CN101553621A - 用于涂饰纺织品和纸张的乳液 - Google Patents

用于涂饰纺织品和纸张的乳液 Download PDF

Info

Publication number
CN101553621A
CN101553621A CNA2007800454765A CN200780045476A CN101553621A CN 101553621 A CN101553621 A CN 101553621A CN A2007800454765 A CNA2007800454765 A CN A2007800454765A CN 200780045476 A CN200780045476 A CN 200780045476A CN 101553621 A CN101553621 A CN 101553621A
Authority
CN
China
Prior art keywords
emulsion
weight
paper
oil
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA2007800454765A
Other languages
English (en)
Other versions
CN101553621B (zh
Inventor
乔尔格·索恩斯
罗尔夫·卡瓦
斯蒂芬·艾科霍恩
安德烈亚·厄本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cognis IP Management GmbH
Original Assignee
Cognis IP Management GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cognis IP Management GmbH filed Critical Cognis IP Management GmbH
Publication of CN101553621A publication Critical patent/CN101553621A/zh
Application granted granted Critical
Publication of CN101553621B publication Critical patent/CN101553621B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/22—Agents rendering paper porous, absorbent or bulky
    • D21H21/24—Surfactants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0208—Tissues; Wipes; Patches
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D06M13/17—Polyoxyalkyleneglycol ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/002—Tissue paper; Absorbent paper
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Emergency Medicine (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Biomedical Technology (AREA)
  • Paper (AREA)
  • Cosmetics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明的主题是油包水乳液，以总组成计，其中含有(a)12～21重量％的聚甘油2－二聚羟基硬脂酸酯、(b)4～7重量％的氢化的乙氧基化蓖麻油、(c)25～35重量％的矿物油、(d)20－30重量％的其他油质物、(e)3～5重量％的水溶助长剂、(f)3～4重量％的金属皂和(g)10～30重量％的水。

