CN101313883B - A kind of cosmetic emulsifier and preparation method thereof - Google Patents
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- CN101313883B CN101313883B CN2008100648254A CN200810064825A CN101313883B CN 101313883 B CN101313883 B CN 101313883B CN 2008100648254 A CN2008100648254 A CN 2008100648254A CN 200810064825 A CN200810064825 A CN 200810064825A CN 101313883 B CN101313883 B CN 101313883B
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 18
- 239000003995 emulsifying agent Substances 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 30
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical class CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 claims abstract description 21
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 claims abstract description 20
- -1 polyoxyethylene Polymers 0.000 claims abstract description 14
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000001263 FEMA 3042 Substances 0.000 claims abstract description 10
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 claims abstract description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 10
- 235000019438 castor oil Nutrition 0.000 claims abstract description 10
- 239000004359 castor oil Substances 0.000 claims abstract description 10
- 235000012000 cholesterol Nutrition 0.000 claims abstract description 10
- 239000008367 deionised water Substances 0.000 claims abstract description 10
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 10
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 10
- 235000015523 tannic acid Nutrition 0.000 claims abstract description 10
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 claims abstract description 10
- 229940033123 tannic acid Drugs 0.000 claims abstract description 10
- 229920002258 tannic acid Polymers 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 8
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229930006000 Sucrose Natural products 0.000 claims abstract description 5
- 239000005720 sucrose Substances 0.000 claims abstract description 5
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 claims abstract description 4
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 claims abstract description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 6
- 229910052740 iodine Inorganic materials 0.000 claims description 6
- 239000011630 iodine Substances 0.000 claims description 6
- 229940083466 soybean lecithin Drugs 0.000 claims description 6
- 238000009903 catalytic hydrogenation reaction Methods 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 150000003904 phospholipids Chemical class 0.000 claims description 3
- 235000010469 Glycine max Nutrition 0.000 claims 5
- WTJKGGKOPKCXLL-RRHRGVEJSA-N phosphatidylcholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCCC=CCCCCCCCC WTJKGGKOPKCXLL-RRHRGVEJSA-N 0.000 claims 5
- 239000012467 final product Substances 0.000 claims 1
- 229940099578 hydrogenated soybean lecithin Drugs 0.000 abstract description 15
- 235000011187 glycerol Nutrition 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 6
- QIZPVNNYFKFJAD-UHFFFAOYSA-N 1-chloro-2-prop-1-ynylbenzene Chemical compound CC#CC1=CC=CC=C1Cl QIZPVNNYFKFJAD-UHFFFAOYSA-N 0.000 abstract description 5
- 229940035023 sucrose monostearate Drugs 0.000 abstract description 5
- 231100000331 toxic Toxicity 0.000 abstract description 5
- 230000002588 toxic effect Effects 0.000 abstract description 5
- 230000007774 longterm Effects 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 2
- 230000003064 anti-oxidating effect Effects 0.000 abstract description 2
- 229960001777 castor oil Drugs 0.000 abstract description 2
- 210000001339 epidermal cell Anatomy 0.000 abstract description 2
