CN101469258B - Color modified phenolic resin adhesive, color phenolic resin overlay film prepared thereby and plated inclusing the same - Google Patents
Color modified phenolic resin adhesive, color phenolic resin overlay film prepared thereby and plated inclusing the same Download PDFInfo
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- CN101469258B CN101469258B CN200810127188A CN200810127188A CN101469258B CN 101469258 B CN101469258 B CN 101469258B CN 200810127188 A CN200810127188 A CN 200810127188A CN 200810127188 A CN200810127188 A CN 200810127188A CN 101469258 B CN101469258 B CN 101469258B
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Abstract
The invention discloses a colorful modified phenolic resin adhesive, which is prepared by the following steps: formaldehyde, phenol, and caustic soda are added into a reaction kettle to be stirred, are heated to be between 60 and 90 DEG C, and are constantly stirred to ensure the full mixing, and a covering agent, a wetting agent and water are added into the mixture to be stirred evenly when the viscosity reaches between 0.10 and 0.23Pa.s; and then a plasticizer, a surfactant and pigment are added into the mixture to be stirred continually and evenly. A colorful phenolic resin coating is prepared by brown paper or cotton cloth impregnated with the colorful modified phenolic resin adhesive. The colorful phenolic resin coating has good burning resistance, water resistance, and chemical resistance, is difficult to fall off, and has the advantages of good durability, uniform color and luster, no fading, no color losing and good glossiness.
Description
Technical field
The present invention relates to a kind of Phenol aldehyde resin, relate in particular to a kind of color modified Phenol aldehyde resin, utilize the colored coating phenolic resin of its preparation and contain the sheet material of this overlay film.
Background technology
Resol has excellent water tolerance, thus its as tackiness agent be widely used in wood veneer, shaving board, in the manufacturing of (height) density board, core-board or other wood-based plate; Developed in recent years this kind tackiness agent was applied to face veneer formation film coated plate.But the color of existing Phenol aldehyde resin is single, has only black and brown.
Summary of the invention
One of the object of the invention provides a kind of uniform color modified Phenol aldehyde resin of good burning resistance, water tolerance, chemical resistant properties and color and luster that has.
Another object of the present invention provides a kind of have good burning resistance, water tolerance, chemical resistant properties, difficult drop-off, has favorable durability, and color and luster even, colour-fast, do not fade, colored coating phenolic resin that glossiness is good.
A purpose more of the present invention provides the sheet material that contains above-mentioned colored coating phenolic resin.
For solving the problems of the technologies described above, the present invention adopts following technical scheme:
A kind of color modified Phenol aldehyde resin, process by following components by part by weight:
Formaldehyde 7-20 part phenol 8-15 part caustic soda 0.5-4 part
Covering agent 0.01-1 part wetting agent 0.01-0.8 part softening agent 0.01-0.6 part
Tensio-active agent 0.01-0.7 part pigment 0.01-2 part water 0.5-5 part
Formaldehyde, phenol, caustic soda added in the retort stir, and be heated to 60 ℃-90 ℃, constantly stir it is fully reacted, when viscosity reaches 0.10Pa.s-0.23Pa.s, add covering agent, wetting agent and water and continue to stir; And then add softening agent, tensio-active agent and pigment and continue to stir, color modified Phenol aldehyde resin.
Color modified Phenol aldehyde resin according to the invention, the preferred weight part of wherein said each component is:
Formaldehyde 10-15 part phenol 11-13 part caustic soda 1-2.5 part
Covering agent 0.2-0.5 part wetting agent 0.3-0.5 part softening agent 0.2-0.4 part
Tensio-active agent 0.2-0.4 part pigment 0.5-1.5 part water 2-3 part
Color modified Phenol aldehyde resin according to the invention, the most preferred weight part of wherein said each component is:
2.5 parts in 12 parts of caustic soda of 15 parts of phenol of formaldehyde
0.4 part in 0.4 part of softening agent of 0.5 part of wetting agent of covering agent
3 parts in 1 part of water of 0.3 part of pigment of tensio-active agent
Color modified Phenol aldehyde resin according to the invention wherein adds covering agent, wetting agent and water and continues to stir when viscosity reaches 0.15Pa.s-0.18Pa.s.
