CN101475886B - Method for manufacturing sisal hemp soap - Google Patents
Method for manufacturing sisal hemp soap Download PDFInfo
- Publication number
- CN101475886B CN101475886B CN2009100101711A CN200910010171A CN101475886B CN 101475886 B CN101475886 B CN 101475886B CN 2009100101711 A CN2009100101711 A CN 2009100101711A CN 200910010171 A CN200910010171 A CN 200910010171A CN 101475886 B CN101475886 B CN 101475886B
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- Prior art keywords
- soap
- sisal
- soap base
- buck
- grease
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- Expired - Fee Related
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- 239000000344 soap Substances 0.000 title claims abstract description 73
- 244000198134 Agave sisalana Species 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 235000011624 Agave sisalana Nutrition 0.000 title claims description 18
- 239000000835 fiber Substances 0.000 claims abstract description 23
- 238000007127 saponification reaction Methods 0.000 claims abstract description 20
- 239000003513 alkali Substances 0.000 claims abstract description 17
- 239000004519 grease Substances 0.000 claims abstract description 17
- 238000009835 boiling Methods 0.000 claims abstract description 16
- 238000005406 washing Methods 0.000 claims abstract description 15
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000002585 base Substances 0.000 claims description 36
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- GMBQZIIUCVWOCD-WWASVFFGSA-N Sarsapogenine Chemical compound O([C@@H]1[C@@H]([C@]2(CC[C@@H]3[C@@]4(C)CC[C@H](O)C[C@H]4CC[C@H]3[C@@H]2C1)C)[C@@H]1C)[C@]11CC[C@H](C)CO1 GMBQZIIUCVWOCD-WWASVFFGSA-N 0.000 claims description 15
- RTMWIZOXNKJHRE-UHFFFAOYSA-N Tigogenin Natural products CC1COC2CC(C)(OC12)C3CCC4C5CCC6CC(O)CCC6(C)C5CCC34C RTMWIZOXNKJHRE-UHFFFAOYSA-N 0.000 claims description 15
- 230000004927 fusion Effects 0.000 claims description 12
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 241001504664 Crossocheilus latius Species 0.000 claims description 3
- 241001465754 Metazoa Species 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 2
- 235000013599 spices Nutrition 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 239000002351 wastewater Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 239000000049 pigment Substances 0.000 abstract description 3
- 238000002360 preparation method Methods 0.000 abstract description 3
- 239000004088 foaming agent Substances 0.000 abstract 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 9
- 229930182490 saponin Natural products 0.000 description 9
- 150000007949 saponins Chemical class 0.000 description 9
- 239000000284 extract Substances 0.000 description 5
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 3
- 241000931143 Gleditsia sinensis Species 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229930002875 chlorophyll Natural products 0.000 description 2
- 235000019804 chlorophyll Nutrition 0.000 description 2
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 2
- 238000004134 energy conservation Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 241000282326 Felis catus Species 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000005267 amalgamation Methods 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009432 framing Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention provides a method for producing sisal soap, which comprises: performing soda boiling on sisal and obtaining sisal fibers and ticogenin genuine soap; utilizing residual aqueous alkali and grease for saponification to prepare fused genuine soap; and utilizing the fused genuine soap to prepare the soap. Because the prepared soap contains ticogenin and grease genuine soap, the prepared soap has the characteristics of good washing effect and non-pollution. Simultaneously, the prepared soap has the characteristics of reducing application of other foaming agent and maintaining a natural pigment, also has the characteristics of realizing preparation of the fibers and the soap by a one-step method, fully utilizing heat energy, improving the preparation speed of the sisal fibers and reducing wastewater emission, and is suitable to be applied to production of washing articles.
Description
Technical field
What the present invention proposed is the articles for washing of filed of daily-use chemical industry, specifically method for manufacturing sisal hemp soap.
Background technology
Saponin is can water-soluble and blistered material, so, can use its washing clothes, have the character that pure natural is easy to decompose, and, injured skin not also, in articles for washing incomplete ancient times, rich and powerful family is just washed with Fructus Gleditsiae Abnormalis extract and is combed one's hair and clothing.
Contain saponin in the Chinese honey locust, be added in the laundry soap, replace rosin, water glass, cats product with its extract.For example be added with the upright white articles for washing of Chinese honey locust.Its Fructus Gleditsiae Abnormalis extract is directly to be added in the washing composition, because direct adding Fructus Gleditsiae Abnormalis extract influences framing of soap and amalgamation, so not only production technique is miscellaneous, but also is difficult to guarantee the proterties of cleaning product.
Contain a large amount of saponin in the sisal hemp, but the sisal hemp main application is the fiber that extracts in the blade, and its saponin is drained in the waste water, not only polluted source also causes the waste of saponin.If concentrate from waste water and obtain saponin, then economy is uneconomical.
