CN101538515B - Ultrasonic cleaning agent of water-based element - Google Patents
Ultrasonic cleaning agent of water-based element Download PDFInfo
- Publication number
- CN101538515B CN101538515B CN2009100385963A CN200910038596A CN101538515B CN 101538515 B CN101538515 B CN 101538515B CN 2009100385963 A CN2009100385963 A CN 2009100385963A CN 200910038596 A CN200910038596 A CN 200910038596A CN 101538515 B CN101538515 B CN 101538515B
- Authority
- CN
- China
- Prior art keywords
- water
- ultrasonic cleaning
- cleaning agent
- based element
- colophony
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 238000004506 ultrasonic cleaning Methods 0.000 title claims abstract description 10
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 9
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002994 raw material Substances 0.000 claims abstract description 7
- -1 Polyoxyethylene nonylphenol Polymers 0.000 claims description 9
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 6
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 claims description 6
- 239000000654 additive Substances 0.000 abstract description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract description 3
- 230000006378 damage Effects 0.000 abstract description 3
- 238000012986 modification Methods 0.000 abstract description 2
- 230000004048 modification Effects 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 8
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical group CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 206010010075 Coma hepatic Diseases 0.000 description 2
- 230000001079 digestive effect Effects 0.000 description 2
- 201000001059 hepatic coma Diseases 0.000 description 2
- 208000007386 hepatic encephalopathy Diseases 0.000 description 2
- 206010040882 skin lesion Diseases 0.000 description 2
- 231100000444 skin lesion Toxicity 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 206010002198 Anaphylactic reaction Diseases 0.000 description 1
- 206010012455 Dermatitis exfoliative Diseases 0.000 description 1
- 206010042033 Stevens-Johnson syndrome Diseases 0.000 description 1
- 231100000168 Stevens-Johnson syndrome Toxicity 0.000 description 1
- 206010044223 Toxic epidermal necrolysis Diseases 0.000 description 1
- 231100000087 Toxic epidermal necrolysis Toxicity 0.000 description 1
- 208000003455 anaphylaxis Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 description 1
- 210000003792 cranial nerve Anatomy 0.000 description 1
- 230000002498 deadly effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000779 depleting effect Effects 0.000 description 1
- 208000004526 exfoliative dermatitis Diseases 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 231100000753 hepatic injury Toxicity 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 230000037384 skin absorption Effects 0.000 description 1
- 231100000274 skin absorption Toxicity 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
The invention belongs to the technical field of cleaning agents, in particular to an ultrasonic cleaning agent of a water-based element, comprising the following raw materials by weight percent: 70 to 83 of water, 10 to 20 of dimethyl formamide, 6 to 8 of ether amine alkoxy and 1 to 2 of other additives. The product enables colophony to be dissolved in water by water modification, achieves the aim of cleaning the colophony and treats the element surface by the special additives so that the cleaned element can be preserved for a long time in a firstly cleaned state without an oxidation phenomenon. The cleaning agent does not damage the environment due to the avoidance of ozone layer damaging substances and is safe in the ultrasonic cleaning process due to the avoidance of volatile solvent.
Description
Technical field:
The invention belongs to the clean-out system technical field, particularly ultrasonic cleaning agent of water-based element.
Background technology:
After electronic component adopts the welding of colophony type soldering flux, the residual existence of rosin will influence the function test or the assembling difficulty of element, therefore the residual rosin after the element welding need carry out ultrasonic cleaning, and the clean-out system that adopts on the market is trichloroethane or trieline at present.
Clean with trichloroethane, trichloroethane itself does not have combustibility, dissolving power is strong, be applicable to that ultrasonic processing procedure cleans, it is extraordinary rosin clean-out system, but in the ODS material that 1987 will eliminate about the Montreal protocol of Ozone Depleting Substances regulation, comprise 94 kinds of six classes at the ODS of China's production and consumption, this six classes material is: CFSs, breathe out dragon, tetracol phenixin, 1,1, the 1-trichloroethane, HCFC and monobromomethane, but because trichloroethane class clean-out system result of use is very good, produce and use so still have so far, the clean-out system in 09 year all outlets Europe must be executed Montreal protocol, so trichloroethane class clean-out system must be eliminated.
