CN101486598B - 一种亚铵法草浆黑液为原料的黄腐酸肥料及其制备方法 - Google Patents
一种亚铵法草浆黑液为原料的黄腐酸肥料及其制备方法 Download PDFInfo
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- CN101486598B CN101486598B CN2008100138406A CN200810013840A CN101486598B CN 101486598 B CN101486598 B CN 101486598B CN 2008100138406 A CN2008100138406 A CN 2008100138406A CN 200810013840 A CN200810013840 A CN 200810013840A CN 101486598 B CN101486598 B CN 101486598B
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- humic acid
- yellow humic
- acid fertilizer
- black liquor
- straw pulp
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 118
- 239000010902 straw Substances 0.000 title claims abstract description 57
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title claims description 98
- 239000004021 humic acid Substances 0.000 title claims description 98
- 238000000034 method Methods 0.000 title claims description 65
- 239000002994 raw material Substances 0.000 title claims description 9
- 238000004537 pulping Methods 0.000 title description 8
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 claims abstract description 49
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 23
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 13
- 239000002253 acid Substances 0.000 claims description 33
- 239000007921 spray Substances 0.000 claims description 28
- 239000007787 solid Substances 0.000 claims description 25
- 238000001704 evaporation Methods 0.000 claims description 24
- 230000008020 evaporation Effects 0.000 claims description 24
- 229910052698 phosphorus Inorganic materials 0.000 claims description 24
- 238000001035 drying Methods 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 22
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 9
- 239000010802 sludge Substances 0.000 claims description 6
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- 239000002351 wastewater Substances 0.000 claims description 5
- 239000002689 soil Substances 0.000 abstract description 55
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 10
- 238000010521 absorption reaction Methods 0.000 abstract description 8
- 239000003895 organic fertilizer Substances 0.000 abstract description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract description 5
- 239000011591 potassium Substances 0.000 abstract description 5
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 abstract 3
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 abstract 3
- 239000002509 fulvic acid Substances 0.000 abstract 3
- 229940095100 fulvic acid Drugs 0.000 abstract 3
- 244000037666 field crops Species 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 13
- 239000000047 product Substances 0.000 description 12
- 241000209140 Triticum Species 0.000 description 11
- 235000021307 Triticum Nutrition 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 9
- 230000007935 neutral effect Effects 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 6
- 230000001976 improved effect Effects 0.000 description 6
- 239000002699 waste material Substances 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 210000003608 fece Anatomy 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 239000010871 livestock manure Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical group [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 238000005341 cation exchange Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000000123 paper Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 229910001415 sodium ion Inorganic materials 0.000 description 4
- 244000025254 Cannabis sativa Species 0.000 description 3
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 235000015097 nutrients Nutrition 0.000 description 3
- 238000009938 salting Methods 0.000 description 3
- 239000011573 trace mineral Substances 0.000 description 3
- 235000013619 trace mineral Nutrition 0.000 description 3
- 230000008016 vaporization Effects 0.000 description 3
- 235000017060 Arachis glabrata Nutrition 0.000 description 2
- 244000105624 Arachis hypogaea Species 0.000 description 2
- 235000010777 Arachis hypogaea Nutrition 0.000 description 2
