CN101545305B - Waterproofing compound and construction method using the compound - Google Patents

Waterproofing compound and construction method using the compound Download PDF

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Publication number
CN101545305B
CN101545305B CN2008101758637A CN200810175863A CN101545305B CN 101545305 B CN101545305 B CN 101545305B CN 2008101758637 A CN2008101758637 A CN 2008101758637A CN 200810175863 A CN200810175863 A CN 200810175863A CN 101545305 B CN101545305 B CN 101545305B
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weight portions
agent
mentioned
waterproofing compound
mulseal
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CN101545305A (en
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张成周
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SAM AN CORP
Space Co Ltd
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Space Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/4505Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00293Materials impermeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Sealing Material Composition (AREA)

Abstract

The invention provides a waterproof composition and configuration and construction method thereof. The waterproof composition is an asphalt waterproof composition using liquid rubber, having high restoring force, cold resistance and adhesiveness. Based on 100 parts of neoprene latex by weight, 100 parts of neoprene latex, 160 to 240 parts of oil-extended styrene buadiene rubber, 160 to 240 parts of carboxylic styrene butadiene rubber, 90 to 1600 parts of emulsified asphalt and 2 to 100 parts of additive by weight are mixed so as to provide the waterproof composition with the pH value of 7 to 12.

Description

A kind of bituminous waterproofing compound and configuration and job practices of utilizing liquid rubber
Technical field
The invention provides a kind of bituminous waterproofing compound, more particularly, provide a kind of polychloroprene latex (Chloroprene Rubber latex that utilizes; CR), oil-extended styrene buadiene rubber (StyreneButadiene Rubber; SBR), carboxylic styrene-butadiene rubber (C arboxylated StyreneButadiene Rubber; XSBR) and the bituminous waterproofing compound of mulseal.
Background technology
Waterproofing compound (water proofing compound) generally be meant utilization building and structure on the wall the waterproof liquid transpiring moisture that is coated with water-based or oiliness or solvent after and the epithelium that stays obtains the constituent of waterproof effect, and above-mentioned waterproofing compound is generally waterproof and is used in the wall of the roof of building and building structure and outside, undreground works and roof, lavatory, bathroom, balcony.
At present the most universal waterproofing compound comprises with rubber asphalt, acryl rubber or acryl resin and is the milkiness waterproofing compound of main component and contains neoprene and chlorosulfonated polyethylene is the reactive waterproofing compound of main component with urethane and epoxy resin that wherein urethane waterproofing compound and rubber-asphalt waterproof compound are the most frequently used.
The rubber-asphalt waterproof compound is that polymer, ethene acetate or oil-filled fourth jasmine rubber improve and makes it to have higher extension rate, crack resistance, cold resistance and zygosity by mixing oil-filled in pitch.And, can add some surfactants or hardener or the thermoplast elastomer improves heat resistance, intensity and hardness.
As mentioned above, the rubber-asphalt waterproof compound has the advantage of high extension rate, crack resistance, cold resistance and zygosity, but also has the shortcoming of low restoring force, chemical resistance, ozone resistance and ultra-violet resistance.
Especially, owing to the restoring force of the waterproofing compound that is main component with oil-filled fourth jasmine rubber is too low, if uphold above-mentioned waterproofing compound repeatedly, the thermalization phenomenon may take place and cause above-mentioned waterproofing compound to lose the consequence of physical characteristic, and also will cause its deterioration.And, the waterproofing compound that is main component with oil-filled fourth jasmine rubber has low chemical resistance, ozone resistance and ultra-violet resistance, if therefore above-mentioned waterproofing compound is exposed to chemical substance and ozone or ultraviolet overlong time, will causes deterioration very soon.
Otherwise, be that the waterproofing compound of main component has low cold resistance with polychloroprene latex, the environmental change around therefore above-mentioned waterproofing compound can not adapt to timely and effectively.
In order to improve the problems referred to above, though now have some countermeasures to be proposed, but these countermeasures to around environmental change still not enough to some extent and can not meet the demands aspect the life-span of waterproof agent, so the present technique field presses for a kind of new technology that can overcome the problems referred to above.
Summary of the invention
One aspect of the present invention provides a kind of waterproofing compound and configuration and job practices with high restoring force, cold resistance and adhibit quality.
And another aspect of the present invention provides a kind of waterproofing compound and configuration and job practices with low temperature dependency, high tortuosity, restoring force, intensity and hardness.
And another aspect of the present invention provides a kind of have chemical resistance, ozone resistance and ultra-violet resistance excellent waterproof compound and configuration and job practices.
And another aspect of the present invention provides a kind of have long life-span and cheap waterproofing compound and configuration and the job practices of maintenance cost.
In order to solve the technical task of foregoing invention, the invention provides a kind of waterproofing compound, it comprises: be as the criterion with polychloroprene latex 100 weight portions, being used to provide the pH value is 7~12 polychloroprene latexs that mix, 100 weight portions, oil-extended styrene buadiene rubber 160~240 weight portions, carboxylic styrene-butadiene rubber 160~240 weight portions, mulseal 90~1600 weight portions and additive 2~100 weight portions.
According to another aspect of the present invention, the invention provides a kind of method that is used for disposing with the construction waterproof compound, it comprises: be as the criterion with polychloroprene latex 100 weight portions, mixing polychloroprene latex 100 weight portions, oil-extended styrene buadiene rubber 160~240 weight portions, carboxylic styrene-butadiene rubber 160~240 weight portions, mulseal 90~1600 weight portions and additive 2~100 weight portions is 7~12 waterproofing compound to be used to provide the pH value; Above-mentioned waterproofing compound is coated on the part that need be capped; On the above-mentioned part that is covered by waterproofing compound, be coated with the intermixture that mixes water purification and hardener; Utilize the rapid association reaction of above-mentioned waterproofing compound and above-mentioned intermixture on the above-mentioned part that is capped, to form the waterproof epithelium.
Wherein above-mentioned mulseal comprises that nonionic is that mulseal or anion are mulseal.
Wherein above-mentioned additive is included at least one that select in defoamer, dispersing agent, surfactant, age resistor, antiruning agent, pitch stabilizing agent, suspending agent and the viscosity agent.
Wherein above-mentioned additive, be as the criterion with polychloroprene latex 100 weight portions, mix defoamer 2~30 weight portions, dispersing agent 0.2~4 weight portion, surfactant 2~30 weight portions, age resistor 10~40 weight portions, antiruning agent 2~12 weight portions, pitch stabilizing agent 1~6 weight portion, suspending agent 0.2~2 weight portion and viscosity agent 0.3~2 weight portion.
Wherein when above-mentioned waterproofing compound being coated on the part that need be capped, above-mentioned waterproofing compound utilizes spray pattern to be sprayed on the part that need be capped or with pen or cylinder mode and is sprayed on the part that need be capped.
Effect of the present invention
According to waterproofing compound of the present invention and configuration and job practices, by comprising that polychloroprene latex, oil-extended styrene buadiene rubber, carboxylic styrene-butadiene rubber and mulseal form the bituminous waterproofing compound, viscosity and restoring force be can improve, physical characteristic for example cold resistance and adhibit quality also can be improved.
Especially, the present invention is to be that to form the bituminous waterproofing compound be mis-behave with the variation of the physical property that is used for preventing can causing along with variations in temperature to main component with polychloroprene latex, oil-extended styrene buadiene rubber and carboxylic styrene-butadiene rubber.
In addition, bituminous waterproofing compound according to the present invention can improve chemical resistance, ozone resistance and ultra-violet resistance.
Simultaneously, the present invention can prolong the life-span of bituminous waterproofing compound and can save maintenance cost.
The specific embodiment
To explain certain exemplary embodiments of the present invention below, not limit but the present invention is not implemented example.When explanation was of the present invention, existing capability or structure can be omitted for the present invention clearly is described.
Waterproofing compound according to the present invention comprises with polychloroprene latex 100 weight portions and being as the criterion that being used to provide the pH value is 7~12 polychloroprene latexs that mix, 100 weight portions, oil-extended styrene buadiene rubber 160~240 weight portions, carboxylic styrene-butadiene rubber 160~240 weight portions, mulseal 90~1600 weight portions and additive 2~100 weight portions.The bituminous waterproofing compound of Hun Heing and comprise that the intermixture of water purification and hardener (metal dichloride) is sprayed on respectively by sprayer on the part that is capped like this, the above-mentioned waterproofing compound and above-mentioned intermixture is mixed together and form the waterproof epithelium by rapid association reaction moisture and solvent evaporation on the part that is used for being capped during moment on the spray way.
