CN101456661B - Curing agent composition and method for making the same - Google Patents
Curing agent composition and method for making the same Download PDFInfo
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- CN101456661B CN101456661B CN2007101793161A CN200710179316A CN101456661B CN 101456661 B CN101456661 B CN 101456661B CN 2007101793161 A CN2007101793161 A CN 2007101793161A CN 200710179316 A CN200710179316 A CN 200710179316A CN 101456661 B CN101456661 B CN 101456661B
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- 239000000203 mixture Substances 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 21
- 239000004568 cement Substances 0.000 claims abstract description 14
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 7
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 claims abstract description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 7
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 7
- 238000000227 grinding Methods 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims abstract description 4
- 239000004575 stone Substances 0.000 claims description 28
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 12
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 12
- 239000004571 lime Substances 0.000 claims description 12
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 6
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 claims description 6
- 239000011507 gypsum plaster Substances 0.000 claims description 6
- 235000019353 potassium silicate Nutrition 0.000 claims description 6
- 238000002156 mixing Methods 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 239000004848 polyfunctional curative Substances 0.000 abstract 2
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 229940103272 aluminum potassium sulfate Drugs 0.000 abstract 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract 1
- 239000000920 calcium hydroxide Substances 0.000 abstract 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 abstract 1
- 235000011116 calcium hydroxide Nutrition 0.000 abstract 1
- 229910052602 gypsum Inorganic materials 0.000 abstract 1
- 239000010440 gypsum Substances 0.000 abstract 1
- 230000003014 reinforcing effect Effects 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 235000019794 sodium silicate Nutrition 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 230000006835 compression Effects 0.000 description 11
- 238000007906 compression Methods 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 9
- 238000007596 consolidation process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 5
- 239000004567 concrete Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000002787 reinforcement Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- 230000005641 tunneling Effects 0.000 description 2
- 238000010009 beating Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003818 cinder Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention relates to a rapid high-strength hardener composition for a pelitization substance of mudstone of a laneway base plate of a mine and a method for preparing the same. The composition is prepared through mixing and grinding sulphate aluminium cement clinker, hydrated gypsum, hydrated lime, sodium sulfate, sodium silicate, aluminum potassium sulfate and sodium hydroxide into powder with specific surface area of between 200m<2>/kg and 900m<2>/kg. The rapid high-strength hardener composition carries out reinforcing treatment on the pelitization substance of mudstone and has the advantages of short time for forming a condensate and high strength of the formed condensate.
Description
Technical field
The present invention relates to a kind of curing agent composition and preparation method thereof, more specifically, the present invention relates to a kind of quick high-strength curing agent composition that is specifically designed to mine working base plate mud stone argillization thing and preparation method thereof.
Background technology
The mine working floor strata is many to be made up of mud stone or mud shale, and mud stone can form the mud stone argillization thing of similar mud under certain condition after meeting water, thereby the phenomenon of softening disintegration occurs, and this makes the mine working base plate become muddy.Passing through of the muddy serious obstruction equipment of roadway floor meeting, vehicle influences the construction and the operating environment in tunnel, tunnelling speed also had a significant impact, thereby cause serious economy loss.
For addressing the above problem, for the processing of described mud stone argillization thing, normally abandon in the stockyard after the desilting of described mud stone argillization thing it being transported the tunnel, in the tunnel, build certain thickness concrete road surface then.Treatment process although it is so can solve the problem that above-mentioned roadway floor becomes muddy, but because concrete needs some days curing time, therefore the tunnel can not traffick and equipment in preserving period, thereby influence the tunneling construction speed in whole tunnel, and described mud stone argillization thing is abandoned in a large number in the stockyard and can be caused serious pollution to the mining area surrounding enviroment.