Trieline is a colourless liquid.Because its fat melting performance is good, be to use one of wider organic solvent on the current industrial, often be used as electron trade and clean wiring board, the good clean-out system of hardware industry clean metal material uses.But the trieline high volatility is harmful; Trieline can be through respiratory tract, digestive tube and skin absorption.
The trieline occupational hazards is the most common with severe anaphylactic reaction, and the patient mostly is morbidity in about 30 days behind the contact trieline, breaks with tremendous force after the morbidity, usually can disable, deadly.Invention performance: heating, serious skin lesion and hepatic injury (hepatic coma) are generally arranged, also can involve cranial nerve, digestive tube, heart and eyes etc.Skin lesion shows as exfoliative dermatitis, Stevens Johnson syndrome or bullous epidermal necrolysis.This disease is distributes, and has 4% people extremely sensitive to trieline approximately.This disease course of disease is long, is difficult to cure, often because of hepatic coma, concurrent infection death.
Though trichloroethane, trieline all have good solvability to rosin is residual, owing to environment, to people's harm, must subdue.
Summary of the invention:
The objective of the invention is to: at environmentally friendly, the harmless aqueous cleaning agent that is used for the ultrasonic cleaning processing procedure of the deficiencies in the prior art research and development.
The object of the present invention is achieved like this: the present invention forms by following raw materials by weight percent, obtains rinse product with simple preparation technology.
Major ingredient content
Water 70%～83%
Dimethyl formamide 10%～20%
Alkoxyl group ether amine oxide 6%～8%
Other additive 1%～2%
The present invention can also form by following prescription:
Major ingredient content
Water 75%～80%
Dimethyl formamide 15%～18%
Alkoxyl group ether amine oxide 7%
Other additive 1.5%
Wherein: alkoxyl group ether amine oxide is a dimethyl dodecyl amine oxide.
Wherein: other additive is a polyoxyethylene nonylphenol ether.
Beneficial effect of the present invention is:
Modification by water makes the water can dissolving rosin, reach and clean the rosiny purpose, by special additive treating element surface, make element clean the back preservation and oxidative phenomena can not take place for a long time, just like the state that has just cleaned, this type of clean-out system can not destroy environment owing to do not contain the material that damages the ozone layer, do not contain easy volatile solvent, not dangerous in the ultrasonic cleaning processing procedure.
Embodiment:
Enumerate preferred embodiment of the present invention below, the present invention may be better understood for these embodiment, but do not limit the present invention in any form.
Embodiment 1:
Following raw materials by weight percent is added in the reaction vessel successively, stir and promptly get product of the present invention.
Major ingredient content
Water 83%
Dimethyl formamide 10%
Dimethyl dodecyl amine oxide 6%
Polyoxyethylene nonylphenol ether 1%
Embodiment 2:
Following raw materials by weight percent is added in the reaction vessel successively, stir and promptly get product of the present invention.
Major ingredient content
Water 70%
Dimethyl formamide 20%
Dimethyl dodecyl amine oxide 8%
Polyoxyethylene nonylphenol ether 2%
Embodiment 3:
Following raw materials by weight percent is added in the reaction vessel successively, stir and promptly get product of the present invention.
Major ingredient content
Water 76.5%
Dimethyl formamide 15%
Dimethyl dodecyl amine oxide 7%
Polyoxyethylene nonylphenol ether 1.5%
The above only is a better embodiment of the present invention, so all equivalences of doing according to the described structure of patent claim of the present invention, feature and principle change or modify, is included in the patent claim of the present invention.
Claims (2)
1. ultrasonic cleaning agent of water-based element is characterized in that: be made up of following raw materials by weight percent:
Water 70%～83%
Dimethyl formamide 10%～20%
Dimethyl dodecyl amine oxide 6%～8%
Polyoxyethylene nonylphenol ether 1%～2%.
