CN105779160A - Cleaning agent specially used in civil explosive industry and preparation method thereof - Google Patents
Cleaning agent specially used in civil explosive industry and preparation method thereof Download PDFInfo
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- CN105779160A CN105779160A CN201610242459.1A CN201610242459A CN105779160A CN 105779160 A CN105779160 A CN 105779160A CN 201610242459 A CN201610242459 A CN 201610242459A CN 105779160 A CN105779160 A CN 105779160A
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- civil explosive
- ether
- explosive industry
- scavenger specially
- agent
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Abstract
The invention discloses a cleaning agent specially used in the civil explosive industry. The cleaning agent is prepared from, an anionic surfactant 3-12%, a non-ionic surfactant 5-15%, an alcohol ether solvent 8-20%, a complexing agent 0.1-0.5%, a defoaming agent 0.05-0.5%, essence 0.1-0.5%, a preservative 0.05-0.2% and the balance deionized water. The preparation method comprises the steps that the anionic surfactant, the non-ionic surfactant, the complexing agent and the water which are proportioned are firstly put into a reaction kettle, then heating is performed to reach 60-85 DEG C, stirring dissolution is performed for 30-60 minutes, then cooling is performed to reach 50-60 DEG C, the alcohol ether solvent, the defoaming agent, the essence and the preservative which are proportioned are added, stirring continues for 10-20 minutes, and cooling, material putting and package are performed. The cleaning agent has the advantages of having the good cleaning effect on oil and wax dirt, has the good demulsification effect on emulsion explosives and being high in oil-water separation efficiency.
Description
Technical field
The present invention relates to a kind of abluent and preparation method thereof, particularly a kind of civil explosive industry scavenger specially
And preparation method thereof.
Background technology
Civil explosive industry product such as emulsion, containing ammonium nitrate, sodium nitrate, complex wax, microwax, machine
Oil, the composition such as water-in-oil emulsifier such as SP-80 emulsifying agent and polyisobutylene succinic acid derivant.This
Kind of dirt drops on floor, residual various installations and facilities on a production line and stick to skin and
On medicated clothing, conventional cleaning way is difficult to wash down wash clean, brings very to the field management of Min Bao manufacturing enterprise
Big inconvenience.The auxiliary such as conventional abluent, such as detergent, liquid detergent etc., needs auxiliary brush, perching knife
Instrument just can clean up.
CN 103571642A discloses a kind of emulsion scavenger specially and preparation method thereof, described in it
The composition of abluent and content be: water 88.5-91.5 part, carboxymethyl cellulose 0.5-1.5 part,
Dodecylbenzene sodium sulfonate 4-5 part, OP-10 emulsifying agent 4-5 part, dehydrated alcohol 4.5-5.5 part, from
From the point of view of its formula technique, the most little with conventional abluent liquid detergent gap, formula introduces ethanol purpose
In order to improve the demulsification of abluent, but the flash-point of ethanol is relatively low, and ethanol is oily, Wax
Solubility property relatively low, and the most insoluble to Derivatives of Polyisobutylene Succinic Anhydrides, therefore, this abluent
Compared with the effect of conventional abluent liquid detergent, do not improve significantly.
Zhang Guansong, Han Yulin etc. provide a kind of emulsion dirt Special cleaning in its paper delivered
The collocation method of agent, its raw material used and content thereof is: NPE 5 parts, fat
Fat polyoxyethylenated alcohol 3 parts, soda 0.4 part, ethanol 2.5 parts, 4 parts of zeolite, auxiliary agent 2 parts,
The components such as 82 parts of water and other anticorrosions, thickening, essence are appropriate.From the point of view of formula technique, with CN
103571642A adds the component such as zeolite, soda, promotes the breakdown of emulsion of abluent, but in general,
These two formula techniques compared with traditional abluent, detergent, the demulsification to emulsion, with
And oil, the abluent effect of Wax are not significantly improved.
Summary of the invention
It is an object of the invention to, it is provided that a kind of civil explosive industry scavenger specially and preparation method thereof.This
It is effective that bright product has the abluent to oil, wax dirt, good to the demulsification of emulsion, and
The feature that the efficiency of oil-water separation is high.
Technical scheme: a kind of civil explosive industry scavenger specially, the composition of described abluent and
Its content is: anion surfactant 3-12%, nonionic surfactant 5-15%, alcohol ether solvents
8-20%, chelating agent 0.1-0.5%, defoamer 0.05-0.5%, essence 0.1-0.5%, preservative
0.05-0.2%, surplus is deionized water.