In addition, for addressing the above problem, industry also adopts another method that described mud stone argillization thing is handled, and promptly uses reinforcement material that described mud stone argillization thing is carried out consolidation process.In this treatment process, employed reinforcement material mainly is cement and lime.Yet the mud more general owing to the microtexture of mud stone argillization thing is more loose, and is being mingled with the bigger cinder of particle diameter and soft rock chip and organic substance, makes the physical property of mud stone argillization thing be different from general mud.Because it is longer that cement and described mud stone argillization thing form the time of cured body, and the intensity of the final cured body that forms is on the low side, therefore uses the effect of the described mud stone argillization of cement stabilization thing unsatisfactory usually.When described mud stone argillization water content of matter was higher, lime was not good enough for its consolidation effect yet, can exist to be reinforced the shortcoming that thing intensity is lower and lime consumption is bigger than normal.
Therefore, the object of the present invention is to provide a kind of quick high-strength curing agent composition that is specifically designed to mine working base plate mud stone argillization thing, to solve the above-mentioned problems in the prior art, thereby can not influence the tunneling construction speed in whole tunnel, and it is not polluted the mining area surrounding enviroment owing to the existence of mine laneway base plate mud stone argillization thing.
Summary of the invention
The object of the present invention is to provide a kind of quick high-strength curing agent composition that is specifically designed to mine working base plate mud stone argillization thing.
Another object of the present invention is to provide a kind of preparation method of above-mentioned composition.
The quick high-strength curing agent composition that is used for mine working base plate mud stone argillization thing provided by the present invention, by weight percentage, said composition is made up of following component:
Sulphoaluminate cement clinker 40～60%
The plaster of Paris 20～40%
White lime 5～15%
Sodium sulfate 0.2～3%
Water glass 0.1～3%
Potassium aluminium sulfate 1～6%
Sodium hydroxide 1～3%
In above-mentioned quick high-strength curing agent composition, by weight percentage, the content of sulphoaluminate cement clinker is preferably 50～55%, the content of the plaster of Paris is preferably 30～40%, the content of white lime is preferably 10～15%, and the content of sodium sulfate is preferably 1.5～2.5%, and the content of water glass is preferably 1.5～2.5%, the content of potassium aluminium sulfate is preferably 2～4%, and the content of sodium hydroxide is preferably 1.5～2.5%.
The method for preparing quick high-strength curing agent composition of the present invention is to be 200m by described each component mixed grinding is become specific surface area
2/ kg～900m
2The powder of/kg, thus quick high-strength curing agent composition of the present invention obtained.
Compared with prior art, quick high-strength curing agent composition provided by the present invention has following beneficial effect:
(1) solidification treatment is effective
Adopt quick high-strength curing agent composition of the present invention that mud stone argillization thing is carried out the characteristics that consolidation process has good high-early-strength, simultaneously can guarantee that again later strength can not reduce, and softening, argillization can not take place under the effect of tunnel water once more and lose intensity;
(2) waste is utilized again
The present invention can be treated to the good roadbed material of engineering properties with script depleted tunnel mud stone argillization thing;
(3) help environment protection
Handling mud stone argillization thing with the present invention can reduce the argillization thing and abandon the problem of environmental pollution that is produced; And
(4) with low cost
The cost that adopts quick high-strength curing agent composition provided by the invention that mud stone argillization thing is carried out consolidation process is lower than and adopts the cost of beating the operational method of concrete floor after traditional desilting.
Embodiment
Further describe quick high-strength curing agent composition provided by the present invention and preparation method thereof below by embodiment and Comparative Examples, but therefore the present invention is not subjected to any restriction.
Embodiment 1
By specified each component in the following table 1 sulphoaluminate cement clinker, the plaster of Paris, white lime, sodium sulfate, water glass, potassium aluminium sulfate and sodium hydroxide mixed grinding being become specific surface area respectively is 200m
2/ kg～900m
2The powder of/kg.
Under normal temperature and normal pressure, mixing weight percent in water ratio is about 50% mud stone argillization compound is that 15% above-mentioned solidifying agent is so that it forms cured article.Then, under the set time of test gained cured article, the normal curing condition and unconfined compression strength and breaking strain under the curing in water condition, in table 1, listed test result.
Embodiment 2
By the method for specified each component concentration repetition embodiment 1 in the following table 1, in table 1, listed test result.
