CN101352167A - Pesticide composition based on nitenpyram - Google Patents
Pesticide composition based on nitenpyram Download PDFInfo
- Publication number
- CN101352167A CN101352167A CNA2008102119611A CN200810211961A CN101352167A CN 101352167 A CN101352167 A CN 101352167A CN A2008102119611 A CNA2008102119611 A CN A2008102119611A CN 200810211961 A CN200810211961 A CN 200810211961A CN 101352167 A CN101352167 A CN 101352167A
- Authority
- CN
- China
- Prior art keywords
- nitenpyram
- composition pesticide
- cyhalothrin
- weight ratio
- biphenthrin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- CFRPSFYHXJZSBI-DHZHZOJOSA-N (E)-nitenpyram Chemical compound [O-][N+](=O)/C=C(\NC)N(CC)CC1=CC=C(Cl)N=C1 CFRPSFYHXJZSBI-DHZHZOJOSA-N 0.000 title claims abstract description 36
- 229940079888 nitenpyram Drugs 0.000 title claims abstract description 36
- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 239000000575 pesticide Substances 0.000 title claims description 18
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 claims abstract description 18
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical group CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 claims abstract description 14
- 230000000749 insecticidal effect Effects 0.000 claims abstract description 9
- 241001124076 Aphididae Species 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 239000004562 water dispersible granule Substances 0.000 claims description 5
- 238000009736 wetting Methods 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 4
- 239000004530 micro-emulsion Substances 0.000 claims description 4
- 239000000375 suspending agent Substances 0.000 claims description 4
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims 2
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 239000005874 Bifenthrin Substances 0.000 abstract description 3
- 239000003905 agrochemical Substances 0.000 abstract 2
- 239000000470 constituent Substances 0.000 abstract 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 241000238631 Hexapoda Species 0.000 description 9
- -1 antifreeze Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 230000002195 synergetic effect Effects 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 239000012452 mother liquor Substances 0.000 description 6
- 231100000820 toxicity test Toxicity 0.000 description 6
- 241001414720 Cicadellidae Species 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 241000176086 Sogatella furcifera Species 0.000 description 4
- 244000269722 Thea sinensis Species 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 239000002917 insecticide Substances 0.000 description 4
- 231100000225 lethality Toxicity 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 230000000740 bleeding effect Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000012937 correction Methods 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 235000014347 soups Nutrition 0.000 description 3
- 239000012085 test solution Substances 0.000 description 3
- 230000001018 virulence Effects 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- 241000982105 Brevicoryne brassicae Species 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 230000002528 anti-freeze Effects 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000006184 cosolvent Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- ZXQYGBMAQZUVMI-RDDWSQKMSA-N (1S)-cis-(alphaR)-cyhalothrin Chemical compound CC1(C)[C@H](\C=C(/Cl)C(F)(F)F)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-RDDWSQKMSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- ZITVKGIRQCDOSX-UHFFFAOYSA-N 1h-cyclopropa[a]naphthalene Chemical compound C1=CC=CC2=C3CC3=CC=C21 ZITVKGIRQCDOSX-UHFFFAOYSA-N 0.000 description 1
- RQJQQSAYDFANNM-UHFFFAOYSA-N 2,3-dibutylnaphthalene-1-sulfonic acid;formaldehyde Chemical compound O=C.C1=CC=C2C(S(O)(=O)=O)=C(CCCC)C(CCCC)=CC2=C1 RQJQQSAYDFANNM-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- CDMGNVWZXRKJNS-UHFFFAOYSA-N 2-benzylphenol Chemical compound OC1=CC=CC=C1CC1=CC=CC=C1 CDMGNVWZXRKJNS-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 206010002091 Anaesthesia Diseases 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 241001674939 Caulanthus Species 0.000 description 1
- 241001498622 Cixius wagneri Species 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- 239000001828 Gelatine Substances 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000037005 anaesthesia Effects 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000000073 carbamate insecticide Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 125000001924 fatty-acyl group Chemical group 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- PKJZYOFPPJHDRW-UHFFFAOYSA-N formaldehyde;sulfuric acid Chemical compound O=C.OS(O)(=O)=O PKJZYOFPPJHDRW-UHFFFAOYSA-N 0.000 description 1
