CN101352992A - Decorative line covered by metallic film and producing method thereof - Google Patents
Decorative line covered by metallic film and producing method thereof Download PDFInfo
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- CN101352992A CN101352992A CNA2008102226596A CN200810222659A CN101352992A CN 101352992 A CN101352992 A CN 101352992A CN A2008102226596 A CNA2008102226596 A CN A2008102226596A CN 200810222659 A CN200810222659 A CN 200810222659A CN 101352992 A CN101352992 A CN 101352992A
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Abstract
The invention provides a decorative line which coats metal films and a manufacturing method thereof and includes the following steps: a modeling substrate is preheated after being decontaminated and dusted and being coated with a surface affinity agent; a flexible metal film is coated with a hot-melt adhesive after being dusted and preheated; the metal film coated with the adhesive is rolled and coated with a modeling roll wheel on the surface of the modeling substrate on one surface of the surface affinity agent and the health is preserved. The decorative line made with the method is characterized by metal texture, high bonding strength, hydrolysis resistance, non-reversibility, weather resistance, and the like, and improves the texture grades of the decorative line.
Description
Technical field
The present invention relates to a kind of moulding and manufacture method thereof, particularly relate to a kind of moulding and manufacture method thereof of clad metal film.
Background technology
Moulding is mainly used in the products such as furniture, cabinet, door and window, picture frame, photo frame, decorations.If the pure solid wood of moulding, its cost is high and waste a large amount of timber, just is difficult to make texture unanimity, create an aesthetic feeling and the high ornament materials of quality class as material such as mould with shaped plastics such as PVC or wood.In order to address this is that, the general method that adopts is to coat on the inexpensive base material to be rich in aesthetic property, ornamental material.Cladding process is the technology that membranaceous ornament materials pliable and tough with quality, surface aesthetic is handled by the professional equipment facing each function face of various section bars (MDF moulding lines, PVC, ABS extrusion profile, aluminium alloy extrusions or Wood-plastic composite section bar).What be used for clad material in the market mainly contains materials such as PVC, pre-painted paper (varnished paper), wooden skin, patent 200610084311.6,200720053842.9 and 97218295.0 discloses this clad material, but use its aesthetic property of this material, ornamental, luxury, reduce cost, aspect such as texture unanimity can not obtain desirable effect, and the bond effect of used adhesive and solidification effect are unsatisfactory.
Summary of the invention
At the defective in the above-mentioned field, the invention provides a kind of moulding and manufacture method thereof of clad metal film.The moulding that manufactures in this way is mainly used in decorates various furniture, door and window, photo frame, picture frame.Having metal-like behind the clad metal film on the cheap various ornament materials, make it have ornamental, aesthetic property, luxury, weatherability, irreversibility, reduce cost, the texture unanimity, improve the price of moulding so that product is appreciated.
In order to address the above problem, technical scheme of the present invention is as follows:
A kind of manufacture method of moulding of clad metal film, it is characterized in that comprising the steps: that (1) will treat to be coated with the interface affinity agent behind the base moulding material decontamination dust of clad metal film, (2) be coated with hot melt adhesive behind the metallic film decontamination dust, (3) step (2) is handled the metallic film that obtains and be coated on the base moulding material profile that step (1) processing obtains with the roll-in of moulding running roller, described metallic film has pliability.
In the described coating process metallic film and base moulding material be in the same way with speed dynamically in applying, its feed speed is 8～25m/min.
Described base moulding material is coated with and is preheating to the base moulding material surface temperature after the affinity agent of interface and reaches 28 ℃～55 ℃, be preheating to surface temperature behind the described metallic film decontamination dust and reach 28 ℃～55 ℃, pre-heating mean adopts the method for heating wire heating, infrared ray and/or light-illuminating.
Carry out health after described moulding coated roller is molded and handle, promptly 15 ℃～32 ℃ temperature, normal humidity, be not subjected to wind speed to influence, be not subjected to solar radiation to influence condition under solidified 6 hours～7 days.
The main component of described interfacial agents is condensation resin and chlorinated hydrocarbon.
Described hot melt adhesive is PUR glue or PO glue, PUR glue is reaction type polyurethane hot-melt adhesive (PolyUrethaneReactive Hot-Melt Adhesive), base-material is a polyurethane, PO glue is that TPO coats PUR (Wrapping Hot Melt Adhesive), and base-material is polyolefin (polyolefin).
