CN101535463B - Self adhesive hard surface cleaning block - Google Patents
Self adhesive hard surface cleaning block Download PDFInfo
- Publication number
- CN101535463B CN101535463B CN2007800422321A CN200780042232A CN101535463B CN 101535463 B CN101535463 B CN 101535463B CN 2007800422321 A CN2007800422321 A CN 2007800422321A CN 200780042232 A CN200780042232 A CN 200780042232A CN 101535463 B CN101535463 B CN 101535463B
- Authority
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- China
- Prior art keywords
- mutually
- block
- tackiness agent
- cleaning block
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 28
- 239000000853 adhesive Substances 0.000 title claims abstract description 11
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 83
- 239000000463 material Substances 0.000 claims description 38
- 230000002209 hydrophobic effect Effects 0.000 claims description 21
- 239000003921 oil Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 7
- 239000006254 rheological additive Substances 0.000 claims description 7
- 239000013543 active substance Substances 0.000 claims description 5
- 229940099259 vaseline Drugs 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 2
- 229920001477 hydrophilic polymer Polymers 0.000 claims description 2
- 235000010446 mineral oil Nutrition 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- 239000012454 non-polar solvent Substances 0.000 claims description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 2
- 230000008719 thickening Effects 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 1
- 239000003599 detergent Substances 0.000 abstract description 17
- 238000004851 dishwashing Methods 0.000 abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 238000011010 flushing procedure Methods 0.000 description 9
- 239000010410 layer Substances 0.000 description 9
- 235000019198 oils Nutrition 0.000 description 8
- 239000007787 solid Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 206010016825 Flushing Diseases 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000002131 composite material Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000005201 scrubbing Methods 0.000 description 2
- 229960001866 silicon dioxide Drugs 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 2
- 235000020238 sunflower seed Nutrition 0.000 description 2
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- 229940123457 Free radical scavenger Drugs 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 238000002679 ablation Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000003165 hydrotropic effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000016507 interphase Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229940045998 sodium isethionate Drugs 0.000 description 1
- LADXKQRVAFSPTR-UHFFFAOYSA-M sodium;2-hydroxyethanesulfonate Chemical compound [Na+].OCCS([O-])(=O)=O LADXKQRVAFSPTR-UHFFFAOYSA-M 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0056—Lavatory cleansing blocks
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0078—Multilayered tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0091—Dishwashing tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
Abstract
The present invention relates to self adhesive hard surface cleaning blocks, and their use. It is an object of the present invention to provide a detergent block that can be easily positioned onto a hard surface; even a wet surface. It is a further object of the invention to provide a detergent block that rinses away in a number of flushes, and does not leave behind any residue that cannot be easily removed with e.g. a toilet brush. We have found that a hard surface cleaning block comprising an adhesive phase meets at least one of these objects. Methods of washing dishes in a sink or in a dishwashing machine are also claimed.
Description
Invention field
The present invention relates to self adhesive hard surface cleaning blocks (cleaning block) and application thereof.
Background technology
Hard surface cleaning block (for example washroom cleaning block) is known in this area, and is made into usually to discharge active ingredient automatically and constantly and/or discharge fragrance in air to the liquid through block (block).For example, they can be suspended in the container of the below, edge that is arranged in urinal (lavatory bowl) or urinal, make in flush cycle, flow through block from the water in the water storage box, thereby dissolve a part of block and the active ingredient of block is discharged into urinal.They also can be used in the dish washing machine, perhaps even can be used to manual dishwashing.
The means of different that block is applied to toilet (toilet) is open in the art.The fixer that is used for the solid cleaning agent piece for example has open at EP-B1-586 137.The washroom is liquid dispensing apparatus (liquid dispenser device), for example disclosed device in GB2389123 with another selection of cleaning block.
Liquid and solid rim device (the liquid and the solid rim device) all need the washroom is connected to cleaning block the fixer of bowl rim.Now, the human consumer dislikes having to touch and operate the idea of having placed the device of a few weeks longer in toilet in the time need refilling or replace.Because the reason of environment, the human consumer does not appreciate the behavior that abandons this device yet.