Description

用于涂饰纺织品和纸张的乳液
技术领域
本发明的主题是可用于浸渍和润湿日用品(commodity)和卫生纸/巾的特定乳液(Emulsionen)。
技术背景
总概念“纸张”是指特性和使用领域在一些情况下差异很大的约3000种不同的类型和用品。生产纸张需要许多添加剂，其中最重要的是填料(如白垩或高岭土)和粘合剂(如淀粉)。对于与人的皮肤紧密接触的薄棉纸和卫生纸的领域，对舒适的轻柔度(Weichgriff)有特别的需求。对纸张而言，轻柔度通常是通过仔细选择纤维材料、特别是是使用高含量的新鲜木浆或纤维素而获得的。然而，考虑到纸张生产的经济性以及从环保角度考虑，期望使用尽可能高含量的劣质废旧纸张。但是，这会造成严重损害纸张轻柔度的后果，会让使用者感觉有问题，特别是在频繁使用时会引起皮肤刺激。
在过去，并不缺乏关于通过浸湿或其他表面处理方法修饰(modify)薄棉纸以获得舒适的轻柔度的研究。对此必须研制出这样的特殊乳状液(Lotionen)和乳液，其一方面可以容易的涂覆于纸张上，另一方面对纸张结构不产生负面影响。为了改善轻柔度，经常使用非离子型表面活性剂或者非离子型表面活性剂和阴离子型表面活性剂的组合物。为了该目的也使用聚硅氧烷和阳离子型聚合物。
国际专利申请WO 95/35411的主题是涂覆了修饰剂(Avivagemitteln)的薄棉纸，所述修饰剂含有20～80重量％的无水软化剂(矿物油、脂肪酸酯、脂肪醇乙氧基化物、脂肪酸乙氧基化物、脂肪醇及其混合)、5～95重量％的润滑剂“固定试剂”(脂肪部分各为12～22个碳原子的脂肪醇、脂肪酸或脂肪醇乙氧基化物)以及1～50重量％的HLB值优选为4～20的表面活性剂。文中所记载的实施例无一例外的都含有矿脂作为润滑剂。国际专利申请WO95/35412公开了类似的薄棉纸，其中软化剂使用了(a)矿物油、(b)脂肪醇或脂肪酸和(c)脂肪醇乙氧基化物的无水混合物。国际专利申请WO 95/16824的主题是用于薄棉纸的修饰剂，其含有矿物油、脂肪醇乙氧基化物和非离子性表面活性剂(失水山梨糖醇酯、葡萄糖胺)。此外，在国际专利申请WO97/30216(Kaysersberg)中记载了基于长链饱和脂肪醇和总计至少24个碳原子的蜡酯的用于手巾纸的液态修饰剂，其含有非常高的水份额。从用途角度来说，纸张的轻柔度、操作行为和感官特性一直都值得改进。DE 10102500A1的主题是含有(a)聚醇聚-12-羟基硬脂酸酯，(b)选自甘油酯、烃类、硅油、二烷基醚和碳酸二烷基酯或其任意混合物的油质物和(c)5～25重量％的水的乳液，并且如在EP 1 225 276 A1中所记载的，其也适于涂覆纸张。在稳定性方面，乳液和乳状液还值得改善。特别地，通常没有植物提取物在加工时不发生颜色改变，这对待涂覆纸张的白度有不利影响。
本发明的目的是提供稳定性得到改进的乳液，在其帮助下，能在不显著降低纸张白度(whiteness)时，涂覆日用纸张(特别是薄棉纸)以及强化织物(Tissue-Gewebe)。所述乳液具有优异的护理性能，在感官特性方面与传统的皮肤护理制剂类似。本发明目的的另一个方面在于，提供一种与高废旧纸张含量的薄棉纸也相容的制剂。同时，应当只使用生物可易降解的助剂，且该制剂应当容易渗入薄纸，分布均匀，具有较低水含量，且以高浓度分布，尽管如此仍具有容易加工的低粘度。
发明内容
现在出人意料的发现，基于某种乳化剂、高含量的矿物油和确定含量的水的制剂不仅确保了纸张制品的轻柔度，也比现有技术中已知的涂料乳液/涂料乳液更稳定。显然在加入自身带有颜色的植物提取物时，用本发明乳液涂覆纸张时的纸张白度不会明显减少。
由此，本发明的主题是油包水乳液，以总组成计，其含有
(a)12～21重量％的聚甘油2-二聚羟基硬脂酸酯；
(b)4～7重量％的氢化的乙氧基化蓖麻油
Figure A20078004547600041
(c)25～35重量％的矿物油(mineral oil)；
(d)20-30重量％的其他油质物(oily substances)；
(e)3～5重量％的水溶助长剂(hydrotropes)；
(f)3～4重量％的金属皂(metal soaps)；
(g)10～30重量％的水。
本发明的乳液是液态的、在20℃下能泵送的，并且因此非常容易处理。由于油的含量高，所以该乳液具有很好的护理特性，且明显比现有技术中用于涂覆的相当乳液更稳定。这些乳液因为对待涂覆的纸张材料的白度影响小而出色，并对皮肤具有很好的感官光滑性。乳液的成分必须精确地彼此配合地调节；优选，除了原料带来的副产物之外，本发明乳液不含其他组分，所述乳液基本含有给定量的成分(a)～(g)。已经发现只有给定比例的混合物能满足稳定性需求，能够吸收(take up)自身带有颜色的活性物质(如草本洋甘菊(Herbalia Chamomila))，而不明显改变所涂覆纸张的白度。成分(a)例如可以使用Cognis Deutschland GmbH & Co.KG的
Figure A20078004547600051
PGPH。本发明特别优选的是这样的乳液，其特征为，在涂覆纸张和非制造布(Vliesen)时，纸张/非制造布的白度减少最多为(不超过)4％，特别是最多为3.5％。这里，根据DIN EN 12625-7，项7.3.2，颜色(D 65/10°)的方法测量白度，其中未经涂覆/未经浸渍的纸张的白度对应于100％。
在一个优选的实施方式中，乳液在23℃具有500～5000mPa·s的粘度，其中优选500～3000mPa·s的粘度，特别优选1000～2000的粘度(Brookfield-RVF，轴5，10rpm，23℃)。
基于总组成，乳液含有最多30重量％的水份额。本发明优选最多25重量％，特别优选最多20重量％的水份额。基于总组成，乳化剂(a)和(b)的总量在16～28重量％之间，并且优选为15～25重量％。本发明优选的是，成分的重量比(a∶b)在(2.5～3.5)∶1的范围变化。成分(b)优选为每摩尔氢化蓖麻油
