CN101525561A - Detergent for animal hair - Google Patents

Detergent for animal hair Download PDF

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CN101525561A
CN101525561A CN200910029574A CN200910029574A CN101525561A CN 101525561 A CN101525561 A CN 101525561A CN 200910029574 A CN200910029574 A CN 200910029574A CN 200910029574 A CN200910029574 A CN 200910029574A CN 101525561 A CN101525561 A CN 101525561A
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hydrocarbon base
compound
composition
animal hair
carbonatoms
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CN101525561B (en
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小室利广
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ZHUBEN OIL (SUZHOU) CO Ltd
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ZHUBEN OIL (SUZHOU) CO Ltd
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Abstract

The invention relates to a detergent for animal hair, which comprises 45 percent to 85 percent of compound 1 coinciding with a general formula (I), 10 percent to 40 percent of compound 2 coinciding with a general formula (II) and of 5 percent to 15 percent of compound 3 coinciding with a general formula (III), wherein R<1> represents the hydrocarbon base with the carbon number of 1 to 16; R<2> represents the hydrocarbon base with the carbon number of 1 to 16; n represents the repeated unit number of 3 to 12; R<3> represents the hydrocarbon base with the carbon number of 11 to 17; R<4> represents the hydrogen atom or the hydroxyl alkyl with the carbon atom number of 8 to 18; R<5> represents the hydrocarbon base with the carbon atom number of 1 to 6; R<6> represents the hydrocarbon base with the carbon atom number of 8 to 18; q and r respectively represent the integer 1 or 2, and q+r=3; and x represents alkali metal or amine. The invention has strong detergency under the condition of low temperature even under the condition of low concentration, and can simultaneously give softness and antistatic property to animal hair after detergency is over; so the invention provides a detergent product with excellent quality.