The melt temperature scope of described hot melt adhesive is 110 ℃～220 ℃, and the glue-spread of described hot melt adhesive is 60g～120g/m
2The thickness of described metallic film is 0.1～0.5mm.Be preferably 0.12～0.2mm.
Described metal is aluminium, gold, silver, copper, aluminium alloy, magnesium alloy or kirsite.
Described base material is that ABS, PVC, wood are moulded, wood-fiber board, solid wood, laminated wood or particieboard.
The moulding of a kind of clad metal film that the said method manufacturing obtains.
Technique effect of the present invention is as follows:
Because metallic film and conventional base material belong to the material of two kinds of dissimilar, quality, be difficult for firm bonding together, the present invention simultaneously is coated with hot melt adhesive having flexible metallic film, on base material, be coated with bonding strength and the ageing resistance that the interface affinity agent increases adhesive again, metal coated face and base material are coated with the interfacial agents coating of simultaneously fitting, with moulding running roller roll-in glue molding, form continuously uniform glue-line, make it to bond together firmly, be difficult for coming unglued, make a kind of ornament materials that is coated with metallic film.
The hot melt adhesive that is coated with on the metallic film is PUR glue or PO glue, PUR glue is reaction type polyurethane hot-melt adhesive (PolyUrethane Reactive Hot-Melt Adhesive), base-material is a polyurethane, PO glue is that TPO coats PUR (Wrapping Hot Melt Adhesive), and base-material is polyolefin (polyolefin).This adhesive has good adhesive property and solidification effect, can be suitable for metal material and nonmetallic materials to bonding more firm of two kinds of different materials; Cold resistance is extremely strong, even bonding and curing back clad material under high and cold state can not rupture on the base material top layer yet; Hear resistance is high, can be under long-time hot environment even bond and solidify the back because of the adhesive fusing is not causing clad material to come unstuck on the base material top layer yet, and glue-line ftractures, bonding is not firm; Very easily in gluing, Bao clad material also can guarantee the surface coating quality again; Applying glue is easy, can supply long-term cycle operation; The applying glue temperature can change, and can decide concrete applying glue temperature according to clad material; The bonding strength height is suitable for the various very fast degree that advance.Especially PUR glue can solidify and have hydrolytic resistance, irreversibility, PUR adhesive apace and is coated in behind the metallic film cooling curing in air, irreversible chemical reaction takes place with airborne moisture, reach required bond effect, after reaction is finished, can under different temperature, have highly stable performance.Will be heated to 110 ℃～220 ℃ before the adhesive coating on special equipment, because of adhesive is in molten when this temperature range, what be suitable for being coated with and being coated with is even, and the glue-spread of adhesive is 60g～120g/m
2, thinner by the glue-line of this glue-spread coating, both satisfied adhesive strength, prevented again that glue-line is too thick and the defective that causes, can not increase the thickness of ornament materials, glue-line is too thick can to influence bond effect sometimes on the contrary.On base material, be coated with the interface affinity agent before the moulding clad metal film, this interface affinity agent main component is condensation resin and chlorinated hydrocarbon, being coated with the interface affinity agent can eject the polarity of material, increased the glue-line ageing resistance of bonding strength, two kinds of different materials are bonded together more affinely, prevent to come unstuck, defective such as layering hollowing.
Metal coated face and base material are coated with the interfacial agents process that coats of simultaneously fitting to carry out on coating machine, and this coating machine is the coating machine of open type, is convenient to the people and is coating hands-operation, just can finish because of cladding process has only the human-computer interaction of realization.The base material that moulding, specification are different and the metallic film of beautiful will be realized overlaying by a plurality of running rollers on the coating machine, thus during the clad metal film with the roll-in of serial moulding roller, base material and metallic film bonding is more firm after the roll-in.Series moulding roller is with about 20～70 roller roll-in, the quantity of roller is relevant with the complexity of base moulding material, the installation of running roller and adjustment need skilled worker's master hand and long term experience to accumulate to realize, the technical staff can regulate the different pieces of information parameter according to different materials when coating roll-in.Have suffered the coating process and be dynamic, metallic film and base moulding material be in the same way with speed dynamically in applying, feed speed is 8～25m/min.Feed speed depends on the shape and the composition of metallic film and moulding lines, and speed can cause the curing (be 7～30 seconds the hardening time as PUR glue) of PUR too slowly, and the roll-in of the too fast serial moulding roller of speed just can't roll-in coat the moulding lines that finish.
