CN101429071B - Non-acidizing method for producing high-efficiency phosphorus fertilizer - Google Patents

Non-acidizing method for producing high-efficiency phosphorus fertilizer Download PDF

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Publication number
CN101429071B
CN101429071B CN2008102381375A CN200810238137A CN101429071B CN 101429071 B CN101429071 B CN 101429071B CN 2008102381375 A CN2008102381375 A CN 2008102381375A CN 200810238137 A CN200810238137 A CN 200810238137A CN 101429071 B CN101429071 B CN 101429071B
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fertilizer
phosphorus fertilizer
pseudomonas fluorescens
ultra tiny
soil
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CN101429071A (en
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刘春生
盖国胜
杨玉芬
赵夫涛
何振全
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SHANDONG QINGDA ECOLOGICAL TECHNOLOGY Co.,Ltd.
Wuxi Qingda Lvfeng Technology Development Co., Ltd
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Shandong Agricultural University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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  • Processing Of Solid Wastes (AREA)

Abstract

The invention relates to a method for preparing high-efficiency phosphorus fertilizer without acidification. In the method, the material is ground by a vibration milling wet method to prepare super fine activated phosphate rock powder which has high specific surface area, the particle size is 90 percent and can passes through a 400-mesh sieve, the super fine activated phosphate rock powder is mixed with biological organic fertilizer according to the weight ratio of between 1 to 4 and 1 to 1, and pseudomonas fluorescens is added for mixing stockpile manure and fermenting so as to prepare the non-acidification high-efficiency phosphorus fertilizer. The method has the advantages of preparing the high-efficiency phosphorus fertilizer by physical and biological methods, reducing the environmental pollution, solving the problems of environmental pollution, high cost and the like existing in the prior phosphorus fertilizer preparation method and lowering cost of producing the phosphorus fertilizer, along with simple technique; moreover, in long-term usage, the phosphorus fertilizer can prevent the sealing of soil, improve the soil and enhance the soil fertility.