The present invention also provides a kind of colored coating phenolic resin, and it is dry and get by the kraft paper that is soaked with above-mentioned color modified Phenol aldehyde resin or cotton.
The present invention also provides a kind of sheet material, and it is formed by many above-mentioned colored coating phenolic resins curing.
The present invention also provides a kind of sheet material that contains the Chromatic color coating phenolic resin, comprises base material, is covered with the above-mentioned colored coating phenolic resin of one deck at least at least one surface of base material.
Wherein, said base material be wood veneer, shaving board, in/high-density plate, core-board or other wood-based plates.
The color modified Phenol aldehyde resin of the present invention has good burning resistance, water tolerance, chemical resistant properties, and color and luster is even.The colored coating phenolic resin of the present invention has good burning resistance, water tolerance and chemical resistant properties, difficult drop-off, has favorable durability, can make the coating phenolic resin of any color, and color and luster even, colour-fast, do not fade, glossiness is good.
Embodiment
Covering agent of the present invention can adopt white titanium pigment, perlite powder etc.; Wetting agent can adopt the modification TX10, AEO, sodium lauryl sulphate or sulfonated alkyl naphathalene etc.; Softening agent can adopt Witcizer 300, DOP, phthalic ester, triphenylphosphate, clorafin etc.; Tensio-active agent can adopt Triple Pressed Stearic Acid, Zinic stearas, calcium stearate, Magnesium Stearate, soybean SULPHOSUCCINIC ACID ESTER etc.; Pigment can adopt any other pigment that can buy on pigment that Hangzhou power standing grain pigment ltd produces or the market.
Embodiment 1
With stirring in 17 kilograms of formaldehyde, 10 kilograms of phenol, 2 kilograms of caustic soda adding retort; And be heated to 60 ℃; Constantly stir it is fully reacted, measure viscosity and when reaching 0.15Pa.s, add 0.5 kilogram of white titanium pigment, 0.3 kilogram of modification TX10 and 0.5L water and continue to stir; And then add 0.01 kilogram of Witcizer 300,0.2 kilogram of Triple Pressed Stearic Acid and 0.01 kilogram of veridian and continue to stir, green modified alkyd resin glue.
Above-mentioned green modified alkyd resin glue is put into the glue groove, kraft paper or cotton are immersed in the green modified alkyd resin glue, form uniformly wet glued membrane, the glued membrane that will wet is sent into and is carried out drying in drying machine or the baking oven, gets green coating phenolic resin.
Embodiment 2
With stirring in 7 kilograms of formaldehyde, 8 kilograms of phenol, 0.6 kilogram of caustic soda adding retort; And be heated to 68 ℃; Constantly stir it is fully reacted, measure viscosity and when reaching 0.10Pa.s, add 0.01 kilogram of white titanium pigment, 0.03 kilogram of modification TX10 and 2L water and continue to stir; And then add 0.35 kilogram of Witcizer 300,0.02 kilogram of Triple Pressed Stearic Acid and 0.5 kilogram of red pigment and continue to stir, red modified alkyd resin glue.
Above-mentioned red modified alkyd resin glue is put into the glue groove, kraft paper or cotton are immersed in the red modified alkyd resin glue, form uniformly wet glued membrane, the glued membrane that will wet is sent into and is carried out drying in drying machine or the baking oven, gets red coating phenolic resin.
Embodiment 3
With stirring in 20 kilograms of formaldehyde, 15 kilograms of phenol, 4 kilograms of caustic soda adding retort; And be heated to 75 ℃; Constantly stir it is fully reacted, measure viscosity and when reaching 0.23Pa.s, add 1 kilogram of white titanium pigment, 0.75 kilogram of modification TX10 and 4.5L water and continue to stir; And then add 0.6 kilogram of Witcizer 300,0.6 kilogram of Triple Pressed Stearic Acid and 1.8 kilograms of black pigments and continue to stir, the black modified alkyd resin glue.
