CN101480742A - Water-in-oil type electric spark machining working solution - Google Patents
Water-in-oil type electric spark machining working solution Download PDFInfo
- Publication number
- CN101480742A CN101480742A CNA2009100137520A CN200910013752A CN101480742A CN 101480742 A CN101480742 A CN 101480742A CN A2009100137520 A CNA2009100137520 A CN A2009100137520A CN 200910013752 A CN200910013752 A CN 200910013752A CN 101480742 A CN101480742 A CN 101480742A
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- China
- Prior art keywords
- working solution
- water
- electric spark
- type electric
- spark machining
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- Granted
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- 239000012224 working solution Substances 0.000 title claims abstract description 27
- 238000003754 machining Methods 0.000 title claims abstract description 23
- 238000010892 electric spark Methods 0.000 title claims abstract description 19
- 239000003921 oil Substances 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 14
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims abstract description 5
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims abstract description 5
- 239000010721 machine oil Substances 0.000 claims description 11
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 3
- 238000003756 stirring Methods 0.000 abstract description 9
- 239000010705 motor oil Substances 0.000 abstract 5
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 239000003350 kerosene Substances 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920001083 polybutene Polymers 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- -1 benzene class aromatic compound Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Landscapes
- Lubricants (AREA)
- Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
Abstract
The invention relates to a water-in-oil type electric spark machining working solution in the field of non-traditional machining, comprising compound emulsifying agent, engine oil and deionized water. The working solution is prepared by the following steps: sorbitan monoleate and polyoxyethylene sorbitan monostearate are put together in proportion, stirring for the sorbitan monoleate and the polyoxyethylene sorbitan monostearate to mix and react and form the compound emulsifying agent; the prepared compound emulsifying agent is added into the engine oil according to a required proportion, stirring for the compound emulsifying agent to be dissolved into the engine oil and form an engine oil colliquefaction solution; and the deionized water is added into the engine oil colliquefaction solution, stirring to obtain the water-in-oil type electric spark machining working solution. The water-in-oil type electric spark machining working solution has the advantages of high dielectric strength, safe use, no pollution and high electric spark machining efficiency.
Description
Technical field
The present invention relates to the water-in-oil type electric spark machining working solution in a kind of special process field.
Background technology
At present, spark machined working solution commonly used has oils working solution and water base working solution both at home and abroad.
The oils working solution mainly contains kerosene, special-purpose mineral oil, synthesis type wet goods.The kerosene application in China's Electric Discharge Machining at present is still comparatively extensive, its major advantage is the dielectric strength height, viscosity is low and good fluidity, its shortcoming is that flash-point is low, volatility big, poor stability, and the fire hazardous accident decomposites pernicious gas etc. in the processing.Special-purpose mineral oil has certain overcoming to some shortcomings of kerosene, but contains a certain amount of aromatic hydrocarbons in such mineral oil, causes the poor stability of oil product, and frowziness also has spread effect to skin.Synthesis type oil mainly make a comment or criticism structure alkane and isoparaffin, owing to do not add phenolic antioxidant, therefore, oily color water-white is bright, the content of aromatic hydrocarbons is extremely low, basic free from extraneous odour.In order to improve the spark machined effect of synthesis type oil, people again on this basis, add additives such as polybutene, developed as companies such as Japan National Oil Corp, auspicious soil, Germany and to have added polybutene, ethene, the polymer of vinyl group and ring benzene class aromatic compound etc., behind the adding polymer, the polymer that boiling point is high will destroy steam blanket rapidly, improve cooling effectiveness, can improve the working (machining) efficiency of electric spark.These additive cost height, technology are difficult for grasping, and institute adds fatty hydrocarbon polymer and easily causes arc phenomenon.
Water base working solution mainly contains emulsion, deionized water etc.Emulsion mainly by oil emulsion, emulsification soap and water-soluble close formulated, the micro emulsion of the emulsion that is made into drips based on oil-in-water, its dielectric strength is more much lower than oils working solution, usually there is certain electrolysis in the spark machined, such working solution is mainly used in Wire EDM, the processing of electric spark high speed aperture at present, is not suitable for Electric Discharge Machining.Deionized water has advantages such as cost is low, nonflammable, free from environmental pollution, domestic and international many scholars study as electric spark machining working solution adding certain additive in deionized water or the deionized water, such working solution mainly is applicable to fine electric spark processing at present, be not suitable for Electric Discharge Machining, its main cause is that working (machining) efficiency is low, and easy-to-rust lathe and workpiece.
Summary of the invention
The object of the present invention is to provide a kind of water-in-oil type electric spark machining working solution, solve preferably that the oils working solution that spark machined uses is volatile, flash-point is low, cost is high, and the dielectric properties of water base working solution are poor, have in the process electrolysis to have, be not suitable for the problem of Electric Discharge Machining etc.
Principle of the present invention is: require in proportion earlier sorbitan mono-oleic acid ester and polyoxyethylene sorbitan monostearate are put together, stir and make their hybrid reaction formation compound emulsifying agent; Require in proportion then the compound emulsifying agent of being prepared is joined in the machine oil, stirring is dissolved in the machine oil compound emulsifying agent, forms the fused liquid of machine oil; In the fused liquid of machine oil, add deionized water at last, stir and just can obtain the water-in-oil type electric spark machining working solution that to prepare.