Be preheating to the material surface temperature behind the affinity agent of base moulding material coating interface and reach 28 ℃～55 ℃, two kinds of materials are coated togather more affinely, be preheating to the material surface temperature behind the metallic film decontamination dust and reach 28 ℃～55 ℃, make adhesive be coated on the metallic film more equably and two kinds of materials are coated togather more affinely, pre-heating mean generally adopts the method for heating wire heating, infrared ray and/or light-illuminating, this method is simple to operate, and cost is low.
The moulding of the clad metal film after the roll-in carries out health with saw Qi Duanhou and handles the moulding that can better solidify the clad metal film, in 15 ℃～32 ℃ temperature, normal humidity, not influenced by wind speed, solidified 6～48 hours under the condition that not influenced by solar radiation, reaching final curing must 5～7 day.
This metallic film can be aluminium foil, goldleaf, silver foil or Copper Foil, also can be the film of aluminium alloy, magnesium alloy or kirsite.The thickness of metallic film is 0.1～0.5mm, the metallic film of preferred 0.12～0.2mm thickness.This metallic film has pliability, lightweight characteristics, and section bars such as heavy, hard, crisp metal such as steel plate are not suitable in the middle of the technology of this invention.The weight of the moulding after this metallic film is coated on easily on the base material and coats is also light; Because of the color of the moulding after coating is the color of metal itself, be coated with up after not, so the phenomenon that can occur fading not can keep attractive and durable moulding for a long time, and the moulding that can be designed to have different shape, color.Improve ornamental, the luxury of moulding behind the clad metal film, smooth surface, texture unanimity make moulding have the texture of metal, improve the class of product.
The base material for the treatment of the clad metal film among the present invention is that ABS, PVC, the wood of inexpensive practicality is moulded, wood-fiber board, solid wood, laminated wood or particieboard, it is simple to use this material can reduce the production cost and the manufacture craft of moulding, make full use of materials such as plastics, inexpensive timber, wood chip, residue timber, saved timber resources in a large number.
Therefore, the moulding behind the clad metal film is rich in metal-like, has higher ornamental, luxury, irreversibility, weatherability, the quality class of raising product, preparation method is simple, keep clean easily, can keep characteristics such as product colour is stable, marketing is more convenient.
Description of drawings:
Fig. 1 is the moulding manufacture craft flow chart of clad metal film of the present invention.
The specific embodiment:
The present invention will be described below in conjunction with accompanying drawing.Fig. 1 is the moulding manufacture craft flow chart of clad metal film of the present invention.The used interfacial agents of the present invention, PUR adhesive or PO glue are the commercially available prod, and interface affinity agent and adhesive are auxiliary products.
Embodiment 1
(1) solid wood is manufactured the charging aperture that is transported to coating machine behind the moulding lines of different shape according to requirement of client, this coating machine is the coating machine of open type, is convenient to the people and is coating hands-operation.
(2) the solid wood lines are carried out decontamination dust on coating machine, carry out dedusting in the mode of air absorption with dust pelletizing system.
(3) wood surface that will need to coat is coated with the interface affinity agent, and this interface affinity agent main component is condensation resin and chlorinated hydrocarbon.
(4) aluminium foil of 0.5mm thickness is transported to another charging aperture of coating machine.
(5) aluminium foil is carried out decontamination dust on coating machine, carry out in the mode of air absorption with dust pelletizing system.
(6) at the one side coating PUR of aluminium foil adhesive.The PUR polyurethane adhesive is particle or solid-state shape in vacuum packaging, the PUR adhesive of particle or solid-state shape is heated to 220 ℃ becomes and be transported on the glue spreading apparatus of coating machine after pumping up after the molten in special equipment, evenly is coated with 90g/m in the one side of aluminium foil
2The PUR adhesive.
(7) solid wood after handle process step (1)～(3) is coated with the interfacial agents one side and coats through the aluminium foil coated face applying after the processing of step (4)～(6), aluminium foil and solid wood be in the same way with speed dynamically in applying, feed speed is 25m/min, and coat with 48 serial moulding running roller roll-ins, this encapsulation steps is also carried out on coating machine, and the technical staff is by the operational procedure operation when coating roll-in.
