CN101429109B - 在具有提高热控制系统的固定床催化部分氧化反应器中制备不饱和酸的方法 - Google Patents
在具有提高热控制系统的固定床催化部分氧化反应器中制备不饱和酸的方法 Download PDFInfo
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- CN101429109B CN101429109B CN200810178918XA CN200810178918A CN101429109B CN 101429109 B CN101429109 B CN 101429109B CN 200810178918X A CN200810178918X A CN 200810178918XA CN 200810178918 A CN200810178918 A CN 200810178918A CN 101429109 B CN101429109 B CN 101429109B
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- 238000000034 method Methods 0.000 title claims abstract description 48
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 33
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- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims description 50
- 230000000694 effects Effects 0.000 claims description 42
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 38
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- KLDZYURQCUYZBL-UHFFFAOYSA-N 2-[3-[(2-hydroxyphenyl)methylideneamino]propyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCN=CC1=CC=CC=C1O KLDZYURQCUYZBL-UHFFFAOYSA-N 0.000 description 2
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
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- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 2
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B41/00—Formation or introduction of functional groups containing oxygen
- C07B41/08—Formation or introduction of functional groups containing oxygen of carboxyl groups or salts, halides or anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR20030096476 | 2003-12-24 | ||
| KR1020030096476 | 2003-12-24 | ||
| KR10-2003-0096476 | 2003-12-24 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004800311170A Division CN100491302C (zh) | 2003-12-24 | 2004-12-21 | 在具有提高热控制系统的固定床催化部分氧化反应器中制备不饱和酸的方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101429109A CN101429109A (zh) | 2009-05-13 |
| CN101429109B true CN101429109B (zh) | 2012-10-03 |
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Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200810178918XA Expired - Lifetime CN101429109B (zh) | 2003-12-24 | 2004-12-21 | 在具有提高热控制系统的固定床催化部分氧化反应器中制备不饱和酸的方法 |
| CNB2004800311170A Expired - Lifetime CN100491302C (zh) | 2003-12-24 | 2004-12-21 | 在具有提高热控制系统的固定床催化部分氧化反应器中制备不饱和酸的方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004800311170A Expired - Lifetime CN100491302C (zh) | 2003-12-24 | 2004-12-21 | 在具有提高热控制系统的固定床催化部分氧化反应器中制备不饱和酸的方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7262324B2 (enExample) |
| EP (1) | EP1697278B1 (enExample) |
| JP (1) | JP4477640B2 (enExample) |
| KR (1) | KR100676066B1 (enExample) |
| CN (2) | CN101429109B (enExample) |
| IN (2) | IN235864B (enExample) |
| TW (1) | TWI288127B (enExample) |
| WO (1) | WO2005061414A1 (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
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| KR100553825B1 (ko) * | 2003-09-01 | 2006-02-21 | 주식회사 엘지화학 | 고정층 촉매 부분 산화 반응기에서 개선된 제열 시스템을통한 불포화알데히드 및 불포화산의 제조 방법 |