Attempted by various means head it offs.A kind of such substitute is the flap that is used in the water storage box.But this device can not be used in the more and more welcome built-in water storage box that just becoming.Another kind of substitute is pumping unit, and it has at the divider at bowl rim place with at the independent bottle with cleaning liq of toilet outside.The shortcoming that this selection scheme has is pipe that edge device is connected with the bottle with cleaning liq.
Another kind of substitute can find in EP-A1-1 086 199, wherein discloses a kind of mashed prod (paste) of self-adhesion, and this mashed prod can for example be administered to toilet surface from pipe.But the idea that mashed prod is applied to toilet surface needs the human consumer to carry out many actions in toilet staving (toilet bowl) inside, for example extruded tube and lay mashed prod.In addition, the human consumer dislikes the appearance of paste strip or agglomerate (blob).
Still need a kind of detergent block that can be placed in easily on the crust.
The object of the present invention is to provide a kind of detergent block, it can be placed in crust easily; Or even on the wet surface.
Another object of the present invention is to provide a kind of detergent block, it is being rinsed in flushing back repeatedly, and can not stay any residue that can not remove easily with for example toilet brush.
Another object of the present invention is to not damage with the be shaped possibility of detergent block of any attracting mode.
We surprisingly find, the hard surface cleaning block that comprises tackiness agent phase (adhesive phase) reaches at least one in these purposes.
Summary of the invention
Therefore, the invention provides a kind of hard surface cleaning block, it comprises:
-sanitising agent phase (detergent phase),
-tackiness agent phase;
Wherein tackiness agent comprises hydrophobic jointing material mutually, and this material comprises:
At least a hydrophobic compound of-25-60%, its total fusing point (aggregate meltingpoint) is 30-60 ℃; With
The polymkeric substance of-5-75%.
As hereinafter further explaining, the present invention further provides and use hard surface cleaning block of the present invention to make the method for bowl sanitation and the method for dishwashing.
After reading following detailed description and claims, these and other aspects, characteristics and advantage will become apparent for a person skilled in the art.For avoiding feeling uncertain, any characteristics of one aspect of the present invention can be used in any other aspect of the present invention.Be noted that the embodiment that provides in the following description explains the present invention, and be not used for the present invention is defined in those embodiment itself.Similarly, except as otherwise noted, all percentage ratio all is w/w percentage ratio.The digital scope of representing with the form of " from x to y " is understood to include x and y.When for certain features with " from x to y " format description during a plurality of preferable range, it being understood that and also contain all in conjunction with the scope of different end points.
The detailed description of invention
Hard surface cleaning block of the present invention comprise tackiness agent mutually with sanitising agent mutually.
The purpose of tackiness agent phase is to apply the detergent phase to crust.
The purpose of sanitising agent phase is to be released into crust with being added in sanitising agent detergent material (detergent material) and other compositions in mutually, to handle this surface.When this usually occurs in block and contacts with water, for example, as toilet block the time, contact with water by flush toilet, or when in the dishwashing application, contacting with water by getting block wet before use.In case contact with water, block is partly dissolved subsequently.
The preferred component of selecting block makes tensio-active agent with equilibrium level (balanced level) and structurising agent (structurant) so that suitable foam and intensity to be provided to block.
One aspect of the present invention is a kind of bonder system of exploitation, and it can be washed off easily by leniently using the surface of block above the friction.Therefore, on the one hand, block is preferably enough adhered to stand the pressure of the flowing water in toilet, tank or shower tray (shower) securely, and but then, bonding is not sacrifices consisting of an ox, a sheep and a pig solid so that be difficult to remove jointing material from the surface after product uses up.
The sanitising agent phase
Sanitising agent can be the sanitising agent phase of any kind of mutually.It can be, for example, and solid, semisolid or gel.Sanitising agent can be transparent, translucent, opaque or opaque fully mutually.Sanitising agent mutually can directly be attached to the tackiness agent phase, or adheres to (for example in cover (cage), or have sealing coat between two-phase) indirectly.
