CN101492582A - Code-jet printing ink modifier - Google Patents
Code-jet printing ink modifier Download PDFInfo
- Publication number
- CN101492582A CN101492582A CN 200810081412 CN200810081412A CN101492582A CN 101492582 A CN101492582 A CN 101492582A CN 200810081412 CN200810081412 CN 200810081412 CN 200810081412 A CN200810081412 A CN 200810081412A CN 101492582 A CN101492582 A CN 101492582A
- Authority
- CN
- China
- Prior art keywords
- code
- printing ink
- jet printing
- weight percent
- total weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention relates to a code spraying ink modifying agent which comprises the components with weight percentage: 20-60wt% of solvent, 10-40wt% of latent solvent, 1-10wt% of anticoagulant, 1-10wt% of electrical conduction control agent, 0.1-6wt% of pH conditioning agent, 5-15wt% of adhesive force promoting agent, 0.1-4wt% of osmotic agent, 0.5-9wt% of stabilizing agent and 0.1-5wt% of coloring agent. The anticoagulant and the latent solvent contained in the code spraying ink modifying agent can effectively improve the phenomenon that a nozzle is easy to plug by code spraying ink, and ensures the code spraying ink to be dried rapidly and print more clearly and smoothly; the contained adhesive force promoting agent can be used for strengthening the adhesiveness of the code spraying ink for base material, especially metal base material, so as to lead the image to be firmer and hard wearing. Various auxiliary agents in the invention are matched for use, so that the performance of the code spraying ink can be effectively enhanced, the image resolution ratio is improved, the separation of ink dots is clear, the problem of trickling and deforming of the ink can be solved, and the corrosion resistance is improved.
Description
Technical field
The present invention relates to a kind of printing-ink properties-correcting agent, be specifically related to a kind of properties-correcting agent of code-spraying printing ink, be mainly used in the every application performance that improves code-spraying printing ink.
Background technology
In the use of code-spraying printing ink, printing ink on various substrate medium, is formed marks such as figure, coding, letter, date by continuous ink jet printing.In this process, what require that code-spraying printing ink can be continuous, even, clear, firm is printed on the medium.For this reason, viscosity, volatility, adhesion property, acid-basicity, the electroconductibility to printing ink all has higher requirement.
Existing code-spraying printing ink can be divided into quick-dry type printing ink, middle dry type printing ink and slow curing type printing ink, and along with the raising of printing efficiency, quick-dry type printing ink has obtained using widely.The shortcoming of quick-dry type printing ink is easy blocking pipeline and shower nozzle at present, has had a strong impact on efficient and the quality printed.There is research to add the polymer wetting agent before this and solves blockage problem, but the adding of polymer wetting agent can influence the volatility of printing ink again, thereby influence the rate of drying of printing ink and the crocking resistance of image, this problem affects the quality and the efficient of code-spraying printing ink printing always.
In the code-spraying printing ink printing, usually need on metallic matrix, print.But metallic matrix is smooth, surface adhesion force is poor, ink indicia easy deformation and wearing and tearing after the spraying.There is research in code-spraying printing ink, to add a certain amount of functional agent before this and improves the adhesive ability of printing ink matrixes such as plastics, glass.Special research at the metallic matrix tack is not arranged at present.
Summary of the invention
The objective of the invention is in order to address the above problem, a kind of code-jet printing ink modifier is provided, this code-jet printing ink modifier in use, print smooth, rate of drying is fast, does not stop up shower nozzle, does not corrode shower nozzle, coding clear picture, firm, wear-resisting has good tack to base material, especially metal base.