| KR100850857B1 (ko) * | 2005-02-01 | 2008-08-06 | 주식회사 엘지화학 | 불포화 지방산의 제조방법 |
| KR100868454B1 (ko) * | 2005-07-08 | 2008-11-11 | 주식회사 엘지화학 | 고정층 촉매 부분산화 반응기에서 고효율의 불포화산의제조방법 |
| TWI322882B (en) * | 2006-02-24 | 2010-04-01 | Lg Chemical Ltd | Annular distributor having guide vane to improve flow rate distribution, reactor/heat exchanger including the annular distributor and method of producing unsaturated aldehyde or unsaturated acid from olefin by catalytic gas phase oxidation in the reactor |
| KR100873271B1 (ko) * | 2006-03-13 | 2008-12-11 | 주식회사 엘지화학 | 고정층 촉매 부분산화 반응기에서 고효율의 불포화알데히드 및/또는 불포화 지방산의 제조방법 |
| KR100942648B1 (ko) * | 2007-04-03 | 2010-02-17 | 주식회사 엘지화학 | 고정층 촉매 부분 산화 반응기를 이용한 불포화 알데히드및/또는 불포화 지방산의 제조방법 |
| WO2009082930A1 (en) * | 2007-12-17 | 2009-07-09 | Accelergy Shanghai R & D Center Co., Ltd. | Methods and apparatus for exothermic catalystic process |
| BRPI0906766A2 (pt) * | 2008-01-17 | 2015-07-14 | Lg Chemical Ltd | Sistema do catalisador, reator de oxidação contendo o mesmo, e método de preparação para acroleíne e ácido acrílico empregando o mesmo |
| JP5232584B2 (ja) * | 2008-09-26 | 2013-07-10 | 東亞合成株式会社 | アクリル酸の製造方法 |
| JP5314983B2 (ja) * | 2008-09-26 | 2013-10-16 | 日本化薬株式会社 | メタクリル酸の製造方法 |
| JP5942391B2 (ja) * | 2011-11-15 | 2016-06-29 | Jsr株式会社 | 反応管、多管式反応器及びこれを用いた不飽和化合物の製造方法 |
| US9440903B2 (en) | 2012-09-24 | 2016-09-13 | Arkema Inc. | Shell and tube oxidation reactor with improved resistance to fouling |
| CN105473539A (zh) * | 2014-04-30 | 2016-04-06 | 三菱丽阳株式会社 | (甲基)丙烯酸的制造方法 |
| KR20170081198A (ko) | 2014-11-03 | 2017-07-11 | 알케마 인코포레이티드 | 중합체 플레이크 및 분말의 밀도 증가 방법 |
| CA2904477A1 (en) | 2015-09-14 | 2017-03-14 | Nova Chemicals Corporation | Heat dissipating diluent in fixed bed reactors |
| BR112018009410B1 (pt) * | 2015-11-30 | 2022-09-20 | Unilever Ip Holdings B.V. | Processo para a fabricação dos hidratos de gás congelados para uso em um produto de confeitaria congelado |
| EP3892367A1 (en) * | 2020-04-09 | 2021-10-13 | Röhm GmbH | A tube bundle reactor and method for the production of methacrylic acid through the partial oxidation of methacrolein |
| CN114813294B (zh) * | 2022-06-02 | 2025-06-13 | 阿拉山口海关技术中心 | 一种自动测汞仪催化管及其制备方法 |
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| CN1215718A (zh) * | 1997-10-27 | 1999-05-05 | 株式会社日本触媒 | 丙烯酸的生产方法 |
| CN1311177A (zh) * | 1999-11-23 | 2001-09-05 | 罗姆和哈斯公司 | 制备不饱和醛及不饱和酸的高烃空间速度法 |
| CN1326915A (zh) * | 2000-05-19 | 2001-12-19 | 株式会社日本触媒 | 生产不饱和醛和不饱和羧酸的方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3147084A (en) | 1962-03-08 | 1964-09-01 | Shell Oil Co | Tubular catalytic reactor with cooler |
| DE2056614C3 (de) | 1970-11-18 | 1981-04-16 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Acrylsäure aus Propylen |
| BE793928A (fr) | 1972-01-13 | 1973-05-02 | Deggendorfer Werft Eisenbau | Appareil pour la mise en oeuvre de processus chimiques exothermiques et endothermiques |
| JPS5283936A (en) | 1976-01-01 | 1977-07-13 | Ortho Pharma Corp | Single herpes virus inactivating acent |