- 229960005150 glycerol Drugs 0.000 abstract description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 4
- PZNPLUBHRSSFHT-RRHRGVEJSA-N 1-hexadecanoyl-2-octadecanoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCCCC(=O)O[C@@H](COP([O-])(=O)OCC[N+](C)(C)C)COC(=O)CCCCCCCCCCCCCCC PZNPLUBHRSSFHT-RRHRGVEJSA-N 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 2
- FHHZOYXKOICLGH-UHFFFAOYSA-N dichloromethane;ethanol Chemical compound CCO.ClCCl FHHZOYXKOICLGH-UHFFFAOYSA-N 0.000 description 2
- 239000000787 lecithin Substances 0.000 description 2
- 235000010445 lecithin Nutrition 0.000 description 2
- 229940067606 lecithin Drugs 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000008347 soybean phospholipid Substances 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
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- Cosmetics (AREA)
Abstract
本发明提供了一种化妆品用乳化剂及其制备方法。它包括重量百分比为氢化大豆卵磷脂10-20份、胆甾醇2-5份、聚氧乙烯蓖麻油1-3份、鞣酸2-3份、甘油5-10份、甘油单硬脂酸蔗糖酯1-3份和去离子水56-79份。本发明具有很强的抗氧化性能，纯天然、无毒副作用，富有多种保健功能。本发明以氢化大豆磷脂为主体原料，辅以胆甾醇、聚氧乙烯蓖麻油、鞣酸、甘油、甘油单硬脂酸蔗糖酯、去离子水而制备的一种化妆品乳化剂，纯天然、无毒副作用，长期使用可以保护人体表皮细胞免受自由基的侵害，从而具有延缓衰老的功效。The invention provides an emulsifier for cosmetics and a preparation method thereof. It includes 10-20 parts by weight of hydrogenated soybean lecithin, 2-5 parts of cholesterol, 1-3 parts of polyoxyethylene castor oil, 2-3 parts of tannic acid, 5-10 parts of glycerin, glycerol monostearate sucrose 1-3 parts of ester and 56-79 parts of deionized water. The invention has strong anti-oxidation performance, is pure natural, has no toxic and side effects, and is rich in various health care functions. The present invention is a cosmetic emulsifier prepared with hydrogenated soybean lecithin as the main raw material, supplemented with cholesterol, polyoxyethylene castor oil, tannic acid, glycerin, sucrose monostearate, and deionized water. Toxic and side effects, long-term use can protect human epidermal cells from free radicals, thus having the effect of delaying aging.
Description
(一)技术领域(1) Technical field
本发明涉及一种化妆品用乳化剂，尤其涉及一种以活性氢化大豆磷脂为主体的化妆品乳化剂及其制备方法。The invention relates to an emulsifier for cosmetics, in particular to a cosmetic emulsifier mainly composed of active hydrogenated soybean lecithin and a preparation method thereof.
(二)技术背景(2) Technical background
化妆品用乳化剂多数是化学合成物质，长期食用对皮肤有一定的毒害作用。氢化大豆卵磷脂由于使用催化和加氢工艺，使大豆磷脂分子结构中不饱和脂肪酸的不饱和链消失，从而大大地提高卵磷脂的化学稳定性、分散性、乳化性，是一种优良的天然乳化剂，对人体皮肤具有保护作用，故可广泛应用于各种化妆品中。Most of the emulsifiers used in cosmetics are chemical synthetic substances, and long-term consumption has certain toxic effects on the skin. Hydrogenated soybean lecithin, due to the use of catalytic and hydrogenation processes, makes the unsaturated chains of unsaturated fatty acids in the molecular structure of soybean lecithin disappear, thereby greatly improving the chemical stability, dispersibility, and emulsification of lecithin. It is an excellent natural Emulsifier has a protective effect on human skin, so it can be widely used in various cosmetics.
(三)发明内容(3) Contents of the invention
本发明的目的在于提供一种具有很强的抗氧化性能，纯天然、无毒副作用，富有多种保健功能的化妆品用乳化剂。The object of the present invention is to provide a kind of emulsifier for cosmetics which has strong anti-oxidation performance, is pure natural, has no toxic and side effects, and is rich in various health care functions.
本发明的目的是这样实现的：它包括重量百分比为氢化大豆卵磷脂10-20份、胆甾醇2-5份、聚氧乙烯蓖麻油1-3份、鞣酸2-3份、甘油5-10份、甘油单硬脂酸蔗糖酯1-3份和去离子水56-79份。The object of the present invention is achieved like this: it comprises weight percentage and is hydrogenated soybean lecithin 10-20 parts, cholesterol 2-5 parts, polyoxyethylene castor oil 1-3 parts, tannic acid 2-3 parts, glycerin 5- 10 parts, 1-3 parts of glycerol sucrose monostearate and 56-79 parts of deionized water.