Code-jet printing ink modifier of the present invention comprises:
(1) it is 20-60% that solvent, its content account for the code-jet printing ink modifier total weight percent;
(2) it is 10-40% that solubility promoter, its content account for the code-jet printing ink modifier total weight percent;
(3) it is 1-10% that anti, its content account for the code-jet printing ink modifier total weight percent;
(4) it is 1-10% that conductivity control agent, its content account for the code-jet printing ink modifier total weight percent;
(5) it is 0.1-6% that acid-basicity conditioning agent, its content account for the code-jet printing ink modifier total weight percent;
(6) it is 5-15% that sticking power promotor, its content account for the code-jet printing ink modifier total weight percent;
(7) it is 0.1-4% that permeate agent, its content account for the code-jet printing ink modifier total weight percent;
(8) it is 0.5-9% that stablizer, its content account for the code-jet printing ink modifier total weight percent;
(9) it is 0.1-5% that tinting material, its content account for the code-jet printing ink modifier total weight percent.
Be elaborated with regard to each component of this code-jet printing ink modifier respectively below.
Used solvent among the present invention comprises acetone, butanone, pimelinketone, cyclopentanone, ethylene glycol monobutyl ether, ethylene glycol monomethyl ether, ethylene glycol monoemethyl ether, ethylene glycol monobutyl ether, trichloromethane, methylene dichloride, tetracol phenixin, tetrahydrofuran (THF), dioxane, pyridine, normal hexane, normal heptane, 1,2-ethylene dichloride, N, dinethylformamide, N,N-dimethylacetamide, the only methyl ether of propylene glycol, the only ether of propylene glycol, gamma-butyrolactone, trieline, benzene, dimethylbenzene, toluene, or its mixture.It is 20-60% that usage quantity accounts for the code-jet printing ink modifier total weight percent.The viscosity that consumption is less than 20% system is too high, makes troubles to use; Consumption is higher than at 60% o'clock, and the effect of properties-correcting agent is not obvious.
Used solubility promoter among the present invention comprises glycol ether, glycerol, polyoxyethylene glycol, phenylcarbinol, vinyl acetic monomer, N-BUTYL ACETATE, Iso Butyl Acetate, the only methyl ether acetate of propylene glycol, the ethylene glycol monomethyl ether acetic ester, diethyl phthalate, dibutyl phthalate, propylparaben, ethyl ethoxy-c acid esters, methyl ethoxy propionic ester, Methyl glutarate or its mixture.Its usage quantity accounts for the 10-40% of code-jet printing ink modifier total weight percent.
Used anti among the present invention comprises N-trihalogenmethyl sulfo-phthalic imidine, N-(2,4, the 6-trichlorophenyl) maleimide, 2,5-dithiocyano thiophene, N, N-dimethyl dichlorophenyl urea or its mixture.Its usage quantity accounts for the 1-10% of code-jet printing ink modifier total weight percent.
Used conductivity control agent among the present invention comprises potassium bisulfide, lithium nitrate, Tetrabutyl amonium bromide or its mixture.Its usage quantity accounts for the 1-10% of code-jet printing ink modifier total weight percent.
Used acid-basicity conditioning agent among the present invention comprises sodium hydroxide, potassium hydroxide, sodium bicarbonate, yellow soda ash etc. or its mixture.Its usage quantity accounts for the 0.1-6% of code-jet printing ink modifier total weight percent.
Used sticking power promotor is an organosilicon alkanes coupling agent among the present invention, comprise polydimethylsiloxane, polyether-modified dimethyl siloxane, aminosiloxane, vinylsiloxane or its mixture, its usage quantity accounts for the 5-15% of code-jet printing ink modifier total weight percent.
Used permeate agent among the present invention comprises dioctyl phthalate (DOP), Tritolyl Phosphate, xylenylphosphate, dioctyl maleate sodium sulfonate or its mixture.Its usage quantity accounts for the 0.1-4% of code-jet printing ink modifier total weight percent.
Used stablizer among the present invention comprises 2-pyridine thiol-1-zinc oxide, 2-pyridine thiol-1-cupric oxide, and dimethyl sulphide is for carbaminate or its mixture.Its usage quantity accounts for the 0.5-9% of code-jet printing ink modifier total weight percent.