Embodiment 2
(1) PVC is manufactured the charging aperture that is transported to coating machine behind the moulding lines of different shape according to requirement of client.
(2) the PVC lines are carried out decontamination dust on coating machine, carry out dedusting in the mode of air absorption with dust pelletizing system.
(3) the PVC surface that will need to coat is coated with the interface affinity agent, and this interface affinity agent main component is condensation resin and chlorinated hydrocarbon.
(4) PVC carries out preheating after being coated with the interface affinity agent, is preheating to the PVC surface temperature and reaches 28 ℃, and pre-heating mean adopts the heating wire method.
(5) aluminum alloy films of 0.1mm thickness is transported to another charging aperture of coating machine.
(6) aluminum alloy films is carried out decontamination dust on coating machine, carry out in the mode of air absorption with dust pelletizing system.
(7) at the one side coating PO of aluminum alloy films adhesive.The PO adhesive is heated to 110 ℃ is transported on the glue spreading apparatus of coating machine after becoming molten in firing equipment, evenly be coated with 60g/m in the one side of aluminum alloy films
2The PO adhesive.
(8) PVC after handle process step (1)～(4) is coated with the interfacial agents one side and coats through the aluminum alloy films coated face applying after the processing of step (5)～(7), PVC and aluminum alloy films be in the same way with speed dynamically in applying, its feed speed is 8m/min, and with the roll-in of 60 serial moulding running rollers, this encapsulation steps is also carried out on coating machine, and the technical staff is by the operational procedure operation when coating roll-in.
(9) lines after the roll-in carry out the health processing with saw Qi Duanhou.In 32 ℃ temperature, normal humidity, be not subjected to wind speed to influence, be not subjected to solidify 6 hours under the condition that solar radiation influences, reach final curing after 5 days.
Embodiment 3
(1) wood-fiber board is manufactured the charging aperture that is transported to coating machine behind the moulding lines of different shape according to requirement of client.
(2) wood-fiber board is carried out decontamination dust on coating machine, carry out dedusting in the mode of air absorption with dust pelletizing system.
(3) the wood-fiber board surface that will need to coat is coated with the interface affinity agent, and this interface affinity agent main component is condensation resin and chlorinated hydrocarbon.
(4) wood-fiber board that is coated with after the affinity agent of interface carries out preheating, is preheating to the wood-fiber board surface temperature and reaches 55 ℃, the pre-ultrared method of thermal recovery.
(5) the kirsite film of 0.15mm thickness is transported to another charging aperture of coating machine.
(6) the kirsite film is carried out decontamination dust on coating machine, carry out in the mode of air absorption with dust pelletizing system.
(7) carry out preheating behind the decontamination dust, the same step of its pre-heating mean (4) is identical.
(8) at the one side coating PUR of kirsite film adhesive.The PUR adhesive of particle or solid-state shape is heated to 130 ℃ becomes and be transported on the glue spreading apparatus of coating machine after pumping up after the molten in the special glue case of sealing, evenly be coated with 80g/m in the one side of kirsite film
2The PUR adhesive.
(9) wood-fiber board after handle process step (1)～(4) is coated with the interfacial agents one side and coats through the kirsite film coated face applying after the processing of step (5)～(8), wood-fiber board and kirsite film be in the same way with speed dynamically in applying, feed speed is 15m/min, and makes the roller wheel roll-in with 70 series.This encapsulation steps is also carried out on coating machine, and the technical staff is by the operational procedure operation when coating roll-in.Coating kirsite film only is coated on the part of the function face (being exposed) of wood-fiber board.
(10) lines after roll-in coats carry out health with saw Qi Duanhou to be handled.In 15 ℃ temperature, normal humidity, be not subjected to wind speed to influence, be not subjected to solidify 48 hours under the condition that solar radiation influences, reach final curing after 7 days.
Embodiment 4
(1) wood is moulded according to requirement of client and manufactured the charging aperture that is transported to coating machine behind the moulding lines of different shape.
(2) wood is moulded on coating machine, carried out decontamination dust, carry out dedusting in the mode of air absorption with dust pelletizing system.
(3) wood that will need to coat is moulded the surface and is coated with the interface affinity agent, and this interface affinity agent main component is condensation resin and chlorinated hydrocarbon.
(4) wood carries out preheating after moulding and being coated with the interface affinity agent, is preheating to wood and moulds surface temperature and reach 40 ℃, the method for pre-thermal recovery infrared ray and light-illuminating.