Description

Detergent for animal hair
Technical field
The present invention relates to a kind of detergent for animal hair, the grease, the dust that are mainly used in adhering on the animal hair fibre wash, and after cleaning, give animal hair with flexibility and static resistance.
Background technology
On the animal hairs such as wool, Aloysia gratissima alpaca, down goat suede, mohair, Angora goat fine hair, adhere to a kind of natural fats and oils that is called lubricating grease.In addition, because these animals in outdoor life, have dust, microorganism etc. are attached on the animal hair.Therefore before the processing animal hair, for example before the weaving operation of producing of spinning, generally to clean it.At present, the clean-out system that uses has the clean-out system (referring to Patent Document 1) that contains polyoxyethylene-2-heptyl 11 ethers, but the shortcoming of this clean-out system is: one, because clean scarce capacity, lubricant component residual on the animal hair fibre of washing back is still many, and scent of is residual, thereby make through the product after cleaning when prolonged preservation, because of corrupt stink generation or the see-through of causing reduces, in the weaving operation, produce problems such as fiber curling round the roll.If two in order to remedy the cleansing power deficiency, and improve clean-out system concentration the time, the foaming degree can increase the weight of, scavenging solution cognition is overflowed from rinse bath, the equipment of not only making dirty causes Working environment to worsen, and bring difficulty also can for the cleaning of fiber, need carry out long rinse, thereby make operation decline.If three carry out the repeated washing method 2 times with common concentration, can make cleaning operation become complicated, and clean the cost height, also many to the damage of animal hair, make its quality of animal hair that finally obtains also greatly descend.
As the better clean-out system of cleaning performance, the nonionogenic tenside (referring to Patent Document 2) of phenol alkyl series is arranged.But these materials might be to upset endocrine chemical substance (internal secretion destruction thing) and human body is damaged.Therefore, need a kind of animal hair clean-out system of upsetting internal secretion chemical substance (internal secretion destruction thing) that do not contain.
[patent documentation 1] spy opens clear 61-60794
The clear 1-192870 of [patent documentation 2] Te Kaiping
Summary of the invention
The object of the invention provides a kind of detergent for animal hair, and purpose is to solve existing detergent for animal hair cleansing power deficiency, and to contain might be the problem that upsets endocrine chemical substance.
For achieving the above object, the technical solution used in the present invention is: a kind of detergent for animal hair is made of the composition of following quality percentage composition:
A composition 45%～85%;
B composition 10%～40%;
C composition 5%～15%;
The A composition is the compound 1 of general molecular formula (I):
Figure A20091002957400041
The B composition is the compound 2 of general molecular formula (II):
Figure A20091002957400042
The C composition is the compound 3 of general molecular formula (III):
Wherein, R 1Representing carbonatoms is 1～16 hydrocarbon base;
R 2Representing carbonatoms is 1～16 hydrocarbon base;
N repeateding unit several 3～12;
R 3Representing carbonatoms is 11～17 hydrocarbon base;
R 4Represent hydrogen atom, perhaps carbonatoms is 1～6 hydroxide radical alkyl;
R 5Representing carbonatoms is 1～6 hydrocarbon base;
R 6Representing carbonatoms is 8～18 hydrocarbon base;
Q, r represent integer 1 or 2 respectively, and q+r=3;
X represents basic metal or amine.
Related content in the technique scheme is explained as follows:
1, in the such scheme, the compound 1 of described general molecular formula (I), R 1Carbonatoms and R in the hydrocarbon base of representative 2Carbonatoms in the hydrocarbon base of representative adds up to 7～17, n repeateding unit several 5～10.
2, in the such scheme, the compound 3 of described general molecular formula (III), R 6Representing carbonatoms is 8～12 hydrocarbon base; X represent sodium or potassium.
3, in the such scheme, the compound 1 of described general molecular formula (I) is to add in secondary alcohol that oxyethane carries out addition reaction and the compound that generates.As secondary alcohol, what can list has isooctyl alcohol (C8), isodecyl alcohol (C10), different lauryl alcohol (C12), different tridecanol (C13), different tetradecyl alcohol (C14), an i-octadecanol (C18), in the middle of these materials, isooctyl alcohol (C8), isodecyl alcohol (C10), different lauryl alcohol (C12), different tridecanol (C13) effect are particularly evident.In addition, the average addition unit number of oxyethane (is CH 2CH 2The number of repeat unit of O) n is 3～12, and wherein n is 5～10 the bests.
4, in the such scheme, the compound 2 of described general molecular formula (II) is the product that lipid acid and alkylolamide reaction back are generated, and its effect mainly is to clean animal hair, but also can give fiber with flexibility simultaneously.As the lipid acid object lesson that constitutes B composition raw material, can list unsaturated fatty acidss such as dodecylic acid (C12), tetradecanoic acid (C14), Palmiticacid (C16), stearic acid saturated fatty acids such as (C18), oleic acid (C18 '), linolic acid (C18 "), linolenic acid (C18 " ').In addition, lipid acid both can be vegetal, also can be the natural lipid acid or the synthetic lipid acid in animality source.As alkylolamide, can list Monoethanolamine MEA BASF, diethanolamine, Yi Bingchunan, diisopropanolamine (DIPA) etc.
5, in the such scheme, the compound 3 of described general molecular formula (III) is an alkyl phosphate salt, if its quality percentage composition surpasses 15%, clean effect can reduce.As the employed feedstock fat alcohol of C composition octanol (C8), decyl alcohol (C10), dodecanol (C12), cetyl alcohol (C16), Stearyl alcohol materials such as (C18) are arranged, these materials can be used alone or as a mixture, consider from the static resistance this point, preferably use octanol (C8), decyl alcohol (C10), dodecanol (C12).In addition, the X in the C composition is basic metal or amine preferably, and potassium or sodium are good especially.Particularly consider, preferably use sodium from static resistance.
6, in the such scheme, treatment agent of the present invention is the compound that is made of A composition 45～80 quality % discussed above, B composition 10～45 quality % and C composition 5～15 quality %.
