CN101389666B - 烯烃聚合物的减粘裂化方法 - Google Patents
烯烃聚合物的减粘裂化方法 Download PDFInfo
- Publication number
- CN101389666B CN101389666B CN2007800063973A CN200780006397A CN101389666B CN 101389666 B CN101389666 B CN 101389666B CN 2007800063973 A CN2007800063973 A CN 2007800063973A CN 200780006397 A CN200780006397 A CN 200780006397A CN 101389666 B CN101389666 B CN 101389666B
- Authority
- CN
- China
- Prior art keywords
- tert
- peroxide
- alkyl
- butyl
- polypropylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/50—Partial depolymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
- B29K2023/06—PE, i.e. polyethylene
- B29K2023/0608—PE, i.e. polyethylene characterised by its density
- B29K2023/0641—MDPE, i.e. medium density polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/12—PP, i.e. polypropylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/10—Chemical modification of a polymer including a reactive processing step which leads, inter alia, to morphological and/or rheological modifications, e.g. visbreaking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L2023/40—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds changing molecular weight
- C08L2023/42—Depolymerisation, vis-breaking or degradation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77657206P | 2006-02-24 | 2006-02-24 | |
| US60/776,572 | 2006-02-24 | ||
| PCT/EP2007/051407 WO2007096276A1 (en) | 2006-02-24 | 2007-02-14 | Viscosity breaking process for olefin polymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101389666A CN101389666A (zh) | 2009-03-18 |
| CN101389666B true CN101389666B (zh) | 2011-09-28 |
Family
ID=37963757
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007800063973A Active CN101389666B (zh) | 2006-02-24 | 2007-02-14 | 烯烃聚合物的减粘裂化方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US20070200272A1 (https=) |
| EP (1) | EP1987070B1 (https=) |
| JP (1) | JP5260321B2 (https=) |
| CN (1) | CN101389666B (https=) |
| CA (1) | CA2640515C (https=) |
| WO (1) | WO2007096276A1 (https=) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101218289A (zh) * | 2005-07-07 | 2008-07-09 | 西巴特殊化学品控股有限公司 | 在膦酸酯存在下制备聚酰胺的方法 |
| WO2010109018A1 (en) | 2009-03-27 | 2010-09-30 | Henkel Ag & Co. Kgaa | Adhesives made from polymer systems |
| JP5706875B2 (ja) | 2009-04-03 | 2015-04-22 | スリーエム イノベイティブ プロパティズ カンパニー | 帯電強化添加剤を含むエレクトレットウェブ |
| EP2414576B1 (en) | 2009-04-03 | 2016-11-09 | 3M Innovative Properties Company | Processing aids for webs, including electret webs |
| WO2010123810A2 (en) * | 2009-04-21 | 2010-10-28 | Basf Performance Products Llc | Rotomolding process for polyethylene articles |
| BR112012033648A2 (pt) * | 2010-06-28 | 2016-11-22 | Polymers Crc Ltd | modificação de polímeros de propileno |
| WO2013025822A1 (en) * | 2011-08-16 | 2013-02-21 | Mba Polymers, Inc. | Control of the melt flow rate of polyolefin mixtures recovered from post-consumer durable goods |
| EP2602367B1 (en) * | 2011-12-06 | 2015-05-13 | Borealis AG | PP copolymers for melt blown/pulp fibrous nonwoven structures with improved mechanical properties and lower hot air consumption |
| CN103173240B (zh) * | 2011-12-22 | 2015-05-20 | 北京低碳清洁能源研究所 | 煤焦油和/或生物质油与重油的共减粘裂化工艺 |
| KR101384489B1 (ko) | 2012-06-28 | 2014-04-10 | 롯데케미칼 주식회사 | 우수한 제립 안정성 및 잠재적 고용융 흐름성을 구비한 폴리프로필렌 수지 조성물 |