Above-mentioned black modified alkyd resin glue is put into the glue groove, kraft paper or cotton are immersed in the black modified alkyd resin glue, form uniformly wet glued membrane, the glued membrane that will wet is sent into and is carried out drying in drying machine or the baking oven, gets the black coating phenolic resin.
Embodiment 4
With stirring in 10 kilograms of formaldehyde, 13 kilograms of phenol, 1 kilogram of caustic soda adding retort; And be heated to 80 ℃; Constantly stir it is fully reacted, measure viscosity and when reaching 0.18Pa.s, add 0.2 kilogram of perlite powder, 0.4 kilogram of sodium lauryl sulphate and 3L water and continue to stir; And then add 0.2 kilogram of phthalic ester, 0.2 kilogram of Zinic stearas and 1.0 kilograms of white pigments and continue to stir, cream-coloured modified alkyd resin glue.
Above-mentioned cream-coloured modified alkyd resin glue is put into the glue groove, kraft paper or cotton are immersed in the cream-coloured modified alkyd resin glue, form uniformly wet glued membrane, the glued membrane that will wet is sent into and is carried out drying in drying machine or the baking oven, gets cream-coloured coating phenolic resin.
Embodiment 5
With stirring in 13 kilograms of formaldehyde, 11 kilograms of phenol, 2.5 kilograms of caustic soda adding retort; And be heated to 90 ℃; Constantly stir it is fully reacted, measure viscosity and when reaching 0.13Pa.s, add 0.5 kilogram of perlite powder, 0.5 kilogram of sodium lauryl sulphate and 3.5L water and continue to stir; And then add 0.4 kilogram of phthalic ester, 0.4 kilogram of Zinic stearas and 1.5 kilograms of basket look pigment and continue to stir, blue modified alkyd resin glue.
Above-mentioned blue modified alkyd resin glue is put into the glue groove, kraft paper or cotton are immersed in the blue modified alkyd resin glue, form uniformly wet glued membrane, the glued membrane that will wet is sent into and is carried out drying in drying machine or the baking oven, gets the blue phenolic resin coating.
Embodiment 6
With stirring in 15 kilograms of formaldehyde, 12 kilograms of phenol, 2.5 kilograms of caustic soda adding retort; And be heated to 83 ℃; Constantly stir it is fully reacted, measure viscosity and when reaching 0.21Pa.s, add 0.5 kilogram of perlite powder, 0.4 kilogram of sodium lauryl sulphate and 3L water and continue to stir; And then add 0.4 kilogram of phthalic ester, 0.3 kilogram of Zinic stearas and 1 kilogram of violet pigment and continue to stir, the purple modified alkyd resin glue.
Above-mentioned purple modified alkyd resin glue is put into the glue groove, kraft paper or cotton are immersed in the purple modified alkyd resin glue, form uniformly wet glued membrane, the glued membrane that will wet is sent into and is carried out drying in drying machine or the baking oven, gets the purple coating phenolic resin.
Embodiment 7
Different with embodiment 1 is: covering agent adopts perlite powder; Wetting agent adopts AEO; Softening agent adopts triphenylphosphate, and tensio-active agent adopts calcium stearate, and pigment adopts orange pigments; Other steps are all identical with embodiment 1, obtain orange Phenol aldehyde resin and orange coating phenolic resin.
Embodiment 8
Different with embodiment 2 is: covering agent adopts perlite powder; Wetting agent adopts sulfonated alkyl naphathalene; Softening agent adopts DOP, and tensio-active agent adopts Magnesium Stearate, and pigment adopts blueness and black pigment; Other steps are all identical with embodiment 2, obtain brown Phenol aldehyde resin and brown Phenol aldehyde resin overlay film.
Embodiment 9
Different with embodiment 3 is: covering agent adopts perlite powder; Wetting agent adopts AEO; Softening agent adopts DOP, and tensio-active agent adopts calcium stearate, and pigment adopts deep green pigment; Other steps are all identical with embodiment 3, obtain deep green Phenol aldehyde resin and deep green Phenol aldehyde resin overlay film.
Embodiment 10
Different with embodiment 4 is: covering agent adopts white titanium pigment; Wetting agent adopts sulfonated alkyl naphathalene; Softening agent adopts clorafin, and tensio-active agent adopts the soybean SULPHOSUCCINIC ACID ESTER, and pigment adopts orange pigments; Other steps are all identical with embodiment 4, obtain orange Phenol aldehyde resin and orange coating phenolic resin.
Embodiment 11
Different with embodiment 5 is: covering agent adopts white titanium pigment; Wetting agent adopts AEO; Softening agent adopts triphenylphosphate, and tensio-active agent adopts Magnesium Stearate, and pigment adopts yellow ultramarine; Other steps are all identical with embodiment 5, obtain yellow Phenol aldehyde resin and yellow coating phenolic resin.
Embodiment 12
Different with embodiment 6 is: covering agent adopts white titanium pigment; Wetting agent adopts sulfonated alkyl naphathalene; Softening agent adopts clorafin, and tensio-active agent adopts the soybean SULPHOSUCCINIC ACID ESTER, and pigment adopts red-brown pigment; Other steps are all identical with embodiment 6, obtain red-brown Phenol aldehyde resin and red-brown coating phenolic resin.
Embodiment 13
Different with embodiment 6 is: wetting agent adopts the modification TX10; Softening agent adopts DOP, and tensio-active agent adopts Magnesium Stearate, and pigment adopts blue pigments; Other steps are all identical with embodiment 6, obtain blue phenolic Resin adhesive and blue phenolic resin coating.
Embodiment 14
Different with embodiment 6 is: wetting agent adopts AEO; Softening agent adopts triphenylphosphate, and tensio-active agent adopts Triple Pressed Stearic Acid, and pigment adopts golden pigment; Other steps are all identical with embodiment 6, obtain golden Phenol aldehyde resin and golden coating phenolic resin.
Embodiment 15
The colored coating phenolic resin that 20 above-mentioned arbitrary embodiment are made is stacked together, and sends into hot pressing in the thermocompressor, and colored coating phenolic resin is solidified, and the sheet material that makes has good burning resistance, water tolerance, chemical resistant properties and weather resistance.The number of colored coating phenolic resin is confirmed according to the thickness and the desirable strength of the sheet material that will make.
Embodiment 16
Existing wood veneer, shaving board, in/the upper and lower surface of high-density plate, core-board or other wood-based plate respectively is covered with the colored coating phenolic resin that the above-mentioned arbitrary embodiment of one deck makes, obtains containing the sheet material of Chromatic color coating phenolic resin.Colored coating phenolic resin can stick on substrate surface or be pressed together on substrate surface through hot pressing through tackiness agent.This sheet material has good burning resistance, water tolerance, chemical resistant properties and weather resistance.
Above-described embodiment describes preferred implementation of the present invention; Be not that scope of the present invention is limited; Design under the prerequisite of spirit not breaking away from the present invention; Various distortion and improvement that those of ordinary skills make technical scheme of the present invention all should fall in the definite protection domain of claims of the present invention.
Claims (8)
1. color modified Phenol aldehyde resin is characterized in that being processed by following components by part by weight:
Formaldehyde 7-20 part phenol 8-15 part caustic soda 0.5-4 part
White titanium pigment or perlite powder 0.01-1 part wetting agent 0.01-0.8 part softening agent 0.01-0.6 part
Tensio-active agent 0.01-0.7 part pigment 0.01-2 part water 0.5-5 part
Formaldehyde, phenol, caustic soda added in the retort stir, and be heated to 60 ℃-90 ℃, constantly stir it is fully reacted, when viscosity reaches 0.10Pa.s-0.23Pa.s, add white titanium pigment or perlite powder, wetting agent and water continue to stir; And then add softening agent, tensio-active agent and pigment and continue to stir, color modified Phenol aldehyde resin.
2. color modified Phenol aldehyde resin according to claim 1 is characterized in that the weight part of said each component is:
Formaldehyde 10-15 part phenol 11-13 part caustic soda 1-2.5 part
White titanium pigment or perlite powder 0.2-0.5 part wetting agent 0.3-0.5 part softening agent 0.2-0.4 part
Tensio-active agent 0.2-0.4 part pigment 0.5-1.5 part water 2-3 part.
3. color modified Phenol aldehyde resin according to claim 2 is characterized in that the weight part of said each component is:
2.5 parts in 12 parts of caustic soda of 15 parts of phenol of formaldehyde
0.4 part in 0.4 part of softening agent of 0.5 part of wetting agent of white titanium pigment or perlite powder
3 parts in 1 part of water of 0.3 part of pigment of tensio-active agent.
4. color modified Phenol aldehyde resin according to claim 3 is characterized in that: adding white titanium pigment or perlite powder, wetting agent and water continue to stir when viscosity reaches 0.15Pa.s-0.18Pa.s.
5. colored coating phenolic resin is characterized in that: it is dry and get by the kraft paper that is soaked with each described color modified Phenol aldehyde resin of claim 1-4 or cotton.
6. sheet material is characterized in that: it is solidified by many described colored coating phenolic resins of claim 5 and forms.
7. a sheet material that contains the Chromatic color coating phenolic resin comprises base material, it is characterized in that: be covered with the described colored coating phenolic resin of one deck claim 5 at least at least one surface of base material.
8. the sheet material that contains the Chromatic color coating phenolic resin according to claim 7 is characterized in that: said base material be wood veneer, shaving board, in/high-density plate or core-board.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810127188A CN101469258B (en) | 2008-06-24 | 2008-06-24 | Color modified phenolic resin adhesive, color phenolic resin overlay film prepared thereby and plated inclusing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810127188A CN101469258B (en) | 2008-06-24 | 2008-06-24 | Color modified phenolic resin adhesive, color phenolic resin overlay film prepared thereby and plated inclusing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101469258A CN101469258A (en) | 2009-07-01 |
| CN101469258B true CN101469258B (en) | 2012-08-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN200810127188A Expired - Fee Related CN101469258B (en) | 2008-06-24 | 2008-06-24 | Color modified phenolic resin adhesive, color phenolic resin overlay film prepared thereby and plated inclusing the same |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102977296B (en) * | 2012-11-29 | 2014-09-10 | 开县汇森木材加工厂 | Method for processing high-hardness phenolic resin glue used for surface of building template |
| FI126195B (en) | 2014-01-28 | 2016-08-15 | Upm Kymmene Corp | Fiber-based product |
| CN109796897A (en) * | 2019-02-23 | 2019-05-24 | 常州市顺龙宏源包装有限公司 | A kind of PE protective film |
| CN113043679B (en) * | 2021-04-14 | 2022-08-02 | 山东澳兴绝缘材料有限公司 | Manufacturing method of household article phenolic aldehyde cotton cloth laminated board |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6022947A (en) * | 1998-09-18 | 2000-02-08 | Union Camp Corporation | Light-colored, low molecular weight phenolic-modified rosin esters |
| CN1260374A (en) * | 2000-01-20 | 2000-07-19 | 刘文慧 | Bi-component corrosion-proof gum |
| CN1515600A (en) * | 2003-01-02 | 2004-07-28 | 杨志敏 | Method for making modified phenol-formaldehyde resin and adhesive containing said resin |
-
2008
- 2008-06-24 CN CN200810127188A patent/CN101469258B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6022947A (en) * | 1998-09-18 | 2000-02-08 | Union Camp Corporation | Light-colored, low molecular weight phenolic-modified rosin esters |
| CN1260374A (en) * | 2000-01-20 | 2000-07-19 | 刘文慧 | Bi-component corrosion-proof gum |
| CN1515600A (en) * | 2003-01-02 | 2004-07-28 | 杨志敏 | Method for making modified phenol-formaldehyde resin and adhesive containing said resin |
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| CN101469258A (en) | 2009-07-01 |
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Granted publication date: 20120829 Termination date: 20130624 |