- 238000010413 gardening Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- QBSJMKIUCUGGNG-UHFFFAOYSA-N isoprocarb Chemical compound CNC(=O)OC1=CC=CC=C1C(C)C QBSJMKIUCUGGNG-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000005910 lambda-Cyhalothrin Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical class COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 1
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- JAJWGJBVLPIOOH-IZYKLYLVSA-M sodium taurocholate Chemical compound [Na+].C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(=O)NCCS([O-])(=O)=O)C)[C@@]2(C)[C@@H](O)C1 JAJWGJBVLPIOOH-IZYKLYLVSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000019710 soybean protein Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an agricultural chemical composition, more particularly relates to an agricultural chemical composition which comprises nitenpyram (effective synergy component) and an insecticidal active constituent that is selected from cyhalothrin, bifenthrin and soprocarb. The optimized weight proportion of nitenpyram and cyhalothrin is 50:1-1:20, and further optimized proportion is 25:1-1:1; The optimized weight proportion of nitenpyram and bifenthrin is 50:1-1:20, and further optimized proportion is 25:1-1:1; The optimized weight proportion of nitenpyram and soprocarb is 20:1-1:50, and further optimized proportion is 1:1-1:10.
Description
Technical field
The present invention relates to a kind of synergetic pesticide composition, particularly relate to a kind of synergetic pesticide composition that comprises Nitenpyram and be selected from arbitrary active insecticidal components of cyhalothrin, Biphenthrin and Mobucin.
Background technology
Nitenpyram (nitenpyram) belongs to the nicotimine insecticides, have unique chemical and biological property, cynapse acceptor to insect has the nerve block effect, various aphids, aleyrodid, leafhopper are shown remarkable activity, and have efficient, low toxicity, interior suction, no cross resistance simultaneously, crop had advantage such as poisoning, be widely used in paddy rice, fruit tree, vegetables and tea and prevent and treat multiple sucking insect.
Cyhalothrin (lambda-cyhalothrin) is to copy natural pyrethrin to carry out structure of modification and the insecticides that obtains, to insect than high 1～2 order of magnitude of other common insecticides, and characteristics that quick-acting is good, has repellent, the power of knocking down is fast.This insecticides all has good control efficiency to most of insects of aspects such as agricultural, gardening, warehouse herding, health.
Biphenthrin (bifenthrin) belongs to the pyrethroid Insecticidal and acaricidal agent, have tag, stomach poison function.Its insecticidal spectrum is wide, and effect is difficult for moving in soil rapidly, and environmentally safe, the lasting period is longer.
Mobucin (isoprocarb) belongs to carbamate insecticide.Mobucin has good preventive effect to rice fulgorid, leafhopper etc., and quick-acting is strong, and adult is had special efficacy, but rice fulgorid takes place the heavy time, and is single with the difficult effectively control of Mobucin harm.
The inventor studies have shown that by a series of, Nitenpyram is mixed with the arbitrary active insecticidal components that is selected from cyhalothrin, Biphenthrin and Mobucin target pest is had extremely strong synergistic effect, has the more outstanding double effect of controlling to mixing the insect and the evil mite of taking place on the target crop.
Summary of the invention
The object of the present invention is to provide a kind of mixed ratio reasonable, control efficiency is good, the synergetic pesticide composition that drug cost is low.
Another object of the present invention is to provide by formulations such as the formulated missible oil of this composition pesticide, wetting powder, microemulsion, aqueous emulsion, suspending agent or water dispersible granules.
Technical scheme of the present invention is as described below:
A kind of composition pesticide, the arbitrary active insecticidal components that it is characterized in that containing the Nitenpyram of synergy effective dose and be selected from cyhalothrin, Biphenthrin and Mobucin.
Wherein, the weight ratio of Nitenpyram and cyhalothrin is preferably 50: 1～and 1: 20, more preferably 25: 1～1: 1; The weight ratio of Nitenpyram and Biphenthrin is preferably 50: 1～and 1: 20, more preferably 25: 1～1: 1; The weight ratio of Nitenpyram and Mobucin is preferably 20: 1～and 1: 50, more preferably 1: 1～1: 10.