7, in the such scheme, detergent for animal hair water soluble of the present invention uses.Generally use with 0.05～2.0% mass concentration, relatively more appropriate.In addition, cleaning temperature can be about 10～70 ℃, and preferably 40～60 ℃, 45～55 ℃ are used better down.The hardness of scavenging solution does not have actual influence to degreasing power, at 0.5kg/m 3About high hardness water in also can use, with inorganic salt such as yellow soda ash and with also can.When using inorganic salt, 0.02～0.10 quality % uses according to its concentration.
8, by the use of treatment agent of the present invention, not only grease, the dust that adheres on the animal hair had very strong cleaning force, and can control foaming when cleaning, rinse foamy operability is improved, during cleaning, do not need a large amount of water, can shorten the treatment time, reduce processing cost.In addition, after the cleaning, can give animal hair with flexibility and static resistance.Clean-out system of the present invention is applicable to for example cleaning of animal hairs such as wool, Aloysia gratissima alpaca, down goat suede, mohair, Angora goat fine hair.
9, in the such scheme, described hydrocarbon base had both comprised that alkyl also comprised alkylene.
10, in the such scheme, described hydroxide radical alkyl is meant the residue of removing on the carbochain of Fatty Alcohol(C12-C14 and C12-C18) behind the hydrogen atom, as: HOCH 2CH 2-.
Because the technique scheme utilization, the present invention compared with prior art has following advantage and effect:
The present invention is under cold condition, even the situation of lower concentration also has very strong clearing power to animal hair, after cleaning simultaneously, can give animal hair with flexibility and static resistance, thereby cleaning products of fine qualities is provided.
Embodiment
Below in conjunction with drawings and Examples the present invention is further described:
Embodiment one: a kind of detergent for animal hair
Making method: taken by weighing compound 1, compound 2 and compound 3 according to the prescription shown in the table 1No.1 and used water dissolution, added the yellow soda ash of 0.05% (quality percentage composition) then, finally made scavenging solution.With the scavenging solution that makes wool is cleaned then.
Cleaning process: 64 ' S merino kind wool 10.0g (lubricant component=10.7%) is put in the scavenging solution of 1000ml, soaked the back and clean in 10 minutes.After cleaning, carry out 30 minutes rinsing with flowing water after, carry out centrifuge dehydration (1000rpm, 1 minute).In 105 ℃ drying machine dry 1 hour afterwards.
Result's detection: the wool that cleans the back acquisition is investigated according to Oil and Fat Content, flexibility and three indexs of static resistance.
1, the detection method of Oil and Fat Content is: the wool after will cleaning as solvent, adopts the extraction of rope lattice Z-TEK extraction method with diethyl ether, calculates Oil and Fat Content according to following calculating formula, again according to following standard, judges spatter property.
Judging criterion:
◎: Oil and Fat Content is less than 1.0%;
Zero: Oil and Fat Content is more than 1.0%, and discontented 1.5%;
*: Oil and Fat Content is more than 1.5%.
2, the woolen flexibility after the cleaning, it is fixed to adopt organoleptic test's's (hand touch) method to judge by 10 men and women.Judging criterion:
◎: flexibility is very good;
Zero: flexibility is good;
*: flexibility is bad.
3, the woolen static resistance after cleaning can be when measuring silk by small-sized cotton card (big and machine worker Co., Ltd. product, model SC200), and the static content of generation is judged.Static resistance is that test portion was placed 2 days under 25 ℃, the environment of 50%RH, after carrying out humidity control, (big and machine worker Co., Ltd. produces with small-sized cotton card to allow it pass through test, model SC200), (Kasuga Electric K. K. produces to detect the static content that is produced this moment with the current collection pipe, model KS-525), judge static resistance according to following standard again:
◎: below the 3KV;
Zero: more than the 3KV, and discontented 7KV;
*: more than the 7KV.
Detected result gathers shown in table 5No.1
Embodiment two～75: a kind of detergent for animal hair
Making method, cleaning process and result's detection is with embodiment one, and prescription is shown in No.2～No.75 in table 1～table 3.Detected result is shown in No.2～No.75 in table 5～table 7.
Comparative example one～22
Making method, cleaning process and result's detection is with embodiment one, and prescription is shown in No.1～No.22 in the table 4.Detected result is shown in No.1～No.22 in the table 8.
Table 1
Figure A20091002957400081
In table 1
No.1～No.8: clean temperature=45 ℃, washing lotion concentration=0.1%
No.9～No.15: clean temperature=45 ℃, washing lotion concentration=0.3%
No.16～No.25: clean temperature=45 ℃, washing lotion concentration=0.5%
17, the expression carbonatoms is 17 hydrocarbon base, and a carbon-carbon double bond is arranged on the carbochain; 17 " the expression carbonatoms is 17 hydrocarbon base, and two carbon-carbon double bonds are arranged on the carbochain
Table 2
Figure A20091002957400091
In table 2
No.26～No.37: clean temperature=50 ℃, washing lotion concentration=0.3%
No.38～No.50: clean temperature=50 ℃, washing lotion concentration=0.3%
Table 3
Figure A20091002957400101
In table 3
No.51～No.58: clean temperature=55 ℃, washing lotion concentration=0.1%
No.59～No.65: clean temperature=55 ℃, washing lotion concentration=0.3%
No.66～No.75: clean temperature=55 ℃, washing lotion concentration=0.5%
Table 4
Figure A20091002957400111
In the table 4
No.1～No.25: temperature=55 ℃, washing lotion concentration=0.5% time implement cleaning.
Table 5
No. Cleanliness Flexibility Static resistance
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎
Table 6
No. Cleanliness Flexibility Static resistance
26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎
Table 7
No. Cleanliness Flexibility Static resistance
51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○
Table 8
No. Cleanliness Flexibility Static resistance
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 ○ ○ ○ ○ ○ ○ × × × × ○ ○ ○ × × × × ◎ ○ × × × × × × × × × × × × × × × × × × × × × × × × × × × × × × × ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ × × × ○ ○
The foregoing description only is explanation technical conceive of the present invention and characteristics, and its purpose is to allow the personage who is familiar with this technology can understand content of the present invention and enforcement according to this, can not limit protection scope of the present invention with this.All equivalences that spirit is done according to the present invention change or modify, and all should be encompassed within protection scope of the present invention.

Claims (3)

1, a kind of detergent for animal hair is characterized in that: the composition by following quality percentage composition constitutes:
A composition 45%～85%;
B composition 10%～40%;
C composition 5%～15%;
The A composition is the compound 1 of general molecular formula (I):
The B composition is the compound 2 of general molecular formula (II):
The C composition is the compound 3 of general molecular formula (III):
Figure A2009100295740002C3
Wherein, R 1Representing carbonatoms is 1～16 hydrocarbon base;
R 2Representing carbonatoms is 1～16 hydrocarbon base;
N repeateding unit several 3～12;
R 3Representing carbonatoms is 11～17 hydrocarbon base;
R 4Represent hydrogen atom, perhaps carbonatoms is 1～6 hydroxide radical alkyl;
R 5Representing carbonatoms is 1～6 hydrocarbon base;
R 6Representing carbonatoms is 8～18 hydrocarbon base;
Q, r represent integer 1 or 2 respectively, and q+r=3;
X represents basic metal or amine.
2, detergent for animal hair according to claim 1 is characterized in that: the compound 1 of described general molecular formula (I), R 1Carbonatoms and R in the hydrocarbon base of representative 2Carbonatoms in the hydrocarbon base of representative adds up to 7～17, n repeateding unit several 5～10.
3, detergent for animal hair according to claim 1 is characterized in that: the compound 3 of described general molecular formula (III), R 6Representing carbonatoms is 8～12 hydrocarbon base; X represent sodium or potassium.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102041187A (en) * 2010-12-22 2011-05-04 傅科杰 Raw wool scouring agent
CN108559648A (en) * 2018-06-19 2018-09-21 浙江永金生物科技有限公司 A kind of ecology Wool detergent and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102041187A (en) * 2010-12-22 2011-05-04 傅科杰 Raw wool scouring agent
CN108559648A (en) * 2018-06-19 2018-09-21 浙江永金生物科技有限公司 A kind of ecology Wool detergent and preparation method thereof

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