CN101412603A - Ultra-slow resin anchoring agent - Google Patents
Ultra-slow resin anchoring agent Download PDFInfo
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- CN101412603A CN101412603A CNA2008101952105A CN200810195210A CN101412603A CN 101412603 A CN101412603 A CN 101412603A CN A2008101952105 A CNA2008101952105 A CN A2008101952105A CN 200810195210 A CN200810195210 A CN 200810195210A CN 101412603 A CN101412603 A CN 101412603A
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- resin
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- stablizer
- mineral filler
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Abstract
The invention discloses a super-slow resin anchoring agent. Unsaturated polyester resin is adopted; one or a plurality of tertiary amine accelerant, quinhydrone, naphthaquinone or other polymerization inhibiting stabilizer with similar functions, and other chemical assistant and filler are added in resin production or later process to be mixed into resin cement; initiator (solidifying agent) is one or a plurality of dibenzoyl peroxide or other similar peroxide, pasty or powdered solidifying agent diluted by water, stone powder or other inert materials; and the mixture is packaged into scrolls by a diplopore film bag or packaged by a barrel or other packaging modes. In the formulation, the super-slow resin anchoring agent produced through fine adjustment, which has gelling time of between 10 and 180 minutes and compressive strength not less than 40MPa, so the super-slow resin anchoring agent can meet special requirements of long engineering construction, high strength requirement, and the like.
Description
Technical field:
The present invention relates to anchor and plug with molten metal agent, a kind of specifically ultra-slow resin anchoring agent.
Background technology:
Resin anchoring agent is the polymer bond-anchorage material of being made up of synthetic resins, filler and chemical assistant that requires development and production according to bolt supporting action principle and use technology, the body of rod combination accessory of it and unlike material, specification can constitute the resin anchor and the resin crab-bolt of various ways, purposes.Be applicable to mine, underground works and side slope, bolting and shotcreting, the installation of mine vertical shaft equipment, building slab connection and reinforcing, Equipment Foundations anchoring etc.
Resin anchoring agent is along with the development of anchoring support and the innovation overall trend of construction equipment develop to minor diameter, fast curing, full anchoring.The region of some geologic condition complexity of while, particularly underground works, the oriented major diameter of Hydraulic and Hydro-Power Engineering, big anchor dark, be convenient to apply prestressed direction and develop, use the sand-cement slurry infusion to carry out anchoring in some engineering construction, but its gain in strength speed is slower than anchoring agent.Existing resin anchoring agent can not satisfy the demand that the engineering time is long, requirement of strength is high because of gel time very fast (8s-10min) or ultimate compression strength lower (＜40MPa does not meet MT146.1-2002 technical requirements).
Summary of the invention:
For addressing the above problem, the invention provides a kind of gel time at 10-180min, ultimate compression strength is greater than the ultra-slow resin anchoring agent of 40MPa.
The technical solution used in the present invention:
Ultra-slow resin anchoring agent is characterized in that: comprise resin-bonded mastic and solidifying agent, its raw material weight proportioning is:
1., resin-bonded mastic:
100 parts of unsaturated polyester resins
Tertiary amines promotor 0.3-3 part
The poly-stablizer 0.3-3 part of resistance such as quinhydrones, naphthoquinones
Active silica class thickening thixotropic agent 0-3 part
Mineral filler 100-700 part
Described tertiary amines promotor is meant N, accelerine, N, and N-dimethyl-p-toluidine, N, the N-Diethyl Aniline, the poly-stablizer of resistance is meant quinhydrones, naphthoquinones, the thickening thixotropic agent is meant the active silica class;
2., solidifying agent:
100 parts of dibenzoyl peroxide or other similar superoxide
Water 50-200 part
Cellulose thickener 2-5 part
Contain hydroxyl stablizer 20-40 part
Mineral filler 100-300 part
Described other similar superoxide is meant dilauroyl peroxide, and described cellulose thickener is a carboxymethyl cellulose, and the described hydroxyl stablizer that contains is glycol ether or glycerine, and described mineral filler is talcum powder or marble flour.
Described ultra-slow resin anchoring agent is characterized in that: the raw material weight proportioning of described resin-bonded mastic and solidifying agent is:
1., resin-bonded mastic:
100 parts of unsaturated polyester resins
Tertiary amines promotor 0.3-3 part
The poly-stablizer 0.3-3 part of resistance such as quinhydrones, naphthoquinones
Active silica class thickening thixotropic agent 0-3 part
Mineral filler 100-700 part
2., solidifying agent:
100 parts of dibenzoyl peroxide or other similar superoxide
Water 50-200 part
Cellulose thickener 2-5 part
Contain hydroxyl stablizer 20-40 part
Mineral filler 100-300 part.