Composition pesticide of the present invention can be mixed with missible oil, wetting powder, microemulsion, aqueous emulsion, suspending agent or water dispersible granules etc. according to the method for well known to a person skilled in the art.
Except active component, the also optional functional aid that comprises in the composition pesticide of the present invention.That is to say, composition pesticide of the present invention also can add other components such as functional aid, is mixed with missible oil, wetting powder, microemulsion, aqueous emulsion, suspending agent, water dispersible granules or other formulations with the routine techniques means according to those skilled in the art.
In above-mentioned formulation, except that active component, usually all can contain surfactant, and also can choose wantonly according to different dosage form and to contain organic solvent (or cosolvent), carrier (or filler) and water etc., also can add other auxiliary agents such as antifreeze, thickener, stabilizing agent, defoamer, disintegrant in case of necessity.Surfactant can be emulsifier, dispersant, wetting agent or the bleeding agent of nonionic or ionic, also can be the compound use of two or more surfactants.
Described emulsifier can be alkylphenol-polyethenoxy (polyoxypropylene) ether, benzylphenol APEO, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether, polyoxyethylene carboxylate, phenethyl phenol polyethenoxy polyethenoxy ether, castor oil ethylene oxide adduct, alkylphenol polyoxyethylene formaldehyde condensation products, and the phosphate of these compounds, alkyl benzene sulphonate (calcium salt or sodium salt) or directly use commercially available emulsifier monomer and composite product.The newborn 500# series of concrete example such as farming, 600# series, 1600# series, NP series, OP series, AEO series, 700#, 400# series and composite kind 2201 thereof, 0203B, 2021B, 4103 etc., these all are emulsifier productions well known in the art, and market is on sale.
Described dispersant; wetting agent; bleeding agent can be lignosulfonates (sodium salt or calcium salts); Negel; condensation compound of methyl naphthalene sulfonic acid and formaldehyde sulphate; naphthalene sulfonic acid-formaldehyde condensation product; methanonaphthalene sodium sulfonate dibutyl naphthalene sulfonic acid-formaldehyde condensation product; N-methyl fatty acyl group sodium taurocholate; alkylphenol polyoxyethylene formaldehyde condensation products sulphate; polymerization of carboxylic acid sodium; the alkylphenol polyoxyethylene phosphate; the withered powder of tea; saponin; lignosulfite; aliphatic alcohol sulfate; dodecyl sodium sulfate; alkylbenzenesulfonate; penetrant t; bleeding agent OT; fatty acid amide-N methyl taurine sodium salt; sodium sulfate of polyethenoxy ether of fatty alcohol; draw back powder or JFC etc.They can use separately, also can compoundly use.Above-mentioned surfactant all is materials well known in the art, can obtain by various commercial channel.
Described solvent, cosolvent can be toluene, dimethylbenzene, chlorobenzene, solvent naphtha, alpha-methyl-naphthalene, turpentine oil, carrene, chloroform, methyl alcohol, ethanol, isopropyl alcohol, butanols, isoamyl alcohol, cyclohexanone, isophorone, acetophenone, ethyl acetate, butyl acetate, N.N-dimethyl formamide, dimethyl sulfoxide (DMSO), methyl cellosolve or ethyl cellosolve etc.
Described antifreeze can be ethylene glycol, glycerine, propane diols, urea, glycerine, ether diglycol, polyethylene glycol or isopropyl alcohol etc.
Described carrier, filler can be white carbon, precipitated calcium carbonate, potter's clay, attapulgite, kaolin, diatomite, bentonite, sepiolite, zeolite, quartz sand or talcum powder etc.They can use separately, also can two kinds or above mixing use.
Described disintegrant can be sodium alginate, sodium carboxymethyl starch, sulfuric acid amine, bentonite, urea or calcium chloride etc.
Described defoamer has bubble enemy, silicone, C
8-10Fatty alcohol, C
10-20Saturated fat acids (as capric acid, stearic acid etc.) and amide-type etc.