Figure A20078004547600052
7摩尔环氧乙烷的环氧乙烷加合物。这种产品例如是CognisDeutschland GmbH & Co.KG销售的
Figure A20078004547600053
HRE 7。
油质物：成分(c)和(d)
油质物(c)和(d)的总量在45～65重量％之间变化。在一个优选的实施方式中，油相中矿物油的份额，基于成分(c)和(d)的总量，为至少45重量％，优选至少50重量％，特别优选至少55重量％。该油相的粘度应当尽可能低，即优选粘度为2～230mPa·s的油质物，特别是作为油质物(d)。下列矿物油适合作为成分(c)：白油Pharma 40、低粘度的石蜡油、高粘度的石蜡油、液态石蜡、轻质液态石蜡(Paraffinum perliquidum)、亚液态石蜡。
适合作为另外的油质物(成分d)的是例如下述种类的化合物：基于6至18个碳原子、优选8至10个碳原子的脂肪醇类的古尔伯特(Guerbet)醇，例如2-乙基己醇或2-辛基十二烷醇；直链或支链的、饱和或不饱和的C6-C24脂肪酸与直链或支链的、饱和或不饱和的C6-C24脂肪醇的酯。例如月桂酸己酯、异硬脂酸肉豆寇酯、油酸肉豆寇酯、异硬脂酸鲸蜡酯、油酸鲸蜡酯、异硬脂酸硬脂酯、油酸硬脂酯、肉豆寇酸异硬脂酯、棕榈酸异硬脂酯、硬脂酸异硬脂酯、异硬脂酸异硬脂酯、油酸异硬脂酯、肉豆蔻酸油酯、异硬脂酸油酯、油酸油酯、芥酸油酯、异硬脂酸芥酯、油酸芥酯、椰油醇辛酸/硅酸酯。其他合适的酯是，例如C18-C38烷基羟基羧酸与直链或支链的、饱和或不饱和的C6-C22脂肪醇的酯，直链和/或支链的、饱和或不饱和的脂肪酸与多元醇(如丙二醇、二聚二醇或者三聚三醇)和/或古尔伯特醇的酯，甘油三酸酯或甘油三酸酯混合物，液态的甘油单酸酯/甘油二酸酯/甘油三酸酯混合物，C6-C22脂肪醇和/或古尔伯特醇与芳族羧酸、特别是安息香酸的酯(如
Figure A20078004547600061
TN)，C2-C12二元羧酸与具有1至22个碳原子的直链或支链的、饱和或不饱和的醇或与具有2至10个碳原子和2至6个羟基的多元醇的酯。合适的还有植物油，甘油三酸酯混合物，被取代的环己烷，直链的对称或不对称的碳酸二烷基酯(如CC)，基于具有6至18个碳原子、优选8至10个碳原子的脂肪醇的古尔伯特碳酸酯，每个烷基具有6至22个碳原子的直链或支链的对称或不对称的二烷基醚，如二正辛基醚(OE)，环氧基化脂肪酸酯与多元醇的开环产物，烃类如石蜡油或矿物油，寡聚-α-烯烃或聚-α-烯烃。所述碳酸二烷基酯和二烷基醚可以是对称的或不对称的、支链的或非支链的、饱和的或不饱和的，并且可根据现有技术中熟知的相关方法制备。合适的有机硅化合物例如为二甲基聚硅氧烷、甲基苯基聚硅氧烷、环状聚硅氧烷(cyclische Silicone)(环(二)甲基硅酮)，以及氨基改性的、脂肪酸改性的、醇改性的、聚醚改性的、环氧基改性的、氟改性的、苷改性的和/或烷基改性的有机硅化合物。合适的还有二甲基硅油。
优选适作成分(d)的，具体是铺展值(Spreitwerten)至少为250mm2/10min的油(U.Zeidler：das Spreiten von Lipiden auf der Haut，Fette-Seifen-Anstrichmittel Nr.10，403-408，1985)，特别是具有上述铺展值的酯油、二烷基醚、古尔伯特醇或甘油酯。这些包括例如己二酸二丁酯、棕榈酸异丙酯、月桂酸己酯、硬脂酸乙基己酯、二辛醚(Dicaprylylether)、碳酸二辛酯(Dicaprylylcarbonate)、硬脂酸己基癸酯、油酸油酯、芥酸油酯或植物油。
水溶助长剂(e)
本发明乳液含有至少一种水溶助长剂作为成分(e)，该水溶助长剂有助于改善组合物的感官特性和稳定性，并且具有增溶作用，其也起到保持纸张中乳液的湿度含量稳定的作用。
根据本发明合适的是液态的多元醇和多元醇衍生物，例如，甘油、双甘油、三甘油、乙二醇、丙二醇、丁二醇、1，2，6-己三醇，以及液态的聚乙二醇。本发明优选适合作为保湿剂的是甘油、双甘油和三甘油。按总组成计，水溶助长剂的含量为3～5重量％，特别为3.5～4.5重量％。本发明优选的是甘油、丁二醇或丙二醇及其他甘油。
金属皂(f)
本领域技术人员将术语“金属皂”理解为水溶性低的脂肪酸金属盐(参见
Figure A20078004547600071
Chemielexikon)。由于它的油-增稠性能，其对乳液的稳定性起协同作用。通常，合适的是C12-C24脂肪酸或C12-C24羟基脂肪酸的钙盐、镁盐、铝盐和锌盐。本发明优选作为金属皂的是硬脂酸镁和/或硬脂酸铝。后者由于其结构形式而特别适合于增稠和稳定油相。
缓和刺激/抗炎的活性物质
本发明乳液的优选实施方式含有至少一种缓和刺激/抗炎的活性物质，其特别用于缓和炎性的皮肤护理或变红受伤的皮肤。该缓和刺激的活性物质的含量通常为0.01～10重量％，优选0.05～5重量％，特别是0.05～3重量％。
本发明优选是没药醇、尿囊素和泛醇，特别是没药醇。维生素和维生素前体以及蛋白质水解产物也可促进伤口愈合。
合适的还有植物提取物，其通常含有具有协同作用的愈合伤口物质/缓和刺激物质的组合。通常通过提取整个植物制备这些提取物。在个别情况下也可优选的是，仅从植物的花和/或叶制备提取物。
本发明中特别合适的是甘菊、芦荟、北美金缕梅、菩提树花、鼠尾草(Salbei)和蜜蜂花(Melisse)的提取物。
实施例
在稳定性和白度方面评估两个配方，即本发明的配方(1)和对比配方(V1)。根据DIN EN 12625-7，项7.3.2，颜色(D65/10°)的方法测量白度，其中未涂覆的/未浸渍的纸张的白度定为100％。评估白度的减少，以％表示，其中允许的减少不超过4％。由经训练的人员根据1～6分评分制原则评定感官特性。

Claims (9)

1.油包水乳液，以总组成计，含有
(a)12～21重量％的聚甘油2-二聚羟基硬脂酸酯；
(b)4～7重量％的氢化的乙氧基化蓖麻油；
(c)25～35重量％的矿物油；
(d)20-30重量％的其他油质物；
(e)3～5重量％的水溶助长剂；
(f)3～4重量％的金属皂；
(g)10～30重量％的水。
2.根据权利要求1的乳液，其中，含有每摩尔氢化蓖麻油7摩尔环氧乙烷的环氧乙烷加合物作为成分(b)。
3.根据权利要求1～2中至少一项的乳液，其中，乳化剂(a)和(b)的总量占总组成的15～25重量％。
4.根据权利要求1～3中至少一项的乳液，其中，成分的重量比(a∶b)在(2.5～3.5)∶1的范围内变化。
5.根据权利要求1～4中至少一项的乳液，其中，水溶助长剂(e)选自甘油、丁二醇或丙二醇。
6.根据权利要求1～5中至少一项的乳液，其中，硬脂酸镁和/或硬脂酸铝作为金属皂。
7.根据权利要求1～6中至少一项的乳液，其中，还含有至少一种缓和刺激的活性物质。
8.根据权利要求1～7中至少一项的乳液，其中，在23℃下的粘度为500～5000mPa·S，优选500～3000mPa·S，特别是1000～2000mPa·S。
9.根据权利要求1～8中至少一项的乳液，其中，在涂覆纸张和非制造布时，所述纸张/非制造布白度的降低不超过4％。
CN2007800454765A 2006-12-08 2007-11-29 用于涂饰纺织品和纸张的乳液 Expired - Fee Related CN101553621B (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP06025405A EP1930500A1 (de) 2006-12-08 2006-12-08 Emulsionen zur Avivage von Textilien und Papier
EP06025405 2006-12-08
EPEP06025405 2006-12-08
PCT/EP2007/010349 WO2008067944A1 (de) 2006-12-08 2007-11-29 Emulsionen zur avivage von textilien und papier