Description

A kind of non-acidizing prepares the method for efficient phosphorous fertilizer
One, technical field:
The present invention relates to the method that a kind of non-acidizing prepares efficient phosphorous fertilizer, belong to fertilizer processing and Application Areas.
Two, background technology:
At present, the used main raw material of known production phosphate fertilizer is a Rock Phosphate (72Min BPL), and decomposing phosphate rock stone mainly contains acid system and two kinds of methods of Re Fa.Acid system phosphate fertilizer, phosphate fertilizer or compound manure that general system makes with sulfuric acid, nitric acid, hydrochloric acid or phosphorolytic cleavage Rock Phosphate (72Min BPL), mostly acid system phosphate fertilizer is water soluble phosphorous fertilizer, as calcium superphosphate.Thermal process phosphatic fertilizer is at high temperature to add silica, rhombspar, coke etc. or do not add other batching decomposing phosphate rock stones and the phosphate fertilizer made, and mostly thermal process phosphatic fertilizer is citrate acid soluble phosphatic fertilizer, as fused(calcium magnesium)phosphate.But these methods all are by the preparation of chemical technology method, and the cost height, all have fluorine harm, acid harm, and toxic dust harm etc., and easily cause environmental pollution.The method that a kind of non-acidizing provided by the invention prepares efficient phosphorous fertilizer is in patent of invention " a kind of preparation method of the ultrafine activated phosphorusore compound fertilizer " (patent No.: ZL200610113874.3) the further improvement on the basis.Its major advantage is low-grade phosphorus ore in can utilizing, and production process only needs simple mechanical treatment and compost fermentation, and production cost is low and can not produce environmental pollution, and life-time service can be kept soil from packing together, and increases soil fertility, and improves the soil etc.
Three, summary of the invention:
In order to overcome existing environmental pollution among the conventional phosphate fertilizer preparation method, problems such as cost height the invention provides the method that a kind of non-acidizing prepares efficient phosphorous fertilizer, prepare phosphate fertilizer by physics, biological method, reduce environmental pollution, reduce the production cost of phosphate fertilizer.
The technical solution adopted in the present invention is:
1, (patent No.: ZL200610113874.3) to prepare granularity be 90% to cross the ultra tiny activating phosphorite powders of 400 purposes to disclosed method according to patent of invention " a kind of preparation method of ultrafine activated phosphorusore compound fertilizer ".
2, ultra tiny activating phosphorite powder and biological organic fertilizer (biological ight soil and domestic refuses such as cow dung, chicken manure, pig manure, industrial organic waste) are mixed by a certain percentage, its ratio is 1:4-1:1 by weight.
3, with ultra tiny activating phosphorite powder with after biological organic fertilizer mixes according to the above ratio, add Pseudomonas fluorescens (this bacterial classification is purchased the Institute of Micro-biology in Guangdong Province) again, adopt the secondary compost fermentation, for the first time ferment moisture controlled at 55%-65%, temperature is no less than 7 days greater than 55 ℃, and top temperature is no more than 75 ℃; For the second time ferment the initial stage moisture controlled 55%, the later stage is controlled at 25%-35%, and all turning is once weekly for fermenting twice.Twice compost fermentation periodic Control dried granulation at 30-60 days after fermentation is finished.
The invention has the beneficial effects as follows, the one, available phosphorus content height, the use of can topdressing; The 2nd, fertilizer efficiency is stable permanent, can make base manure and seed manure and use; The 3rd, soil there is improving effect, keep soil from packing together, increase soil fertility; The 4th, step of preparation process is few, and production process does not have the waste discharge, and is pollution-free; The 5th, the preparation method is simple, and cost is low; Low-grade phosphorus ore in can utilizing is saved mineral wealth.
Four, specific embodiments:
Embodiment one:
With the ball milling prepared sizes is the ultra tiny activating phosphorite powders of 90% mistake 400 purposes, and the ultra tiny activating phosphorite powder of 20g is mixed with 80g cow dung, adds Pseudomonas fluorescens 2.5ml (10 again 7-10 8Individual/ml), (adopt the secondary compost fermentation, ferment moisture controlled at 55%-65% for the first time, temperature was no less than 7 days greater than 55 ℃ to compost fermentation, and top temperature is no more than 75 ℃ in 30 days; For the second time ferment the initial stage moisture controlled 55%, the later stage is controlled at 25%-35%, and all turning is once weekly for fermenting twice.) dry granulation then and obtain the non-acidizing efficient phosphorous fertilizer.
Embodiment two:
With the vibration mill prepared sizes is the ultra tiny activating phosphorite powders of 90% mistake 400 purposes, and the ultra tiny activating phosphorite powder of 40g is mixed with 80g cow dung, adds Pseudomonas fluorescens 2.5ml (10 again 7-10 8Individual/ml), (adopt the secondary compost fermentation, ferment moisture controlled at 55%-65% for the first time, temperature was no less than 7 days greater than 55 ℃ to compost fermentation, and top temperature is no more than 75 ℃ in 45 days; For the second time ferment the initial stage moisture controlled 55%, the later stage is controlled at 25%-35%, and all turning is once weekly for fermenting twice.)。Dry granulation then and obtain the non-acidizing efficient phosphorous fertilizer.
Embodiment three:
With the vibration mill prepared sizes is the ultra tiny activating phosphorite powders of 90% mistake 400 purposes, and the ultra tiny activating phosphorite powder of 80g is mixed with 80g cow dung, adds Pseudomonas fluorescens 2.5ml (10 again 7-10 8Individual/ml), (adopt the secondary compost fermentation, ferment moisture controlled at 55%-65% for the first time, temperature was no less than 7 days greater than 55 ℃ to compost fermentation, and top temperature is no more than 75 ℃ in 60 days; For the second time ferment the initial stage moisture controlled 55%, the later stage is controlled at 25%-35%, and all turning is once weekly for fermenting twice.) dry granulation then and obtain the non-acidizing efficient phosphorous fertilizer.
Embodiment four:
With the vibration mill prepared sizes is the ultra tiny activating phosphorite powders of 90% mistake 400 purposes, and the ultra tiny activating phosphorite powder of 80g is mixed with the 80g chicken manure, adds Pseudomonas fluorescens 2.5ml (10 again 7-10 8Individual/ml), (adopt the secondary compost fermentation, ferment moisture controlled at 55%-65% for the first time, temperature was no less than 7 days greater than 55 ℃, and top temperature is no more than 75 ℃ in compost fermentation 30-60 days; For the second time ferment the initial stage moisture controlled 55%, the later stage is controlled at 25%-35%, and all turning is once weekly for fermenting twice.)。Dry granulation then and obtain the non-acidizing efficient phosphorous fertilizer.
Embodiment five:
With the vibration mill prepared sizes is the ultra tiny activating phosphorite powders of 90% mistake 400 purposes, and the ultra tiny activating phosphorite powder of 80g is mixed with the 80g pig manure, adds Pseudomonas fluorescens 2.5ml (10 again 7-10 8Individual/ml), (adopt the secondary compost fermentation, ferment moisture controlled at 55%-65% for the first time, temperature was no less than 7 days greater than 55 ℃, and top temperature is no more than 75 ℃ in compost fermentation 30-60 days; For the second time ferment the initial stage moisture controlled 55%, the later stage is controlled at 25%-35%, and all turning is once weekly for fermenting twice.)。Dry granulation then and obtain the non-acidizing efficient phosphorous fertilizer.

