CN101486135A - GH4169 high-temperature alloy welding wire - Google Patents
GH4169 high-temperature alloy welding wire Download PDFInfo
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- CN101486135A CN101486135A CNA2008100101435A CN200810010143A CN101486135A CN 101486135 A CN101486135 A CN 101486135A CN A2008100101435 A CNA2008100101435 A CN A2008100101435A CN 200810010143 A CN200810010143 A CN 200810010143A CN 101486135 A CN101486135 A CN 101486135A
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- 238000003466 welding Methods 0.000 title claims abstract description 41
- 239000000956 alloy Substances 0.000 title claims abstract description 34
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 33
- 229910052751 metal Inorganic materials 0.000 claims abstract description 29
- 239000002184 metal Substances 0.000 claims abstract description 29
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000010438 heat treatment Methods 0.000 claims abstract description 17
- 238000000137 annealing Methods 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 238000009792 diffusion process Methods 0.000 claims abstract description 11
- 229910052742 iron Inorganic materials 0.000 claims abstract description 10
- 230000032683 aging Effects 0.000 claims abstract description 9
- 239000012535 impurity Substances 0.000 claims abstract description 5
- 239000000126 substance Substances 0.000 claims abstract description 4
- 238000009413 insulation Methods 0.000 claims description 15
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- 229910052698 phosphorus Inorganic materials 0.000 claims description 7
- 229910052796 boron Inorganic materials 0.000 claims description 6
- 238000005516 engineering process Methods 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 239000010955 niobium Substances 0.000 abstract description 21
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 15
- 239000010936 titanium Substances 0.000 abstract description 13
- 229910052758 niobium Inorganic materials 0.000 abstract description 11
- 229910052750 molybdenum Inorganic materials 0.000 abstract description 10
- 229910052719 titanium Inorganic materials 0.000 abstract description 8
- 229910052782 aluminium Inorganic materials 0.000 abstract description 7
- 229910052759 nickel Inorganic materials 0.000 abstract description 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 5
- 239000011733 molybdenum Substances 0.000 abstract description 5
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 abstract description 5
- 150000002739 metals Chemical class 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 10
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- 229910001068 laves phase Inorganic materials 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 238000005266 casting Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- 238000003723 Smelting Methods 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000005864 Sulphur Substances 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 229910000816 inconels 718 Inorganic materials 0.000 description 5
- 239000000395 magnesium oxide Substances 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 238000005204 segregation Methods 0.000 description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 239000006104 solid solution Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000005242 forging Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 210000001519 tissue Anatomy 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000004453 electron probe microanalysis Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910000882 Ca alloy Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 238000002389 environmental scanning electron microscopy Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000000161 steel melt Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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Abstract
The invention relates to a GH4169 high-temperature alloy welding wire, which comprises the following chemical compositions in percentage by weight: 3.0 to 3.31 percent of molybdenum, 0.45 to 0.65 percent of aluminum, 0.8 to 1.2 percent of titanium, 5.0 to 5.7 percent of niobium, 0.35 to 0.65 percent of manganese, 0.02 to 0.03 percent of copper, 50 to 55 percent of nickel, and the balance being iron and impurities. The GH4169 high-temperature alloy welding wire is subjected to diffusion annealing, solution heat treatment and aging heat treatment after welding, and can make deposited metals have an elongation percentage of more than or equal to 18 percent when simultaneously guaranteeing the strength and the hardness of the deposited metals.
Description
Technical field
The present invention relates to the technology of preparing of high temperature alloy high temperature welding wire, a kind of GH4169 high temperature alloy special welding wire is provided especially.
Background technology
The welding of GH4169 high temperature alloy is general adopts the welding material identical or close with mother metal, and adopts the argon tungsten-arc welding welding under argon shield.A large amount of practices show that modal problem is to produce fire check at weld seam and heat affected area in the welding of GH4169 high temperature alloy, and ageing crack appears in postwelding, and the welding point plasticity and toughness are far below the problems such as plasticity and toughness of mother metal.Though cooling velocity is very fast during welding, as if the condition that Laves generates mutually do not possess, but there are some researches show since the GH4169 high temperature alloy in Nb content up to about 5%, Nb is easy in dendritic intergranular enrichment, observe seam organization down at 1000 times, can see interdendritic adularescent tissue, and these tissues to be suspect to be the Laves phase.Electron probe microanalysis (EPMA) confirms that the composition of these white portions approaches the Laves phase composition.So decidable, the enrichment of Nb has promoted the serious component segregation of phase, the existence of this phenomenon will cause the rapid decline of welding point plasticity and toughness.