Resin adopts unsaturated polyester resin, adds tertiary amines promotor in production of resins or later process, quinhydrones, naphthoquinones or other rise similar effect the poly-stablizer of resistance one or more, and other chemical assistant and filler are mixed into resin-bonded mastic.Employing initiator (solidifying agent) is one or more of dibenzoyl peroxide or other similar superoxide; the pasty state or the powdery solidifying agent that diluted through water, stone flour or other inert material; use the diplopore bag film to be packaged into scroll, or adopt barreled and other packaged form.
The advantage of invention:
By prescription provided by the invention, by the adjustment of each group component, the super anchoring agent at a slow speed of producing, gel time is at 10-180min, anti-pressure degree ≧ 40MPa, it is long to satisfy the engineering construction time, particular requirements such as requirement of strength height.
Embodiment:
Example 1:
Gel time comprises resin-bonded mastic and solidifying agent at the ultra-slow resin anchoring agent of 10-30min, and its raw material weight proportioning is:
1., resin-bonded mastic:
100 parts of unsaturated polyester resins
Tertiary amines promotor 0.3-3 part
The poly-stablizer 0.3-3 part of resistance such as quinhydrones, naphthoquinones
Active silica class thickening thixotropic agent 0-3 part
Mineral filler 100-700 part
Described tertiary amines promotor is meant N, accelerine, and N, the N-dimethyl-p-toluidine, N, the N-Diethyl Aniline, the poly-stablizer of resistance is meant quinhydrones, naphthoquinones etc., the thickening thixotropic agent is meant the active silica class.2., solidifying agent:
100 parts of dibenzoyl peroxide or other similar superoxide
Water 50-200 part
Cellulose thickener 2-5 part
Contain hydroxyl stablizer 20-40 part
Mineral filler 100-300 part
Described other similar superoxide is meant dilauroyl peroxide, and described cellulose thickener is a carboxymethyl cellulose, and the described hydroxyl stablizer that contains is glycol ether, glycerine, and described mineral filler is talcum powder, marble flour.
Example 2:
Gel time comprises resin-bonded mastic and solidifying agent at the ultra-slow resin anchoring agent of 30-60min, and its raw material weight proportioning is:
1., resin-bonded mastic:
100 parts of unsaturated polyester resins
Tertiary amines promotor 0.3-3 part
The poly-stablizer 0.3-3 part of resistance such as quinhydrones, naphthoquinones
Active silica class thickening thixotropic agent 0-3 part
Mineral filler 100-700 part
Described tertiary amines promotor is meant N, accelerine, and N, the N-dimethyl-p-toluidine, N, the N-Diethyl Aniline, the poly-stablizer of resistance is meant quinhydrones, naphthoquinones etc., the thickening thixotropic agent is meant the active silica class.2., solidifying agent:
100 parts of dibenzoyl peroxide or other similar superoxide
Water 50-200 part
Cellulose thickener 2-5 part
Contain hydroxyl stablizer 20-40 part
Mineral filler 100-300 part
Described other similar superoxide is meant dilauroyl peroxide, and described cellulose thickener is a carboxymethyl cellulose, and the described hydroxyl stablizer that contains is glycol ether, glycerine, and described mineral filler is talcum powder, marble flour.
Example 3:
Gel time comprises resin-bonded mastic and solidifying agent at the ultra-slow resin anchoring agent of 100-180min, and its raw material weight proportioning is:
1., resin-bonded mastic:
1. unsaturated polyester resin is 100 parts
2. tertiary amines promotor 0.3-3 part
3. resistance such as quinhydrones, naphthoquinones gathers stablizer 0.3-3 part
4. active silica class thickening thixotropic agent 0-3 part
5. mineral filler 100-700 part
6. described tertiary amines promotor is meant N, accelerine, and N, the N-dimethyl-p-toluidine, N, the N-Diethyl Aniline, the poly-stablizer of resistance is meant quinhydrones, naphthoquinones etc., the thickening thixotropic agent is meant the active silica class.
2., solidifying agent:
100 parts of dibenzoyl peroxide or other similar superoxide
Water 50-200 part
Cellulose thickener 2-5 part
Contain hydroxyl stablizer 20-40 part
Mineral filler 100-300 part
Described other similar superoxide is meant dilauroyl peroxide, and described cellulose thickener is a carboxymethyl cellulose, and the described hydroxyl stablizer that contains is glycol ether, glycerine, and described mineral filler is talcum powder, marble flour.