Sometimes, utilize pen or cylinder mode to be coated with above-mentioned bituminous waterproofing compound on the part that is capped, above-mentioned bituminous waterproofing compound can not flow down and had viscosity greater than predetermined value this moment.
Table one illustrates according to the different physical property of the kind of rubber.
Figure G2008101758637D00041
<A: excellent, B: good, C: good, D: bad 〉
[table one] is according to the comparison sheet of the physical property of the kind of rubber
As shown in Table 1, the polychloroprene latex that constitutes according to waterproofing compound of the present invention has better restoring force, weather resistance, ozone resistance, heat resistance, resistance to chemical reagents and anti-old property than other rubber.
Above-mentioned oil-extended styrene buadiene rubber (SBR) is meant the closing property rubber with certain ratio polymerization, and it has cold resistance, intensity and hardness all is excellent feature.Above-mentioned oil-extended styrene buadiene rubber is as the criterion with polychloroprene latex 100 weight portions and may be provided in 160~240 weight portions, better is provided as 180~220 weight portions.
Above-mentioned carboxylic styrene-butadiene rubber (XSBR) is meant the rubber that has high score substring and carboxyl (COOH-) and be categorized as R, and it has the excellent good feature of adhibit quality, intensity and hardness.Above-mentioned carboxylic styrene-butadiene rubber is as the criterion with polychloroprene latex 100 weight portions and may be provided in 160~240 weight portions, better is provided as 180~220 weight portions.
Can select to have the pitch of different characteristic for above-mentioned mulseal.The example that uses above-mentioned mulseal will be described below.Alleged mulseal is meant and as petroleum bitumen a kind of pitch is made particulate and be dispersed in the material of water.Above-mentioned mulseal is divided into that to have cationic cation be mulseal, have anionic anion is mulseal and does not have cation and anionic nonionic is a mulseal, is that mulseal or anion are mulseal and only use nonionic in the present invention.Above-mentioned mulseal is as the criterion with polychloroprene latex 100 weight portions and may be provided in 90~1600 weight portions, better is provided as 140~220 weight portions.
Above-mentioned additive is included in for example higher alcohol of defoamer (antifoaming agent), dispersing agent (dispersing agent), surfactant (surface active agent), age resistor (antioxidant), antiruning agent (antisagging agent), pitch stabilizing agent (Asphaltstabilizing agent) is soap for example, alkylsulfonate (alkyl sulfonate), polyxyethylated (poly oxyethylene alkyl) and phenol ether (phenol ether), at least one that select in suspending agent (suspending agent) and the viscosity agent (viscosity agent).Can add other functional additives sometimes and be provided.Above-mentioned additive is as the criterion with polychloroprene latex 100 weight portions and may be provided in 2~100 weight portions, better is provided as 6~100 weight portions.
Following meeting illustrates in greater detail the weight portion of above-mentioned additive.Above-mentioned additive, be as the criterion with polychloroprene latex 100 weight portions, mix defoamer 2~30 weight portions, dispersing agent 0.2~4 weight portion, surfactant 2~30 weight portions, age resistor 10~40 weight portions, antiruning agent 2~12 weight portions, pitch stabilizing agent 1~6 weight portion, suspending agent 0.2~2 weight portion and viscosity agent 0.3~2 weight portion.More preferably above-mentioned additive comprises, be as the criterion defoamer 6~16 weight portions, dispersing agent 1~2 weight portion, surfactant 4~12 weight portions, age resistor 20~40 weight portions, antiruning agent 4~10 weight portions, pitch stabilizing agent 1.8~2.8 weight portions, suspending agent 0.2~2 weight portion and viscosity agent 0.3~2 weight portion with polychloroprene latex 100 weight portions.
Table two illustrates the constituent ratio according to waterproofing compound of the present invention.