Summary of the invention
The purpose of this invention is to provide a kind of high temperature alloy GH4169 welding wire.
The invention provides a kind of GH4169 high temperature alloy welding wire, described GH4169 high temperature alloy welding wire chemical composition is percentage by weight:
Mo 3.0~3.31;
Al 0.45~0.65;
Ti 0.8~1.2;
Nb 5.0~5.7;
Mn 0.35~0.65;
C 0.02~0.03;
Ni 50~55;
Surplus is iron and impurity.
GH4169 high temperature alloy welding wire provided by the invention, described impurity comprises Si, S, P, B, Co, Si≤0.0080 wherein, S≤0.0050, P≤0.0050, B≤0.002, Co≤0.002.
The post weld heat treatment technology of GH4169 high temperature alloy welding wire provided by the invention, the deposited metal postwelding passes through diffusion annealing, solution treatment, Ageing Treatment successively, is specially:
Diffusion annealing: 1150 ℃~1250 ℃ insulation 10~15h, preferred 1190 ± 10 ℃ of insulation 12h, stove is cold;
Solution treatment: 990 ℃~1200 ℃ insulation 20~40min, preferred 1030 ± 10 ℃ of insulation 30min, water-cooled;
Ageing Treatment: 700 ℃~750 ℃ insulation 8~12h, preferred 720 ± 10 ℃ of insulation 8~12h, air cooling.
A kind of high temperature alloy GH4169 welding wire provided by the invention, after the welding through diffusion annealing+solid solution, timeliness heat treatment, can be when guaranteeing deposited metal intensity, hardness, deposited metal is had 〉=18% percentage elongation.
Description of drawings
Fig. 1 is the metallographic structure of GH4169 high temperature alloy deposited metal
Fig. 2 amplifies down 1000 times the shape appearance figure 3 of the as-welded metallographic structure of deposited metal white any any scan image mutually and on the matrix between dendrite in Fig. 2 for ESEM
Fig. 1 is the metallographic tissue of the high temperature alloy deposited metal of GH4169, and the GH4169 alloy is at standard heat place Mainly " and carbide forms with strengthening mutually γ ', γ by the γ matrix under the reason state. And deposited alloy is in the welding process In experienced the process that again fusing is solidified, γ ' originally or γ ", boride equates all to dissolve in the matrix, Its room temperature texture mainly is made of γ solid solution. Because cooling speed is very fast when deposited, γ solid solution is main The dendritic crystal that axle is very long.
Fig. 2 is that the as-welded metallographic of deposited metal is organized under the scanning Electronic Speculum and amplifies 1000 times, utilizes back scattering The morphology analysis that electronic atom ordinal number contrast principle is carried out, observe the tree interdendritic all adularescent generate mutually, The shape looks are the bone shape as shown in Figure 2. White selects one arbitrarily mutually and on the matrix in Fig. 2 Zhong Shu interdendritic Point is done scanning, and the result as shown in Figure 3. As seen from Figure 3, it is mutually rich to compare between crystalline substance white with matrix Collect a large amount of Nb and Mo element, illustrate that obvious Nb and Mo element segregation have taken place in the tree interdendritic, Nb and Mo content are higher. Can qualitatively judge white from the shape looks of white phase and element enrichment condition is mutually Laves phase (Ni, Fe, Cr)2(Nb, Mo, Ti). Crisp hard metallic compound Laves phase Existence must cause the mechanical properties decrease of alloy, therefore need to be at Laves phase fusing point more than 1093 ℃ Temperature heat-treat, to eliminate the Laves phase.