(5) the magnesium alloy film of 0.18mm thickness is transported to another charging aperture of coating machine.
(6) the magnesium alloy film is carried out decontamination dust on coating machine, carry out in the mode of air absorption with dust pelletizing system.
(7) carry out preheating behind the magnesium alloy film decontamination dust, the same step of its pre-heating mean (4) is identical.
(8) at the one side coating PUR of magnesium alloy film adhesive.The PUR adhesive of particle or solid-state shape is heated to 180 ℃ becomes and be transported on the glue spreading apparatus of coating machine after pumping up after the molten in the glue case of sealing, evenly be coated with 120g/m in the one side of magnesium alloy film
2The PUR adhesive.
(9) wood after handling through step (1)～(4) mould be coated with the interfacial agents one side and handle through step (5)～(8) after magnesium alloy film coated face fit and coat, wood mould with the magnesium alloy film be in the same way with speed dynamically in applying, feed speed is 20m/min, and make the pressure roller roll-in with 50 series, this encapsulation steps is also carried out on coating machine, and the technical staff is by the operational procedure operation when coating roll-in.Coat the magnesium alloy film and only be coated on the part of the function face (being exposed) that wood moulds.
(10) lines after the roll-in carry out the health processing with saw Qi Duanhou.In 25 ℃ temperature, normal humidity, be not subjected to wind speed to influence, be not subjected to solidify 24 hours under the condition that solar radiation influences, reach final curing after 6 days.
Used base moulding material also can be ABS, laminated wood or particieboard in the foregoing description 1 to embodiment 4, and metallic film also can be goldleaf, silver foil or Copper Foil.
Adopt the moulding of the covered by metallic film that above method makes to have metal-like and improve the quality shelves of moulding That inferior, the furniture with this moulding, door and window, picture frame, photo frame can have more is ornamental, luxury, aesthetic property, irreversible The property, weatherability, and have that texture is consistent, the characteristics such as reduce cost.
Claims (10)
1. the manufacture method of the moulding of a clad metal film, it is characterized in that comprising the steps: that (1) will treat to be coated with the interface affinity agent behind the base moulding material decontamination dust of clad metal film, (2) be coated with hot melt adhesive behind the metallic film decontamination dust, (3) step (2) is handled the metallic film that obtains and be coated on the base moulding material profile that step (1) processing obtains with the roll-in of moulding running roller, described metallic film has pliability.
2. the manufacture method of the moulding of clad metal film according to claim 1 is characterized in that: in the described coating process metallic film and base moulding material be in the same way with speed dynamically in applying, its feed speed is 8～25m/min.
3. the manufacture method of the moulding of clad metal film according to claim 1, it is characterized in that: described base moulding material is coated with and is preheating to the base moulding material surface temperature after the affinity agent of interface and reaches 28 ℃～55 ℃, be preheating to surface temperature behind the described metallic film decontamination dust and reach 28 ℃～55 ℃, pre-heating mean adopts the method for heating wire heating, infrared ray and/or light-illuminating.
4. the manufacture method of the moulding of clad metal film according to claim 1, it is characterized in that: carry out health after described moulding roll-in is Overmolded and handle, promptly 15 ℃～32 ℃ temperature, normal humidity, be not subjected to wind speed to influence, be not subjected to solar radiation to influence condition under solidified 6 hours～7 days.
5. the manufacture method of the moulding of clad metal film according to claim 1 is characterized in that: the main component of described interface affinity agent is condensation resin and chlorinated hydrocarbon.
6. the manufacture method of the moulding of clad metal film according to claim 1, it is characterized in that: described hot melt adhesive is that reaction type polyurethane hot-melt adhesive or TPO coat PUR, the melt temperature scope of described hot melt adhesive is 110 ℃～220 ℃, and the glue-spread of described hot melt adhesive is 60g～120g/m
2
7. the manufacture method of the moulding of clad metal film according to claim 1 is characterized in that: the thickness of described metallic film is 0.1～0.5mm.
8. the manufacture method of the moulding of clad metal film according to claim 7 is characterized in that: the thickness of described metallic film is 0.12～0.2mm.
9. the manufacture method of the moulding of clad metal film according to claim 1, it is characterized in that: described base material is that ABS, PVC, wood are moulded, wood-fiber board, solid wood, laminated wood or particieboard, and described metal is aluminium, gold, silver, copper, aluminium alloy, magnesium alloy or kirsite.
