Summary of the invention
The purpose of this invention is to provide and a kind ofly can effectively shorten dyeing, enhance productivity, reduce the terylene/cotton/chinlon/spandex polycomponent seamless underwear dyeing of blowdown.
The present invention is terylene/cotton/chinlon/spandex polycomponent seamless underwear dyeing, it is characterized in that being undertaken by following processing step:
A, oxygen float the refining oil removing: with existing technology, terylene/cotton/chinlon/spandex polycomponent seamless underwear is put into dye vat, carry out the refining oil removing that cotton oxygen floats refining, terylene/cotton/chinlon/spandex by the technological requirement that existing oxygen floats the refining oil removing, then through hot water wash, washing;
B, dye terylene/cotton/chinlon/spandex: add various dying material and auxiliary agent respectively and carry out dying terylene/cotton/chinlon/spandex,, soap, wash then through hot water wash with bathing with bathing;
C, soft treatment: carry out soft treatment by existing soft treatment technological requirement;
Dying material among the described step B and auxiliary agent be by DISPERSE DYES, the neutral fixation REACTIVE DYES of high temperature, and faintly acid or neutral dye, chelated dispersants, Kayaku Buffer P-7) glauber salt disperses levelling agent, pH value conditioning agent P-7 (English name: composition such as.
The addition of dying material and auxiliary agent can be respectively among the described step B: chelated dispersants 0.3~0.8g/L, pH value conditioning agent P-70.5~1g/L disperses levelling agent 0.25~1g/L, glauber salt 5~20g/L.
The neutral fixation REACTIVE DYES of described high temperature can be CN type REACTIVE DYES or NF type REACTIVE DYES or L type REACTIVE DYES.
Described DISPERSE DYES can be the low form DISPERSE DYES.
Described bath is together dyed terylene/cotton/chinlon/spandex and can be carried out according to the following steps: adding assistant in the time of 30 ± 5 ℃, the order of adding assistant is chelated dispersants, disperses levelling agent, pH value conditioning agent P-7, glauber salt, adds to add another kind of auxiliary agent again after changeing 2-3min behind a kind of auxiliary agent; Add weak acid dye or neutral dye after all auxiliary agents all add and change 3~8min, add again and disperse dyestuff to change 3~8min, be warmed up to 50 ± 5 ℃ with 1~1.5 ℃/min and add the neutral fixation REACTIVE DYES commentaries on classics of high temperature 3~8min, be warmed up to 113 ± 3 ℃ of insulation 60 ± 5min with 1~1.5 ℃/min, cool to 80 ℃ again to sample, cool to 60 ℃ of drainings at last.
The present invention compared with prior art has following outstanding advantage and good effect:
1, dyeing with three bath methods originally, dyes, shortened technological process, shortened dyeing time, reduced the consumption of steam and water, reduced blowdown, improved production efficiency, reduced the dyeing cost by process modification and innovation back single bath process.
2, according to dying terylene, dye cotton, dye the dyeing requirement of chinlon/spandex single bath process, in the required DISPERSE DYES of prior art, REACTIVE DYES, faintly acid or neutral dye, chelated dispersants, disperse levelling agent, on the basis of dying such as glauber salt material and auxiliary agent, through repeatedly repetition test comparison, rationally select the low form DISPERSE DYES for use, the neutral fixation REACTIVE DYES of high temperature and part faintly acid or neutral dye, saved acid levelling agent, glacial acetic acid, sodium acetate, auxiliary agents such as soda ash, added pH value conditioning agent P-7, make dye bath remain on neutrallty condition, thereby make one-bath dyeing processing technology energy smooth implementation.
3, according to the requirement of terylene/cotton/chinlon/spandex co-bathing dyeing and dying material and auxiliary agent to technology, through repeatedly repetition test comparison, rationally determine the interpolation order of dying material and auxiliary agent and temperature, time, prevent between each dyestuff, the auxiliary agent, interaction between dyestuff and the auxiliary agent, help stablizing dyeing, improve the once successful probability of dyeing.
The specific embodiment:
CN type REACTIVE DYES or the NF type REACTIVE DYES of Yanyun Textile Chemical Co., Ltd., Shanghai's product or the L type REACTIVE DYES that Shanghai Annuoqi Spinning Chemical Co.,Ltd produces that the neutral fixation REACTIVE DYES of high temperature among the embodiment of the present invention selects for use Nippon Kayaku K. K to produce, these REACTIVE DYES can dyeing between 80 ℃ to 130 ℃ under neutrallty condition.Disperse red ACE, disperse yellow ACE, disperse blue ACE that the low form DISPERSE DYES selects for use Zhejiang Province Runtu intercalated Co., Ltd to produce.
Embodiment 1:
Raw material is formed: 65%75D/72F COOLMAX and 60 cotton blending (blending rate 65/35), 35% 40D/36F and 20/70-48F bag yarn.
Product: male jersey and swimming trunk; Color: cream-coloured.