Distinguish Constituent ratio (being as the criterion) with polychloroprene latex 100 weight portions
Polychloroprene latex 100
Oil-extended styrene buadiene rubber 160-240
Carboxylic styrene-butadiene rubber 160-240
Mulseal 90-1600
Defoamer 2-30
Dispersing agent 0.2-4
Surfactant 2-30
Age resistor 10-40
Antiruning agent 2-12
The pitch stabilizing agent 1-6
Suspending agent 0.2-2
Viscosity agent 0.3-2
[table two] is according to the constituent ratio of waterproofing compound of the present invention
As mentioned above, comprise polychloroprene latex, oil-extended styrene buadiene rubber, carboxylic styrene-butadiene rubber and mulseal and have higher elasticity, chemical resistance, ozone resistance and ultra-violet resistance than normally used waterproof agent with sprayer by the waterproofing compound that sprayer is sprayed.Especially, because waterproofing compound comprises polychloroprene latex, waterproofing compound according to the present invention has high restoring force, low temperature dependency degree and high tortuosity than general waterproofing compound.Therefore, can prolong its life-span and can save maintenance cost according to waterproofing compound of the present invention.
In addition, owing to comprise not only that according to waterproofing compound of the present invention polychloroprene latex also comprises oil-extended styrene buadiene rubber, waterproofing compound according to the present invention has more excellent cold resistance, hardness and abrasion performance than common waterproofing compound.Simultaneously, because above-mentioned waterproofing compound comprises that not only polychloroprene latex also comprises carboxylic styrene-butadiene rubber, above-mentioned waterproofing compound has more excellent stickup degree, intensity, hardness and abrasion performance than common waterproofing compound.
The pH value of the waterproofing compound of above-mentioned mixing is 7~12.If waterproofing compound has the pH value greater than 7, then can not react as the metal chloride of hardener, therefore the Ph value that is provided of waterproofing compound needs according to the present invention is 7~12.For example the Combination between polychloroprene latex, oil-extended styrene buadiene rubber, the carboxylic styrene-butadiene rubber was fine for bitumen emulsion and macromolecule emulsus liquid when the Ph value was 7~12, therefore can make the product of multiple quality, and the speed step-down that the pH value is condensed greater than 7 time, so the keeping of product has good stable.
Table three is to measure according to the waterproofing compound of the present invention and the physical characteristic of other waterproof agents of using always to put the form of its characteristic in order.
Figure G2008101758637D00071
[table three] is according to the comparison of physical characteristic between waterproofing compound of the present invention and other goods
From table three as can be known, waterproofing compound according to the present invention has higher stickup degree and restoring force and has lower temperature dependency than other goods.
As shown in table 3, waterproofing compound according to the present invention at the concrete slab that has restoring force 80% as parent (concrete slab) be full of cracks takes place can be upheld or compress when for example chapping along with variations in temperature to be used for suppressing this be full of cracks effectively.Yet, because the restoring force of other goods is too little, along with the be full of cracks of parent takes place and other goods of being upheld, if the be full of cracks of parent reduces then can not be resumed, so the part of having been upheld of other goods can attenuation, can die down and cause losing its unique physical characteristic heat.
Especially, change in the big country along with the variation of variation of temperature article characteristic is the smaller the better at temperature in four seasons.Article according to the invention is not too big from-20 ℃ to 60 ℃ elongation at break modulus change, and other goods 1 reduce about 1/14 and reduce 1/4 60 ℃ elongation at break modular ratio 20 ℃ elongation at break modulus-20 ℃ elongation at break modular ratio 20 ℃ elongation at break modulus, and from then on the temperature dependency of article according to the invention is minimum as can be known.
And most critical is to the parent stickup degree of concrete slab for example for waterproofing compound.Article according to the invention has stickup degree about twice than other goods.
In addition, the physical characteristic of the article according to the invention of the 2mm of having thickness as shown in table 3 is better than the physical characteristic of other goods 1 with thickness 4mm and 2.Therefore, though the present invention uses less waterproof agent, the present invention can obtain best waterproof effect, therefore can save building costs and time.
Utilize the water proof building of waterproofing compound can be used for preventing soil around leaking of coming from the waste material seepage of waste material made ground is penetrated into it and contaminated land and underground water, and can be used to dispose the exterior wall and the reservoir in the passage of waterproof subway, the roof of building, underground room.
Comprise according to the method for configuration buildings waterproof compound of the present invention and to be as the criterion with polychloroprene latex 100 weight portions that to mix polychloroprene latex 100 weight portions, oil-extended styrene buadiene rubber 160~240 weight portions, carboxylic styrene-butadiene rubber 160~240 weight portions, mulseal 90~1600 weight portions and additive 2~100 weight portions be 7~12 waterproofing compound to be used to provide the pH value; Above-mentioned waterproofing compound is coated on the part that is capped; On the above-mentioned part that is capped, be coated with the intermixture that mixes water purification and hardener; Utilize the rapid association reaction of above-mentioned waterproofing compound and above-mentioned intermixture on the above-mentioned part that is capped, to form the waterproof epithelium.