Sanitising agent comprises tensio-active agent mutually.Suitable tensio-active agent is at " Surface ActiveAgents (tensio-active agent) " the 1st volume, Schwartz ﹠amp; Perry, Interscience 1949 and the 2nd volume, Schwartz, Perry ﹠amp; Berch, Interscience 1958; " McCutcheon ' s Emulsifiersand Detergents (emulsifying agent of McCutcheon and sanitising agent) " of the current version of being published by ManufacturingConfectioners Company; Or " Tenside-Taschenbuch ", H.Stache, the 2nd edition, Carl Hauser Verlag has description in 1981.
The tackiness agent phase
Tackiness agent preferably is suitable for sanitising agent is attached to crust mutually mutually.
Usually, the detergent block of self-adhesion of the present invention, no matter block is adhered to tank, dishwasher or toilet, all will be subjected to water impact.When flushing, water is applied to toilet block, and (front surface is 10cm
2) power on average be 0.3N.Therefore, discharge the required power of block from the surface and be preferably greater than described 0.3N.
Tackiness agent comprises hydrophobic jointing material mutually and randomly comprises hydrophilic jointing material.For the present invention, need hydrophobic jointing material to obtain the suitable resistance to water.For obtaining more firm adhesion, this component can further comprise hydrophilic jointing material.
Hydrophobic jointing material comprises at least a hydrophobic compound that total fusing point is 30 to 60 ℃ (preferred 45 to 55 ℃), and polymkeric substance.Hydrophobic compound is with the 25-60% that accounts for hydrophobic jointing material weight, preferred 35-55%, more preferably the concentration of 40-50% is present in the hydrophobic jointing material.Tackiness agent further comprises the 5-75% that concentration is hydrophobic jointing material weight, preferred 20-70%, more preferably 40-65%, the polymkeric substance of 50-60% most preferably mutually.
Hydrophobic compound is preferably selected from non-polar solvent or low HLB nonionic surface active agent and their combination of natural oil or mineral oil, vaseline, blown oil, partially hydrogenated oil or fat, silicone oil and derivative, thickening.The low HLB of this paper definition refers to preferably to be more preferably less than 10 less than 12.
Polymkeric substance is preferably selected from natural and synthetic cellulosic polymer (cellulosicpolymers) (for example carboxymethyl cellulose), polyacrylic ester, polyvinylpyrrolidone (polyvinylpyrolidone), Malaysia acids/ethylenic copolymer (maleic/vinyl copolymers), based on the polymkeric substance of silicon and their mixture.
Polymkeric substance in hydrophobic jointing material is preferably water-insoluble, and preferred expansion when contacting with water.
Tackiness agent randomly comprises hydrophilic jointing material mutually.Just contact dissolving immediately for preventing hydrophilic tackiness agent mutually in case with water, hydrophilic jointing material (if exist) preferably be arranged to make it to be connected to crust and sanitising agent mutually or sanitising agent and tackiness agent phase between intermediate phase, and in every other side, it is surrounded by hydrophobic jointing material.Even expect that hydrophilic jointing material can be dissolved fast by water, but think that (be reluctant bound by theory) is by obtaining the adhesion of described further improvement in conjunction with the hydrophobic jointing material that surrounds hydrophilic jointing material, because hydrophobic jointing material stops the infiltration of water, and hydrophilic jointing material further improves the bond strength of block.
Hydrophilic tackiness agent is preferably selected from jointing material, hydrophilic polymer, soap and/or their mixture based on starch mutually.An example of this hydrophile adhesive mass is the mixture that comprises PVP polymkeric substance and sodium stearate.
Hydrophilic jointing material exists with the amount of the 0-60% that accounts for total binder phase weight.Preferably, hydrophobic jointing material: the ratio of hydrophilic jointing material is between 10: 1 and 1: 10, more preferably between 5: 1 and 1: 5, also more preferably between 4: 1 and 1: 2, most preferably between 2: 1 and 1: 1.
Described jointing material any or two kinds all can further comprise suitable rheology modifier.Preferably, rheology modifier exists with the concentration of 0-10%.Polymeric viscosifier is the example for the suitable rheology modifiers of vapor deposition silicon-dioxide or silicone oil (silica oil); The triglyceride level of hydrogenation or lipid acid are the examples for the suitable rheology modifiers of lipid acid and triglyceride level; And the example that is used for the suitable rheology modifier of anhydrous, hydrophobic oil is the 12-oxystearic acid.