The specific embodiment
One, material melting
1, knotting crucible: pay for magnesia about 100mm first in moulding MgO crucible bottom, fill magnesia around and, with waterglass and magnesia powder knotting mouth of pot, fix again watering the road junction with pneumatic pick, crooked chisel compacting;
2, baking crucible: in the crucible that ties, put into a certain amount of pure iron, with small-power baking 1~2 hour;
3, weighing and the Ni that rechecked, Fe, Mo, Cr, raw material such as Nb, C are put into knotting and baked MgO crucible, Al, Ti are put into hopper, vacuumize then, power send electrical heating raw material to the crucible all to melt by smelting process;
4, after molten steel melts clearly, refining 1/4 hour;
5, have a power failure and in stove, charge into a certain amount of argon gas, send electricity again and adjust heating power molten steel temperature is remained near the fusing point, add alloy material (Al, Ti), and add the deoxidation of a certain amount of Mg-Ca alloy, sulphur, phosphorus;
6, adjust molten steel temperature near fusing point, charged heating is at the uniform velocity cast.
Two, heat treatment, forging, hot rolling
Carry out homogenising heat treatment watering the ingot casting that outpours: 1190 ℃ * 20h, air cooling, elements segregation such as δ phase that produces in the elimination casting process and Nb.Steel ingot is reheated, open and forge 1120 ℃ of temperature, final forging temperature: 930~950 ℃.Forging is of a size of 35mm * 35mm * 1600mm, is hot-rolled down to Φ 8mm wire rod, 1080 ℃ of hot-rolled temperatures after the reconditioning of outer surface process emery wheel.
Three, silk material processing
Carry out cold-drawn on the silk material dish circle drawing machine, cumulative deformation is no more than 50%, and intermediate annealing heat treatment is carried out on the protective atmosphere heat-treatment furnace, and temperature is 1020~1040 ℃, and the time by equal temperate zone is no less than 5 minutes.Pony-roughing pass silk material tolerance is by controlling at d ± 0.03mm, and the finished size tolerance is pressed
Control.The finished product wire size is d1.6mm.
Four, welding
Adopt the GTAW method to obtain overlay, the mother metal composition is Inconel 718 nickel-based high-temperature alloy sheet materials that generally use on the engineering, and thickness of slab is 3mm.Owing to remove mother metal fully during processing sample, so the mother metal composition does not have influence to deposited metal composition.
Concrete welding condition is as follows: welding current is 50A, and weldingvoltage is 12V, and protective gas is an argon gas, and shield gas flow rate is 10L/min, interlayer temperature<150 ℃.
Five, post weld heat treatment
Find out (Fig. 1) from the metallographic structure of postwelding deposited metal, the main cause of Inconel 718 alloy weldability differences is the enrichments that generate Laves phase and the NbC of crystal boundary place.This is because Inconel 718 alloys when welding, alloy has experienced the process of solidifying again, and the existence of a large amount of niobiums has promoted Laves to form mutually, and these factors have caused the moulding of Inconel 718 alloy welding points, toughness to reduce, thereby it is lower to show as percentage elongation, and strength factor is not high yet.Therefore to carry out diffusion annealing heat treatment, reach interdendritic Nb element segregation mutually to eliminate Laves.Diffusion annealing has been eliminated fragility Laves that deposited metal forms mutually and the segregation of Nb in welding process, improved plasticity, passes through solid solution, timeliness heat treatment again, and " phase makes Inconel 718 alloys obtain intensive treatment to separate out γ ', γ.Concrete Technology for Heating Processing is:
Diffusion annealing: 1190 ℃ of insulation 12h, stove is cold; Solution treatment: 1030 ℃ of insulation 30min, water-cooled; Ageing Treatment: 720 ℃ of insulation 10h, air cooling.
Embodiment 1
The composition of GH4169 welding wire is, molybdenum Mo:3.10, and aluminium Al:0.53, titanium Ti:1.15, niobium Nb:5.02, silicon Si:0.0045, sulphur S:0.0012, phosphorus P:0.0035, manganese 0.38, carbon 0.011, boron 0.0014, cobalt Co0.0003, nickel 52.8, iron Fe is surplus.