2. ultrasonic cleaning agent of water-based element according to claim 1 is characterized in that: by following weight
The raw material of per-cent is formed:
Water 75%～80%
Dimethyl formamide 15%～18%
Dimethyl dodecyl amine oxide 7%
Polyoxyethylene nonylphenol ether 1.5%
Described component sum is absolutely.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100385963A CN101538515B (en) | 2009-04-14 | 2009-04-14 | Ultrasonic cleaning agent of water-based element |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100385963A CN101538515B (en) | 2009-04-14 | 2009-04-14 | Ultrasonic cleaning agent of water-based element |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101538515A CN101538515A (en) | 2009-09-23 |
| CN101538515B true CN101538515B (en) | 2011-04-06 |
Family
ID=41121906
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100385963A Active CN101538515B (en) | 2009-04-14 | 2009-04-14 | Ultrasonic cleaning agent of water-based element |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101538515B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103706601A (en) * | 2013-12-18 | 2014-04-09 | 常熟市天河机械设备制造有限公司 | Water-aqua ultrasonic cleaning process for steel belt |
| CN111763577A (en) * | 2019-12-18 | 2020-10-13 | 张春岩 | Kitchen oil stain cleaning agent and preparation method thereof |
| CN111575124A (en) * | 2020-06-10 | 2020-08-25 | 苏州世华新材料科技股份有限公司 | Circuit board residual glue cleaning agent and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002095502A1 (en) * | 2001-05-21 | 2002-11-28 | Dongjin Semichem Co., Ltd. | Resist remover composition |
| CN101121913A (en) * | 2006-06-28 | 2008-02-13 | 天津晶岭电子材料科技有限公司 | LCD water-base cleaning liquid |
-
2009
- 2009-04-14 CN CN2009100385963A patent/CN101538515B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002095502A1 (en) * | 2001-05-21 | 2002-11-28 | Dongjin Semichem Co., Ltd. | Resist remover composition |
| CN101121913A (en) * | 2006-06-28 | 2008-02-13 | 天津晶岭电子材料科技有限公司 | LCD water-base cleaning liquid |
Non-Patent Citations (2)
| Title |
|---|
| JP特开2004-162031A 2004.06.10 |
| JP特开平9-3676A 1997.01.07 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101538515A (en) | 2009-09-23 |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| ASS | Succession or assignment of patent right |
Owner name: SUZHOU YOUNUO ELECTRONIC MATERIALS TECHNOLOGY CO., Free format text: FORMER OWNER: DONGGUAN YOUNUO ELECTRONIC WELDING MATERIAL CO., LTD. Effective date: 20100419 |
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Free format text: CORRECT: ADDRESS; FROM: 523829 DONGGUAN YOUNUO ELECTRONIC WELDING MATERIAL CO., LTD., TAIGONGLING VILLAGE, DALINGSHAN TOWN, DONGGUAN CITY, GUANGDONG PROVINCE TO: 215152 NO.8, AIMIN ROAD, XIANGCHENG DISTRICT, SUZHOU CITY, JIANGSU PROVINCE |
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| TA01 | Transfer of patent application right |
Effective date of registration: 20100419 Address after: 215152 No. 8 Aimin Road, Suzhou, Jiangsu, Xiangcheng District Applicant after: EUNOW ELECTRONIC TECHNOLOGY Co.,Ltd. (SUZHOU) Address before: 523829 Guangdong Province, Dongguan City Dalingshan Town of Tai Gong Ling Cun Dongguan uneed electronic welding material Co. Ltd. Applicant before: DONGGUAN EUNOW ELECTRONIC WELDING MATERIAL Co.,Ltd. |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: DONGGUAN EUNOW ELETRONIC WELDING MATERIAL CO., LTD Free format text: FORMER OWNER: SUZHOU EUNOW ELECTRONIC MATERIAL TECHNOLOGY CO., LTD. Effective date: 20120301 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 215152 SUZHOU, JIANGSU PROVINCE TO: 523829 DONGGUAN, GUANGDONG PROVINCE |
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| TR01 | Transfer of patent right |
Effective date of registration: 20120301 Address after: Dalingshan Town Village 523829 Tai Gong in Guangdong province Dongguan City Patentee after: DONGGUAN EUNOW ELECTRONIC WELDING MATERIAL Co.,Ltd. Address before: 215152 No. 8 Aimin Road, Suzhou, Jiangsu, Xiangcheng District Patentee before: EUNOW ELECTRONIC TECHNOLOGY Co.,Ltd. (SUZHOU) |
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Effective date of registration: 20231026 Address after: No. 364 Gangxin Road, Nanshui Town, Jinwan District, Zhuhai City, Guangdong Province, 519000 Patentee after: Zhuhai Youbang New Materials Co.,Ltd. Address before: Dalingshan Town Village 523829 Tai Gong in Guangdong province Dongguan City Patentee before: DONGGUAN EUNOW ELECTRONIC WELDING MATERIAL Co.,Ltd. |