A, oxygen float refining oil removing prescription:
Degreaser FT-128 2g/L
Scouring agent L-100Z 0.5g/L
Hydrogen peroxide 2.5g/L
Oxygen floats auxiliary agent 1.5g/L
B, the same bath are dyed terylene/cotton/chinlon/spandex prescription:
Disperse yellow ACE 0.145%
Disperse red ACE 0.085%
Disperse blue ACE 0.0215%
CN-EX Huang 0.10%
CN-3B red 0.025%
CN-MG indigo plant 0.011%
Neutral yellow GL 0.065%
Neutral brown RL ' 0.05%
Neutral orange RL 0.015%
Chelated dispersants 1g/L
Glauber salt 10g/L
Disperse levelling agent 1g/L
PH conditioning agent P-7 1g/L
C, soft treatment prescription:
Suction speed is in softener HK-530 3g/L
Citric acid 0.2g/L
The technological operation step: product put into dye vat → add hydrogen peroxide and oxygenic bleaching aids turn 95 ℃ of oxygen of 5min → directly be warmed up to float cool to behind the 30min 60 ℃ of drainings → 60 degree hot water wash → normal temperature washing → water inlet add chelated dispersants turn 5min → add disperse levelling agent and buffer P-7 turn 5min → add neutral dye turn 5min → add disperse dyestuff turn 5min → add glauber salt turn 5min → with 1.5 ℃/min be warmed up to 50 ℃ → add reactive dye and turn 5min → with 1 ℃/min and be warmed up to and cool to 60 ℃ of drainings → 60 degree hot water wash → normal temperature washing → soft treatment behind 115 ℃ of insulation 40min: 40 ℃ of softnesses 20 minutes.
Dye the back fabric after tested: WASHING COLOR FASTNESS reaches 4 grades, and anti-dry fastness reaches 4 grades, fastness to wet rubbing 3-4 level.Water pollutes 4 grades of fastness.
Embodiment 2:
Raw material is formed: 78% wash/cotton (wash account for 54.6%/cotton account for 23.4%), 22% 20/30 bag yarn.
Product: male short sleeve shirt; Color: orange colour.
A, pre-treatment:
The sheet alkali of 15g/L was handled 20 minutes for 120 ℃
B, one-bath dyeing prescription:
Chelated dispersants 1g/L
Refining agent 0.5g/L
Degreaser 1g/L
Disperse yellow ACE 0.085%
Disperse red ACE 0.05%
Neutral fixation REACTIVE DYES CN-EX Huang 0.10%
Neutral fixation REACTIVE DYES CN-3B red 0.05%
Neutral yellow GL 0.01%
Neutral orange RL 0.03%
Glauber salt 5g/L
Disperse levelling agent 0.5g/L
PH conditioning agent P-7 1g/L
C, soft treatment prescription:
Water-absorbing fast-drying softener HK-530 3g/L
Citric acid 0.2g/L
The technological operation step: the good sheet alkali that adds priorization turn 10min → product put into 120 ℃ in HTHP dye vat → directly be warmed up to process cool to behind the 20min 60 ℃ of drainings → 95 degree hot water wash → normal temperature washing → acid neutralization → normal temperature washing → water inlet add chelated dispersants turn 5min → add disperse levelling agent and buffer P-7 turn 5min → add neutral dye turn 5min → add disperse dyestuff turn 5min → add glauber salt turn 5min → with 1.5 ℃/min be warmed up to 50 ℃ → add reactive dye and turn 5min → with 1 ℃/min and be warmed up to and cool to 60 ℃ of drainings → 60 behind 115 ℃ of insulation 40min and spend hot water wash → normal temperature washing → soft treatment: 40 ℃ of softnesses 20 minutes.
Dye the back fabric after tested: WASHING COLOR FASTNESS reaches 4 grades, and anti-dry fastness reaches 4 grades, fastness to wet rubbing 3-4 level.Water pollutes fastness 3-4 level.
Dying material in the above embodiment of the present invention and auxiliary agent except that the neutral fixation REACTIVE DYES of high temperature and HP value conditioning agent P-7 for the present invention selects for use especially, other dying material and auxiliary agent are prior art and use always.The foregoing description only is can not limit the present invention to explanation of the present invention, in implication suitable with the present invention and any change and the combination in the scope, all should think within the scope of the invention.
The present invention compared with prior art, has following economic and social benefit through practical application:
Dyeing time and output: former three bath methods are normally dyed the used time of a cylinder and are wanted 20 hours, as long as the new technology dyeing time is 8 hours, dying a cylinder product dyeing time can dwindle 12 hours, calculated by one day 24 hours, former technology dyeing can only be dyed a cylinder, and reducible three cylinders that dye of new technology dyeing have improved production efficiency greatly, shorten delivery date.
Steam consumption: former technology is compared few operation with steam to be had with new technology: three road hot water wash, reduction cleaning is dyed cotton, dyes polyamide fibre, can economize on vapour more than 1/3rd.
The consumption of water, electricity: former technology is compared with new technology, and new technology is reduced to 8 cylinder water from 16 cylinder water, and water consumption has reduced half, but half amount of conserve water resource, save electricity half.
Auxiliary dosage: the comparable former technology of new technology is used following auxiliary agent less: reduction cleaner, and the glauber salt of half amount, soda ash, the polyamide fibre levelling agent, can be saved the cost of this part auxiliary agent at glacial acetic acid, sodium acetate.
Integrated cost: except that dye dosage, from water, electricity, vapour, time, artificial, auxiliary dosage, blowdown and production efficiency analysis-by-synthesis, new technology cost-saved nearly 1/2nd.Also reduce cost of sewage disposal, reduced the sewage discharge pollution on the environment.