Optional member
Hard surface cleaning block of the present invention can further comprise washing assistant (builder), dyestuff, spices, sunitizing (hygiene agent), antioxidant, free-radical scavengers, sequestrant, hydrotropic agent, inhibitor, opalizer, whitening agent, sanitas and/or abrasive.
Every kind of optional member (if existence) can be included in sanitising agent phase, tackiness agent mutually or these two mutually in.
Intermediate phase
For some purpose, separating tackiness agent by intermediate phase may be favourable with sanitising agent mutually mutually.This intermediate phase is passable, for example, exists to prevent interphase interaction, perhaps is used for improving alternate bonding.Intermediate phase is waterproof membrane preferably.Middle layer (when existing) is as protective layer, and it does not allow the water infiltration between tackiness agent phase and sanitising agent phase, thereby extra protection is provided mutually for tackiness agent.
Observe, sanitising agent mutually and tackiness agent have waterproof membrane between mutually, further improved during the flushing of wanting number of times and/or rinsing block to the adhesion of crust.
Intermediate phase can be polymeric film, solid barrier or any other known sealing coat.The suitable polymers film has description in co-pending application WO-02/090475 or WO-03/046119.Suitable non-sealing coat based on polymkeric substance can, for example find among EP-B-1 491 622, EP-B-1 522 575 or the EP-B-1 705 241.The thickness in middle layer is at least 50 microns, and preferably less than 500 microns.Most preferred scope is the 100-200 micron.If thickness is less than about 50 microns, tectal undercapacity is with protection adhesive (glue).Expensive and unhelpful during greater than 500 microns.
Perhaps, sanitising agent also can be surrounded by the mutually accompanying shell of tackiness agent (casing) mutually.This shell can be similar to for the common type of toilet with most of outer covers (housing cage) of solid block.
Block size and shape
The shape of hard surface cleaning block can influence the binding property of block.Preferably, block has hydrodynamic shape, and this helps to control better the ablation of block, and this helps better block to be adhered to the surface.Therefore, Yuan Xing smooth-shaped is because hydrodynamic property and than the square/rectangular block with sharp edges more preferably preferably.
The block time limit of service is directly related with prescription (formulation) and the size of block.The toilet block of normal size is generally about 40 grams between 30 to 50 grams.This block can stand at least 100 flushings usually, preferably surpasses 200 flushings.Block preferably stands up to about 300 flushings.
The aequum of tackiness agent phase is determined by the surface of detergent block.In order to form suitable binder layer mutually, the amount of adhesive phase material is preferably 0.01g/cm at least
2, 0.05g/cm at least more preferably
2, 0.1g/cm at least more preferably also
2, but preferably be no more than 1.5g/cm
2, more preferably no more than 0.3g/cm
2, also more preferably no more than 0.2g/cm
2
Using method
Hard surface cleaning block can be used to clean the crust of any kind of.Only surface is the surface that usually contacts with water, for example toilet surface, kitchen basin and shower tray.
Therefore, the invention provides a kind of method that makes bowl sanitation, it comprises the step that block of the present invention is applied to toilet surface.When sanitising agent ran out mutually, the residue of tackiness agent phase was preferably brushed away or is washed away.
The present invention further provides the method for dishwashing, it comprises and block of the present invention is applied to kitchen basin and with the step of tank water-filling.Therefore, water contacts with block, and the part sanitising agent is released in the water mutually.
The present invention further provides a kind of method of dishwashing, this method comprises the step that block of the present invention is applied to dish washing machine inside.
Binder layer of the present invention preferably is directly attached to crust mutually with sanitising agent.But scope of the present invention is not got rid of following situation: sanitising agent phase quilt cover holds, and cover is adhered to the surface.
Embodiment
Now by following non-restrictive example explaination the present invention.
Embodiment 1
Four embodiment (Adh 1-4) of the composition of tackiness agent phase provide in following table 1.