Summary of the invention
In order to make a kind of soap products that contains tigogenin, the present invention proposes method for manufacturing sisal hemp soap.This method is used the direct saponification of last buck and grease again by the sisal leaves soda boiling is obtained sisal fibers, obtains soap base, makes soap again, solves the technical problem of the direct soapmaking of sisal hemp with this.
The scheme that technical solution problem of the present invention is adopted is:
1, the sisal hemp soda boiling obtains sisal fibers and tigogenin soap base: bright sisal leaves or dried sisal leaves are torn becomes strip, join and be loaded with boiling in the saucepan that mass percent is 30～50% caustic-soda aqueous solution, after 30 minutes to 1 hour boiling, pull sisal fibers out, and press filtration goes out unnecessary buck, put in the clear water and wash, sisal fibers and alkali wash water after obtaining to wash;
2, utilize last buck and grease to carry out saponification and make the fusion soap base
Last buck of sisal hemp boiling and alkali wash water are put back in the saucepan, boil, add animal grease by saponification value, and continue the heating saponification, grease and alkali reaction form sodium soap and are mixed into the fusion soap base with the tigogenin soap base.
3, utilize the fusion soap base to produce soap
The fusion soap base that saponification is good shifts out saucepan in the lump together with buck and is poured in the cooling vessel, and the soap base cooled and solidified becomes stone roller, and after pulling out from buck, salt is washed and alkali cleaning, through preparation, moulding, makes the soap products that contains tigogenin.
Positively effect: sisal fibers and saponin soap base are produced in a soda boiling of sisal hemp, and with last thermokalite water and fat saponification, tigogenin soap base and grease soap base are merged, and make the articles for washing of finished product soap or other type again through cooperation.Owing to contain tigogenin and sodium soap in the sisal hemp soap, save and add rosin or water glass raw material and link, it is good to have washing effect, realize single stage method system fiber and soap, make full use of heat simultaneously, reduce energy consumption, improve the speed of producing of sisal fibers, reduce discharge of wastewater, have the characteristics of energy-conservation, efficient and environmental protection.Suitable articles for washing manufacturing is used.
Embodiment
1, the sisal hemp soda boiling obtains sisal fibers and tigogenin soap base
A, bright sisal leaves or dried sisal leaves torn become strip, standby;
B, by mass percentage that sodium hydroxide is soluble in water makes 30～50% caustic-soda aqueous solution;
C, caustic-soda aqueous solution is joined in the saucepan, heated and boiled is put into the sisal leaves bar in the thermokalite water then, and the amount of putting into is lower than plane on the alkali lye, the sisal leaves bar is immersed in below the liquid level, continue the boiling of heating, stir simultaneously, after 30 minutes to 1 hour boiling, pull sisal fibers out, and press filtration goes out unnecessary buck, puts in the clear water and washs, and obtains sisal fibers and alkali wash water after the washing;
2, utilize last buck and grease to carry out saponification and make the fusion soap base
Last buck of sisal hemp boiling and alkali wash water are put back in the saucepan, boil, add animal grease by saponification value, and continue the heating saponification, grease and alkali reaction form sodium soap and merge with the tigogenin soap base, become the fusion soap base.
Before adding grease, from buck, take a sample, detect its alkali content, carry out saponification test with grease again, obtain saponification value, decision adds greasy amount according to saponification value.
3, utilize the fusion soap base to produce soap
The fusion soap base that saponification is good swims in the upper strata of saucepan, buck and soap base are shifted out saucepan in the lump to be poured in the cooling vessel, the soap base cooled and solidified becomes stone roller, from buck, pull out, wash and alkali cleaning through supersalt by traditional soapmaking method again, obtain pure soap base, behind pure soap base cooperation spices, the soap products that finished product contains tigogenin is made in moulding.
Owing to contain chlorophyll and xenthophylls in the sisal leaves, and chlorophyll and xenthophylls also can participate in saponification, so if with bright sisal leaves soapmaking, then soap is natural green, if with dried sisal leaves soapmaking, then soap is natural yellow.So, need not add the pigment of synthetic with sisal leaves soapmaking, keep natural colour.
By method soapmaking of the present invention, directly obtain sisal fibers, produce sisal fibers than cooking process and save time, save the energy simultaneously, also without high-tension apparatus, safety.More can save time than aging process, and reduce the discharging of waste water, odorlessness, pollution-free.Biggest advantage is to utilize the saponin in the sisal hemp system fiber institute water, turns waste into wealth.
Tigogenin soap base and grease soap base form and merge soap base, produce in the process of soap with it, do not need to add rosin or water glass whipping agent, have reduced consumption of raw materials and production link, have reduced production cost.And the water capacity of tigogenin after being used to wash is easily by biological degradation, thereby reduces the pollution to natural water area.
Proceed fat saponification with the thermokalite water of producing the sisal fibers gained and sisal fibers bath water, do not need process of cooling, realized that heat makes full use of and the making full use of of alkali lye, reached energy-conservation and reduced the effect of caustic soda.