Claims (1)

1. a non-acidizing prepares the method for efficient phosphorous fertilizer, it is characterized in that may further comprise the steps:
(1) prepared sizes are the ultra tiny activating phosphorite powders of 90% mistake 400 purposes;
(2) ultra tiny activating phosphorite powder is mixed by a certain percentage with biological organic fertilizer, its ratio is 1 by weight: 4-1: 1;
(3) with ultra tiny activating phosphorite powder with after biological organic fertilizer mixes according to the above ratio, add Pseudomonas fluorescens (Pseudomonas fluorescens) 2.5ml again, every ml Pseudomonas fluorescens contains 10 7-10 8Individual viable count; Adopt the secondary compost fermentation, ferment moisture controlled at 55%-65% for the first time, temperature is no less than 7 days greater than 55 ℃, and top temperature is no more than 75 ℃; For the second time ferment the initial stage moisture controlled 55%, the later stage is controlled at 25%-35%, and all turning is once weekly for fermenting twice; Twice compost fermentation periodic Control dried granulation at 30-60 days after fermentation is finished;
Described biological organic fertilizer is meant cow dung, chicken manure, pig manure, domestic refuse or industrial organic waste.
CN2008102381375A 2008-12-09 2008-12-09 Non-acidizing method for producing high-efficiency phosphorus fertilizer Active CN101429071B (en)

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104230446B (en) * 2014-10-21 2016-08-24 中山市巴斯德农业科技有限公司 A kind of preparation method of selenium-enriched organic fertilizer
CN104557214A (en) * 2015-02-04 2015-04-29 中山市巴斯德农业科技有限公司 Method for preparing biological organic fertilizer from cassava waste
CA3112312A1 (en) * 2018-10-05 2020-04-09 Fertinagro Biotech, S.L. Method for obtaining a granulated phosphate fertiliser and phosphate fertiliser obtained
CN109485469A (en) * 2018-12-10 2019-03-19 淄博清大粉体材料工程有限公司 A kind of preparation method for the eutrophy organic fertilizer adding phosphorus potassium breeze

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD147772A3 (en) * 1978-05-30 1981-04-22 Romann Paudert PROCESS FOR THE PREPARATION OF PHOSPHORUS SUBSTANCES
CN1373108A (en) * 2001-10-16 2002-10-09 广东省生态环境与土壤研究所 Activated phosphate fertilizer composition
CN1935749A (en) * 2006-10-20 2007-03-28 清华大学 Method for preparing ultrafine activated phosphorusore compound fertilizer
CN1325437C (en) * 2004-12-22 2007-07-11 中国农业科学院土壤肥料研究所 Production process of nanometer-submicron acidifier rock phosphate mixture

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD147772A3 (en) * 1978-05-30 1981-04-22 Romann Paudert PROCESS FOR THE PREPARATION OF PHOSPHORUS SUBSTANCES
CN1373108A (en) * 2001-10-16 2002-10-09 广东省生态环境与土壤研究所 Activated phosphate fertilizer composition
CN1325437C (en) * 2004-12-22 2007-07-11 中国农业科学院土壤肥料研究所 Production process of nanometer-submicron acidifier rock phosphate mixture
CN1935749A (en) * 2006-10-20 2007-03-28 清华大学 Method for preparing ultrafine activated phosphorusore compound fertilizer

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