Used tinting material among the present invention comprises metallized dye, and alkalescence is purple, malachite green, eosin, oil soluble is black, oil soluble palm fibre, Victoria's ethereal blue, methylene blue, oil soluble is red, Viola crystallina, alkaline bright yellow, Luo Daming B, magenta, vesuvine, indigo, the blue B of oil soluble, xylenol blue, Nile blue A, ethyl violet, Congo red, m-cresol purple, Rose Bengale B, 1-phenyl-3-methyl-4-is to diethylin phenylimino-5-pyrazolone etc. or its mixture.Its usage quantity accounts for the 0.1-5% of code-jet printing ink modifier total weight percent.
The invention has the advantages that the code-jet printing ink modifier of forming by various suitable supplementary additives, can effectively improve the performance of code-spraying printing ink.Wherein solubility promoter and scale inhibitor be used the phenomenon that can effectively solve spray nozzle clogging because the boiling point of solubility promoter is higher, can play certain wetting effect, prevent the ink-jet pipeline that the quick volatilization of printing ink causes and the latch up phenomenon of nozzle; Can reduce simultaneously the surface tension of code-spraying printing ink, make its surface tension less than 28mN.m
-1, make ink-jet can form effective drop, improve imaging effect.In addition, this solubility promoter also has certain polarity, and anti-static electrification is arranged, and can prevent " spittle " phenomenon of coding image.Being used of various auxiliary agents among the present invention strengthened the combine fastness of code-spraying printing ink with metal base, makes the clear picture of printing firm, be difficult for fuzzy, difficult drop-off, burnish resistance is strong.Ink application wearability test instrument detects, and the result makes the wear resistance of jetted ink increase by 20% after showing use code-jet printing ink modifier of the present invention.
Embodiment
The present invention will describe more specifically by following examples, but the present invention is not limited in these embodiment.
Embodiment 1
A kind of code-jet printing ink modifier is made up of following component and content
Ethylene glycol monomethyl ether 40%
Pimelinketone 15%
The only methyl ether acetate 30% of propylene glycol
N-trihalogenmethyl sulfo-phthalic imidine 5%
Tetrabutyl amonium bromide 2%
Sodium bicarbonate 1.5%
Polydimethylsiloxane 5.7%
Metallized dye black-29 0.8%
All percentage ratios are weight percentage
Embodiment 2
A kind of code-jet printing ink modifier is made up of following component and content
Trichloromethane 25%
The only methyl ether 25% of propylene glycol
The only methyl ether acetate 28% of propylene glycol
N-trihalogenmethyl sulfo-phthalic imidine 6%
Tetrabutyl amonium bromide 2%
Sodium bicarbonate 2.5%
Polydimethylsiloxane 6.9%
Dioctyl phthalate (DOP) 3.8%
Metallized dye black-29 0.8%
All percentage ratios are weight percentage
Embodiment 3
A kind of code-jet printing ink modifier is made up of following component and content
Ethylene glycol monomethyl ether 58%
The only methyl ether acetate 25% of propylene glycol
2,5-dithiocyano thiophene 5%
Tetrabutyl amonium bromide 2%
Sodium bicarbonate 2%
Polyether-modified dimethyl siloxane 5.3%
2-pyridine thiol-1-zinc oxide 1.9%
Metallized dye indigo plant-5 0.8%
All percentage ratios are weight percentage.
Claims (9)
1, a kind of code-jet printing ink modifier, this code-jet printing ink modifier comprises:
(1) it is 20-60% that solvent, its content account for the code-jet printing ink modifier total weight percent;
(2) it is 10-40% that solubility promoter, its content account for the code-jet printing ink modifier total weight percent;
(3) it is 1-10% that anti, its content account for the code-jet printing ink modifier total weight percent;
(4) it is 1-10% that conductivity control agent, its content account for the code-jet printing ink modifier total weight percent;
(5) it is 0.1-6% that acid-basicity conditioning agent, its content account for the code-jet printing ink modifier total weight percent;
(6) it is 5-15% that sticking power promotor, its content account for the code-jet printing ink modifier total weight percent;
(7) it is 0.1-4% that permeate agent, its content account for the code-jet printing ink modifier total weight percent;
(8) it is 0.5-9% that stablizer, its content account for the code-jet printing ink modifier total weight percent;
(9) it is 0.1-5% that tinting material, its content account for the code-jet printing ink modifier total weight percent.