Water-in-oil type electric spark machining working solution of the present invention have the dielectric strength height, nonflammable, safe in utilization, pollution-free, can improve advantages such as spark machined efficient.
The specific embodiment
The first step is put sorbitan mono-oleic acid ester and polyoxyethylene sorbitan monostearate together by quality proportioning 99:7, stirs to make them hybrid reaction form compound emulsifying agent; Second step is by quality proportioning 1:(5~7), compound emulsifying agent of being prepared and machine oil to be put together, stirring is dissolved in the machine oil compound emulsifying agent, forms the fused liquid of machine oil; Quality proportioning 1:(5~7 that the 3rd step press compound emulsifying agent, machine oil and deionized water): the relation of (2~5), in the fused liquid of machine oil, add deionized water, stirring just can obtain the water-in-oil type electric spark machining working solution that will prepare.
Claims (3)
1. water-in-oil type electric spark machining working solution, it is characterized in that: this working solution is made up of compound emulsifying agent, machine oil and deionized water.
2. water-in-oil type electric spark machining working solution as claimed in claim 1 is characterized in that: described compound emulsifying agent is formulated by the sorbitan mono-oleic acid ester and the polyoxyethylene sorbitan monostearate that are 99:7 by the quality proportioning.
3. water-in-oil type electric spark machining working solution as claimed in claim 1 is characterized in that: the quality proportioning of compound emulsifying agent, machine oil and deionized water is 1:(5~7 in this water-in-oil type electric spark machining working solution): (2~5).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2009100137520A CN101480742B (en) | 2009-01-07 | 2009-01-07 | Water-in-oil type electric spark machining working solution |
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CN2009100137520A CN101480742B (en) | 2009-01-07 | 2009-01-07 | Water-in-oil type electric spark machining working solution |
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Publication Number | Publication Date |
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CN101480742A true CN101480742A (en) | 2009-07-15 |
CN101480742B CN101480742B (en) | 2010-12-08 |
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CN2009100137520A Expired - Fee Related CN101480742B (en) | 2009-01-07 | 2009-01-07 | Water-in-oil type electric spark machining working solution |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102260581A (en) * | 2011-06-14 | 2011-11-30 | 中国石油大学(华东) | Water-in-oil type mixed powder working solution |
CN102794515A (en) * | 2011-05-24 | 2012-11-28 | 昆山市瑞捷精密模具有限公司 | Short electric arc machining operating fluid |
CN104191052A (en) * | 2014-09-17 | 2014-12-10 | 中国石油大学(华东) | Environment-friendly and efficient water-in-oil electric spark forming machining working fluid |
CN107790836A (en) * | 2017-12-05 | 2018-03-13 | 江西创迪科技有限公司 | A kind of electric discharge machine cleaning device |
CN109365931A (en) * | 2018-12-04 | 2019-02-22 | 中国石油大学(华东) | Sinking EDM water-in-oil type nanometer working solution |
CN114523163A (en) * | 2022-01-04 | 2022-05-24 | 中国石油大学(华东) | High-energy electric spark machining oil-in-water nano working fluid |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6059314B2 (en) * | 1982-04-03 | 1985-12-24 | 株式会社ソデイツク | electrical discharge machining fluid |
CN100586628C (en) * | 2008-01-08 | 2010-02-03 | 常熟市周行润达化工厂 | Electric spark processing liquid |
-
2009
- 2009-01-07 CN CN2009100137520A patent/CN101480742B/en not_active Expired - Fee Related
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102794515A (en) * | 2011-05-24 | 2012-11-28 | 昆山市瑞捷精密模具有限公司 | Short electric arc machining operating fluid |
CN102260581A (en) * | 2011-06-14 | 2011-11-30 | 中国石油大学(华东) | Water-in-oil type mixed powder working solution |
CN102260581B (en) * | 2011-06-14 | 2013-03-13 | 中国石油大学(华东) | Water-in-oil type mixed powder working solution |
CN104191052A (en) * | 2014-09-17 | 2014-12-10 | 中国石油大学(华东) | Environment-friendly and efficient water-in-oil electric spark forming machining working fluid |
CN104191052B (en) * | 2014-09-17 | 2016-08-10 | 中国石油大学(华东) | Green high-efficient water-in-oil type sinking EDM working solution |
CN107790836A (en) * | 2017-12-05 | 2018-03-13 | 江西创迪科技有限公司 | A kind of electric discharge machine cleaning device |
CN109365931A (en) * | 2018-12-04 | 2019-02-22 | 中国石油大学(华东) | Sinking EDM water-in-oil type nanometer working solution |
CN114523163A (en) * | 2022-01-04 | 2022-05-24 | 中国石油大学(华东) | High-energy electric spark machining oil-in-water nano working fluid |
CN114523163B (en) * | 2022-01-04 | 2023-08-11 | 中国石油大学(华东) | High-energy electric spark machining water-in-oil nano working solution |
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CN101480742B (en) | 2010-12-08 |
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