Table 1: tackiness agent phase composite (representing with %)
| Component | Adh 1 | Adh 2 | Adh 3 | Adh 4 |
| Vaseline | 24.1 | 40 | 35 | |
| Vaseline (mineral) oil | 19.6 | 5 | ||
| Carbopol 974 | 9.8 | |||
| Sunflower seed oil | 40 | |||
| The 12-oxystearic acid | 5 | |||
| Vapor deposition silicon-dioxide | 5 | |||
| PVP | 1.9 | |||
| CMC | 9.8 | 30 | 40 | 25 |
| The toxilic acid analog copolymer | 34.8 | 30 | 20 | 30 |
The tackiness agent of embodiment is preparation by the following method mutually.
By with about 60 ℃ of heating mixers, and with vaseline and
Be melted in (sunflower seed oil is fit to treated as such) in the mixing tank.Polymkeric substance and other components are added in the clarification melt and are slowly mixed to avoid any ventilation.If ventilation has during mixing taken place, then need before cooling, apply vacuum so that the mixture degassing.The material (mass) that is outgased can be poured onto to be used in the groove (application tank), and this material directly is extracted on the surface of product from using groove.The colorant composition can be added into tackiness agent to provide better properties to product with fragrance component.
Four embodiment (Det 1-4) of sanitising agent phase composite provide in following table 2.
Table 2: sanitising agent phase composite (representing with %)
| Component | Det 1 | Det 2 | Det 3 | Det 4 |
| Coconut oil soap (coco soap) | 28 | 15 | 15 | 24 |
| Sodium stearate | 25 | 10 | 16 | |
| Sodium oleate | 29 | |||
| The cocoyl sodium isethionate | 35 | 35 | ||
| α ethylenic sulfonate (alfa olefinesulfonate) | 3 |
| Stearic acid | 25 | 25 | ||
| The 12-oxystearic acid | 10 | |||
| Sucrose | ||||
| Glycerol | 5 | 5 | 10 | |
| Propylene glycol | 5 | 5 | 15 | |
| Water | 15 | 5 | 5 | 20 |
The sanitising agent of embodiment is preparation by the following method mutually.
Detergent block can be by conventional extrusion molding or the preparation of melt cast (melt casting) method, and method depends on the type of prescription.In extrusion molding, component is mixed together, and is extruded with stick (billet) form subsequently.These sticks are cut into the required size of block subsequently, and apply the tackiness agent phase.In the melt cast method, component is mixed and by being melted with the temperature heating that raises.Extra component, for example the colorant composition can be added into sanitising agent mutually in this stage with fragrance component, to provide better properties to product.Homogeneous mass (homogeneous mass) is poured onto in the mould subsequently and is cooled to room temperature to solidify.In case block is cured, tackiness agent is applied to block mutually.The amount of employed tackiness agent phase is about 100mg/cm
2
When being applied to toilet surface, tackiness agent phase (100mg/cm
2, derive from table 1) with sanitising agent mutually any combination of (40 gram, derive from table 1) be found to keep firmly being attached to the toilet staving, can experience at least 100 flushings.
After block runs out in dissolution process, by use toilet brush leniently friction surface remove the thin layer of tackiness agent phase.After scrubbing, do not stay residue on the surface.
Embodiment 2
In embodiment 2, use table 1 and 2 sanitising agent mutually with tackiness agent mutually, but by the middle layer that it is spaced now.
Middle layer among this embodiment is made up of the material (as disclosed in WO03/046119) that the uv based on epoxy acrylate solidifies, and bed thickness is about 100 microns.
Apply about 100mg/cm
2The tackiness agent phase.
When being administered to toilet surface, any combination that tackiness agent phase (deriving from table 1), intermediate phase and sanitising agent (derive from table 2) mutually is found between its whole usage period (for about 200 flushings) and keeps firmly being attached to the toilet staving.
After block runs out in dissolution process, by use toilet brush leniently friction surface remove the thin layer of tackiness agent phase.After scrubbing, do not stay residue on the surface.