2, solvent according to claim 1 comprises acetone, methyl ethyl ketone, pimelinketone, cyclopentanone, vinyl acetic monomer, N-BUTYL ACETATE, Iso Butyl Acetate, ethylene glycol monobutyl ether, ethylene glycol monomethyl ether, ethylene glycol monoemethyl ether, methyl alcohol, ethanol, propyl carbinol, primary isoamyl alcohol, n-Octanol, propylene glycol, trichloromethane, methylene dichloride, tetracol phenixin, tetrahydrofuran (THF), dioxane, pyridine, N, dinethylformamide, N,N-dimethylacetamide, the only methyl ether of propylene glycol, the only ether of propylene glycol, gamma-butyrolactone, trieline, benzene, dimethylbenzene, toluene, 1,2-ethylene dichloride etc. or its mixture.
3, solubility promoter according to claim 1 comprises glycol ether, glycerol, the only methyl ether acetate of propylene glycol, ethylene glycol monobutyl ether, phenylcarbinol, the ethylene glycol monomethyl ether acetic ester, normal hexane, normal heptane, hexone, polyoxyethylene glycol, N-Methyl pyrrolidone, diethyl phthalate, dibutyl phthalate, propylparaben, ethyl ethoxy-c acid esters, methyl ethoxy propionic ester, Methyl glutarate or its mixture.
4, comprise anti according to claim 1, comprise N-trihalogenmethyl sulfo-phthalic imidine, N-(2,4, the 6-trichlorophenyl) maleimide, 2,5-dithiocyano thiophene, N, N-dimethyl dichlorophenyl urea etc. or its mixture.
5, conductivity control agent according to claim 1 comprises potassium bisulfide, lithium nitrate, Tetrabutyl amonium bromide etc. or its mixture; The acid-basicity conditioning agent comprises sodium hydroxide, potassium hydroxide, sodium bicarbonate, yellow soda ash etc. or its mixture.
6, sticking power promotor according to claim 1 comprises polydimethylsiloxane, polyether-modified dimethyl siloxane, aminosiloxane, vinylsiloxane or its mixture.
7, permeate agent according to claim 1 comprises dioctyl phthalate (DOP), Tritolyl Phosphate, dioctyl maleate sodium sulfonate etc. or its mixture.
8, stablizer according to claim 1 comprises 2-pyridine thiol-1-zinc oxide, 2-pyridine thiol-1-cupric oxide, and dimethyl sulphide is for carbaminate etc. or its mixture.