Described binding agent has starch, dextrin, gum Arabic, soybean protein, gelatine, sodium sulphate, gypsum, polyvinyl alcohol, polyethylene glycol, rosin, paraffin, CMC or sodium silicate etc.They can use separately, also can two or morely use with.
Can contain toner in the preparation, inorganic pigment iron oxide for example, titanium oxide or Prussian blue; Organic dyestuff is as A Lizhalin, azo dyes, metal phthalocyanine or kiton colors.In water-base preparation, for preventing moldy metamorphism, can choose wantonly and add a certain amount of preservative, described preservative has Sodium Benzoate, polyformaldehyde, sorbitol, formalin, citric acid, to yl benzoic acid methyl esters, O-SyL sodium, 1,2-benzisothiazole-3-ketone etc.
Component of the present invention is reasonable, and drug cost is low, good disinsection effect, and its insecticidal effect and activity level are not the stacks of simple each composition activity, but the effect of synergy is arranged.The present invention especially has good control efficiency to sucking pest such as plant hopper, aphid, leafhopper etc.
Embodiment
The invention will be further described below in conjunction with embodiment.But the present invention only limits to these examples absolutely not.Percentage all is weight percentage in all prescriptions, and proportioning is a weight ratio.It is known that the processing technology of the various preparations of the present composition and equipment are the public.
Example of formulations 1:
Taking by weighing 25% Mobucin, 10% Nitenpyram, 5% lignosulfonates, 4%NO, 10% talcum powder, diatomite mends to 100%.The frequent regulation of above-mentioned raw materials is got steps such as the pulverizing, mixing of granule and is produced 35% Mobucin Nitenpyram wetting powder.
Example of formulations 2:
Taking by weighing 10% Biphenthrin, 50% Nitenpyram, 8% dispersant, 4% wetting agent, 8% ammonium sulfate, 2% white carbon, diatomite mends to 100%.Above-mentioned raw materials is produced 60% Biphenthrin Nitenpyram water dispersible granules through ultramicro grinding, mixing, extruder grain step.
Example of formulations 3:
Take by weighing 5% Biphenthrin, 10% Nitenpyram, 8% emulsifier special, toluene or dimethylbenzene and complement to 100%.Stirring and dissolving obtains 15% Biphenthrin Nitenpyram missible oil to mixing.
Biological Examples 1: Nitenpyram and cyhalothrin are used the toxicity test to cabbage aphid with
On the basis of preliminary experiment, behind former medicine of 95% Nitenpyram and the former medicinal proper amount of acetone preliminarily solubilised of 91% cyhalothrin, and be mixed into the mother liquor of different proportionings in set ratio.Each mother liquor is mixed with 5 serial test solutions with distilled water, and concentration range can cause that supplying to try insect mortality reaches 10%～90%, puts in the beaker stand-by.The blade infusion process of recommending with reference to FAO is carried out Toxicity Determination then.Gathering the blade of band aphid on wild cabbage ground takes back indoor at the binocular stereo microscopically, remove winged viviparious female aphid and other insect and impurity with writing brush, the wingless aphid that keeps individual big or small basically identical, be dipped in each dilution together with leaf and take out behind the 10S, about 50 of every processing are blotted unnecessary soup with suction paper, put into the glass culture dish of the wet filter paper of pad, every reason weighs 3 times, handles in contrast with clear water, places in the greenhouse of (25 ± 1) ℃.Handle back 48h and check dead, the aphid number of living, calculate lethality,, calculate LC50 and virulence regression equation with DPS software with each lethality of handling of Abbott formula correction.Adopt Sun Pei cloud method to obtain the co-toxicity coefficient (CTC) of each mixed ratio with reference to NY/T 1154.7-2006, and estimate the synergistic effect that the two is used with.The result is as shown in table 1:
Table 1: Nitenpyram and cyhalothrin are to the toxicity test result of cabbage aphid
Alkene: merit=Nitenpyram: cyhalothrin