Aforesaid civil explosive industry scavenger specially, the composition of described abluent and content thereof is: anion
Surfactant 5-10%, nonionic surfactant 9-12%, alcohol ether solvents 12-16%, chelating agent
0.15-0.3%, defoamer 0.1-0.25%, essence 0.15-0.3%, preservative 0.08-0.12%, remaining
Amount is deionized water.
Aforesaid civil explosive industry scavenger specially, described anion surfactant is aliphatic alcohol polyethenoxy
One or both mixture in ether sodium sulfate, sodium n-alkylbenzenesulfonate.
Aforesaid civil explosive industry scavenger specially, described nonionic surfactant is octyl phenol polyoxy
In vinyl Ether-10, octyl phenol polyoxyethylene ether-20 or octyl phenol polyoxyethylene ether-30 one
Kind or multiple mixture.
Aforesaid civil explosive industry scavenger specially, described alcohol ether solvents is diethylene glycol monobutyl ether, three second
The mixture of one or more in glycol monobutyl ether or Dipropylene glycol mono-n-butyl Ether.
Aforesaid civil explosive industry scavenger specially, described chelating agent be sodium citrate, sodium gluconate or
The mixture of one or more in disodiumedetate.
Aforesaid civil explosive industry scavenger specially, described defoamer is polypropylene glycerol aether, polyoxy second
The mixture of one or more in alkene glycerin ether or polydimethylsiloxane.
A kind of method preparing aforesaid civil explosive industry scavenger specially, first by the anion table of described proportioning
Face activating agent, non-surface-active agent, chelating agent and water put into reactor, then heat to 60-85 DEG C,
Stirring and dissolving 30-60min, is then cooled to 50-60 DEG C, adds the alcohol ether solvents of described proportioning, disappears
Infusion, essence and preservative, continue stirring 10-20min, cooling, blowing, pack.
Beneficial effects of the present invention: compared with prior art, the present invention has a following remarkable advantage:
(1) use nonionic surfactant OPEO OP-10, OP-20 and
OP-30, the nonionic emulsifier such as the AEO-9 used with conventional formulation, OP-4 is compared, and has more preferably
Penetrating power, it is possible to increase the demulsification of abluent and to oil, the abluent effect of wax material.
(2) nonionic surfactant that the cloud point of OP-10, OP-20 and OP-30 is higher is used,
Abluent can adapt to the use occasion that temperature is higher, has preferable oil-water separation to waste emulsion explosive
Effect.
(3) the alcohol ether solvents diethylene glycol monobutyl ether that uses, triethylene glycol butyl ether, dipropylene glycol list
Butyl ether, this kind of alcohol ether solvents has preferable water solublity, has oil, wax and macromolecular compound relatively
Good solubility property, it is possible to significantly improve the demulsification of abluent, and to oil, Wax clear
Removing, and this kind solvent flash-point is high, environmental protection, security performance is high.
For further illustrating beneficial effects of the present invention, inventor has done following experiment:
The technical requirement of a kind of civil explosive industry scavenger specially is as shown in table 1.
The quality index requirement of table 1 scavenger specially
Sequence number | Project | Quality index |
1 | Outward appearance | Clarification, transparency liquid |
2 | PH value (10% aqueous solution) | 7-10 |
3 | Active matter content (%) | 15-45 |
To prepared through the embodiment of the present invention 1, embodiment 2, embodiment 3 and embodiment 4 special clearly
Lotion is tested the most in accordance with the following methods with the liquid detergent of market sale, the demulsification of detergent:
Experimental technique: weigh 10g abluent in beaker, adds 10g tap water and stirs, then
Add 10g emulsion, after standing 12 hours, compare the demulsification of abluent.
Result of the test: scavenger specially and the liquid detergent of market sale, the demulsification such as table 2 of detergent
Shown in.
The demulsification of table 2 abluent
As shown in table 2, commercially available liquid detergent and commercial laundry powder are poor to the demulsification of emulsion,
There is i.e. demulsifying phenomenon of turning white on the emulsion surface only touching abluent, and illustrates that abluent is to emulsion
In oil, wax, emulsifying agent solute effect poor, wherein, the reason that detergent detergent solution is muddy
It is that the concentration of detergent causes more greatly, is not the phenomenon that produces of breakdown of emulsion.The embodiment of the present invention 1, reality
Executing example 2, embodiment 3 and the scavenger specially prepared by embodiment 4, emulsion is molten at abluent
In liquid can breakdown of emulsion completely, detergent solution is uniform milky, and the abluent that embodiment is prepared is described
Ideal to the demulsification of emulsion, to the dissolving effect of oil, wax and emulsifying agent in emulsion
Fruit is preferably, it is possible to be applicable to the equal oil of the emulsifying of civil explosive industry, expanded explosive and compound oil, wax pattern dirt
Cleaning, it is possible to be applicable to oil phase melting pot, emulsator, explosive cooling steel band, sensitizing device, conveyer belt,
The cleaning of the equipment such as charging machine and field mixed loading truck, and be applicable to process waste emulsion explosive.