The ultimate compression strength of each prescription
| Numbering | Gel time (min) | Ultimate compression strength (24h MPa) |
| Prescription one | 22 | 60 |
| Prescription two | 45 | 55 |
| Prescription three | 140 | 45 |
Claims (2)
1, ultra-slow resin anchoring agent is characterized in that: comprise resin-bonded mastic and solidifying agent, its raw material weight proportioning is:
1., resin-bonded mastic:
100 parts of unsaturated polyester resins
Tertiary amines promotor 0.3-3 part
The poly-stablizer 0.3-3 part of resistance such as quinhydrones, naphthoquinones
Active silica class thickening thixotropic agent 0-3 part
Mineral filler 100-700 part
Described tertiary amines promotor is meant N, accelerine, N, and N-dimethyl-p-toluidine, N, the N-Diethyl Aniline, the poly-stablizer of resistance is meant quinhydrones, naphthoquinones, the thickening thixotropic agent is meant the active silica class;
2., solidifying agent:
100 parts of dibenzoyl peroxide or other similar superoxide
Water 50-200 part
Cellulose thickener 2-5 part
Contain hydroxyl stablizer 20-40 part
Mineral filler 100-300 part
Described other similar superoxide is meant dilauroyl peroxide, and described cellulose thickener is a carboxymethyl cellulose, and the described hydroxyl stablizer that contains is glycol ether or glycerine, and described mineral filler is talcum powder or marble flour.
2, ultra-slow resin anchoring agent according to claim 1 is characterized in that: the raw material weight proportioning of described resin-bonded mastic and solidifying agent is:
1., resin-bonded mastic:
100 parts of unsaturated polyester resins
Tertiary amines promotor 0.3-3 part
The poly-stablizer 0.3-3 part of resistance such as quinhydrones, naphthoquinones
Active silica class thickening thixotropic agent 0-3 part
Mineral filler 100-700 part
2., solidifying agent:
100 parts of dibenzoyl peroxide or other similar superoxide
Water 50-200 part
Cellulose thickener 2-5 part
Contain hydroxyl stablizer 20-40 part
Mineral filler 100-300 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101952105A CN101412603B (en) | 2008-11-07 | 2008-11-07 | Ultra-slow resin anchoring agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101952105A CN101412603B (en) | 2008-11-07 | 2008-11-07 | Ultra-slow resin anchoring agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101412603A true CN101412603A (en) | 2009-04-22 |
| CN101412603B CN101412603B (en) | 2011-06-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008101952105A Active CN101412603B (en) | 2008-11-07 | 2008-11-07 | Ultra-slow resin anchoring agent |
Country Status (1)
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102161574A (en) * | 2011-02-17 | 2011-08-24 | 安徽淮河化工股份有限公司 | Resin anchoring agent for initiation system |
| CN102212172A (en) * | 2011-02-17 | 2011-10-12 | 安徽淮河化工股份有限公司 | Resin special for anchoring agent and preparation method thereof |
| CN102515627A (en) * | 2011-12-29 | 2012-06-27 | 安徽淮河化工股份有限公司 | Early-strength CK anchoring agent and application thereof |
| CN102515597A (en) * | 2011-12-29 | 2012-06-27 | 安徽淮河化工股份有限公司 | Optimal grading method of grain sizes of filler in anchoring agent |
| CN102585467A (en) * | 2011-12-29 | 2012-07-18 | 安徽淮河化工股份有限公司 | Treating method of waste water produced in producing unsaturated polyester resin of resin anchoring agent |
| CN102757532A (en) * | 2011-04-27 | 2012-10-31 | 喜利得股份公司 | Catalyst mixture for peroxide hardeners and dual component mortar system containing same |
| CN103011676A (en) * | 2012-12-07 | 2013-04-03 | 安徽淮河化工股份有限公司 | Compounded thixotropic agent for anchoring agent cement |
| CN102146271B (en) * | 2010-02-09 | 2014-04-02 | 江苏力宝建材工业有限公司 | Marble adhesive and preparation process thereof |
| CN105037688A (en) * | 2015-06-23 | 2015-11-11 | 陈良伢 | Latent curing agent and preparation method thereof |
| CN105626110A (en) * | 2016-01-25 | 2016-06-01 | 唐永志 | Full-sized anchoring construction method |
| CN106007443A (en) * | 2016-05-13 | 2016-10-12 | 美亚高新材料股份有限公司 | Special accelerant for anchoring agent resin |
| CN106082784A (en) * | 2016-06-08 | 2016-11-09 | 晋城宏圣科威矿用材料有限公司 | A kind of resin anchoring agent |
| CN107417170A (en) * | 2017-06-30 | 2017-12-01 | 常州瑞坦商贸有限公司 | A kind of anti-aging resin anchoring agent of high temperature resistant |