Ingot casting that smelting is finished welds back test deposited metal room-temperature mechanical property and hardness through hot-working, cold-drawn Cheng Sihou, as table 1:
The composition of GH4169 welding wire is, molybdenum Mo:3.12, and aluminium Al:0.57, titanium Ti:1.19, niobium Nb:5.52, silicon Si:0.0041, sulphur S:0.0010, phosphorus P:0.0035, manganese 0.40, carbon 0.021, boron 0.0015, cobalt Co 0.0005, nickel 52.3, iron Fe is surplus.
Ingot casting that smelting is finished welds back test deposited metal room-temperature mechanical property and hardness through hot-working, cold-drawn Cheng Sihou, as table 1:
Table 1 GH4169 high temperature alloy welding wire deposited metal performance
The composition of GH4169 welding wire is, molybdenum Mo:3.18, and aluminium Al:0.51, titanium Ti:1.09, niobium Nb:5.60, silicon Si:0.0044, sulphur S:0.0011, phosphorus P:0.0037, manganese 0.45, carbon 0.021, boron 0.0014, cobalt Co 0.0003, nickel 52.7, iron Fe is surplus.
Ingot casting that smelting is finished welds back test deposited metal room-temperature mechanical property and hardness through hot-working, cold-drawn Cheng Sihou, as table 2:
The composition of GH4169 welding wire is, molybdenum Mo:3.08, and aluminium Al:0.53, titanium Ti:1.12, niobium Nb:4.69, silicon Si:0.0041, sulphur S:0.0008, phosphorus P:0.0031, manganese 0.41, carbon 0.0015, boron 0.0010, cobalt Co 0.0007, nickel 52.3, iron Fe is surplus.
Ingot casting that smelting is finished welds back test deposited metal room-temperature mechanical property and hardness through hot-working, cold-drawn Cheng Sihou, as table 2:
Table 2 GH4169 high temperature alloy welding wire deposited metal performance
As can be seen from Table 1, 2, no matter be the intensity that yield strength, fracture strength and the hardness of deposited metal has all surpassed the GH4169 mother metal, and percentage elongation has also reached the mother metal requirement, therefore welding wire of the present invention is adopted in explanation, can make deposited metal have very high intensity and has certain toughness.
Claims (4)
1, a kind of GH4169 high temperature alloy welding wire is characterized in that described GH4169 high temperature alloy welding wire chemical composition is percentage by weight:
Mo 3.0~3.31;
Al 0.45~0.65;
Ti 0.8~1.2;
Nb 5.0~5.7;
Mn 0.35~0.65;
C 0.02~0.03;
Ni 50~55;
Surplus is iron and impurity.
2, GH4169 high temperature alloy welding wire as claimed in claim 1 is characterized in that described impurity comprises Si, S, P, B, Co, Si≤0.0080 wherein, S≤0.0050, P≤0.0050, B≤0.002, Co≤0.002.
3, the post weld heat treatment technology of the described GH4169 high temperature alloy of a kind of claim 1 welding wire, it is characterized in that: the deposited metal postwelding passes through diffusion annealing, solution treatment, Ageing Treatment successively, be specially: diffusion annealing: 1150 ℃~1250 ℃ insulation 10~15h, stove is cold;
Solution treatment: 1000 ℃~1050 ℃ insulation 20~40min, water-cooled;
Ageing Treatment: 700 ℃~750 ℃ insulation 8~12h, air cooling.
4, the post weld heat treatment technology of the described GH4169 high temperature alloy of a kind of claim 3 welding wire, it is characterized in that: the deposited metal postwelding passes through diffusion annealing, solution treatment, Ageing Treatment successively, be specially: diffusion annealing: 1190 ± 10 ℃ of insulation 12h, stove is cold;
Solution treatment: 1030 ± 10 ℃ of insulation 30min, water-cooled;
Ageing Treatment: 720 ± 10 ℃ of insulation 10h, air cooling.