Embodiment 3
Use is assembled the mensuration that texture analyser (texture analyser) that (rigged) be used for measuring horizontal force carries out bounding force.In this experiment, used Lloyd lntruments LRX Plus texture analyser.But similar texture analyser can obtain from for example Instron.
In these embodiments, three kinds of tackiness agent phase composites of the present invention have been compared.
Be assembled the bounding force that is used to measure different tackiness agent phase systems for the texture analyser of measuring horizontal force.The jointing material of 2g is applied to detergent block (smooth) bottom surface (15cm
2).The surface pressure that will have binder layer is investing on the ceramic surface of texture analyser.Be parallel to ceramic surface and move horizontally block, and the data of record compelling force (N).The required power (representing with N) of mobile detergent block provides in following table.
When 25 ℃ temperature T R, use Brookfield (RVT), utilize the axle (spindle) of TD-20.4mm, with the viscosity of the tachometric survey tackiness agent phase of 5rpm.The unit of viscosity is cps (mPa.s).
All experiments all repeat.Average provides in following table.
| Embodiment | Time (s) | Average vertical power (N) | Adhesive viscosity |
| A | 3.10 | 2.15 | 100,000cps |
| B | 3.95 | 2.60 | 300,000cps |
| C | 7.70 | 3.95 | 800,000cps |
The needed time of mobile block also is presented, with can force calculation (effort) (that is power * time=reactive force).
The detergent block that adheres to the staving of toilet is subjected to water currents when each flushing.Water is applied to this toilet block, and (front surface is 10cm
2) power be 0.3N.
In table, can find out, be applied to the bottom (15cm of this toilet block
2) binder phase thing of the present invention be suitable for such situation because the power of bounding force during than the water flush toilet is much bigger.
Claims (10)
1. self adhesive hard surface cleaning blocks, it comprises:
A. sanitising agent phase,
B. tackiness agent phase;
Wherein said tackiness agent comprises hydrophobic jointing material mutually, and this material comprises:
I.25-60% at least a hydrophobic compound of weight, described hydrophobic compound is selected from the non-polar solvent of natural oil or mineral oil, vaseline, blown oil, partially hydrogenated oil or fat, silicone oil, thickening or HLB less than 12 nonionic surface active agent and their combination, and its total fusing point is 30-60 ℃; With
The insoluble polymer of ii.5-75% weight, described polymkeric substance are selected from natural and synthetic cellulose polymer compound, polyacrylic ester, polyvinylpyrrolidone, toxilic acid/ethylenic copolymer and their mixture,
Wherein said tackiness agent is suitable for sanitising agent is invested crust mutually mutually.
2. the cleaning block of claim 1, wherein said is that front surface is 10cm
2Toilet block, and discharge the required power of block greater than 0.3N from the surface.
3. claim 1 or 2 cleaning block, wherein said tackiness agent further comprises hydrophilic jointing material mutually.
4. the cleaning block of claim 3, wherein said hydrophilic jointing material is selected from viscosity hydrophilic polymer and/or their combination.
5. claim 1 or 2 cleaning block, wherein said hydrophobic jointing material further comprises rheology modifier.
6. the cleaning block of claim 3, wherein said hydrophilic jointing material further comprises rheology modifier.
7. claim 1 or 2 cleaning block, wherein said tackiness agent further comprises tensio-active agent mutually.
8. claim 1 or 2 cleaning block, it further is included in described sanitising agent mutually and the intermediate phase of described tackiness agent between mutually.
9. method that makes bowl sanitation, it comprises the step that each described cleaning block of claim 1-7 is applied to toilet surface.
