CN101343846A - Long fibre nonwoven wallpaper base stock and preparation method thereof, and nonwoven wallpaper prepared by the same - Google Patents
Long fibre nonwoven wallpaper base stock and preparation method thereof, and nonwoven wallpaper prepared by the same Download PDFInfo
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- CN101343846A CN101343846A CNA2008100633780A CN200810063378A CN101343846A CN 101343846 A CN101343846 A CN 101343846A CN A2008100633780 A CNA2008100633780 A CN A2008100633780A CN 200810063378 A CN200810063378 A CN 200810063378A CN 101343846 A CN101343846 A CN 101343846A
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- 239000000835 fiber Substances 0.000 title claims abstract description 198
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000000853 adhesive Substances 0.000 claims abstract description 38
- 229920001131 Pulp (paper) Polymers 0.000 claims abstract description 27
- 230000001070 adhesive effect Effects 0.000 claims description 36
- 244000085692 Cordia alliodora Species 0.000 claims description 25
- 235000004258 Cordia alliodora Nutrition 0.000 claims description 25
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 18
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 18
- 229920002472 Starch Polymers 0.000 claims description 16
- 239000008107 starch Substances 0.000 claims description 16
- 235000019698 starch Nutrition 0.000 claims description 16
- -1 polypropylene Polymers 0.000 claims description 13
- 229920001971 elastomer Polymers 0.000 claims description 8
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 8
- 229920002994 synthetic fiber Polymers 0.000 claims description 8
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- 239000012209 synthetic fiber Substances 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 229920000793 Azlon Polymers 0.000 claims description 4
- 108010076876 Keratins Proteins 0.000 claims description 4
- 102000011782 Keratins Human genes 0.000 claims description 4
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- 239000004826 Synthetic adhesive Substances 0.000 claims description 4
- 239000000227 bioadhesive Substances 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims description 4
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- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- 239000004416 thermosoftening plastic Substances 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- 244000068988 Glycine max Species 0.000 claims description 3
- 235000010469 Glycine max Nutrition 0.000 claims description 3
- 241001465754 Metazoa Species 0.000 claims description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 235000003276 Apios tuberosa Nutrition 0.000 claims description 2
- 244000105624 Arachis hypogaea Species 0.000 claims description 2
- 235000010777 Arachis hypogaea Nutrition 0.000 claims description 2
- 235000010744 Arachis villosulicarpa Nutrition 0.000 claims description 2
- 229920002261 Corn starch Polymers 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims description 2
- 108010022355 Fibroins Proteins 0.000 claims description 2
- 244000043261 Hevea brasiliensis Species 0.000 claims description 2
- TZRXHJWUDPFEEY-UHFFFAOYSA-N Pentaerythritol Tetranitrate Chemical compound [O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O TZRXHJWUDPFEEY-UHFFFAOYSA-N 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000004693 Polybenzimidazole Substances 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004642 Polyimide Substances 0.000 claims description 2
- 229920001800 Shellac Polymers 0.000 claims description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 2
- 229920002494 Zein Polymers 0.000 claims description 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 2
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims description 2
- 229920000180 alkyd Polymers 0.000 claims description 2
- 239000008280 blood Substances 0.000 claims description 2
- 210000004369 blood Anatomy 0.000 claims description 2
- 229920005549 butyl rubber Polymers 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 239000005018 casein Substances 0.000 claims description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims description 2
- 235000021240 caseins Nutrition 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- QKSIFUGZHOUETI-UHFFFAOYSA-N copper;azane Chemical compound N.N.N.N.[Cu+2] QKSIFUGZHOUETI-UHFFFAOYSA-N 0.000 claims description 2
- 239000008120 corn starch Substances 0.000 claims description 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 235000019439 ethyl acetate Nutrition 0.000 claims description 2
- 229920003052 natural elastomer Polymers 0.000 claims description 2
- 229920001194 natural rubber Polymers 0.000 claims description 2
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 2
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920006376 polybenzimidazole fiber Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001721 polyimide Polymers 0.000 claims description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 2
- 229920003225 polyurethane elastomer Polymers 0.000 claims description 2
- 239000004208 shellac Substances 0.000 claims description 2
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 claims description 2
- 229940113147 shellac Drugs 0.000 claims description 2
- 235000013874 shellac Nutrition 0.000 claims description 2
- 229920002379 silicone rubber Polymers 0.000 claims description 2
- 229920001567 vinyl ester resin Polymers 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 210000002268 wool Anatomy 0.000 claims description 2
- 239000005019 zein Substances 0.000 claims description 2
- 229940093612 zein Drugs 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 13
- 239000000123 paper Substances 0.000 description 83
- 238000000576 coating method Methods 0.000 description 33
- 239000011248 coating agent Substances 0.000 description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 239000012530 fluid Substances 0.000 description 16
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 14
- 238000010009 beating Methods 0.000 description 13
- 238000010521 absorption reaction Methods 0.000 description 12
- 239000011122 softwood Substances 0.000 description 11
- 238000003618 dip coating Methods 0.000 description 10
- 230000008602 contraction Effects 0.000 description 9
- 235000010216 calcium carbonate Nutrition 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 7
- 239000002002 slurry Substances 0.000 description 7
- 241001417490 Sillaginidae Species 0.000 description 6
- 238000005703 Whiting synthesis reaction Methods 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 6
- 239000010419 fine particle Substances 0.000 description 6
- 239000004816 latex Substances 0.000 description 6
- 229920000126 latex Polymers 0.000 description 6
- 239000000314 lubricant Substances 0.000 description 6
- 239000005871 repellent Substances 0.000 description 6
- 230000002940 repellent Effects 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000011111 cardboard Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000011087 paperboard Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 229920006231 aramid fiber Polymers 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
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- 238000004513 sizing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
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Landscapes
- Paper (AREA)
Abstract
The invention relates to a piece of non-woven wall paper, in particular to a piece of long fiber non-woven wall paper raw paper and a preparation method thereof and the non-woven wall paper prepared by the method. The long fiber non-woven wall paper raw paper comprises fiber stuff and an adhesive agent, wherein the fiber stuff comprises wood pulp fibers and functional fibers, the weight proportion between the wood pulp fibers and the functional fibers is 0 to 95 percent to 5 to 100 percent, and the adhesive agent accounts for 1 to 10 percent of the total weight of the raw paper; the functional fibers at least contain functional fibers with the fineness of 0.8 to 25 D and length of 15 to 60 mm. The surface of the wall paper presents natural stripes, the outer appearance is artistic, and further treatment is not required. Meanwhile, during the wall paper product processing, no shrinkage and moist feeling occur, the paper uncover is complete, and the paper flexibility is good. The wall paper product adopting flame-resistant fibers can be burnt on the fire source, the fire is extinguished after leaving the fire source, and the non-woven wall paper has the good flame-resistant performance.
Description
Technical field
The present invention relates to a kind of nonwoven wallpaper, especially relate to a kind of long fibre nonwoven wallpaper base stock and preparation method thereof and nonwoven wallpaper prepared therefrom.
Background technology
Nonwoven wallpaper is a kind of novel decorative material for wall surface.It has rich color, the myoplasm sense is strong, pattern is gorgeous, environmental protection, easy construction, price suitable, and characteristics such as the noble elegance of decorative effect are that other multiple indoor ornament materials is incomparable.But wallpaper in the past all is basic material with the wood pulp fibre, this wallpaper low price, shortcoming be poor performance, not water-fast, be not easy to clean, be not easy to construction, because wood pulp fibre can absorb airborne moisture content in a large number, the surface can have damp, time to grow often can existing stain.When changing wallpaper, owing to himself intensity difference, cause and peel off not exclusively, sticking wall phenomenon appears.Aspect fire prevention,, can not prevent fires in addition, so this wallpaper is difficult for promoting because wood pulp fibre belongs to inflammable thing.
The main raw material(s) of wallpaper is exactly a wallpaper base stock, and wallpaper base stock is a kind of basic material.The finished product wallpaper is exactly that the coating by variety of way, printing, embossing etc. process pattern on its surface, and its main performance is determined by body paper.Whole wood pulp body paper in the past causes the pattern displacement unintelligible adding the phenomenon that contraction appears in man-hour easily.Because of it is done, wet strength is poor, the difficulty of construction is also big simultaneously.
For this reason, the applicant has applied for that application number is: 200810060243.9 applyings date: the patent of invention on March 31st, 2008, nonwoven wallpaper base stock is disclosed, it comprises fibre stuff and adhesive, fibre stuff comprises wood pulp fibre and functional fibre, wood pulp fibre and functional fibre are 0～95%: 5～100% by part by weight between the two, and adhesive accounts for 1～10% of body paper gross weight.
In actual production, if the applicant finds the length of functional fibre is extended, owing to have long fiber destroying long fibre nonwoven wallpaper base stock surface made of paper, then long fibre nonwoven wallpaper base stock is after coating, the surface of wallpaper can show the striped of nature, good looking appearance does not need to handle in addition.
Summary of the invention
The objective of the invention is in order to solve traditional wallpaper profile not attractive in appearance, defective in needing to handle in addition an object of the present invention is to provide the anti-water of a kind of energy, mildew-resistant, anti-wiping, easily peels off, the long fibre nonwoven wallpaper base stock of good looking appearance behind the good processability, coating.An other purpose of the present invention provides the preparation method of above-mentioned long fibre nonwoven wallpaper base stock, and it adopts copies the preparation of paper method.The 3rd purpose of the present invention provides the nonwoven wallpaper that is prepared by above-mentioned wallpaper base stock, and it has the striped of nature, good looking appearance.
In order to realize first above-mentioned purpose, the present invention has adopted following technical scheme:
Long fibre nonwoven wallpaper base stock, this body paper comprises fibre stuff and adhesive, fibre stuff comprises wood pulp fibre and functional fibre, and wood pulp fibre and functional fibre are 0～95%: 5～100% by part by weight between the two, and adhesive accounts for 1～10% of body paper gross weight; It is 0.8～25D that described functional fibre contains a kind of fineness at least, and length is the functional fibre of 15～60mm.
In order to make paper can not occur man-hour shrinking adding, the functional fibre that adds can be animal fiber, artificial fibre, synthetic fiber and inorfil, as everyone knows, functional fibre becomes the tightness of paper all lower because its smooth surface, in raw material, add functional fibre after, the tightness of paper reduces, elasticity increases, and makes paper in process, and the shrinkage phenomenon of paper disappears.The water absorbent surface performance of chemical fibre is far below wood pulp fibre, and wood pulp fibre generally can absorb and be equivalent to self 9 times water, and the regain of chemical fibre is all below 5.0%, is zero especially as the regain of fibers such as polyvinyl chloride fibre, polypropylene fibre.Under equal tightness, the paper that adds functional fibre has just had the raising of matter than the paper WATER RESISTANCE of whole wood pulp like this.When functional fibre has fire resistance, become paper also certain fire resistance being arranged with regard to corresponding, just can allow paper have fire resistance as addings such as polyvinyl chloride fibre, aramid fiber and carbon fiber back.
Simultaneously, the adding fineness is 0.8～25D, length is the functional fibre of 15～60mm, owing to have long fiber destroying long fibre nonwoven wallpaper base stock surface made of paper, then long fibre nonwoven wallpaper base stock is after coating, the surface of wallpaper can show the striped of nature, and good looking appearance does not need to handle in addition.As preferably, it is 0.8～25D that functional fibre contains a kind of fineness at least, and length is the functional fibre of 30～60mm.As preferred again, it is 0.8～25D that functional fibre contains a kind of fineness at least, and length is the functional fibre of 40～60mm.
The addition of functional fibre generally between 5-100%, is less than at 5% o'clock in the functional fibre addition, and the characteristics of functional fibre can not embody, the amount that different fibers adds is differentiated, some fiber is not hydrophilic fully, after addition is many, manufactures paper with pulp and will become difficult unusually; And the picture viscose is owing to itself get by wood pulps spray silk, and its regain is than cotton also height, even 100% use, it is also out of question to manufacture paper with pulp.
Simultaneously in order to guarantee that paper has certain air permeability, the beating degree of wood pulp fibre is lower, and most functional fibres are to improve the intensity of paper and tightness by making beating, in order to guarantee the intensity of paper, must strengthen, what the present invention adopted is coating method in the machine, can certainly adopt the mode of adding in the slurry to increase the intensity of paper.
As preferably, functional fibre is a hydrophilic fibre, and the content ratio of hydrophilic fibre and wood pulp fibre is 10～100%: 0～90%, and optimum hydrophilic fibre addition is between 20～60%.As preferably, described hydrophilic fibre is one or more in animal fiber and the artificial fibre.Hydrophilic fibre is one or more in collagenous fibres, keratin fiber, fibroin fiber, regenerated celulose fibre and the azlon.As preferred again, above-mentioned keratin fiber is a wool, regenerated celulose fibre is one or more in viscose, copper ammonia fibre, the acetic ester fiber, and azlon is one or more in casein fibre, Zein fibers, ground nut fiber, the soybean fiber.
As preferably, functional fibre is hydrophilic fibre not, and the content of hydrophilic fibre and wood pulp fibre ratio is not 10～70%: 30～90%.Optimum not hydrophilic fibre addition is higher than 80% back page and is difficult to manufacture paper with pulp between 20～50%.As preferably, one or more in described not hydrophilic fibre synthetic fiber and the inorfil.As preferred again, above-mentioned synthetic fiber is in polyacrylonitrile fibre, polypropylene fibre, polyethylene fiber, polyvinyl acetal fiber, polyvinyl chloride fibre, polytetrafluoroethylene fibre, polyester fiber, polyamide fiber, polyurethane elastomeric fiber, polyimide fiber, polybenzimidazole fiber and the polyhenylene three nitrine fibers one or more.Certainly, hydrophilic fibre can not mix use with hydrophilic fibre yet.
As preferably, the part by weight of wood pulp and polyster fibre is 70～90%: 10～30% in the above-mentioned long fibre nonwoven wallpaper base stock, and the use amount of adhesive accounts for 1～10% of body paper gross weight.As preferably, above-mentioned adhesive adopts polyvinyl alcohol, starch, Cypres, and by solution oven dry weight vinyl alcohol: starch: Cypres is 2～8: 0.5～2: 0.04～0.15.
Adhesive of the present invention can comprise one or more in natural adhesive and the synthetic adhesive.Natural adhesive is one or more in shellac, gelatinized corn starch, specimens of one's blood and the natural rubber adhesive; Synthetic adhesive is one or more in thermosetting adhesive, thermoplastic adhesive, rubber based adhesives and the inorganic adhesive.Thermosetting adhesive comprises one or more in phenolic aldehyde, urea aldehyde, epoxy, polyester, organosilicon, the polyurethane; The thermoplastic adhesive comprises one or more in vinyl esters, esters of acrylic acid, phenylethylene, cellulose family, the alkyd resins class; Rubber based adhesives comprises one or more in reclaimed rubber, butadiene-styrene rubber, neoprene, cyano group rubber, butyl rubber, silicon rubber, the polyurethane rubber.
The used adhesive consumption of the present invention is decided on the requirement of strength of paper, generally between 1-10%, be lower than 1%, the intensity of paper can be not enough, is higher than 10%, and the intensity of paper is high, but the microcellular structure of paper is blocked, influence the permeability of paper, and the deflection of paper is too high, is unfavorable for the processing and the use of follow-up workshop section.
In order further to increase the water repelling property of wallpaper, also can add Cypres when in machine, being coated with, the consumption of Cypres is generally at the 0.5%-5% of adhesive consumption, be lower than 0.5%, sizing efficiency is not obvious, be higher than 5%, the surface of paper has soapy feeling, is unfavorable for the processing of follow-up workshop section.
In order to realize second above-mentioned purpose, the present invention has adopted following technical scheme:
The preparation method of above-mentioned long fibre nonwoven wallpaper base stock makes by comprising that functional fibre, wood pulp fibre and adhesive mix to copy that paper is made or mixed to copy to adopt to be coated with in the adhesive machine behind the paper by functional fibre, wood pulp fibre.
In order to realize the 3rd above-mentioned purpose, the present invention has adopted following technical scheme:
A kind of nonwoven wallpaper adopts above-mentioned long fibre nonwoven wallpaper base stock to be coated with and makes.The coating formulation of ordinary copper paperboard is adopted in coating, and prescription can show in an embodiment to some extent.
The present invention is owing to adopted above technical scheme, and the surface of wallpaper can show the striped of nature, and good looking appearance does not need to handle in addition.Simultaneously, the wallpaper product adds in process and does not shrink man-hour, the free from dampness sense, and it is complete to take off paper, and the pliability of paper is very good.Adopt the wallpaper product of fire resistance fibre under burning things which may cause a fire disaster, can burn, promptly extinguish after leaving burning things which may cause a fire disaster, have good flame retardancy.
The specific embodiment
Embodiment 1
Fibre furnish: softwood pulp 50%, broad-leaved slurry 30% mixes 20 ° of SR of the degree of beating, polyster fibre 20%, 1.5D * 10mm, the quantitative 122g/m of basic paper
2, dip-coating polyvinyl alcohol, starch and Cypres in the machine, coating fluid concentration 4%, coating weight 6%.Polyvinyl alcohol: starch: Cypres=4: 1: 0.8 (all referring to the solution oven dry weight) gets the quantitative 135g/m of body paper
2
Machine is coated with 15g/m outward
2Coating fluid prescription: 70 parts of 90 coarse whitings, 25 parts of 95 fine particle calcium carbonates, 25 parts of china clay, 50 parts in water, CMC1 part, 1 part of dispersant (solid content 40%), 2 parts of lubricants, 1.5 parts of water repellent agents, 40 parts in latex, paper basis weight 150g/m
2, become the paper index as follows: quantitative 150g/m
2, tightness 0.45g/cm
3, tensile strength 9.5kn/m, wet strength 2.5kn/m, surface absorption 30g/m
2, opacity 86%, the vertical 5100mn of tearability, horizontal 6300mn, expansion and contraction 0.3%.
Embodiment 2
Fibre furnish: softwood pulp 40%, broad-leaved slurry 30%, 18 ° of SR of the degree of beating, soybean fiber 30%, 3.5D * 5mm, the quantitative 83g/m of basic paper
2, dip-coating epoxy resin and Cypres=10: 0.5 (all referring to the solution oven dry weight) in the machine, coating fluid concentration 4%, coating weight 5%.Get the quantitative 91g/m of body paper
2
Machine is coated with 20g/m outward
2, coating fluid prescription, 70 parts of 90 coarse whitings, 25 parts of 95 fine particle calcium carbonates, 25 parts of china clay, 50 parts in water, CMC1 part, 1 part of dispersant (solid content 40%), 2 parts of lubricants, 1.5 parts of water repellent agents, 40 parts in latex, paper basis weight 111g/m
2Become the paper index as follows: quantitative 111g/m
2, tightness 0.56g/cm
3, tensile strength 7.8kn/m, wet strength 1.7kn/m, surface absorption 28g/m
2, opacity 78%, the vertical 2500mn of tearability, horizontal 3200mn, expansion and contraction 0.6%.
Embodiment 3
Fibre furnish: softwood pulp 20%, 25 ° of SR of the degree of beating, viscose 80%, 5D * 2mm, the quantitative 122g/m of basic paper
2, dip-coating butadiene-styrene rubber and Cypres=20: 1 (all referring to the solution oven dry weight) in the machine, coating fluid concentration 4%, coating weight 6%,, get the quantitative 135g/m of body paper
2, machine is coated with 15g/m outward
2
The coating fluid prescription, 70 parts of 90 coarse whitings, 25 parts of 95 fine particle calcium carbonates, 25 parts of china clay, 50 parts in water, CMC1 part, 1 part of dispersant (solid content 40%), 2 parts of lubricants, 1.5 parts of water repellent agents, 40 parts in latex, paper basis weight 150g/m
2, become the paper index as follows: quantitative 150g/m
2, tightness 0.38g/cm
3, tensile strength 3.5kn/m, wet strength 1.2kn/m, surface absorption 35g/m
2, opacity 89%, the vertical 2300mn of tearability, horizontal 2900mn, expansion and contraction 0.2%.
Embodiment 4
Fibre furnish: softwood pulp 60%, 31 ° of SR of the degree of beating, aramid fiber 40%, 25D * 40mm, the quantitative 122g/m of basic paper
2, dip-coating polyvinyl alcohol, starch and Cypres in the machine, coating fluid concentration 4%, coating weight 3%, polyvinyl alcohol: starch: Cypres=4: 1: 0.8 (all referring to the solution oven dry weight) gets the quantitative 135g/m of body paper
2
Machine is coated with 15g/m outward
2, coating fluid prescription, 70 parts of 90 coarse whitings, 25 parts of 95 fine particle calcium carbonates, 25 parts of china clay, 50 parts in water, CMC1 part, 1 part of dispersant (solid content 40%), 2 parts of lubricants, 1.5 parts of water repellent agents, 40 parts in latex, paper basis weight 150g/m
2, become the paper index as follows: quantitative 150g/m
2, tightness 0.41g/cm
3, tensile strength 6.1kn/m, wet strength 1.8kn/m, surface absorption 21g/m
2, opacity 79%, the vertical 5600mn of tearability, horizontal 7400mn, expansion and contraction 0.23%.
Embodiment 5
Fibre furnish: softwood pulp 40%, broad-leaved slurry 40%, 27 ° of SR of the degree of beating, nylon fibre 20%, 15D * 10mm, the quantitative 122g/m of basic paper
2, dip-coating polyvinyl alcohol and Cypres in the machine, coating fluid concentration 4%, coating weight 4%, polyvinyl alcohol: Cypres=4: 0.8 (all referring to the solution oven dry weight) gets the quantitative 135g/m of body paper
2
Become the paper index as follows: quantitative 135g/m
2, tightness 0.45g/cm
3, tensile strength 7.7kn/m, wet strength 1.7kn/m, surface absorption 22g/m
2, opacity 83%, the vertical 3500mn of tearability, horizontal 4700mn, expansion and contraction 0.5%.
Embodiment 6
Fibre furnish: softwood pulp 70%, 25 ° of SR of the degree of beating, polyvinyl alcohol fibre 20%, 4D * 15mm, carbon fiber 10%, powdery, 200 orders filter, the quantitative 122g/m of basic paper
2, dip-coating polyvinyl alcohol, starch and Cypres in the machine, coating fluid concentration 10%, coating weight 10%, polyvinyl alcohol: starch: Cypres=4: 1: 0.8 (all referring to the solution oven dry weight) gets the quantitative 135g/m of body paper
2
Become the paper index as follows: quantitative 135g/m
2, tightness 0.36g/cm
3, tensile strength 5.7kn/m, wet strength 1.2kn/m, surface absorption 26g/m
2, opacity 88%, the vertical 6700mn of tearability, laterally 5100mn.
Embodiment 7
Fibre furnish: softwood pulp 30%, 20 ° of SR of the degree of beating, polypropylene fiber 70%, 15D * 10mm, the quantitative 122g/m of basic paper
2, dip-coating polyvinyl alcohol, starch and Cypres in the machine, coating fluid concentration 10%, coating weight 10%, polyvinyl alcohol: starch: Cypres=4: 1: 0.8 (all referring to the solution oven dry weight) gets the quantitative 135g/m of body paper
2
Become the paper index as follows: quantitative 135g/m
2, tightness 0.35g/cm
3, tensile strength 4.7kn/m, wet strength 1.2kn/m, surface absorption 18g/m
2, opacity 77%, the vertical 6200mn of tearability, laterally 4800mn.
Embodiment 8
Fibre furnish: softwood pulp 20%, broad-leaved slurry 60% mixes 20 ° of SR of the degree of beating, polyster fibre 10%, 1.5 * 6mm, 10%, 1.5 * 15mm, the quantitative 85g/m of basic paper
2, water-soluble acrylic acid resin of dip-coating and Cypres in the machine, coating fluid concentration 4%, coating weight 4%.Water-soluble acrylic acid portions of resin Cypres=4: 0.8 (all referring to the solution oven dry weight) gets the quantitative 87.5g/m of body paper
2
Machine is coated with 15g/m outward
2Coating fluid prescription: 90 coarse whitings: 70 parts, 95 fine particle calcium carbonates: 25 parts, china clay: 25 parts, water: 50 parts, CMC:1 part, dispersant (solid content 40%): 1 part, 2 parts of lubricants, water repellent agent: 1.5 parts, latex: 40 parts.Paper basis weight 108.7g/m
2, become the paper index as follows: quantitative 110g/m
2, tightness 0.55g/cm
3, tensile strength 8.5kn/m, wet strength 2.5kn/m, surface absorption 25g/m
2, opacity 86%, the vertical 3100mn of tearability, horizontal 4830mn, expansion and contraction 0.3%.
Embodiment 9
Fibre furnish: softwood pulp 60%, broad-leaved slurry 20%, 18 ° of SR of the degree of beating, polyster fibre 10%1.5 * 6mm, 10%1.5 * 12mm, the quantitative 65g/m of basic paper
2, the wet strength agent of adding 3.2% and 4% water-soluble polyamine fat resin, 10% china clay, 10% calcium carbonate in the machine.Get the quantitative 65.2g/m of body paper
2
Become the paper index as follows: quantitative 65.2g/m
2, tightness 0.45g/cm
3, tensile strength 4.7kn/m, wet strength 1.4kn/m, surface absorption 18g/m
2, opacity 75%, the vertical 2200mn of tearability, laterally 3500mn.
Embodiment 10
Fibre furnish: softwood pulp 50%, broad-leaved slurry 30% mixes 20 ° of SR of the degree of beating, polyster fibre 15%, 1.5D * 10mm, polyster fibre 5%, 1.5D * 50mm, the quantitative 122g/m of basic paper
2, dip-coating polyvinyl alcohol, starch and Cypres in the machine, coating fluid concentration 4%, coating weight 6%.Polyvinyl alcohol: starch: Cypres=4: 1: 0.8 (all referring to the solution oven dry weight) gets the quantitative 135g/m of body paper
2
Machine is coated with 15g/m outward
2Coating fluid prescription: 70 parts of 90 coarse whitings, 25 parts of 95 fine particle calcium carbonates, 25 parts of china clay, 50 parts in water, CMC1 part, 1 part of dispersant (solid content 40%), 2 parts of lubricants, 1.5 parts of water repellent agents, 40 parts in latex, paper basis weight 150g/m
2, become the paper index as follows: quantitative 150g/m
2, tightness 0.45g/cm
3, tensile strength 9.5kn/m, wet strength 2.5kn/m, surface absorption 30g/m
2, opacity 86%, the vertical 5100mn of tearability, horizontal 6300mn, expansion and contraction 0.3%.
Embodiment 11
Fibre furnish: softwood pulp 70%, 25 ° of SR of the degree of beating, polyvinyl alcohol fibre 20%, 4D * 10mm, polypropylene fiber 10%, 15D * 30mm, the quantitative 122g/m of basic paper
2, dip-coating polyvinyl alcohol, starch and Cypres in the machine, coating fluid concentration 10%, coating weight 10%, polyvinyl alcohol: starch: Cypres=4: 1: 0.8 (all referring to the solution oven dry weight) gets the quantitative 135g/m of body paper
2
Become the paper index as follows: quantitative 135g/m
2, tightness 0.36g/cm
3, tensile strength 5.7kn/m, wet strength 1.2kn/m, surface absorption 26g/m
2, opacity 88%, the vertical 6700mn of tearability, laterally 5100mn.
Method of testing:
Quantitative GB/T451.2 paper and the quantitative determination method of cardboard
The determination method of thickness G B/T451.3 paper and cal(l)iper
The determination method of tearability GB/T455.1 paper tearability
The determination method of expansion and contraction GB/T451.3 paper retractility
The determination method of tensile strength after wet strength GB/T465.2 paper and cardboard soak in required time
The absorptive determination method of surface absorption GB/T1540 paper and cardboard
The determination method of thickness G B/T1543 paper opacity
The determination method of tensile strength GB/T12914 paper and cardboard tensile strength
More than the common wallpaper of 11 patterns and the speciality paper Co., Ltd of dragon trip China group that on market, purchases, try out in Jiangsu North Platform wallpaper company together, find after making wallpaper, shrinkage phenomenon appears in the product of China group in process, behind the sticking wall under standard humidity, paper has damp after 3 hours, adhesion phenomenon is arranged when taking off paper, and embodiment 1-11 sample adds and do not shrink man-hour, the free from dampness sense, and it is complete to take off paper, the pliability of paper is very good, embodiment 4 samples can burn under burning things which may cause a fire disaster in addition, promptly extinguish after leaving burning things which may cause a fire disaster, have good flame retardancy.Embodiment 4,6,8,10,11 is after coating, and the surface of wallpaper can show the striped of nature, good looking appearance; Other embodiment then do not have tangible striped.
Claims (16)
1. long fibre nonwoven wallpaper base stock, it is characterized in that: this body paper comprises fibre stuff and adhesive, fibre stuff comprises wood pulp fibre and functional fibre, and wood pulp fibre and functional fibre are 0～95%: 5～100% by part by weight between the two, and adhesive accounts for 1～10% of body paper gross weight; It is 0.8～25D that described functional fibre contains a kind of fineness at least, and length is the functional fibre of 15～60mm.
2. long fibre nonwoven wallpaper base stock according to claim 1 is characterized in that: functional fibre is a hydrophilic fibre, and the content ratio of hydrophilic fibre and wood pulp fibre is 10～100%: 0～90%.
3. long fibre nonwoven wallpaper base stock according to claim 2 is characterized in that: hydrophilic fibre is animal fiber and artificial fibre.
4. long fibre nonwoven wallpaper base stock according to claim 3 is characterized in that: hydrophilic fibre is one or more in collagenous fibres, keratin fiber, fibroin fiber, regenerated celulose fibre and the azlon.
5. long fibre nonwoven wallpaper base stock according to claim 4, it is characterized in that: keratin fiber is a wool, regenerated celulose fibre is one or more in viscose, copper ammonia fibre, the acetic ester fiber, and azlon is one or more in casein fibre, Zein fibers, ground nut fiber, the soybean fiber.
6. long fibre nonwoven wallpaper base stock according to claim 1 is characterized in that: functional fibre is hydrophilic fibre not, and the content of hydrophilic fibre and wood pulp fibre ratio is not 10～70%: 30～90%.
7. long fibre nonwoven wallpaper base stock according to claim 6 is characterized in that: one or more in hydrophilic fibre synthetic fiber and the inorfil not.
8. long fibre nonwoven wallpaper base stock according to claim 7 is characterized in that: synthetic fiber are one or more in polyacrylonitrile fibre, polypropylene fibre, polyethylene fiber, polyvinyl acetal fiber, polyvinyl chloride fibre, polytetrafluoroethylene fibre, polyester fiber, polyamide fiber, polyurethane elastomeric fiber, polyimide fiber, polybenzimidazole fiber and the polyhenylene three nitrine fibers.
9. long fibre nonwoven wallpaper base stock according to claim 8 is characterized in that: the part by weight of wood pulp and polyster fibre is 70～90%: 10～30%, and the use amount of adhesive accounts for 1～10% of body paper gross weight.
10. long fibre nonwoven wallpaper base stock according to claim 9 is characterized in that: adhesive adopts polyvinyl alcohol, starch, Cypres, and by solution oven dry weight vinyl alcohol: starch: Cypres is 2～8: 0.5～2: 0.04～0.15.
11. long fibre nonwoven wallpaper base stock according to claim 1 is characterized in that: adhesive comprises one or more in natural adhesive and the synthetic adhesive.
12. long fibre nonwoven wallpaper base stock according to claim 11 is characterized in that: natural adhesive is one or more in shellac, gelatinized corn starch, specimens of one's blood and the natural rubber adhesive; Synthetic adhesive is one or more in thermosetting adhesive, thermoplastic adhesive, rubber based adhesives and the inorganic adhesive.
13. long fibre nonwoven wallpaper base stock according to claim 12 is characterized in that: thermosetting adhesive comprises one or more in phenolic aldehyde, urea aldehyde, epoxy, polyester, organosilicon, the polyurethane; The thermoplastic adhesive comprises one or more in vinyl esters, esters of acrylic acid, phenylethylene, cellulose family, the alkyd resins class; Rubber based adhesives comprises one or more in reclaimed rubber, butadiene-styrene rubber, neoprene, cyano group rubber, butyl rubber, silicon rubber, the polyurethane rubber.
14. long fibre nonwoven wallpaper base stock according to claim 1 is characterized in that: adhesive comprises the Cypres that accounts for adhesive weight 0.5～5%.
15. the preparation method of long fibre nonwoven wallpaper base stock according to claim 1 is characterized in that: make by comprising that functional fibre, wood pulp fibre and adhesive mix to copy that paper is made or mixed to copy to adopt to be coated with in the adhesive machine behind the paper by functional fibre, wood pulp fibre.
16. a nonwoven wallpaper is characterized in that: adopt any described long fibre nonwoven wallpaper base stock of claim of claim 1～15 to be coated with and make.
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Effective date of registration: 20100921 Address after: 323300 No. 108 Kaine Road, Suichang County, Zhejiang Applicant after: Zhejiang KAN Specialties Material Co.,Ltd. Co-applicant after: ZHEJIANG KAIFENG PAPER Co.,Ltd. Address before: 323300 No. 108 Kaine Road, Suichang County, Zhejiang Applicant before: Zhejiang KAN Specialties Material Co.,Ltd. |
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Effective date of registration: 20151216 Address after: 323300 No. 108 Kaine Road, Suichang County, Zhejiang Patentee after: Zhejiang KAN Specialties Material Co.,Ltd. Address before: 323300 No. 108 Kaine Road, Suichang County, Zhejiang Patentee before: Zhejiang KAN Specialties Material Co.,Ltd. Patentee before: ZHEJIANG KAIFENG PAPER Co.,Ltd. |
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Effective date of registration: 20211013 Address after: 323300 Yuankou Village, Miaogao Street, Suichang County, Lishui City, Zhejiang Province Patentee after: Zhejiang Kaien New Material Co.,Ltd. Patentee after: ZHEJIANG KAN SPECIAL PAPER Co.,Ltd. Address before: 323300 No. 108 Kaine Road, Suichang County, Zhejiang Patentee before: ZHEJIANG KAN SPECIALTIES MATERIAL Co.,Ltd. |
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Denomination of invention: Long fiber non-woven wallpaper base paper and its preparation method, as well as non-woven wallpaper prepared from it Effective date of registration: 20230907 Granted publication date: 20110615 Pledgee: Industrial Commercial Bank of China Ltd. Suichang branch Pledgor: Zhejiang Kaien New Material Co.,Ltd. Registration number: Y2023330001977 |
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