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102806337A (en) * | 2012-08-16 | 2012-12-05 | 太原钢铁(集团)有限公司 | Processing method of solution strengthening-type nickel-based alloy electroslag ingot hot delivery homogenous cogging |
CN104439762A (en) * | 2014-11-12 | 2015-03-25 | 江苏兴海特钢有限公司 | Technique for manufacturing high-niobium and high-molybdenum nickel-base superalloy welding wire |
CN105081605A (en) * | 2015-08-03 | 2015-11-25 | 合肥通用机械研究院 | Microalloying 25Cr35NiNb welding wire for ethylene cracking furnace tube |
CN106521121A (en) * | 2016-11-14 | 2017-03-22 | 攀钢集团攀枝花钢铁研究院有限公司 | Heat treatment method for high-temperature alloy steel |
CN106929652A (en) * | 2017-02-15 | 2017-07-07 | 贵州大学 | A kind of GH4169 separates out heat treatment method to connecting bolt second-phase dispersion |
WO2018188398A1 (en) * | 2017-04-13 | 2018-10-18 | 中国石油大学(华东) | Nickel-based material brazing joint component and method for use in mechanical property homogenization |
CN108672980A (en) * | 2018-05-25 | 2018-10-19 | 兰州威特焊材科技股份有限公司 | A kind of GH4169 alloy welding wires short flow process |
CN113927044A (en) * | 2021-09-24 | 2022-01-14 | 南昌航空大学 | Solid solution treatment method for laser additive manufacturing of high-temperature alloy |
CN115505710A (en) * | 2022-09-24 | 2022-12-23 | 中国航空工业标准件制造有限责任公司 | Heat treatment method of stress-enduring GH4169 bolt |
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2008
- 2008-01-18 CN CNA2008100101435A patent/CN101486135A/en active Pending
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CN102806337A (en) * | 2012-08-16 | 2012-12-05 | 太原钢铁(集团)有限公司 | Processing method of solution strengthening-type nickel-based alloy electroslag ingot hot delivery homogenous cogging |
CN104439762A (en) * | 2014-11-12 | 2015-03-25 | 江苏兴海特钢有限公司 | Technique for manufacturing high-niobium and high-molybdenum nickel-base superalloy welding wire |
CN105081605A (en) * | 2015-08-03 | 2015-11-25 | 合肥通用机械研究院 | Microalloying 25Cr35NiNb welding wire for ethylene cracking furnace tube |
CN106521121A (en) * | 2016-11-14 | 2017-03-22 | 攀钢集团攀枝花钢铁研究院有限公司 | Heat treatment method for high-temperature alloy steel |
CN106929652A (en) * | 2017-02-15 | 2017-07-07 | 贵州大学 | A kind of GH4169 separates out heat treatment method to connecting bolt second-phase dispersion |
CN106929652B (en) * | 2017-02-15 | 2018-07-24 | 贵州大学 | Heat treatment method is precipitated to connecting bolt second-phase dispersion in a kind of GH4169 |
WO2018188398A1 (en) * | 2017-04-13 | 2018-10-18 | 中国石油大学(华东) | Nickel-based material brazing joint component and method for use in mechanical property homogenization |
US10858724B2 (en) | 2017-04-13 | 2020-12-08 | China University Of Petroleum (East China) | Method for homogenizing the compositions and mechanical performances of nickel-based material brazed joints |
CN108672980A (en) * | 2018-05-25 | 2018-10-19 | 兰州威特焊材科技股份有限公司 | A kind of GH4169 alloy welding wires short flow process |
CN108672980B (en) * | 2018-05-25 | 2020-10-20 | 兰州威特焊材科技股份有限公司 | Short-process preparation method of GH4169 alloy welding wire |
CN113927044A (en) * | 2021-09-24 | 2022-01-14 | 南昌航空大学 | Solid solution treatment method for laser additive manufacturing of high-temperature alloy |
CN113927044B (en) * | 2021-09-24 | 2023-11-03 | 南昌航空大学 | Solution treatment method for manufacturing high-temperature alloy by laser additive |
CN115505710A (en) * | 2022-09-24 | 2022-12-23 | 中国航空工业标准件制造有限责任公司 | Heat treatment method of stress-enduring GH4169 bolt |
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