10. the method for claim 9, wherein when described sanitising agent ran out mutually, the residue of described tackiness agent phase was brushed away easily or is washed away.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06124234.3 | 2006-11-16 | ||
| EP06124234 | 2006-11-16 | ||
| PCT/EP2007/061823 WO2008058853A1 (en) | 2006-11-16 | 2007-11-02 | Self adhesive hard surface cleaning block |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101535463A CN101535463A (en) | 2009-09-16 |
| CN101535463B true CN101535463B (en) | 2013-07-17 |
Family
ID=37965037
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007800422321A Expired - Fee Related CN101535463B (en) | 2006-11-16 | 2007-11-02 | Self adhesive hard surface cleaning block |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP2082020B1 (en) |
| CN (1) | CN101535463B (en) |
| AR (1) | AR063824A1 (en) |
| AU (1) | AU2007321362B2 (en) |
| BR (1) | BRPI0718778B1 (en) |
| CL (1) | CL2007003287A1 (en) |
| HK (1) | HK1134517A1 (en) |
| MX (1) | MX2009005178A (en) |
| MY (1) | MY153644A (en) |
| PL (1) | PL2082020T3 (en) |
| RU (1) | RU2443770C2 (en) |
| UA (1) | UA97967C2 (en) |
| WO (1) | WO2008058853A1 (en) |
| ZA (1) | ZA200902458B (en) |
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|---|---|---|---|---|
| US7709433B2 (en) | 2007-02-12 | 2010-05-04 | S.C. Johnson & Son, Inc. | Self-sticking disintegrating block for toilet or urinal |
| EA019083B1 (en) * | 2007-04-16 | 2014-01-30 | Юнилевер Н.В. | Toilet cleaning block |
| US8980813B2 (en) | 2008-02-21 | 2015-03-17 | S. C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion on a vertical hard surface and providing residual benefits |
| US9410111B2 (en) | 2008-02-21 | 2016-08-09 | S.C. Johnson & Son, Inc. | Cleaning composition that provides residual benefits |
| US8993502B2 (en) | 2008-02-21 | 2015-03-31 | S. C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion to a vertical hard surface and providing residual benefits |
| ES2422261T5 (en) | 2008-02-21 | 2017-05-12 | S.C. Johnson & Son, Inc. | Cleaning composition that has high self-adhesion and provides residual benefits |
| US8143206B2 (en) | 2008-02-21 | 2012-03-27 | S.C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion and providing residual benefits |
| US9481854B2 (en) | 2008-02-21 | 2016-11-01 | S. C. Johnson & Son, Inc. | Cleaning composition that provides residual benefits |
| US8835371B2 (en) | 2008-02-29 | 2014-09-16 | Buck-Chemie Gmbh | Adhesive agent for application on a sanitary object |
| DE102008012092A1 (en) * | 2008-02-29 | 2009-09-10 | Buck- Chemie Gmbh | Agent, useful e.g. as cold adhesive in sanitary applications, comprises fillers comprising a surfactant and a bonding agent comprising e.g. polyalkylene derivative, polyalkylene chains and polyglycerin polyether alkyl carbonic acid |
| US8444771B2 (en) | 2008-02-29 | 2013-05-21 | Buck-Chemie Gmbh | Method for cleaning and/or deodorizing toilet bowl or urinal using an adhesive agent |
| DK2275524T3 (en) | 2008-02-29 | 2012-01-30 | Buck Chemie Gmbh | Adhesive for application to a sanitary object |
| ITMI20081202A1 (en) * | 2008-06-30 | 2010-01-01 | Bolton Manitoba S P A | PRODUCT ADHESIVE DETERGENT AND DEVICE CONTAINER AND APPLICATOR FOR THIS PRODUCT |
| US7919447B1 (en) | 2010-03-12 | 2011-04-05 | S.C. Johnson, Inc | Array of self-adhesive cleaning products |
| WO2012119838A1 (en) | 2011-03-04 | 2012-09-13 | Unilever Nv | Self-adhesive hard surface cleaning composition |
| GB2502763B (en) | 2011-10-14 | 2016-09-28 | Jeyes Group Ltd | An Applicator for a sanitary ware surface |
| CN104093826B (en) | 2012-01-20 | 2017-12-01 | 荷兰联合利华有限公司 | The hard-surface cleaning compositions of foam enhancing |