本发明的另一目的在于提供一种化妆品用乳化剂的制备方法：首先以大豆磷脂为原料经催化加氢，反应后分离催化剂、双氧水脱色、脱除溶剂，获得碘价为20～30的氢化大豆磷脂，将重量百分比为氢化大豆磷脂10-20份、胆甾醇2-5份、聚氧乙烯蓖麻油1-3份、鞣酸2-3份、甘油5-10份、甘油单硬脂酸蔗糖酯1-3份和去离子水56-79份充分混合均匀，制得化妆品用乳化剂。Another object of the present invention is to provide a method for preparing an emulsifier for cosmetics: first, soybean lecithin is used as a raw material through catalytic hydrogenation, after the reaction, the catalyst is separated, hydrogen peroxide decolorizes, and the solvent is removed to obtain a hydrogenated emulsifier with an iodine value of 20-30. Soy lecithin, the percentage by weight is 10-20 parts of hydrogenated soybean lecithin, 2-5 parts of cholesterol, 1-3 parts of polyoxyethylene castor oil, 2-3 parts of tannic acid, 5-10 parts of glycerin, glycerol monostearate 1-3 parts of sucrose ester and 56-79 parts of deionized water are thoroughly mixed evenly to prepare an emulsifier for cosmetics.
本发明的制备方法还有这样一些技术特征：Preparation method of the present invention also has some technical features:
1、所述的氢化大豆卵磷脂的制备条件以二氯甲烷——乙醇混合物(V∶V＝3∶1)为溶剂，选用钯催化剂、其加入量为磷脂用量的5％，在55℃、氢气压力为0.6MPa，在1L高压釜中恒温反应3h即可，反应生成物经分离催化剂、双氧水脱色、脱除溶剂后，可获得碘价为20～30，色呈淡黄，无难闻气味的氢化大豆卵磷脂。1, the preparation condition of described hydrogenated soybean lecithin takes dichloromethane-ethanol mixture (V: V=3: 1) as solvent, selects palladium catalyst, and its add-on is 5% of phospholipid consumption, at 55 ℃, The hydrogen pressure is 0.6MPa, and it is enough to react at a constant temperature in a 1L autoclave for 3 hours. After the reaction product is separated from the catalyst, hydrogen peroxide decolorizes, and the solvent is removed, the iodine value can be obtained. The iodine value is 20-30, the color is light yellow, and there is no unpleasant smell. Hydrogenated Soy Lecithin.
本发明中大豆卵磷脂采用催化加氢方法，使磷脂所含有的不饱和键部分饱和，提高其稳定性并减弱或消除其颜色和气味。本发明采用了催化加氢方法制备了一种氢化大豆磷脂，为日化工业等提供了一种新型原料。In the present invention, soybean lecithin adopts a catalytic hydrogenation method to partially saturate the unsaturated bonds contained in the phospholipids, improve its stability and weaken or eliminate its color and smell. The invention adopts a catalytic hydrogenation method to prepare a hydrogenated soybean lecithin, which provides a new type of raw material for the daily chemical industry and the like.
本发明的优点是：The advantages of the present invention are:
1.大豆磷脂经催化加氢，使磷脂所含有的不饱和键部分饱和，提高其稳定性并减弱或消除其颜色和气味。1. Soybean lecithin is catalytically hydrogenated to partially saturate the unsaturated bonds contained in the lecithin, improve its stability and weaken or eliminate its color and smell.
2.本发明以氢化大豆磷脂为主体原料，辅以胆甾醇、聚氧乙烯蓖麻油、鞣酸、甘油、甘油单硬脂酸蔗糖酯、去离子水而制备的一种化妆品乳化剂，纯天然、无毒副作用，长期使用可以保护人体表皮细胞免受自由基的侵害，从而具有延缓衰老的功效。2. The present invention is a cosmetic emulsifier prepared with hydrogenated soybean lecithin as the main raw material, supplemented with cholesterol, polyoxyethylene castor oil, tannic acid, glycerin, sucrose monostearate, and deionized water. It is pure natural , No toxic side effects, long-term use can protect human epidermal cells from free radicals, so it has the effect of delaying aging.