Publications (2)

Publication Number Publication Date
CN101553621A true CN101553621A (zh) 2009-10-07
CN101553621B CN101553621B (zh) 2012-05-23

Family

ID=37770817

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2007800454765A Expired - Fee Related CN101553621B (zh) 2006-12-08 2007-11-29 用于涂饰纺织品和纸张的乳液

Country Status (9)

Country Link
US (1) US7879915B2 (zh)
EP (2) EP1930500A1 (zh)
JP (1) JP5345068B2 (zh)
KR (1) KR101466415B1 (zh)
CN (1) CN101553621B (zh)
AT (1) ATE473321T1 (zh)
DE (1) DE502007004350D1 (zh)
ES (1) ES2348196T3 (zh)
WO (1) WO2008067944A1 (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102770112A (zh) * 2009-11-25 2012-11-07 考格尼斯知识产权管理有限责任公司 用于处理基材的浓缩物
CN104762848A (zh) * 2015-04-30 2015-07-08 陈朝民 造纸用水性润滑剂
CN104902864A (zh) * 2012-12-21 2015-09-09 莱雅公司 化妆品组合物

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2953119B1 (fr) 2009-12-01 2012-07-27 Gen Electric Base mobile et appareil a rayons x monte sur une telle base mobile
JP6356382B2 (ja) 2012-12-21 2018-07-11 ロレアル 化粧品組成物
EP3288645B1 (de) 2015-04-28 2019-10-16 Basf Se Niedrigviskose öl-in-wasser emulsionen für kosmetische anwendungen
RS62545B1 (sr) 2017-11-17 2021-12-31 Dr Schumacher Gmbh Emulzija v/u za impregnaciju netkane tkanine
CN109225057B (zh) * 2018-10-15 2019-09-10 广州正浩新材料科技有限公司 一种水性硬脂酸乳液及其制备方法
KR102423954B1 (ko) * 2021-12-27 2022-07-25 한국콜마주식회사 유중수형 화장료 조성물

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3896807A (en) * 1974-06-13 1975-07-29 Gilbert Buchalter Article impregnated with skin-care formulations
US4112167A (en) * 1977-01-07 1978-09-05 The Procter & Gamble Company Skin cleansing product having low density wiping zone treated with a lipophilic cleansing emollient
GB2069333A (en) * 1980-02-19 1981-08-26 Hasbro Industries Inc Cosmetic composition
US4786367A (en) * 1987-08-06 1988-11-22 Scott Paper Company Chemically treated paper products--towel and tissue
DE4125847A1 (de) * 1991-08-03 1993-02-04 Henkel Kgaa Mittel zum behandeln gewaschener waesche in einem waeschetrockner
CA2177038A1 (en) * 1993-12-13 1995-06-22 Alrick Vincent Warner Lotion composition for imparting soft, lubricious feel to tissue paper
JP4169784B2 (ja) 1994-06-17 2008-10-22 ザ プロクター アンド ギャンブル カンパニー ティッシュペーパーを処理するための改良されたローション組成物
CN1106481C (zh) * 1994-06-17 2003-04-23 普罗克特和甘保尔公司 洗剂处理过的薄页纸
FR2745013B1 (fr) * 1996-02-19 1998-04-03 James River Composition pour une lotion adoucissante, utilisation de la lotion pour le traitement de fibres et produit papetier absorbant ainsi traite
WO1998005294A1 (en) * 1996-08-02 1998-02-12 Plum Kemi Produktion A/S An oil-in-water emulsion for use on human skin for cleansing, preserving or improving the condition of the skin
JP3778237B2 (ja) * 1997-09-19 2006-05-24 ライオン株式会社 Ｏ／ｗ型エマルジョンの製造方法
US6183766B1 (en) * 1999-02-12 2001-02-06 The Procter & Gamble Company Skin sanitizing compositions
EP1029977A1 (en) * 1999-02-18 2000-08-23 SCA Hygiene Products GmbH Composition for treating an absorbent paper product and an absorbent paper product treated with said composition
DE19934944A1 (de) * 1999-07-26 2001-02-01 Beiersdorf Ag Kosmetische und dermatologische Zubereitungen auf der Grundlage von O/W-Emulsionen
DE19934943B4 (de) * 1999-07-26 2007-08-02 Beiersdorf Ag Kosmetische und dermatologische Zubereitungen auf der Grundlage von O/W-Emulsionen
DE19938757A1 (de) * 1999-08-16 2001-02-22 Beiersdorf Ag Kosmetische oder dermatologische Zubereitungen vom Typ Öl-in-Wasser
US6576228B1 (en) * 2000-03-10 2003-06-10 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Personal wash sunscreen compositions which deposit and lather well
DE10059430A1 (de) * 2000-11-30 2002-06-06 Cognis Deutschland Gmbh Feinteilige Emulsionen
DE10102500A1 (de) 2001-01-19 2002-08-01 Cognis Deutschland Gmbh Emulsionen auf Basis spezieller Emulgatoren
EP1225276A1 (en) 2001-01-19 2002-07-24 SCA Hygiene Products GmbH Tissue paper
DE10206237A1 (de) * 2002-02-15 2003-08-28 Cognis Deutschland Gmbh Desodorierende Zubereitungen mit Chitosanen und/oder Chitosanderivaten
DE10245727A1 (de) * 2002-10-01 2004-04-15 Beiersdorf Ag Als Aerosol versprühbare W/O-Emulsionen
DE102004002997A1 (de) * 2004-01-19 2005-08-04 Beiersdorf Ag Dünnflüssige W/O Emulsionen ohne O/W-Emulgatoren