| US4203906A (en) | 1977-07-13 | 1980-05-20 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Process for catalytic vapor phase oxidation |
| AU606160B2 (en) | 1987-05-27 | 1991-01-31 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Process for production of acrylic acid |
| JPH0784400B2 (ja) | 1990-04-03 | 1995-09-13 | 株式会社日本触媒 | 不飽和アルデヒドおよび不飽和酸の製造方法 |
| DE4431949A1 (de) | 1994-09-08 | 1995-03-16 | Basf Ag | Verfahren zur katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure |
| JPH09117664A (ja) * | 1995-10-23 | 1997-05-06 | Mitsubishi Rayon Co Ltd | 不飽和アルデヒド及び不飽和カルボン酸合成用触媒の製造法 |
| JP3463529B2 (ja) * | 1997-09-04 | 2003-11-05 | 東亞合成株式会社 | 気相接触酸化反応方法及び反応器 |
| DE19910508A1 (de) * | 1999-03-10 | 2000-09-21 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure |
| MY119958A (en) * | 1999-03-10 | 2005-08-30 | Basf Ag | Catalytic gas-phase oxidation of propene to acrylic acid |
| JP3732080B2 (ja) * | 1999-08-31 | 2006-01-05 | 株式会社日本触媒 | 接触気相酸化反応器 |
| JP3895527B2 (ja) * | 1999-08-31 | 2007-03-22 | 株式会社日本触媒 | 接触気相酸化方法 |
| JP3646027B2 (ja) * | 1999-11-05 | 2005-05-11 | 株式会社日本触媒 | 接触気相酸化用反応器およびそれを使用した（メタ）アクリル酸の製造方法 |
| KR100450234B1 (ko) | 2002-07-10 | 2004-09-24 | 주식회사 엘지화학 | 개선된 열교환 시스템을 갖는 촉매 산화 반응기 |
| KR100553825B1 (ko) * | 2003-09-01 | 2006-02-21 | 주식회사 엘지화학 | 고정층 촉매 부분 산화 반응기에서 개선된 제열 시스템을통한 불포화알데히드 및 불포화산의 제조 방법 |
-
2004
- 2004-12-21 IN IN738KO2006 patent/IN235864B/en unknown
- 2004-12-21 EP EP04808504.7A patent/EP1697278B1/en not_active Expired - Lifetime
- 2004-12-21 CN CN200810178918XA patent/CN101429109B/zh not_active Expired - Lifetime
- 2004-12-21 TW TW093139897A patent/TWI288127B/zh not_active IP Right Cessation
- 2004-12-21 CN CNB2004800311170A patent/CN100491302C/zh not_active Expired - Lifetime
- 2004-12-21 IN IN738KON2006 patent/IN2006KN00738A/en unknown
- 2004-12-21 WO PCT/KR2004/003373 patent/WO2005061414A1/en not_active Ceased
- 2004-12-21 JP JP2006535279A patent/JP4477640B2/ja not_active Expired - Fee Related
- 2004-12-23 US US11/019,363 patent/US7262324B2/en not_active Expired - Lifetime
- 2004-12-24 KR KR1020040112105A patent/KR100676066B1/ko not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1215718A (zh) * | 1997-10-27 | 1999-05-05 | 株式会社日本触媒 | 丙烯酸的生产方法 |
| CN1311177A (zh) * | 1999-11-23 | 2001-09-05 | 罗姆和哈斯公司 | 制备不饱和醛及不饱和酸的高烃空间速度法 |
| CN1326915A (zh) * | 2000-05-19 | 2001-12-19 | 株式会社日本触媒 | 生产不饱和醛和不饱和羧酸的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1871189A (zh) | 2006-11-29 |
| KR20050065425A (ko) | 2005-06-29 |
| EP1697278B1 (en) | 2016-06-01 |
| EP1697278A4 (en) | 2010-03-31 |
| IN235864B (enExample) | 2009-09-04 |
| JP4477640B2 (ja) | 2010-06-09 |
| WO2005061414A1 (en) | 2005-07-07 |
| US20050143601A1 (en) | 2005-06-30 |
| CN101429109A (zh) | 2009-05-13 |
| IN2006KN00738A (enExample) | 2007-08-03 |
| KR100676066B1 (ko) | 2007-01-29 |
| JP2007523054A (ja) | 2007-08-16 |
| TWI288127B (en) | 2007-10-11 |
| US7262324B2 (en) | 2007-08-28 |
| CN100491302C (zh) | 2009-05-27 |
| TW200602290A (en) | 2006-01-16 |
| EP1697278A1 (en) | 2006-09-06 |
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