(四)具体实施方式(4) Specific implementation methods
下面结合具体实施例对本发明作进一步描述：The present invention will be further described below in conjunction with specific embodiment:
实施例1：Example 1:
本实施例选取精制大豆磷脂200g，用400ml等二氯甲烷——乙醇混合物(V∶V＝3∶1)为溶剂，加入10g钯催化剂在1L高压釜中加热至55℃、氢气压力为0.6MPa，恒温反应3h后，反应生成物经分离催化剂、双氧水脱色、脱除溶剂，获得碘价为20～30，色呈淡黄，无难闻气味的氢化大豆磷脂。In this example, 200 g of refined soybean lecithin was selected, and 400 ml of dichloromethane-ethanol mixture (V: V=3: 1) was used as a solvent, and 10 g of palladium catalyst was added and heated to 55 ° C in a 1 L autoclave under a hydrogen pressure of 0.6 MPa. , After constant temperature reaction for 3 hours, the reaction product is decolorized by separation catalyst, hydrogen peroxide, and solvent removed to obtain hydrogenated soybean lecithin with an iodine value of 20-30, a light yellow color, and no unpleasant smell.
取上述工艺制备的氢化大豆磷脂10g，再分别加入胆甾醇2g、聚氧乙烯蓖麻油3g、鞣酸2g、甘油5g、甘油单硬脂酸蔗糖酯1g和去离子水77g，将上述原料经高速(5000r/m)混匀后，即可应用于各种化妆品。Get 10g of hydrogenated soybean lecithin prepared by the above-mentioned process, then add 2g of cholesterol, 3g of polyoxyethylene castor oil, 2g of tannic acid, 5g of glycerin, 1g of sucrose monostearate and 77g of deionized water respectively, and the above-mentioned raw materials are processed by high-speed (5000r/m) After mixing, it can be applied to various cosmetics.
实施例2：Example 2:
本实施例中氢化大豆卵磷脂的制备过程同实施例1，不同在于取上述工艺制备的氢化大豆卵磷脂15g，再分别加入胆甾醇4g、聚氧乙烯蓖麻油2g、鞣酸3g、甘油8g、甘油单硬脂酸蔗糖酯2g和去离子水66g，将上述原料经高速(5000r/m)混匀后，即可应用于各种化妆品。The preparation process of hydrogenated soybean lecithin in this example is the same as in Example 1, the difference is that 15g of hydrogenated soybean lecithin prepared by the above process is taken, and then 4g of cholesterol, 2g of polyoxyethylene castor oil, 3g of tannic acid, 8g of glycerin, Glycerol sucrose monostearate 2g and deionized water 66g, after mixing the above raw materials at high speed (5000r/m), they can be applied to various cosmetics.
实施例3：Example 3:
本实施例中氢化大豆卵磷脂的制备过程同实施例1，不同在于取上述工艺制备的氢化大豆卵磷脂20g、胆甾醇5g、聚氧乙烯蓖麻油3g、鞣酸3g、甘油10g、甘油单硬脂酸蔗糖酯3g和去离子水56g，将上述原料经高速(5000r/m)混匀后，即可应用于各种化妆品。The preparation process of hydrogenated soybean lecithin in this example is the same as in Example 1, except that 20 g of hydrogenated soybean lecithin, 5 g of cholesterol, 3 g of polyoxyethylene castor oil, 3 g of tannic acid, 10 g of glycerin, and glycerin monohard prepared by the above process are used. Sucrose fatty acid ester 3g and deionized water 56g, after mixing the above raw materials at high speed (5000r/m), they can be applied to various cosmetics.
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101214199A (en) * | 2007-12-29 | 2008-07-09 | 广东拉芳日化有限公司 | Nano active acne-eliminating cosmetic composition |
Non-Patent Citations (2)
| Title |
|---|
| 化妆品配方.日用化妆品配方Vol.30 No.3.2007,Vol.30(No.3),46-48. * |
| 化妆品配方.日用化妆品配方Vol.30No.3.2007 Vol.30(No.3) |
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| Publication number | Publication date |
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| CN101313883A (en) | 2008-12-03 |
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