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102770112A (zh) * 2009-11-25 2012-11-07 考格尼斯知识产权管理有限责任公司 用于处理基材的浓缩物
CN102770112B (zh) * 2009-11-25 2015-04-22 考格尼斯知识产权管理有限责任公司 用于处理基材的浓缩物
CN104902864A (zh) * 2012-12-21 2015-09-09 莱雅公司 化妆品组合物
CN104902864B (zh) * 2012-12-21 2020-09-01 莱雅公司 化妆品组合物
CN104762848A (zh) * 2015-04-30 2015-07-08 陈朝民 造纸用水性润滑剂
CN104762848B (zh) * 2015-04-30 2017-01-11 江苏双能太阳能有限公司 造纸用水性润滑剂

Also Published As

Publication number Publication date
JP5345068B2 (ja) 2013-11-20
DE502007004350D1 (de) 2010-08-19
CN101553621B (zh) 2012-05-23
WO2008067944A1 (de) 2008-06-12
EP2097584B1 (de) 2010-07-07
EP2097584A1 (de) 2009-09-09
ES2348196T3 (es) 2010-12-01
KR20090095583A (ko) 2009-09-09
US20100242796A1 (en) 2010-09-30
ATE473321T1 (de) 2010-07-15
US7879915B2 (en) 2011-02-01
KR101466415B1 (ko) 2014-11-28
EP1930500A1 (de) 2008-06-11
JP2010511754A (ja) 2010-04-15

Similar Documents

Publication Publication Date Title
CN101553621B (zh) 用于涂饰纺织品和纸张的乳液
US7452917B2 (en) Emulsions made from particular emulsifers
AU734066B2 (en) Composition containing moisture regulators for tissue products, process for the production of these products, use of the composition for the treatment of tissue products as well as tissue products in the form of wet-laid, including TAD, or air-laid products (non wovens) on the basis of sheet-like support materials containing primarily cellulose fibers
US8716336B2 (en) Smooth-feeling wax-based compositions for personal care preparations
US6623746B1 (en) PIT emulsions, methods of softening paper using the same, and paper substrates treated therewith
US7285283B2 (en) Paper substrate impregnated with an emulsion having a polyol, poly-12-hydroxystearate emulsifier, an oil component and water
US20090314444A1 (en) Tissue Paper Comprising a Softening Lotion
US7622021B1 (en) Process for paper substrates using an emulsion and products produced thereby
AU2005244384B2 (en) Anti acne skincare composition and skincare article
EP1029977A1 (en) Composition for treating an absorbent paper product and an absorbent paper product treated with said composition
ZA200303131B (en) Paper products with oil-in-water emulsions.
KR101786449B1 (ko) 클렌징 시트
DE19817301A1 (de) Verwendung von Pflege- und Reinigungszubereitungen zur Befeuchtung von Reinigungstüchern
EP2233124A1 (en) Textile support impregnated with a cleansing/moisturizing composition
CN106619435A (zh) 海洋贝类活性肽润肤霜

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120523

Termination date: 20191129

CF01 Termination of patent right due to non-payment of annual fee