| EP3187194A1 (en) * | 2012-07-16 | 2017-07-05 | Reckitt Benckiser LLC | Self-adhesive lavatory treatment compositions |
| DE102012106742A1 (en) | 2012-07-25 | 2014-01-30 | Geting Solutions Gmbh | Piece-shaped agent for application to a sanitary object |
| US9376793B2 (en) | 2012-11-09 | 2016-06-28 | Reckitt Benckiser Llc | Single use, foldable dispenser for an adhesive lavatory treatment composition |
| DE102012224159A1 (en) * | 2012-12-21 | 2014-06-26 | Henkel Ag & Co. Kgaa | Self-adhesive detergent strip for hard surfaces |
| DE102013108019B3 (en) * | 2013-07-26 | 2014-08-28 | Buck-Chemie Gmbh | Adhesive agent for application to a sanitary article |
| DE102013226523A1 (en) * | 2013-12-18 | 2015-06-18 | Henkel Ag & Co. Kgaa | Cleaning block for hard surfaces |
| US10196591B2 (en) * | 2015-07-10 | 2019-02-05 | S. C. Johnson & Sons, Inc. | Gel cleaning composition |
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| CA2298105A1 (en) * | 1997-12-30 | 2000-05-07 | Henkel Kommanditgesellschaft Auf Aktien | Dishwasher detergent shaped bodies containing chlorine bleaching agents |
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| JP3743864B2 (en) * | 1995-04-03 | 2006-02-08 | 小林製薬株式会社 | Toilet toilet cleaner |
| ATE242312T1 (en) * | 1998-07-17 | 2003-06-15 | Procter & Gamble | DETERGENT TABLET |
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| DE10336796B4 (en) * | 2003-08-08 | 2005-05-19 | Henkel Kgaa | Washing or cleaning agents |
| ES2285350T5 (en) * | 2004-01-08 | 2011-06-17 | Unilever N.V. | PADS FOR TOILETS. |
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- 2007-11-02 WO PCT/EP2007/061823 patent/WO2008058853A1/en active Application Filing
- 2007-11-02 ZA ZA200902458A patent/ZA200902458B/en unknown
- 2007-11-02 UA UAA200906092A patent/UA97967C2/en unknown
- 2007-11-02 MX MX2009005178A patent/MX2009005178A/en active IP Right Grant
- 2007-11-02 RU RU2009122702/04A patent/RU2443770C2/en active
- 2007-11-02 EP EP07847106A patent/EP2082020B1/en active Active
- 2007-11-02 PL PL07847106T patent/PL2082020T3/en unknown
- 2007-11-02 BR BRPI0718778-5A patent/BRPI0718778B1/en not_active IP Right Cessation
- 2007-11-02 CN CN2007800422321A patent/CN101535463B/en not_active Expired - Fee Related
- 2007-11-02 AU AU2007321362A patent/AU2007321362B2/en not_active Ceased
- 2007-11-02 MY MYPI20091978A patent/MY153644A/en unknown
- 2007-11-15 AR ARP070105073A patent/AR063824A1/en active IP Right Grant
- 2007-11-15 CL CL200703287A patent/CL2007003287A1/en unknown
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2009
- 2009-12-15 HK HK09111771.3A patent/HK1134517A1/en not_active IP Right Cessation
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CA2298105A1 (en) * | 1997-12-30 | 2000-05-07 | Henkel Kommanditgesellschaft Auf Aktien | Dishwasher detergent shaped bodies containing chlorine bleaching agents |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2007321362B2 (en) | 2010-09-02 |
| CL2007003287A1 (en) | 2008-06-20 |
| ZA200902458B (en) | 2010-07-28 |
| RU2009122702A (en) | 2010-12-27 |
| PL2082020T3 (en) | 2012-11-30 |
| CN101535463A (en) | 2009-09-16 |
| RU2443770C2 (en) | 2012-02-27 |
| EP2082020A1 (en) | 2009-07-29 |
| MX2009005178A (en) | 2009-05-25 |
| UA97967C2 (en) | 2012-04-10 |
| BRPI0718778B1 (en) | 2017-11-21 |
| EP2082020B1 (en) | 2012-08-22 |
| HK1134517A1 (en) | 2010-04-30 |
| MY153644A (en) | 2015-03-13 |
| AR063824A1 (en) | 2009-02-18 |
| BRPI0718778A2 (en) | 2015-01-06 |
| WO2008058853A1 (en) | 2008-05-22 |
| AU2007321362A1 (en) | 2008-05-22 |
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