Biological Examples 2: Nitenpyram and Biphenthrin are used with the tea lesser leafhopper toxicity test
On the basis of preliminary experiment, behind former medicinal proper amount of acetone preliminarily solubilised, and be mixed into the mother liquor of different proportionings in set ratio.Each mother liquor is mixed with 5 serial test solutions with distilled water, and concentration range can cause that supplying to try insect mortality reaches 10%～90%, puts in the beaker stand-by.The drop method that adopts NY/T 1154.1-2006 to recommend during mensuration, places 9cm culture dish CO to worm earlier
2Slight anesthesia, then with 1 μ L microsyringe 0.2 μ L soup point on polypide, be contrast with 0.2 μ L acetone treatment.Moisture releasing profit cotton balls is preserved moisture, and every ware is handled 20 of examination worms, moves in the climatic cabinate of (28+1) ℃, RH80% to raise.Handle back 48h, check dead borer population that each is handled, to be that polypide is immobile all be judged to death to dead standard.With each lethality of handling of Abbott formula correction, calculate LC with DPS software
50And virulence regression equation.Adopt Sun Pei cloud method to obtain the co-toxicity coefficient (CTC) of each mixed ratio with reference to NY/T 1154.7-2006, and estimate the synergistic effect that the two is used with.The result is as shown in table 2:
Table 2: Biphenthrin and Nitenpyram are used with tea lesser leafhopper toxicity test result
Alkene: connection=Nitenpyram: Biphenthrin
Biological Examples 3: Nitenpyram and Mobucin are used the toxicity test to rice fulgorid with
On the basis of preliminary experiment, behind former medicinal proper amount of acetone preliminarily solubilised, and be mixed into the mother liquor of different proportionings in set ratio.Each mother liquor is mixed with 5 serial test solutions with distilled water, and concentration range can cause that supplying to try insect mortality reaches 10%～90%, puts in the beaker stand-by.The drop method that adopts NY/T 1154.1-2006 to recommend during mensuration, places worm the 9cm culture dish slightly to anaesthetize with CO2 earlier, then with 1 μ L microsyringe 0.2 μ L soup point on polypide, be contrast with 0.2 μ L acetone treatment.Moisture releasing profit cotton balls is preserved moisture, and every ware is handled 20 of examination worms, moves in the climatic cabinate of (28+1) ℃, RH80% to raise.Handle back 48h, check dead borer population that each is handled, to be that polypide is immobile all be judged to death to dead standard.With each lethality of handling of Abbott formula correction, calculate LC with DPS software
50And virulence regression equation.Adopt Sun Pei cloud method to obtain the co-toxicity coefficient (CTC) of each mixed ratio with reference to NY/T 1154.7-2006, and estimate the synergistic effect that the two is used with.The result is as shown in table 3:
Table 3: Nitenpyram and Mobucin are used the toxicity test result to rice fulgorid with
Alkene: different=Nitenpyram: Mobucin
Claims (8)
1. composition pesticide, the arbitrary active insecticidal components that it is characterized in that containing the Nitenpyram of synergy effective dose and be selected from cyhalothrin, Biphenthrin and Mobucin.
2. according to the composition pesticide of claim 1, it is characterized in that the weight ratio of Nitenpyram and cyhalothrin is preferably 50: 1～1: 20.
3. according to the composition pesticide of claim 1-2, it is characterized in that the weight ratio more preferably 25: 1～1: 1 of Nitenpyram and cyhalothrin.
4. according to the composition pesticide of claim 1, it is characterized in that the weight ratio of Nitenpyram and Biphenthrin is preferably 50: 1～1: 20.
5. according to the composition pesticide of claim 1 or 4, it is characterized in that the weight ratio of Nitenpyram and Biphenthrin is preferably 25: 1～1: 1.
6. according to the composition pesticide of claim 1, it is characterized in that the weight ratio of Nitenpyram and Mobucin is preferably 20: 1～1: 50.
7. according to the composition pesticide of claim 1 or 6, it is characterized in that the weight ratio of pyrrole aphid ketone and chlorfenapyr is preferably 1: 1～1: 10.