The soap of making by the inventive method has natural pigment, natural saponin, belongs to natural environment-friendly type articles for washing.According to said method can also make products such as washings, bathing agents, shampoo, for the washing field has increased new variety.
Claims (1)
1. method for manufacturing sisal hemp soap is characterized in that: obtains sisal fibers and tigogenin soap base (1), utilizes last buck and grease to carry out saponification to make and merge soap base (2) and utilization fusion soap base and produce soap (3) process and finish by the sisal hemp soda boiling, wherein:
(1), the sisal hemp soda boiling obtains sisal fibers and tigogenin soap base
A, bright sisal leaves or dried sisal leaves torn become strip, standby;
B, by mass percentage that sodium hydroxide is soluble in water makes 30～50% caustic-soda aqueous solution;
C, caustic-soda aqueous solution is joined in the saucepan, heated and boiled is put into the sisal leaves bar in the thermokalite water then, and the amount of putting into is lower than plane on the alkali lye, the sisal leaves bar is immersed in below the liquid level, continue the boiling of heating, stir simultaneously, after 30 minutes to 1 hour boiling, pull sisal fibers out, and press filtration goes out unnecessary buck, puts in the clear water and washs, and obtains sisal fibers and alkali wash water after the washing;
(2), utilize last buck and grease to carry out saponification and make the fusion soap base
Last buck of sisal hemp boiling and alkali wash water are put back in the saucepan, boil, add animal grease by saponification value, and continue the heating saponification, grease and alkali reaction form sodium soap and merge with the tigogenin soap base, become the fusion soap base;
(3), utilize the fusion soap base to produce soap
Buck and soap base are shifted out saucepan in the lump be poured in the cooling vessel, the soap base cooled and solidified becomes stone roller, pulls out from buck, washes and alkali cleaning through supersalt, obtains pure soap base, pure soap base is cooperated spices after, the soap products that finished product contains tigogenin is made in moulding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100101711A CN101475886B (en) | 2009-01-20 | 2009-01-20 | Method for manufacturing sisal hemp soap |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100101711A CN101475886B (en) | 2009-01-20 | 2009-01-20 | Method for manufacturing sisal hemp soap |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101475886A CN101475886A (en) | 2009-07-08 |
| CN101475886B true CN101475886B (en) | 2011-03-30 |
Family
ID=40836665
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100101711A Expired - Fee Related CN101475886B (en) | 2009-01-20 | 2009-01-20 | Method for manufacturing sisal hemp soap |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101475886B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102031207B (en) * | 2010-11-05 | 2012-07-11 | 辽宁唐人神曙光农牧集团有限公司 | Method for producing soap base by utilizing waste water containing grease |
| CN105543017A (en) * | 2016-03-07 | 2016-05-04 | 黄圭鹏 | Sisal hemp soap |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1528782A (en) * | 2003-10-09 | 2004-09-15 | 滕明星 | Sisal hemp steroid hormone production method |
| CN1830997A (en) * | 2005-09-22 | 2006-09-13 | 王锦军 | Process for producing high purity hecogenin and tigogenin |
-
2009
- 2009-01-20 CN CN2009100101711A patent/CN101475886B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1528782A (en) * | 2003-10-09 | 2004-09-15 | 滕明星 | Sisal hemp steroid hormone production method |
| CN1830997A (en) * | 2005-09-22 | 2006-09-13 | 王锦军 | Process for producing high purity hecogenin and tigogenin |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101475886A (en) | 2009-07-08 |
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Owner name: HANGZHOU CONIE INDUSTRY CO., LTD. Free format text: FORMER OWNER: LI JUNTING Effective date: 20131031 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| C53 | Correction of patent for invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wang Lihua Inventor before: Li Junting |
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| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 125000 HULUDAO, LIAONING PROVINCE TO: 311258 HANGZHOU, ZHEJIANG PROVINCE Free format text: CORRECT: INVENTOR; FROM: LI JUNTING TO: WANG LIHUA |
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Effective date of registration: 20131031 Address after: 311258, No. 1801 Asia Pacific Road, Wen Yan Town, Xiaoshan District, Zhejiang, Hangzhou Patentee after: HANGZHOU KANGLI INDUSTRIAL CO., LTD. Address before: 125000, Huludao, Liaoning province Longgang District Longwan Street No. 17-1 Huludao days Patent Office Patentee before: Li Junting |
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Effective date of registration: 20160111 Address after: 310008, No. 1801, Asia Pacific Road, Dao Yan Street, Xiaoshan District, Zhejiang, Hangzhou Patentee after: Hangzhou ship Biotechnology Co., Ltd. Address before: 311258, No. 1801 Asia Pacific Road, Wen Yan Town, Xiaoshan District, Zhejiang, Hangzhou Patentee before: HANGZHOU KANGLI INDUSTRIAL CO., LTD. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110330 Termination date: 20180120 |