Embodiment 3
By the method for specified each component concentration repetition embodiment 1 in the following table 1, in table 1, listed test result.
Embodiment 4
By the method for specified each component concentration repetition embodiment 1 in the following table 1, in table 1, listed test result.
Embodiment 5
By the method for specified each component concentration repetition embodiment 1 in the following table 1, in table 1, listed test result.
Comparative Examples 1
By specified each component in the following table 2 cement, lime are mixed respectively.
Under normal temperature and normal pressure, mixing weight percent in water ratio is about 50% mud stone argillization compound is that 15% said mixture is so that it forms cured article.Then, under the set time of test gained cured article, the normal curing condition and unconfined compression strength and breaking strain under the curing in water condition, in table 2, listed test result.
Comparative Examples 2
By the method for specified each component concentration repetition Comparative Examples 1 in the following table 2, in table 2, listed test result.
The test data explanation of set time, unconfined compression strength and the breaking strain of each Comparative Examples in each embodiment and the following table 2 in the following table 1, no matter on single performance, what the method that still adopts quick high-strength curing agent composition of the present invention that mud stone argillization thing is carried out consolidation process on over-all properties was better than significantly all that industry generally adopts carries out the method for consolidation process with cement and lime to mud stone argillization thing as reinforcement material.And the mud stone argillization thing cured body under normal curing and curing in water condition all satisfies the intensity and the deformation requirements of one-level and the following road base layer cement stabilizing of one-level great soil group material in the road engineering, can be used as the base material on road surface, tunnel.
Table 1
| Each component concentration (weight part) and solidifying agent performance | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Sulphoaluminate cement clinker | 40 | 45 | 50 | 55 | 60 |
| The plaster of Paris | 40 | 35 | 30 | 25 | 20 |
| White lime | 5 | 12 | 10 | 13 | 15 |
| Sodium sulfate | 3 | 1.5 | 2 | 1.75 | 0.2 |
| Water glass | 3 | 1.5 | 2 | 1.75 | 0.1 |
| Potassium aluminium sulfate | 6 | 2.25 | 4 | 1 | 3.7 |
| Sodium hydroxide | 3 | 2.25 | 2 | 2.5 | 1 |
| Set time (hour) | 8 | 7.5 | 5.5 | 6 | 8 |
| The unconfined compression strength (MPa) of normal curing condition cured body in the following 1 day length of time | 2.20 | 2.65 | 3.12 | 2.95 | 2.33 |
| The breaking strain (%) of normal curing condition cured body in the following 1 day length of time | 1.81 | 1.73 | 1.41 | 1.65 | 1.79 |
| The unconfined compression strength (MPa) of normal curing condition cured body in the following 180 day length of time | 2.83 | 3.16 | 3.59 | 3.32 | 3.01 |
| Each component concentration (weight part) and solidifying agent performance | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| The breaking strain (%) of normal curing condition cured body in the following 180 day length of time | 1.276 | 0.997 | 0.846 | 0.913 | 1.121 |
| The unconfined compression strength (MPa) of curing in water condition cured body in the following 1 day length of time | 1.89 | 2.11 | 2.24 | 2.13 | 2.06 |
| The breaking strain (%) of curing in water condition cured body in the following 1 day length of time | 1.92 | 1.85 | 1.67 | 1.78 | 1.92 |
| The unconfined compression strength (MPa) of curing in water condition cured body in the following 180 day length of time | 2.610 | 2.733 | 3.052 | 2.841 | 2.712 |
| The breaking strain (%) of curing in water condition cured body in the following 180 day length of time | 0.935 | 0.816 | 0.784 | 0.819 | 0.913 |
Table 2
| Each component concentration (weight part) and solidifying agent performance | Comparative Examples 1 | Comparative Examples 2 |
| Cement | 50 | 60 |
| Lime | 50 | 40 |
| Set time (hour) | 18 | 12 |
| The unconfined compression strength (MPa) of normal curing condition cured body in the following 1 day length of time | 0.66 | 0.81 |
| The breaking strain (%) of normal curing condition cured body in the following 1 day length of time | 2.87 | 2.21 |