For example metal chloride and water purification are sprayed by sprayer with the intermixture that estimated rate mixes the waterproofing compound that mixes with aforesaid constituent ratio respectively with comprising hardener.So utilizing independent sprayer to be sprayed on waterproofing compound on the part that is capped and intermixture is mixed together simultaneously in the moment of spraying and hardens to be used to form the waterproof epithelium by rapid association reaction moisture and solvent evaporation.Utilize pen or cylinder mode on the part that is capped, to be coated with above-mentioned waterproofing compound and not to use intermixture sometimes, after the moisture natural evaporation that contains through scheduled time waterproofing compound to be used for forming the waterproof epithelium.
In addition, can add the processing of adjusting above the part that is capped as the pre-treatment engineering of aforesaid water proof building engineering.
Although shown and described the present invention with reference to its certain exemplary embodiments, but it should be appreciated by those skilled in the art, or else break away under the situation by the spirit and scope of the present invention of claim definition, can carry out various changes on form and the details it.

Claims (9)

1. method that is used for disposing with the construction waterproof compound, it comprises:
Be as the criterion with polychloroprene latex 100 weight portions, mixing polychloroprene latex 100 weight portions, oil-extended styrene buadiene rubber 160~240 weight portions, carboxylic styrene-butadiene rubber 160~240 weight portions, mulseal 90~1600 weight portions and additive 2~100 weight portions is 7~12 waterproofing compound to be used to provide the pH value;
Above-mentioned waterproofing compound is coated on the part that need be capped;
On the above-mentioned part that is covered by waterproofing compound, be coated with the intermixture that mixes water purification and hardener;
Utilize the rapid association reaction of above-mentioned waterproofing compound and above-mentioned intermixture on the above-mentioned part that is capped, to form the waterproof epithelium.
2. the method for claim 1, wherein above-mentioned mulseal comprises that nonionic is that mulseal or anion are mulseal.
3. the method for claim 1, wherein above-mentioned additive is included at least one that select in defoamer, dispersing agent, surfactant, age resistor, antiruning agent, pitch stabilizing agent, suspending agent and the viscosity agent.
4. the method for claim 1, wherein above-mentioned additive, be as the criterion with polychloroprene latex 100 weight portions, mix defoamer 2~30 weight portions, dispersing agent 0.2~4 weight portion, surfactant 2~30 weight portions, age resistor 10~40 weight portions, antiruning agent 2~12 weight portions, pitch stabilizing agent 1~6 weight portion, suspending agent 0.2~2 weight portion and viscosity agent 0.3~2 weight portion.
5. the method for claim 1, wherein when above-mentioned waterproofing compound being coated on the part that need be capped, above-mentioned waterproofing compound utilizes spray pattern to be sprayed on the part that need be capped or with pen or cylinder mode and is sprayed on the part that need be capped.
6. waterproofing compound, it comprises:
Be as the criterion with polychloroprene latex 100 weight portions, being used to provide the pH value is 7~12 polychloroprene latexs that mix, 100 weight portions, oil-extended styrene buadiene rubber 160~240 weight portions, carboxylic styrene-butadiene rubber 160~240 weight portions, mulseal 90~1600 weight portions and additive 2~100 weight portions.
7. waterproofing compound as claimed in claim 6, wherein above-mentioned mulseal comprise that nonionic is that mulseal or anion are mulseal.
8. waterproofing compound as claimed in claim 6, wherein above-mentioned additive is included at least one that select in defoamer, dispersing agent, surfactant, age resistor, antiruning agent, pitch stabilizing agent, suspending agent and the viscosity agent.
9. waterproofing compound as claimed in claim 6, wherein above-mentioned additive, be as the criterion with polychloroprene latex 100 weight portions, mix defoamer 2~30 weight portions, dispersing agent 0.2~4 weight portion, surfactant 2~30 weight portions, age resistor 10~40 weight portions, antiruning agent 2~12 weight portions, pitch stabilizing agent 1~6 weight portion, suspending agent 0.2~2 weight portion and viscosity agent 0.3~2 weight portion.
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