Detailed description of the invention
Embodiments of the invention
Embodiment 1:
A kind of civil explosive industry scavenger specially, its component and proportioning are as follows: fatty alcohol-polyoxyethylene ether sulphuric acid
Sodium 5%, octyl phenol polyoxyethylene ether-20 12%, Dipropylene glycol mono-n-butyl Ether 12%, sodium citrate 0.3%,
Polyoxyethylene glycerol ether 0.15%, essence 0.2%, preservative 0.1%, deionized water 70.25%.
The preparation method of above-mentioned cleaning agent: feed intake according to the component in formula and deal, first by poly alkyl alcohol
Oxygen vinyl Ether sodium sulfate, octyl phenol polyoxyethylene ether-20, sodium citrate and deionized water put into
Reactor, is warming up to 85 DEG C, and stirring and dissolving 30min is cooled to 60 DEG C, is subsequently adding dipropylene glycol
Monobutyl ether, polyoxyethylene glycerol ether, essence, preservative, continue stirring 20min, cooling, blowing,
Packaging.
Embodiment 2:
A kind of civil explosive industry scavenger specially, its component and proportioning are as follows: fatty alcohol-polyoxyethylene ether sulphuric acid
Sodium 5%, sodium n-alkylbenzenesulfonate 5%, octyl phenol polyoxyethylene ether-10 10%, diethylene glycol list
Butyl ether 15%, disodiumedetate 0.2%, polydimethylsiloxane 0.1%, essence 0.15%,
Preservative 0.08%, deionized water 64.47%.
The preparation method of above-mentioned cleaning agent: feed intake according to the component in formula and deal, first by poly alkyl alcohol
Oxygen vinyl Ether sodium sulfate, sodium n-alkylbenzenesulfonate, octyl phenol polyoxyethylene ether-10, ethylenediamine
Tetraacethyl disodium and deionized water put into reactor, are warming up to 75 DEG C, stirring and dissolving 40min, cooling
To 56 DEG C, it is subsequently adding diethylene glycol monobutyl ether, polydimethylsiloxane, essence, preservative, continues
Continuous stirring 16min, cooling, blowing, packaging.
Embodiment 3:
A kind of civil explosive industry scavenger specially, its component and proportioning are as follows: fatty alcohol-polyoxyethylene ether sulphuric acid
Sodium 6%, sodium n-alkylbenzenesulfonate 4%, octyl phenol polyoxyethylene ether-20 10%, triethylene glycol list
Butyl ether 12%, disodiumedetate 0.2%, polydimethylsiloxane 0.1%, essence 0.15%,
Preservative 0.08%, deionized water 67.47%.
The preparation method of above-mentioned cleaning agent: feed intake according to the component in formula and deal, first by poly alkyl alcohol
Oxygen vinyl Ether sodium sulfate, sodium n-alkylbenzenesulfonate, octyl phenol polyoxyethylene ether-20, ethylenediamine
Tetraacethyl disodium and deionized water put into reactor, are warming up to 65 DEG C, stirring and dissolving 50min, cooling
To 54 DEG C, add remaining remaining ingredient, continue stirring 14min, cooling, blowing, packaging.
Embodiment 4:
A kind of civil explosive industry scavenger specially, its component and proportioning are as follows: fatty alcohol-polyoxyethylene ether sulphuric acid
Sodium 10%, octyl phenol polyoxyethylene ether-20 4%, octyl phenol polyoxyethylene ether-30 5%, two
Propylene glycol monobutyl ether 16%, sodium gluconate 0.15%, polypropylene glycerol aether 0.25%, essence 0.3%,
Preservative 0.12%, deionized water 64.18%.
The preparation method of above-mentioned cleaning agent: feed intake according to the component in formula and deal, first by poly alkyl alcohol
Oxygen vinyl Ether sodium sulfate, octyl phenol polyoxyethylene ether-20, octyl phenol polyoxyethylene ether-30,
Sodium gluconate and deionized water put into reactor, are warming up to 60 DEG C, stirring and dissolving 60min, cooling
To 50 DEG C, it is subsequently adding Dipropylene glycol mono-n-butyl Ether, polypropylene glycerol aether, essence, preservative, continues
Continuous stirring 10min, cooling, blowing, packaging.