| CN107628766A (en) * | 2017-10-23 | 2018-01-26 | 淮南舜天合成材料有限责任公司 | A kind of preparation method of curing agent for resin anchoring agent |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100343333C (en) * | 2006-06-30 | 2007-10-17 | 王厚东 | Antistatic resin anchoring agent |
| CN100374503C (en) * | 2006-06-30 | 2008-03-12 | 王厚东 | Flame-proof antistatic resin anchoring agent |
| CN101041745B (en) * | 2007-02-13 | 2010-12-01 | 耿会英 | Water-resistant type resin anchoring agent |
-
2008
- 2008-11-07 CN CN2008101952105A patent/CN101412603B/en active Active
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102146271B (en) * | 2010-02-09 | 2014-04-02 | 江苏力宝建材工业有限公司 | Marble adhesive and preparation process thereof |
| CN102212172B (en) * | 2011-02-17 | 2013-07-03 | 安徽淮河化工股份有限公司 | Resin special for anchoring agent and preparation method thereof |
| CN102212172A (en) * | 2011-02-17 | 2011-10-12 | 安徽淮河化工股份有限公司 | Resin special for anchoring agent and preparation method thereof |
| CN102161574A (en) * | 2011-02-17 | 2011-08-24 | 安徽淮河化工股份有限公司 | Resin anchoring agent for initiation system |
| US9463449B2 (en) | 2011-04-27 | 2016-10-11 | Hilti Aktiengesellschaft | Accelerator mixture for peroxide hardener and two-component mortar system containing same |
| EP2518033A3 (en) * | 2011-04-27 | 2016-11-16 | HILTI Aktiengesellschaft | Catalyst mixture for peroxide hardeners and dual component mortar system containing same |
| CN102757532A (en) * | 2011-04-27 | 2012-10-31 | 喜利得股份公司 | Catalyst mixture for peroxide hardeners and dual component mortar system containing same |
| CN102757532B (en) * | 2011-04-27 | 2017-08-15 | 喜利得股份公司 | Bi-component plaster system for the accelerator mixture of peroxide hardener and containing it |
| CN102515597B (en) * | 2011-12-29 | 2013-05-01 | 安徽淮河化工股份有限公司 | Optimal grading method of grain sizes of filler in anchoring agent |
| CN102585467A (en) * | 2011-12-29 | 2012-07-18 | 安徽淮河化工股份有限公司 | Treating method of waste water produced in producing unsaturated polyester resin of resin anchoring agent |
| CN102515597A (en) * | 2011-12-29 | 2012-06-27 | 安徽淮河化工股份有限公司 | Optimal grading method of grain sizes of filler in anchoring agent |
| CN102515627A (en) * | 2011-12-29 | 2012-06-27 | 安徽淮河化工股份有限公司 | Early-strength CK anchoring agent and application thereof |
| CN103011676A (en) * | 2012-12-07 | 2013-04-03 | 安徽淮河化工股份有限公司 | Compounded thixotropic agent for anchoring agent cement |
| CN105037688A (en) * | 2015-06-23 | 2015-11-11 | 陈良伢 | Latent curing agent and preparation method thereof |
| CN105626110A (en) * | 2016-01-25 | 2016-06-01 | 唐永志 | Full-sized anchoring construction method |
| CN106007443A (en) * | 2016-05-13 | 2016-10-12 | 美亚高新材料股份有限公司 | Special accelerant for anchoring agent resin |
| CN106082784A (en) * | 2016-06-08 | 2016-11-09 | 晋城宏圣科威矿用材料有限公司 | A kind of resin anchoring agent |
| CN107417170A (en) * | 2017-06-30 | 2017-12-01 | 常州瑞坦商贸有限公司 | A kind of anti-aging resin anchoring agent of high temperature resistant |
| CN107628766A (en) * | 2017-10-23 | 2018-01-26 | 淮南舜天合成材料有限责任公司 | A kind of preparation method of curing agent for resin anchoring agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101412603B (en) | 2011-06-15 |
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Address after: 232046 cave West Road, Huainan, Anhui Patentee after: Meiya Updated High-Tech Material Industry Co., Ltd. Address before: 232046 cave West Road, Huainan, Anhui Patentee before: Anhui Huaihe Chemical Industry Co., Ltd. |
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Effective date of registration: 20201125 Address after: No.38 Xingfu Road, Wulian County, Rizhao City, Shandong Province Patentee after: Wulian County Industrial and Commercial Office Address before: 232046 cave West Road, Huainan, Anhui Patentee before: MEIYA UPDATED HIGH-TECH MATERIAL INDUSTRY Co.,Ltd. |
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Effective date of registration: 20210910 Address after: No.15 Renmin Road, Wulian County, Rizhao City, Shandong Province 262300 Patentee after: Wulian County measurement and Testing Service Center Address before: No.38 Xingfu Road, Wulian County, Rizhao City, Shandong Province Patentee before: Wulian County Industrial and Commercial Office |