8. missible oil, wetting powder, microemulsion, aqueous emulsion, suspending agent or the water dispersible granules formulated according to the described composition pesticide of arbitrary claim of claim 1-7.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008102119611A CN101352167B (en) | 2008-09-12 | 2008-09-12 | Pesticide composition based on nitenpyram |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008102119611A CN101352167B (en) | 2008-09-12 | 2008-09-12 | Pesticide composition based on nitenpyram |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010181551 Division CN101843252B (en) | 2008-09-12 | 2008-09-12 | Pesticide composite based on nitenpyram |
| CN 201010181520 Division CN101843253B (en) | 2008-09-12 | 2008-09-12 | Pesticide composite based on nitenpyram |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101352167A true CN101352167A (en) | 2009-01-28 |
| CN101352167B CN101352167B (en) | 2011-04-20 |
Family
ID=40305378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008102119611A Expired - Fee Related CN101352167B (en) | 2008-09-12 | 2008-09-12 | Pesticide composition based on nitenpyram |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101352167B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101999395A (en) * | 2010-11-22 | 2011-04-06 | 陕西美邦农药有限公司 | Insecticidal composition containing pymetrozine |
| CN102017994A (en) * | 2009-09-22 | 2011-04-20 | 南京华洲药业有限公司 | Nitenpyram and chlorpyrifos methyl contained synergia insecticidal composite and application thereof |
| CN101444210B (en) * | 2008-12-27 | 2011-11-23 | 深圳诺普信农化股份有限公司 | Desinsection composite with synergy and application thereof |
| CN101502267B (en) * | 2009-03-24 | 2012-05-23 | 德强生物股份有限公司 | Pesticide for preventing and controlling rice planthopper |
| WO2012017428A3 (en) * | 2010-08-05 | 2012-08-09 | Makhteshim Chemical Works Ltd. | Synergistic insecticidal mixtures containing a pyrethroid, a neonicotinoid and a benzoylphenylurea insecticide |
| CN108576041A (en) * | 2018-01-31 | 2018-09-28 | 福建省农业科学院植物保护研究所 | A kind of chemical agent of prevention false eye leafhopper |
| CN111777673A (en) * | 2020-07-27 | 2020-10-16 | 江苏省农业科学院 | Plasma membrane internal aquaporin for absorbing and transporting neonicotinoid insecticides, and coding gene and application thereof |
| CN116019120A (en) * | 2022-11-01 | 2023-04-28 | 山东曹达化工有限公司 | Pesticide for preventing and treating agricultural aphids and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101843253B (en) * | 2008-09-12 | 2013-06-19 | 福建新农大正生物工程有限公司 | Pesticide composite based on nitenpyram |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101480193A (en) * | 2008-01-07 | 2009-07-15 | 青岛凯源祥化工有限公司 | Pesticide composition containing nitenpyram |
| CN101366381B (en) * | 2008-06-16 | 2012-07-04 | 江西正邦化工有限公司 | Insecticidal composition |
-
2008
- 2008-09-12 CN CN2008102119611A patent/CN101352167B/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101444210B (en) * | 2008-12-27 | 2011-11-23 | 深圳诺普信农化股份有限公司 | Desinsection composite with synergy and application thereof |
| CN101502267B (en) * | 2009-03-24 | 2012-05-23 | 德强生物股份有限公司 | Pesticide for preventing and controlling rice planthopper |
| CN102017994A (en) * | 2009-09-22 | 2011-04-20 | 南京华洲药业有限公司 | Nitenpyram and chlorpyrifos methyl contained synergia insecticidal composite and application thereof |
| WO2012017428A3 (en) * | 2010-08-05 | 2012-08-09 | Makhteshim Chemical Works Ltd. | Synergistic insecticidal mixtures containing a pyrethroid, a neonicotinoid and a benzoylphenylurea insecticide |
| CN101999395A (en) * | 2010-11-22 | 2011-04-06 | 陕西美邦农药有限公司 | Insecticidal composition containing pymetrozine |
| CN101999395B (en) * | 2010-11-22 | 2013-11-27 | 陕西美邦农药有限公司 | Insecticidal composition containing pymetrozine |
| CN108576041A (en) * | 2018-01-31 | 2018-09-28 | 福建省农业科学院植物保护研究所 | A kind of chemical agent of prevention false eye leafhopper |