- 235000018262 Arachis monticola Nutrition 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 230000004308 accommodation Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000035558 fertility Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 235000020232 peanut Nutrition 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002681 soil colloid Substances 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 101100283604 Caenorhabditis elegans pigk-1 gene Proteins 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- -1 aluminium chlorohydroxide Chemical compound 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 235000021120 animal protein Nutrition 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010866 blackwater Substances 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000000881 depressing effect Effects 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
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- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 230000000051 modifying effect Effects 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000011238 particulate composite Substances 0.000 description 1
- 239000002367 phosphate rock Substances 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229920005575 poly(amic acid) Polymers 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 239000005031 sulfite paper Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
Description
本发明产量(kg/亩) | 对照组产量(kg/亩) | 增产百分比 | |
第一季第二季第三季第四季 | 427.38424.56440.32409.13 | 414.82409.05413.08392.52 | 3.03.86.64.2 |
处理 | 株高cm | 最高分蘖数万/亩 | 有效分蘖数万/亩 | 穗数万/亩 | 穗粒数粒/穗 | 千粒重g | 理论产量kg/亩 | 增产率% |
本发明肥料复合肥CK | 92.791.091.7 | 47.6240.0143.81 | 20.9517.1413.33 | 39.5837.0834.86 | 29.0228.5526.18 | 38.037.737.2 | 436.47399.1339.22 | 22.2811.30 |
土壤比表面积(m2/g) | 土壤电荷量cmol/kg | 土壤阳离子交换量cmol/kg | 土壤pH | |
CK实施例3实施例4 | 21.8341.3638.12 | 17.5227.7231.14 | 2.614.514.58 | 4.896.436.02 |
实施例5实施例6 | 37.7636.89 | 44.1449.23 | 4.864.93 | 5.976.22 |
CO3 2- | HCO3 - | Cl- | SO4 2- | Ca2+ | Mg2+ | K+Na+ | 总盐 | pH值 |
处理前处理后 | 0.1010.051 | 0.4750.402 | 15.51722.960 | 235.61341.282 | 6.2362.870 | 0.0820.016 | 115.87731.518 | 373.9199.104 | 10.169.22 |
Claims (15)
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CN2008100138406A CN101486598B (zh) | 2008-01-16 | 2008-01-16 | 一种亚铵法草浆黑液为原料的黄腐酸肥料及其制备方法 |
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CN101486598B true CN101486598B (zh) | 2011-04-20 |
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Cited By (1)
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CN106032341A (zh) * | 2015-03-20 | 2016-10-19 | 山东泉林纸业有限责任公司 | 一种腐植酸组合物及其应用 |
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CN102442846B (zh) * | 2010-10-12 | 2013-03-27 | 上海绿乐生物科技有限公司 | 一种利用喷浆造粒生产生物有机肥的方法 |
CN110922278A (zh) * | 2019-11-26 | 2020-03-27 | 刘传远 | 造纸废液鳌合腐殖酸肥料的制备方法 |
CN114115144B (zh) * | 2021-11-09 | 2024-04-12 | 武汉理工大学 | Rdf条件下水泥窑分解炉自动退煤控制方法及系统 |
Citations (4)
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---|---|---|---|---|
ES2107945A1 (es) * | 1995-03-02 | 1997-12-01 | Turol Trading S L | Empleo del licor negro procedente de la fabricacion de pulpa de papel en la produccion de enmiendas organicas, solidas y liquidas, para suelos agricolas. |
CN1280968A (zh) * | 1999-07-16 | 2001-01-24 | 江西贵溪化肥厂 | 利用造纸黑液固化物生产有机氮磷钾复合肥的工艺 |
CN1104379C (zh) * | 1998-04-17 | 2003-04-02 | 赵德志 | 亚铵法造纸黑水处理方法 |
CN1915911A (zh) * | 2005-08-19 | 2007-02-21 | 北京中航宏源环境工程技术有限公司 | 利用碱法含亚钠法造纸黑液制备有机、有机复混肥的方法 |
-
2008
- 2008-01-16 CN CN2008100138406A patent/CN101486598B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2107945A1 (es) * | 1995-03-02 | 1997-12-01 | Turol Trading S L | Empleo del licor negro procedente de la fabricacion de pulpa de papel en la produccion de enmiendas organicas, solidas y liquidas, para suelos agricolas. |
CN1104379C (zh) * | 1998-04-17 | 2003-04-02 | 赵德志 | 亚铵法造纸黑水处理方法 |
CN1280968A (zh) * | 1999-07-16 | 2001-01-24 | 江西贵溪化肥厂 | 利用造纸黑液固化物生产有机氮磷钾复合肥的工艺 |
CN1915911A (zh) * | 2005-08-19 | 2007-02-21 | 北京中航宏源环境工程技术有限公司 | 利用碱法含亚钠法造纸黑液制备有机、有机复混肥的方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106032341A (zh) * | 2015-03-20 | 2016-10-19 | 山东泉林纸业有限责任公司 | 一种腐植酸组合物及其应用 |
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