庆华 Production method of attapulgite environmental-friendly snow melt agent
CN102533222B (en) * 2011-07-06 2013-10-23 大连工业大学 Antifreezing snow melting agent and preparation method thereof
CN102277134B (en) * 2011-09-09 2012-11-21 罗田县富阳化肥有限公司 Snow-melting agent
CN102399534A (en) * 2011-12-01 2012-04-04 北京化工大学 Organic/inorganic composite environment-friendly snow melting agent and preparation method thereof
CN102775959A (en) * 2012-07-16 2012-11-14 深圳市科中大交通建材有限公司 Novel environment-friendly snow-melting agent and preparation method thereof
CN115975737A (en) * 2022-12-13 2023-04-18 新疆金雪驰科技股份有限公司 Multifunctional environment-friendly aromatic glass water composition and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1648192A (en) * 2003-12-05 2005-08-03 张洋 Corrosion free compound snow thawing agent
CN1834189A (en) * 2006-04-24 2006-09-20 杨毅男 Ice, snow fast thawing agent

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1648192A (en) * 2003-12-05 2005-08-03 张洋 Corrosion free compound snow thawing agent
CN1834189A (en) * 2006-04-24 2006-09-20 杨毅男 Ice, snow fast thawing agent

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
JP特开2005-29682A 2005.02.03

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