The present invention is not restricted to the described embodiments, and can come according to technical scheme and practical situation
Determine specific embodiment.
Claims (8)
1. a civil explosive industry scavenger specially, it is characterised in that: the composition of described abluent and content thereof
For: anion surfactant 3-12%, nonionic surfactant 5-15%, alcohol ether solvents 8-20%,
Chelating agent 0.1-0.5%, defoamer 0.05-0.5%, essence 0.1-0.5%, preservative 0.05-0.2%,
Surplus is deionized water.
2. civil explosive industry scavenger specially as claimed in claim 1, it is characterised in that: described abluent
Composition and content be: anion surfactant 5-10%, nonionic surfactant 9-12%,
Alcohol ether solvents 12-16%, chelating agent 0.15-0.3%, defoamer 0.1-0.25%, essence 0.15-0.3%,
Preservative 0.08-0.12%, surplus is deionized water.
3. civil explosive industry scavenger specially as claimed in claim 1, it is characterised in that: described anion table
Face activating agent is one or both in polyoxyethylenated alcohol sodium sulfate, sodium n-alkylbenzenesulfonate
Mixture.
4. civil explosive industry scavenger specially as claimed in claim 1, it is characterised in that: described nonionic table
Face activating agent is octyl phenol polyoxyethylene ether-10, octyl phenol polyoxyethylene ether-20 or octane
The mixture of one or more in base phenol polyoxyethylene ether-30.
5. civil explosive industry scavenger specially as claimed in claim 1, it is characterised in that: described alcohol ether is molten
Agent is one or more in diethylene glycol monobutyl ether, triethylene glycol butyl ether or Dipropylene glycol mono-n-butyl Ether
Mixture.
6. civil explosive industry scavenger specially as claimed in claim 1, it is characterised in that: described chelating agent
For the mixture of one or more in sodium citrate, sodium gluconate or disodiumedetate.
7. civil explosive industry scavenger specially as claimed in claim 1, it is characterised in that: described defoamer
Mixing for one or more in polypropylene glycerol aether, polyoxyethylene glycerol ether or polydimethylsiloxane
Compound.
8. a preparation method for the civil explosive industry scavenger specially as described in any one of claim 1-7, its
It is characterised by: first by anion surfactant, non-surface-active agent, chelating agent and the water of described proportioning
Put into reactor, then heat to 60-85 DEG C, stirring and dissolving 30-60min, then it is cooled to 50-60 DEG C,
Add the alcohol ether solvents of described proportioning, defoamer, essence and preservative, continue stirring 10-20min,
Cooling, blowing, pack.
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106566703A (en) * | 2016-11-15 | 2017-04-19 | 安徽理工大学 | Detergent for emulsive explosives, preparation method for detergent and application of detergent |
CN109576074A (en) * | 2018-10-31 | 2019-04-05 | 新疆舰目摩托车有限公司 | A kind of lithium battery diaphragm cleaning agent |
CN111548669A (en) * | 2020-05-28 | 2020-08-18 | 江苏冠军科技集团股份有限公司 | High-flash-point exemption diluent and preparation method and application thereof |
CN111763579A (en) * | 2020-06-04 | 2020-10-13 | 山东将军烟草新材料科技有限公司 | Paraffin cleaning agent in production of cigarette blasting beads as well as preparation method and use method thereof |
CN112226305A (en) * | 2020-11-10 | 2021-01-15 | 张函 | Efficient detergent for cleaning explosives and preparation method thereof |
CN113626978A (en) * | 2021-06-23 | 2021-11-09 | 浙江中控技术股份有限公司 | On-line prediction method and system for detonation velocity of civil explosive emulsion explosive |
CN115819157A (en) * | 2022-12-21 | 2023-03-21 | 雅化集团雅安实业有限公司 | Recovery processing method for unqualified emulsion explosive |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106566703A (en) * | 2016-11-15 | 2017-04-19 | 安徽理工大学 | Detergent for emulsive explosives, preparation method for detergent and application of detergent |
CN106566703B (en) * | 2016-11-15 | 2019-02-19 | 安徽理工大学 | A kind of emulsion cleaning agent, preparation method and application |
CN109576074A (en) * | 2018-10-31 | 2019-04-05 | 新疆舰目摩托车有限公司 | A kind of lithium battery diaphragm cleaning agent |
CN111548669A (en) * | 2020-05-28 | 2020-08-18 | 江苏冠军科技集团股份有限公司 | High-flash-point exemption diluent and preparation method and application thereof |
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