10. the moulding of a kind of clad metal film that arbitrary described method manufacturing obtains according to claim 1-9.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008102226596A CN101352992A (en) | 2008-09-19 | 2008-09-19 | Decorative line covered by metallic film and producing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CNA2008102226596A CN101352992A (en) | 2008-09-19 | 2008-09-19 | Decorative line covered by metallic film and producing method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102441974A (en) * | 2011-10-14 | 2012-05-09 | 高红 | Production method of aluminum-plastic wood fiber composite profile |
| CN102493731A (en) * | 2011-12-13 | 2012-06-13 | 上海研和门窗系统有限公司 | Energy-saving door and window profile formed by adhering aluminum on solid wood and manufacture method thereof |
| CN103395273A (en) * | 2013-07-23 | 2013-11-20 | 索菲亚家居股份有限公司 | Manufacture method of soft clad door |
| CN103722747A (en) * | 2013-12-31 | 2014-04-16 | 山东华信塑胶股份有限公司 | Preparation method of metal coated PVC (Polyvinyl Chloride) sectional material for improving plasticity |
| CN103899190A (en) * | 2012-12-25 | 2014-07-02 | 陈国东 | Solid wood copper-clad energy-saving door and window sectional material and manufacturing method thereof |
| CN104612555A (en) * | 2014-12-22 | 2015-05-13 | 常熟宝成五金制品有限公司 | High-temperature-resistant crystal steel door plate |
| CN108442642A (en) * | 2018-04-12 | 2018-08-24 | 安徽森泰木塑集团股份有限公司 | A kind of outdoor flooring and its preparation process |
| CN114348338A (en) * | 2022-02-10 | 2022-04-15 | 泰州市龙洋木业有限公司 | Film laminating process for anti-curling plate |
| CN116718116A (en) * | 2023-08-11 | 2023-09-08 | 烟台泰和新材高分子新材料研究院有限公司 | Quick and accurate test method for high-performance fiber cross-section structure |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102441974A (en) * | 2011-10-14 | 2012-05-09 | 高红 | Production method of aluminum-plastic wood fiber composite profile |
| CN102493731A (en) * | 2011-12-13 | 2012-06-13 | 上海研和门窗系统有限公司 | Energy-saving door and window profile formed by adhering aluminum on solid wood and manufacture method thereof |
| CN103899190A (en) * | 2012-12-25 | 2014-07-02 | 陈国东 | Solid wood copper-clad energy-saving door and window sectional material and manufacturing method thereof |
| CN103899190B (en) * | 2012-12-25 | 2016-01-13 | 浙江研和新材料股份有限公司 | Solid wood covers copper energy saving door and window section bar and preparation method thereof |
| CN103395273B (en) * | 2013-07-23 | 2015-06-17 | 索菲亚家居股份有限公司 | Manufacture method of soft clad door |
| CN103395273A (en) * | 2013-07-23 | 2013-11-20 | 索菲亚家居股份有限公司 | Manufacture method of soft clad door |
| CN103722747A (en) * | 2013-12-31 | 2014-04-16 | 山东华信塑胶股份有限公司 | Preparation method of metal coated PVC (Polyvinyl Chloride) sectional material for improving plasticity |
| CN103722747B (en) * | 2013-12-31 | 2016-04-13 | 山东华信塑胶股份有限公司 | A kind of preparation method improving plastic metal film coated PVC profile |
| CN104612555A (en) * | 2014-12-22 | 2015-05-13 | 常熟宝成五金制品有限公司 | High-temperature-resistant crystal steel door plate |
| CN108442642A (en) * | 2018-04-12 | 2018-08-24 | 安徽森泰木塑集团股份有限公司 | A kind of outdoor flooring and its preparation process |
| CN114348338A (en) * | 2022-02-10 | 2022-04-15 | 泰州市龙洋木业有限公司 | Film laminating process for anti-curling plate |
| CN116718116A (en) * | 2023-08-11 | 2023-09-08 | 烟台泰和新材高分子新材料研究院有限公司 | Quick and accurate test method for high-performance fiber cross-section structure |
| CN116718116B (en) * | 2023-08-11 | 2023-11-14 | 烟台泰和新材高分子新材料研究院有限公司 | Quick and accurate test method for high-performance fiber cross-section structure |
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