| The unconfined compression strength (MPa) of normal curing condition cured body in the following 180 day length of time | 1.83 | 2.13 |
| The breaking strain (%) of normal curing condition cured body in the following 180 day length of time | 1.883 | 1.566 |
| The unconfined compression strength (MPa) of curing in water condition cured body in the following 1 day length of time | 0.31 | 0.59 |
| Each component concentration (weight part) and solidifying agent performance | Comparative Examples 1 | Comparative Examples 2 |
| The breaking strain (%) of curing in water condition cured body in the following 1 day length of time | 2.73 | 2.32 |
| The unconfined compression strength (MPa) of curing in water condition cured body in the following 180 day length of time | 1.61 | 1.93 |
| The breaking strain (%) of curing in water condition cured body in the following 180 day length of time | 1.632 | 1.367 |
Claims (9)
1. a quick high-strength curing agent composition is used for mine working base plate mud stone argillization thing, it is characterized in that by weight percentage, described composition is made up of following component:
Sulphoaluminate cement clinker 40～60%
The plaster of Paris 20～40%
White lime 5～15%
Sodium sulfate 0.2～3%
Water glass 0.1～3%
Potassium aluminium sulfate 1～6%
Sodium hydroxide 1～3%.
2. composition according to claim 1 is characterized in that, by weight percentage, the content of described sulphoaluminate cement clinker is 50～55%.
3. composition according to claim 1 is characterized in that, by weight percentage, the content of the described plaster of Paris is 30～40%.
4. composition according to claim 1 is characterized in that, by weight percentage, the content of described white lime is 10～15%.
5. composition according to claim 1 is characterized in that, by weight percentage, the content of described sodium sulfate is 1.5-2.5%.
6. composition according to claim 1 is characterized in that, by weight percentage, the content of described water glass is 1.5-2.5%.
7. composition according to claim 1 is characterized in that, by weight percentage, the content of described potassium aluminium sulfate is 2-4%.
8. composition according to claim 1 is characterized in that, by weight percentage, the content of described sodium hydroxide is 1.5-2.5%.
9. one kind is used to prepare the described method for compositions of one of claim 1～8, it is characterized in that described composition is is 200m by described each component mixed grinding is become specific surface area
2/ kg～900m
2The powder of/kg and obtaining.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007101793161A CN101456661B (en) | 2007-12-12 | 2007-12-12 | Curing agent composition and method for making the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007101793161A CN101456661B (en) | 2007-12-12 | 2007-12-12 | Curing agent composition and method for making the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101456661A CN101456661A (en) | 2009-06-17 |
| CN101456661B true CN101456661B (en) | 2010-11-10 |
Family
ID=40767826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007101793161A Active CN101456661B (en) | 2007-12-12 | 2007-12-12 | Curing agent composition and method for making the same |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103275730B (en) * | 2013-06-13 | 2017-05-10 | 成都理工大学 | Barium-containing sulphoaluminate soft soil curing agent and preparation method thereof |
| CN103641290A (en) * | 2013-12-09 | 2014-03-19 | 天津工业大学 | Sludge dewatering concentration and consolidation treatment method |
| CN112194329B (en) * | 2020-10-19 | 2022-11-15 | 四川清和科技有限公司 | Harmless recycling treatment method for river and lake sludge |
| CN112250390B (en) * | 2020-10-29 | 2022-02-15 | 长沙理工大学 | Nano-fiber curing agent for disintegrating carbonaceous mudstone and preparation and use methods thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101081981A (en) * | 2007-07-13 | 2007-12-05 | 浙江大学 | Muck soil composite curing agent |
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- 2007-12-12 CN CN2007101793161A patent/CN101456661B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101081981A (en) * | 2007-07-13 | 2007-12-05 | 浙江大学 | Muck soil composite curing agent |
Non-Patent Citations (1)
| Title |
|---|
| JP特开平7-138564A 1995.05.30 |
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| CN101456661A (en) | 2009-06-17 |
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