| WO2014047589A1 (en) * | 2012-09-21 | 2014-03-27 | Northwestern University | Peroxy-derivative functionalization of polypropylene via solid-state shear pulverization |
| US20160311944A1 (en) * | 2013-12-13 | 2016-10-27 | Braskem S.A. | Method for producing controlled rheology polypropylene, polypropylene, use thereof and manufactured articles |
| ES2728677T3 (es) * | 2013-12-19 | 2019-10-28 | Dow Global Technologies Llc | Procedimiento para reducir la viscosidad de polímeros a base de propileno con iniciadores de C-C |
| US10400096B2 (en) | 2014-03-14 | 2019-09-03 | Milliken & Company | Modified heterophasic polyolefin composition |
| ES2657303T3 (es) | 2014-03-31 | 2018-03-02 | Sabic Global Technologies B.V. | Método de fabricación de polipropileno de baja emisión |
| WO2016085535A1 (en) | 2014-11-26 | 2016-06-02 | Milliken & Company | Modified heterophasic polyolefin composition |
| DK3034552T4 (da) * | 2014-12-15 | 2024-09-16 | Borealis Ag | Synergistic visbreaking-sammensætning af peroxid og hydroxylaminester til øgning af visbreaking-effektivitet |
| CN107531936B (zh) | 2015-02-10 | 2019-05-14 | 美利肯公司 | 热塑性聚合物组合物 |
| BR112017017721B1 (pt) | 2015-03-05 | 2021-10-26 | Milliken & Company | Composição de poliolefina heterofásica e processo de preparação da mesma |
| KR101958609B1 (ko) | 2015-09-13 | 2019-07-04 | 밀리켄 앤드 캄파니 | 헤테로상 중합체 조성물의 제조 방법 |
| WO2017055173A1 (en) * | 2015-10-02 | 2017-04-06 | Borealis Ag | Melt-blown webs with improved properties |
| FR3060584B1 (fr) | 2016-12-15 | 2018-12-07 | Arkema France | Composition a base de peroxyde de dialkyle pour la modification de la rheologie a l'etat fondu du polypropylene |
| CN109593146A (zh) * | 2017-09-30 | 2019-04-09 | 中国石化扬子石油化工有限公司 | 一种溶液聚合后降解工艺 |
| EP4244285A1 (en) * | 2020-11-13 | 2023-09-20 | Braskem, S.A. | Processing of polyethylene-based compositions and products therefrom |
| MX2024000061A (es) * | 2021-06-22 | 2024-02-23 | Equistar Chem Lp | Procesos y productos de reciclado de polimero. |
| US20250353938A1 (en) * | 2024-05-17 | 2025-11-20 | Braskem America, Inc. | Dynamically crosslinked polyolefin produced through a post-reactor process with a dynamic disulfide crosslinker |
| WO2026008347A1 (en) | 2024-07-01 | 2026-01-08 | Basell Poliolefine Italia S.R.L. | Process for improving melt flow rate of a polyolefin recyclate composition |
| WO2026012892A1 (en) * | 2024-07-08 | 2026-01-15 | Basf Se | Use of carboxylate sodium salt and nitrogen base chelating agents to restore the controlled degradation performance of n-acyloxyamine in the presence of magnesium metal salt |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5530073A (en) * | 1995-06-30 | 1996-06-25 | Amoco Corporation | Process for increased peroxide efficiency in controlled rheology polypropylene resin |
| US6133414A (en) * | 1996-06-26 | 2000-10-17 | Ciba Specialy Chemicals Corporation | Decomposing polymers using NOR-HALS compounds |
| US20030216494A1 (en) * | 2000-05-19 | 2003-11-20 | Michael Roth | Hydroxylamine esters as polymerization initiators |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1495285C3 (de) * | 1963-03-02 | 1975-07-03 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Erniedrigung des Molekulargewichts von Polyolefinen |
| DE1545155A1 (de) * | 1964-01-31 | 1970-01-22 | Glanzstoff Ag | Verfahren zur Verbesserung der Stabilitaet von Polyolefinen |
| US3383531A (en) * | 1967-07-18 | 1968-05-14 | Mini Transporturilor Aut | Electric one-way unharmonical vibarator |