9, tinting material according to claim 1 comprises metallized dye, and alkalescence is purple, malachite green, eosin, oil soluble is black, oil soluble palm fibre, Victoria's ethereal blue, methylene blue, oil soluble is red, Viola crystallina, alkaline bright yellow, the bright B of Luo Da, magenta, vesuvine, indigo, the blue B of oil soluble, the thymol sulfonephthalein, xylenol blue, Nile blue A, ethyl violet, Congo red, m-cresol purple, Rose Bengale B, 1-phenyl-3-methyl-4-is to diethylin phenylimino-5-pyrazolone etc. or its mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200810081412 CN101492582B (en) | 2008-02-19 | 2008-02-19 | Code-jet printing ink modifier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200810081412 CN101492582B (en) | 2008-02-19 | 2008-02-19 | Code-jet printing ink modifier |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101492582A true CN101492582A (en) | 2009-07-29 |
| CN101492582B CN101492582B (en) | 2013-05-01 |
Family
ID=40923379
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200810081412 Expired - Fee Related CN101492582B (en) | 2008-02-19 | 2008-02-19 | Code-jet printing ink modifier |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101492582B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103764764A (en) * | 2011-08-24 | 2014-04-30 | Dic株式会社 | Polyurethane polyurea resin composition, binder for printing inks, and printing ink |
| CN107011734A (en) * | 2017-04-24 | 2017-08-04 | 黄山市古城歙砚有限公司 | A kind of anti-agglomeration ink |
| CN109171709A (en) * | 2018-07-23 | 2019-01-11 | 京东方科技集团股份有限公司 | A kind of dry electrode and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3448577B2 (en) * | 2000-10-11 | 2003-09-22 | 日立マクセル株式会社 | Aqueous fluorescent ink composition |
| CN1534069A (en) * | 2003-03-31 | 2004-10-06 | 上海乐丽喷印技术有限公司 | Formula of acrylic resin code spray ink |
-
2008
- 2008-02-19 CN CN 200810081412 patent/CN101492582B/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103764764A (en) * | 2011-08-24 | 2014-04-30 | Dic株式会社 | Polyurethane polyurea resin composition, binder for printing inks, and printing ink |
| CN103764764B (en) * | 2011-08-24 | 2015-10-21 | Dic株式会社 | Polyurethane-polyurea resin combination, printing ink binding agent and printing ink |
| CN107011734A (en) * | 2017-04-24 | 2017-08-04 | 黄山市古城歙砚有限公司 | A kind of anti-agglomeration ink |
| CN109171709A (en) * | 2018-07-23 | 2019-01-11 | 京东方科技集团股份有限公司 | A kind of dry electrode and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101492582B (en) | 2013-05-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101602906B (en) | Clear ink composition | |
| CN101781519B (en) | Transparent anti-graffiti dirt-resistant anti-weathering coating | |
| CN107459871B (en) | 3D inkjet printings photocuring transparent ink and preparation method thereof | |
| US20090176071A1 (en) | Ink composition for ink jet recording | |
| JP2004526016A (en) | Water-resistant inkjet ink containing UV-curable resin | |
| TWI452093B (en) | Inkjet ink composition | |
| CN101652436B (en) | Nonaqueous inkjet ink composition | |
| CN102015923A (en) | Ink composition for inkjet recording | |
| JP5103799B2 (en) | Inkjet ink for polyvinyl chloride resin sheet | |
| US20090031922A1 (en) | Ink composition and method for forming the same | |
| JP2015196731A (en) | Oily ink composition for inkjet recording and inkjet recording method | |
| CN101928486A (en) | Ink composition for ink-jet recording | |
| US20120252948A1 (en) | Quick-drying and coating-free inkjet ink composition | |
| CN106366762A (en) | Pigment dispersion liquid for inkjet inks, active energy beam-curable inkjet ink, and print | |
| JP2012072355A (en) | Aqueous ink for inkjet, ink cartridge, and inkjet recording method | |
| CN101492582B (en) | Code-jet printing ink modifier | |
| JP2010111741A (en) | Water-based ink composition | |
| CN105199474A (en) | Metal sheet UV (ultraviolet curing) printing ink and use method of metal sheet UV printing ink | |
| CN107513309A (en) | Three-dimensionally shaped photocuring transparent ink composition and its preparation method and application | |
| US20210115280A1 (en) | Aqueous ink or lacquer composition for coating or printing a substrate | |
| CN113004818A (en) | Self-adhesion type polypropylene decoration film | |
| CN101790569B (en) | Ink composition for color filter, method for preparing a color filter using the same, and color filter | |
| CN105273486A (en) | Preparation method for water-based ink with fluorosilicone-modified acrylate core-shell emulsion as binder | |
| CN101801675B (en) | Inkjet accepting agent for oily pigment ink, inkjet recording medium for oily pigment ink and printed article | |
| CN106905765A (en) | UV solidification scrubbing resistance ink composites and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130501 Termination date: 20210219 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |