CN101348706A - Railway coal transportation dust-depressor and manufacturing method thereof - Google Patents

Railway coal transportation dust-depressor and manufacturing method thereof Download PDF

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Publication number
CN101348706A
CN101348706A CNA2008102122915A CN200810212291A CN101348706A CN 101348706 A CN101348706 A CN 101348706A CN A2008102122915 A CNA2008102122915 A CN A2008102122915A CN 200810212291 A CN200810212291 A CN 200810212291A CN 101348706 A CN101348706 A CN 101348706A
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water
soluble
depressor
dust
coal
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CNA2008102122915A
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CN100537696C (en
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叶修
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Heye Precision Chemical Engineering Co ltd
Ye Xiu
Ye Xuan
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Abstract

The invention discloses a coal railway transportation dust depressor, which is invented for solving the problems of high cost, poor depression effect and so on in the prior art. The raw materials by weight percent for preparing effective compositions in the coal railway transportation dust depressor are: 2 to 7 percent of synthesized water-soluble polymer, 0.1 to 5 percent of modified cellulose water-soluble polymer, 85 to 95 percent of water and 0 to 2 percent of bluestone, wherein the synthesized water-soluble polymer is prepared by complexing at least two water-soluble polymers. The coal railway transportation dust depressor consists of more than two synthesized water-soluble polymers and a small amount of auxiliary agent, and has the advantages of high viscosity and low cost. When used, the coal railway transportation dust depressor is uniformly sprayed on particles on the surface of a coal bed to form a curing layer with certain strength, thereby the coal-dust particles of various grain sizes are bonded together and have certain toughness, and the aim of preventing flying dust on the surface of the coal bed is achieved.

Description

Railway coal transportation dust-depressor and manufacture method thereof
Technical field:
The present invention relates to a kind of railway Coal Transport dust-inhibitor and manufacture method thereof.
Background technology:
Along with going deep into of railway great-leap-forward development process, train running speed is greatly enhanced, and the transportation of the diffusing coal of railway accounts for whole volume of rail freigh 40%.Because at present in the way of railway carriage carry coal or other powder things, generally do not take to isolate powder and fly upward measure, unit train jolts and wind effect, the coal dust on surface and particle are by the car body that blows off, pollute both for railway environment along the line, and also caused waste also to bring sizable financial loss simultaneously to the owner of cargo to coal resources.According to statistics, in each hundred kilometers transportation of train in row 30 joint compartments, have nearly two tons of coals and run off, waft in the atmosphere that into we breathe, well imagine to the injury that human body brings.
In order to overcome above-mentioned problem, someone adopts paulin body periphery and vertical or horizontal with the method for tension rope colligation on the compartment mouth, prevented that effectively coal dust or other powder things from flying out with the wind in the compartment, reduced loss of material, and reduced pollution on the environment, but when using, it need artificial going on the compartment, to waste time and energy with these paulin colligations at every turn.
Also the someone attempts adopting the caking agents by making after the steaming heating such as polyethylene alcohol and water, when it uses, only need above-mentioned caking agent is sprayed at the surface, coal seam, to utilize reactive adhesive to excite the dust surfactivity, react with the dust active ingredient, generate adhesive layer, the top layer bisque is solidified, and have certain intensity, thereby reach the purpose of anti-airborne dust.This mode is very simple in use, has obtained user's favorable comment.But, can't obtain the high coating of bonding strength because the consolidation of its single dependence polyvinyl alcohol is subjected to the influence of polyvinyl alcohol molecular structure and molecular weight.Therefore this caking agent is long set time, and solidification effect is poor, and Fugitive dust covering flux more (the per car railway carriage or compartment reaches more than the 120 kg) is sprayed in the per car railway carriage or compartment has increased cost.
Summary of the invention
For overcoming above-mentioned defective, the object of the present invention is to provide that a kind of cost is low, set time is short, railway coal transportation dust-depressor that solidification effect is good and manufacture method thereof.
For achieving the above object, railway coal transportation dust-depressor of the present invention is made raw materials of effective components consisting of of percentage composition meter by weight: synthetic polymer 2-7, modified-cellulose class water-soluble polymers 0.1-5, water 85-95,0-2.
Wherein, described synthetic polymer is at least by two kinds of composite forming of water-soluble polymers.Like this, by the synergy of performance between polymkeric substance, the adhesive effect after the raising inhibitor is fixed.
Particularly, described synthetic polymer is by water-soluble poval and water-soluble sodium polyacrylate; Both are consisting of of percentage composition meter by weight: water-soluble poval 30-50, water-soluble sodium polyacrylate 50-70.
Particularly, described synthetic polymer is by water-soluble polyacrylamide and water-soluble sodium polyacrylate is composite forms, and both are consisting of of percentage composition meter by weight: water-soluble polyacrylamide 40-50, water-soluble sodium polyacrylate 50-60.
Particularly, described synthetic polymer is by water-soluble polyacrylamide and water-soluble poval is composite forms, and both are consisting of of percentage composition meter by weight: water-soluble polyacrylamide 40-50, water-soluble poval 50-60.
Particularly, described synthetic polymer forms by water-soluble sodium polyacrylate, water-soluble polyacrylamide and water-soluble poval are composite, the three is consisting of of percentage composition meter by weight: water-soluble sodium polyacrylate 30-50, water-soluble polyacrylamide 40-50, water-soluble poval 50-60.
For achieving the above object, railway coal transportation dust-depressor manufacture method of the present invention is put into 85-95 part normal-temperature water (20 ℃-30 ℃) in reactor; Add composite back water-soluble polymers 2-7; After being stirred to whole dissolvings, slowly add modified-cellulose class water-soluble polymers 0.1-5, be stirred to whole dissolvings, add copper sulfate 0.01-2 at last, stirring gets final product.
Among the present invention, adopt two or more synthetic polymers and a small amount of auxiliary to form, during use it evenly is sprayed on the coal seam surface particles, form a kind of cured layer with certain intensity, thereby the pulverized coal particle of various particle diameters is tied together, and have certain toughness, thus reach the purpose that prevents surface, coal seam airborne dust greatly, and its manufacturing is implemented very simple.
Embodiment
The raw material of railway coal transportation dust-depressor of the present invention and its manufacture method is by synthetic polymer, and modified-cellulose class water-soluble polymers and water are formed.
Wherein, synthetic polymer can be polyvinyl alcohol (PVA), sodium polyacrylate (PAAS) and polyacrylamide (PAM) etc., and it can be wherein a kind of; Also two or more composite forming, the consumption that like this can be by adjusting different polymkeric substance or the structural parameter of change polymkeric substance (as molecular weight etc.) and the performance of cured layer is regulated.For aspects such as economy and finished product cohesiveness reason, recommendation is carried out composite with any two kinds in three kinds of polyvinyl alcohol (PVA), sodium polyacrylate (PAAS) and the polyacrylamides (PAM), when composite, the shared separately ratio of two kinds of synthetic polymers can be selected from 0%-100% (owing to being composite, so do not comprise 0% and 100%) according to practical situation.
Through test, following compound scheme effect is preferable:
Composite embodiment 1:
Above-mentioned synthetic polymer is by water-soluble poval and water-soluble sodium polyacrylate; Both are consisting of of percentage composition meter by weight: water-soluble poval 5, water-soluble sodium polyacrylate 100.
Composite embodiment 2:
Above-mentioned synthetic polymer is by water-soluble polyacrylamide and water-soluble sodium polyacrylate is composite forms, and both are consisting of of percentage composition meter by weight: water-soluble polyacrylamide 40, water-soluble sodium polyacrylate 50.
Composite embodiment 3:
Above-mentioned synthetic polymer is by water-soluble polyacrylamide and water-soluble poval is composite forms, and both are consisting of of percentage composition meter by weight: water-soluble polyacrylamide 90, water-soluble poval 10.
Composite embodiment 4:
Above-mentioned synthetic polymer forms by water-soluble sodium polyacrylate, water-soluble polyacrylamide and water-soluble poval are composite, the three is consisting of of percentage composition meter by weight: water-soluble sodium polyacrylate 50, water-soluble polyacrylamide 50, water-soluble poval 20.
Through experimental results show that, with the prepared railway coal transportation dust-depressor of the present invention in the composite back of two or more synthetic polymers, better with coal seam surface particles bonding, the advantages such as (average 80 kilograms of per car railway carriage or compartments) that has that film forming speed is fast, consumption is few, the usage quantity that has reduced dust-inhibitor has greatly reduced use cost.And each advantages of nontoxic raw materials side effect, raw material are easily purchased easy to use.
Above-mentioned modified-cellulose class water-soluble polymers can be carboxymethyl cellulose (CMC), methylcellulose gum (MC), Natvosol (HEC) or hydroxypropylcellulose (HPC) and sodium salt thereof etc.
The railway coal transportation dust-depressor of the invention described above can adopt customary way production.With embodiment the present invention is further described below.
Embodiment 1
In reactor, put into 95 parts of normal-temperature water (20 ℃-30 ℃), add among the above-mentioned composite embodiment 15 parts of composite good synthetic polymers, be stirred to whole dissolvings after, slowly add 1 part of carboxymethyl cellulose, be stirred to whole dissolvings and get final product.
Embodiment 2
In reactor, put into 90 parts of normal-temperature water (20 ℃-30 ℃), add 2 parts of above-mentioned composite embodiment 2 composite good synthetic polymers, be stirred to whole dissolvings after, slowly add 5 parts of methylcellulose gum, be stirred to whole dissolvings, add copper sulfate at last and stir for 0.01 part and get final product.
Embodiment 3
In reactor, put into 85 parts of normal-temperature water (20 ℃-30 ℃), add 2 parts of above-mentioned composite embodiment 3 composite good synthetic polymers, be stirred to whole dissolvings after, slowly add 2 parts of Xylo-Mucines, be stirred to whole dissolvings, add copper sulfate at last and stir for 0.05 part and get final product.
Embodiment 4
In reactor, put into 95 parts of normal-temperature water (20 ℃-30 ℃), add 7 parts of above-mentioned composite embodiment 4 composite good synthetic polymers, be stirred to whole dissolvings after, slowly add 5 parts of Xylo-Mucines, be stirred to whole dissolvings, add copper sulfate at last and stir for 1.5 parts and get final product.
The finished product of above-mentioned railway coal transportation dust-depressor of the present invention is tasteless nontoxic liquid, preparation very simple (can on-the-spotly directly prepare); Liquid after the preparation is faint yellow substantially or oyster white (different raw material color and lusters is slightly different), room temperature (20 ℃) density (g/cm 3) be 1.00-1.10, pH value (stoste) is 6-8, room temperature (25 ℃) viscosity (mPa.s)>30, solids content (%) is less than 5, and heavy metal content conforms to environmental requirement.And railway car and annex thereof there is not corrosion.

Claims (7)

1, a kind of railway coal transportation dust-depressor is characterized in that: make raw materials of effective components consisting of of percentage composition meter by weight: synthetic polymer 2-7, modified-cellulose class water-soluble polymers 0.1-5, water 85-95, copper sulfate 0-2.
2, railway coal transportation dust-depressor as claimed in claim 1 is characterized in that: described synthetic polymer is at least by two kinds of composite forming of water-soluble polymers.
3, railway coal transportation dust-depressor as claimed in claim 1 is characterized in that: described synthetic polymer is by water-soluble poval and water-soluble sodium polyacrylate; Both are consisting of of percentage composition meter by weight: water-soluble poval 30-50, water-soluble sodium polyacrylate 50-70.
4, railway coal transportation dust-depressor as claimed in claim 1, it is characterized in that: described synthetic polymer is by water-soluble polyacrylamide and water-soluble sodium polyacrylate is composite forms, both are consisting of of percentage composition meter by weight: water-soluble polyacrylamide 40-50, water-soluble sodium polyacrylate 50-60.
5, railway coal transportation dust-depressor as claimed in claim 1, it is characterized in that: described synthetic polymer is by water-soluble polyacrylamide and water-soluble poval is composite forms, both are consisting of of percentage composition meter by weight: water-soluble polyacrylamide 40-50, water-soluble poval 50-60.
6, railway coal transportation dust-depressor as claimed in claim 1, it is characterized in that: described synthetic polymer forms by water-soluble sodium polyacrylate, water-soluble polyacrylamide and water-soluble poval are composite, both are consisting of of percentage composition meter by weight: water-soluble sodium polyacrylate 30-50, water-soluble polyacrylamide 40-50, water-soluble poval 50-60.
7, a kind of railway coal transportation dust-depressor manufacture method is characterized in that: put into 85-95 part normal-temperature water in reactor; Add composite back water-soluble polymers 2-7; After being stirred to whole dissolvings, slowly add modified-cellulose class water-soluble polymers 0.1-5, be stirred to whole dissolvings, add copper sulfate 0.01-2 at last, stirring gets final product.
CNB2008102122915A 2008-09-09 2008-09-09 Railway coal transportation dust-depressor and manufacturing method thereof Expired - Fee Related CN100537696C (en)

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CN100537696C CN100537696C (en) 2009-09-09

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101899283A (en) * 2009-05-26 2010-12-01 世纪汉元(北京)科技有限公司 Method for preparing dust suppressant for coal dust transportation, loading and unloading
CN102086376A (en) * 2011-02-24 2011-06-08 东南大学 Dust emission inhibitor
CN102153991A (en) * 2010-06-21 2011-08-17 北京金元易生态工程技术中心 High-efficiency dust suppressant and preparation method thereof
CN102212337A (en) * 2011-03-30 2011-10-12 山西大学 Coal dust inhibitor and production method thereof
CN102295915A (en) * 2011-09-20 2011-12-28 北京中盛益世环保科技有限公司 Dust inhibitor
CN102585770A (en) * 2012-01-05 2012-07-18 沈阳铁道工业集团有限公司 Dust suppressant for railway transportation of mineral powder and coal and preparation method of dust suppressant
CN102766437A (en) * 2012-05-23 2012-11-07 南风化工集团股份有限公司 Coal dust inhibitor of rapid infiltration type and preparation method thereof
CN105295845A (en) * 2015-11-18 2016-02-03 天津港海湾园林绿化有限公司 Treatment agent for raise dust at open ground, preparation method and application thereof
CN105419730A (en) * 2015-12-16 2016-03-23 无锡吉进环保科技有限公司 Preparation method of heavy metal lead powder chemical dedusting agent
CN105542718A (en) * 2015-12-16 2016-05-04 无锡吉进环保科技有限公司 Heavy metal lead powder chemical dedusting agent
CN105646788A (en) * 2016-01-07 2016-06-08 江苏锦宇环境工程有限公司 Preparation method of peanut-shell degradable nano dust suppressant
CN106928901A (en) * 2017-03-27 2017-07-07 济南福君新材料科技有限公司 Colorful environmentally friendly dust suppressant and its preparation and application
CN112898951A (en) * 2021-02-02 2021-06-04 山西大同大学 Coal dust suppressant with indication function, preparation method and coal dust suppression method

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101899283A (en) * 2009-05-26 2010-12-01 世纪汉元(北京)科技有限公司 Method for preparing dust suppressant for coal dust transportation, loading and unloading
CN102153991B (en) * 2010-06-21 2013-06-05 北京金元易生态工程技术中心 High-efficiency dust suppressant and preparation method thereof
CN102153991A (en) * 2010-06-21 2011-08-17 北京金元易生态工程技术中心 High-efficiency dust suppressant and preparation method thereof
CN102086376A (en) * 2011-02-24 2011-06-08 东南大学 Dust emission inhibitor
CN102212337A (en) * 2011-03-30 2011-10-12 山西大学 Coal dust inhibitor and production method thereof
CN102295915B (en) * 2011-09-20 2014-01-01 北京中盛益世环保科技有限公司 Dust inhibitor
CN102295915A (en) * 2011-09-20 2011-12-28 北京中盛益世环保科技有限公司 Dust inhibitor
CN102585770A (en) * 2012-01-05 2012-07-18 沈阳铁道工业集团有限公司 Dust suppressant for railway transportation of mineral powder and coal and preparation method of dust suppressant
CN102585770B (en) * 2012-01-05 2016-07-06 沈阳铁道工业集团有限公司 Railway breeze, Coal Transport dust suppressant and preparation method thereof
CN102766437A (en) * 2012-05-23 2012-11-07 南风化工集团股份有限公司 Coal dust inhibitor of rapid infiltration type and preparation method thereof
CN105295845A (en) * 2015-11-18 2016-02-03 天津港海湾园林绿化有限公司 Treatment agent for raise dust at open ground, preparation method and application thereof
CN105419730A (en) * 2015-12-16 2016-03-23 无锡吉进环保科技有限公司 Preparation method of heavy metal lead powder chemical dedusting agent
CN105542718A (en) * 2015-12-16 2016-05-04 无锡吉进环保科技有限公司 Heavy metal lead powder chemical dedusting agent
CN105646788A (en) * 2016-01-07 2016-06-08 江苏锦宇环境工程有限公司 Preparation method of peanut-shell degradable nano dust suppressant
CN105646788B (en) * 2016-01-07 2018-02-13 太原理工大学 A kind of preparation method of peanut shell degradable nano dust suppressant
CN106928901A (en) * 2017-03-27 2017-07-07 济南福君新材料科技有限公司 Colorful environmentally friendly dust suppressant and its preparation and application
CN106928901B (en) * 2017-03-27 2019-06-18 济南福君新材料科技有限公司 Colorful environmental protection dust suppressant and its preparation and application
CN112898951A (en) * 2021-02-02 2021-06-04 山西大同大学 Coal dust suppressant with indication function, preparation method and coal dust suppression method

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