| CN111777673A (en) * | 2020-07-27 | 2020-10-16 | 江苏省农业科学院 | Plasma membrane internal aquaporin for absorbing and transporting neonicotinoid insecticides, and coding gene and application thereof |
| CN116019120A (en) * | 2022-11-01 | 2023-04-28 | 山东曹达化工有限公司 | Pesticide for preventing and treating agricultural aphids and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101352167B (en) | 2011-04-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101352167B (en) | Pesticide composition based on nitenpyram | |
| CN101352172B (en) | Pesticide composition based on Thiamethoxam | |
| CN101352169B (en) | Pesticide composition based on ivermectin | |
| CN101755797A (en) | Bactericide composition containing boscalid | |
| CN101366386B (en) | Agricultural chemical composition based on Pymetrozine | |
| CN102365970A (en) | Synergistic pesticidal composition containing Clothianidin and emamectin benzoate, and its application | |
| CN103004867B (en) | Insecticidal composition with synergism | |
| CN102960361A (en) | Insecticide composition and application thereof | |
| CN101919401B (en) | Thiamethoxam based pesticide composition | |
| CN102228056B (en) | Pesticide composition containing sulfur-fluorine oxime ether and part of organophosphorus pesticides | |
| CN106689186A (en) | Efficient insecticidal composition containing bifenthrin and pyriproxyfen | |
| CN107361069A (en) | A kind of Synergistic herbicide compositions | |
| CN101366387B (en) | Agricultural chemical composition | |
| CN109169709B (en) | Synergistic composition for preventing and treating brassicaceous vegetable pests | |
| CN101843252B (en) | Pesticide composite based on nitenpyram | |
| CN101843253B (en) | Pesticide composite based on nitenpyram | |
| CN101366380A (en) | Agricultural chemical composition based on chlorfenapyr | |
| CN103518773B (en) | Insecticidal composition with synergism | |
| CN101708002A (en) | Synergistic pesticide composition and application thereof | |
| CN101843247B (en) | Pesticide composition based on pymetrozine | |
| CN112568224A (en) | Insecticidal composition containing bromofenoxaprop-p-fluorobenzene bisamide and diafenthiuron | |
| CN104255735A (en) | Pyridalyl and tetra-chlorantraniliprole compounded insecticidal composition | |
| CN104824011A (en) | Insecticidal composition containing pyridine quinazoline and guadipyr | |
| CN103250713A (en) | Synergistic pesticide composition for killing gall midge insects | |
| CN104255759B (en) | Containing the Pesticidal combination of matrine and metaflumizone |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Free format text: FORMER OWNER: YOU WENLI Owner name: XINNONG DAZHENG BIOLOGICAL ENGINEERING CO., LTD., Free format text: FORMER OWNER: CHEN ZHANGYAN Effective date: 20110512 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| C53 | Correction of patent for invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Chen Weimin Inventor after: Chen Fan Inventor before: Chen Zhangyan Inventor before: You Wenli |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 350002 FUJIAN SINO-DASHING BIOTECHNOLOGY CO., LTD., 6/F, TAIYANGCHENG BUILDING, NO. 268, YANGQIAO WEST ROAD, FUZHOU CITY, FUJIAN PROVINCE TO: 350000 UNIT 6F, BUILDING 2, TAIYANGCHENG COMPREHENSIVE BUILDING, NO. 268, YANGQIAO WEST ROAD, FUZHOU CITY, FUJIAN PROVINCE Free format text: CORRECT: INVENTOR; FROM: CHEN ZHANGYAN YOU WENLI TO: CHEN WEIMIN CHEN FAN |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20110512 Address after: Unit 6F No. 2 Yangqiao road Fuzhou Fujian province 350000 City 268 Sun City Building Patentee after: Xinnong Dazheng Biological Engineering Co., Ltd., Fujian Address before: Fuzhou City, Fujian province 350002 Yangqiao Road No. 268, Solar City Tower Rio de Janeiro, 6 floor Fujian sinodashing Bioengineering Co. Ltd. Co-patentee before: You Wenli Patentee before: Chen Zhangyan |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110420 Termination date: 20150912 |
|
| EXPY | Termination of patent right or utility model |