| AT319589B (de) * | 1972-07-25 | 1974-12-27 | Chemie Linz Ag | Verfahren zur Herstellung von Polypropylen |
| JPS5143520B2 (https=) * | 1972-09-06 | 1976-11-22 | ||
| JPS535715B2 (https=) * | 1973-01-25 | 1978-03-01 | ||
| US4080364A (en) * | 1976-09-27 | 1978-03-21 | Argus Chemical Corporation | Stabilization of polyolefins against degradative deterioration as a result of exposure to light and air at elevated temperatures |
| US4749505A (en) * | 1985-07-08 | 1988-06-07 | Exxon Chemical Patents Inc. | Olefin polymer viscosity index improver additive useful in oil compositions |
| CN1040544C (zh) * | 1992-03-03 | 1998-11-04 | 贾玉良 | 一种再生塑料 |
| US6306509B2 (en) * | 1996-03-21 | 2001-10-23 | Showa Denko K.K. | Ion conductive laminate and production method and use thereof |
| US5834541A (en) * | 1997-05-02 | 1998-11-10 | Montell North America Inc. | Olefin polymer composition having low smoke generation and fiber and film prepared therefrom |
| US6165563A (en) * | 1998-11-12 | 2000-12-26 | National Starch And Chemical Investment Holding Corporation | Radiation curable free radically polymerized star-branched polymers |
| US6583076B1 (en) * | 1999-01-08 | 2003-06-24 | Kimberly-Clark Worldwide, Inc. | Nonwoven fabrics prepared using visbroken single-site catalyzed polypropylene |
| FR2792321B1 (fr) * | 1999-04-19 | 2003-12-12 | Atochem Elf Sa | Procede de fabrication d'une resine de polypropylene a rheologie controlee |
| WO2002031045A2 (en) * | 2000-10-11 | 2002-04-18 | Sunoco, Inc. (R & M) | Polypropylene materials with high melt flow rate and good molding characteristics and methods of making |
| US7956109B2 (en) * | 2004-09-09 | 2011-06-07 | Basf Se | Degradation of polypropylene with hydroxylamine ester compositions |
| US20060094636A1 (en) * | 2004-11-01 | 2006-05-04 | National Starch And Chemical Investment Holding Corp. | Hydrophobically modified polymers |
-
2007
- 2007-02-14 CN CN2007800063973A patent/CN101389666B/zh active Active
- 2007-02-14 JP JP2008555749A patent/JP5260321B2/ja active Active
- 2007-02-14 EP EP07726363.0A patent/EP1987070B1/en active Active
- 2007-02-14 CA CA2640515A patent/CA2640515C/en active Active
- 2007-02-14 WO PCT/EP2007/051407 patent/WO2007096276A1/en not_active Ceased
- 2007-02-20 US US11/708,943 patent/US20070200272A1/en not_active Abandoned
-
2013
- 2013-05-14 US US13/893,530 patent/US8618224B2/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5530073A (en) * | 1995-06-30 | 1996-06-25 | Amoco Corporation | Process for increased peroxide efficiency in controlled rheology polypropylene resin |
| US6133414A (en) * | 1996-06-26 | 2000-10-17 | Ciba Specialy Chemicals Corporation | Decomposing polymers using NOR-HALS compounds |
| US20030216494A1 (en) * | 2000-05-19 | 2003-11-20 | Michael Roth | Hydroxylamine esters as polymerization initiators |
Also Published As
| Publication number | Publication date |
|---|---|
| US8618224B2 (en) | 2013-12-31 |
| JP5260321B2 (ja) | 2013-08-14 |
| US20130245203A1 (en) | 2013-09-19 |
| JP2009527608A (ja) | 2009-07-30 |
| EP1987070B1 (en) | 2019-04-10 |
| US20070200272A1 (en) | 2007-08-30 |
| CA2640515C (en) | 2014-06-10 |
| WO2007096276A1 (en) | 2007-08-30 |
| EP1987070A1 (en) | 2008-11-05 |
| CA2640515A1 (en) | 2007-08-30 |
| CN101389666A (zh) | 2009-03-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |