CN101302129A - Calcium hydrophosphate suspending agent - Google Patents
Calcium hydrophosphate suspending agent Download PDFInfo
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- CN101302129A CN101302129A CNA2008101085251A CN200810108525A CN101302129A CN 101302129 A CN101302129 A CN 101302129A CN A2008101085251 A CNA2008101085251 A CN A2008101085251A CN 200810108525 A CN200810108525 A CN 200810108525A CN 101302129 A CN101302129 A CN 101302129A
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Abstract
The invention relates to a microelement fertilizer for agricultural use. The microelement fertilizer is calcium hydrogen phosphate suspending agent which is sticky with high concentration. The compositions by mass percent of the microelement fertilizer are: 20 to 80 percent of raw calcium hydrogen phosphate powder, 1 to 7 percent of wetting agent, 2 to 10 percent of dispersant, 2 to 6 percent of antifreeze, 0.2 to 1.0 percent of defoaming agent, 0.1 to 0.8 percent of thickening agent, and 2.2 to 76.7 percent of water. The compositions are mixed evenly with high shear and are grinded to the fineness between 0.5 and 6 micron; the viscosity coefficient of the mixture is adjusted by the thickening agent to obtain the calcium hydrogen phosphate suspending agent. The microelement fertilizer is prepared through adopting the high-performance addition agent and advanced technology. The microelement fertilizer is characterized by high content of activity components, good dispersion performance and stable heat storing performance. In the application, the microelement fertilizer has the advantages of rapid calcium supplement speed, good effect, small dosage of the fertilizer and environmental protection.
Description
Technical field
This invention relates to a kind of agricultural trace element fertilizer, relates to secondary calcium phosphate suspension agent and composition thereof.
Technical background
In China's agricultural production, need to use multiple agricultural fertilizer.Wherein nitrogen, phosphorus, potassium are the maximum elements of crop demand, are called macroelement; Boron (B), manganese (Mn), zinc (Zn), copper (Cu), molybdenum (Mo), iron (Fe), chlorine (Cl) element crop requirement are little, are called trace element; Calcium (Ca), magnesium (Mg), sulphur (S) element requirement claim moderate-element between the centre.In the process of China's agriculture production, macroelement is by being replenished crop at a large amount of chemically composited fertilizer of soil application; Trace element also obtains peasant's attention, by application of organic fertilizers material or blade spraying trace element recombiner crop is replenished; Secondary nutrients has limited the further raising of crop yield and quality because wrong on the understanding or think little of lacks available moderate-element in the soil (mainly referring to calcium and magnesium).Wherein calcium deficiency to the plant growth influence obviously.The intravital calcium of plant has multiple function, as the regulatory function to biological membrane permeability.Calcium is also relevant with the formation of cell walls, owing to the middle lamella of cell walls is made up of Pectin calcium, so calcium is a kind of very important element that constitutes cell walls.During calcium deficiency, the formation of cell walls is hindered, and influences cell fission, or cell fission is incomplete, can not form new cell walls, syncyte can occur, so meristematic tissue is injured the earliest.Therefore during calcium deficiency, cell fission and growth all are suppressed, the tender organ of children (tip of a root, the stem end) necrosis (withered worry) of festering when serious.Calcium has certain effect to plant disease-resistant in addition, if the plant calcic is more abundant, then easily forms callus.
In present stage, China's plant husbandry is replenished the calcium based on lime, gypsum to fruit and vegetables, also uses phosphate fertilizer or the additional calcium of nitrogenous fertilizer such as fused(calcium magnesium)phosphate, calcium superphosphate, nitrocalcite simultaneously.Application process adopts the mode of soil application to use more.The soil application method is used when being applicable to the prevention calcium deficiency owing to absorbing slowly, absorbing incomplete reason.Too much can reduce the validity of micronutrient elements such as boron, zinc and cause soil compaction but use.When peasant household found the fruit tree and vegetable calcium deficiency, calcium deficiency had often arrived more serious degree, at this moment only carries out foliage applying and could effectively control the crop calcium deficiency.Foliage-spray nitrocalcite, calcium chloride can be replenished the calcium rapidly, but nitrocalcite, calcium chloride belong to acid inorganic chemical, and the active calcium ion content is low, and consumption is big, very easily produce the fertilizer evil.Therefore, need to seek more efficient, absorb fast, safety, and be applicable to the fertilizer agent of replenishing the calcium of crop Foliage Absorption.
Secondary calcium phosphate is a kind of Chemicals commonly used, is used for feedstuff industry, food service industry more.Secondary calcium phosphate is a kind of powdery solid, and the calcium content height also can replenish phosphorus simultaneously.But directly use, crop leaf is difficult for absorbing.It is crucial that secondary calcium phosphate is mixed with appropriate formulation.At present, prepare and use still unmanned report at the preparation of China's secondary calcium phosphate suspension agent.
Summary of the invention
Purpose of the present invention is exactly slowly, easily to produce environmental pollution or be difficult for shortcoming such as absorptions and a kind of high-content, environment-friendly type, the easy high secondary calcium phosphate suspension agent of absorption rate developed in order to overcome existing fruit tree and the vegetables technology medium velocity of replenishing the calcium.Suspension agent is the Water-borne modification formulation, has the low characteristics of environmental protection and cost concurrently, is a megatrend of present agricultural fertilizer formulations processing development.
The objective of the invention is to realize that by following technical scheme the effective ingredient of secondary calcium phosphate suspension agent is a secondary calcium phosphate, it is characterized in that said preparation is the sticky shape white liquid of high density.Its component content is by percentage to the quality:
The former powder of secondary calcium phosphate: 20%-80%
Wetting agent: 1%-7%
Dispersion agent: 2%-10%
Frostproofer: 2%-6%
Defoamer: 0.2%-1.0%
Thickening material: 0.1%-0.8%
Thinner: 2.2%-76.7%
Wherein:
Wetting agent can be a kind of of sodium alkyl sulfate, sodium alkyl benzene sulfonate, alkylphenol polyoxyethylene formaldehyde condensation products, nonyl phenol ethoxy compound (10EO), styroyl phenol polyethenoxy ether condenses, alkylphosphonic acid carboxylic acid sodium, styroyl phenol polyethenoxy ether sodium sulfate and alkylphenol-polyethenoxy base sodium sulfate.
Dispersion agent can be how sodium sulfonate, sodium lignosulfonate, styroyl phenol polyethenoxy ether formaldehyde condensation products, sulfomethylated lignin acid amide, sodium alkyl naphthalene sulfonate formaldehyde condensation products, sulfonated lignin, fatty alcohol-ether phosphorylated ligand, nonyl phenol ether phosphate, polyoxyethylene polyoxypropylene block copolymer a kind of of fatty alcohol-ether Succinic Acid half ester sodium sulfonate, naphthalenesulfonic acid-formaldehyde condensate, nonyl phenolic ester Succinic Acid half ester sodium sulfonate, dialkyl group.
Frostproofer can be a kind of of ethylene glycol, propylene glycol, glycerol, polyoxyethylene glycol, ethylene glycol methyl ether.
Defoamer can be a kind of of methyl alcohol, ethanol, organosilicon, Virahol, sec-butyl alcohol, tributyl phosphate, trioctyl phosphate, phosphoric acid penta monooctyl ester, polypropylene glycol and derivative thereof, polyoxyethylene carboxylate, oleic acid.
Thickening material can be xanthan gum, methylcellulose gum, carboxymethyl cellulose Natvosol, anhydrous Succinic Acid-styrol copolymer, anhydrous Succinic Acid-isobutyl diene copolymers, a kind of.
Thinner is a water.
The preparation method of secondary calcium phosphate suspension agent:
Description of drawings
Accompanying drawing is preparation method's of the present invention process flow sheet.
Embodiment
Below the present invention will be described in more detail with the fertilizer agent embodiment:
Embodiment one
Take by weighing the former powder 60% of secondary calcium phosphate, wetting agent alkylphosphonic acid carboxylic acid sodium 6%, dispersion agent nonyl phenol ether phosphate 4%, sodium lignosulfonate 3%, frostproofer propylene glycol 4.1%, water 22%, above raw material is pressed general method mix, pour the high-shear homogenizer into and stir homogeneous phase, pour sand mill again into and carry out sand milling, sand milling adds thickening material xanthan gum 0.1% and defoamer tributyl phosphate 0.8% later again, obtains 60% secondary calcium phosphate suspension agent after fully stirring.Through check effective ingredient secondary calcium phosphate 59.8%, pH value 7.5, suspensibility 〉=90%, screening (by 70 μ m testing sieves) 〉=99%, mercury, arsenic, cadmium, lead, chromium harmful substance contents≤0.05%, topple over back residue≤3%, the residual spy in washing back≤0.05% quickens the heat storage and quickens cold storage qualified stability.Be used to prevent and treat apple calcium deficiency (water core, acne pinta) in actual applications, use at the calcium deficiency initial stage, carry out foliar spray with fertilizer 250-350mg/L (effective ingredient consumption), prevention effect is 85-95%.
Embodiment two
Take by weighing the former powder 51% of secondary calcium phosphate, wetting agent nonyl phenol ethoxy compound (10EO) 5%, dispersion agent styroyl phenol polyethenoxy ether formaldehyde condensation products 5%, sodium lignosulfonate 3%, frostproofer propylene glycol 5%, water 30%, above raw material is pressed general method to be mixed, pour the high-shear homogenizer into and stir homogeneous phase, pour sand mill again into and carry out sand milling, sand milling adds thickening material xanthan gum 0.3% and defoamer polyoxyethylene carboxylate 0.7% later again, obtains 50% secondary calcium phosphate suspension agent after fully stirring.Through check effective ingredient secondary calcium phosphate 50.2%, pH value 7.9, suspensibility 〉=95%, screening (by 75 μ m testing sieves) 〉=99.6%, mercury, arsenic, cadmium, lead, chromium harmful substance contents≤0.05%, topple over back residue≤3%, the residual spy in washing back≤0.05% quickens the heat storage and quickens cold storage qualified stability.Be used to prevent and treat Chinese cabbage calcium deficiency (Chinese cabbage dry combustion method worry) in actual applications, use at the calcium deficiency initial stage, carry out foliar spray with fertilizer 233-350mg/L (effective ingredient consumption), prevention effect is 80-90%.
Embodiment three
Take by weighing the former powder 51% of secondary calcium phosphate, wetting agent styroyl phenol polyethenoxy ether condenses 6%, dispersion agent nonyl phenol ether phosphate 8%, antifreeze glycol 5%, water 29.2% is pressed general method with above raw material and is mixed, pour the high-shear homogenizer into and stir homogeneous phase, pour sand mill again into and carry out sand milling, sand milling adds thickening material xanthan gum 0.3% and defoamer polyoxyethylene carboxylate 0.5% later again, obtains 50% secondary calcium phosphate suspension agent after fully stirring.Through check effective ingredient secondary calcium phosphate 50.1%, pH value 7.7, suspensibility 〉=92%, screening (by 75 μ m testing sieves) 〉=99.5%, mercury, arsenic, cadmium, lead, chromium harmful substance contents≤0.05%, topple over back residue≤2%, the residual spy in washing back≤0.05% quickens the heat storage and quickens cold storage qualified stability.Be used to prevent and treat tomato calcium deficiency (tomato blossom-end rot) in actual applications, use at the calcium deficiency initial stage, carry out foliar spray with fertilizer 233-350mg/L (effective ingredient consumption), prevention effect is 88-98%.
Embodiment four
Take by weighing the former powder 41% of secondary calcium phosphate, wetting agent nonyl phenol ethoxy compound (10EO) 6%, dispersion agent fatty alcohol-ether Succinic Acid half ester sodium sulfonate 4%, sodium lignosulfonate 3%, wood frostproofer polyoxyethylene glycol 3.5%, water 41%, above raw material is pressed general method to be mixed, pour the high-shear homogenizer into and stir homogeneous phase, pour sand mill again into and carry out sand milling, sand milling adds thickening material carboxymethyl cellulose Natvosol 0.8% and defoamer propylene glycol 0.7% later again, obtains 50% secondary calcium phosphate suspension agent after fully stirring.Through check effective ingredient secondary calcium phosphate 50.1%, pH value 7.8, suspensibility 〉=95%, screening (by 75 μ m testing sieves) 〉=99.5%, mercury, arsenic, cadmium, lead, chromium harmful substance contents≤0.05%, topple over back residue≤2%, the residual spy in washing back≤0.05% quickens the heat storage and quickens cold storage qualified stability.Be used to prevent and treat the eggplant calcium deficiency in actual applications, use at the calcium deficiency initial stage, carry out foliar spray with fertilizer 200-300mg/L (effective ingredient consumption), prevention effect is 85-90%.
Embodiment five
Take by weighing the former powder 30% of secondary calcium phosphate, wetting agent alkylphosphonic acid carboxylic acid sodium 7%, dispersion agent nonyl phenolic ester Succinic Acid half ester sodium sulfonate 8%, antifreeze glycol methyl ether 5%, water 49% is pressed general method with above raw material and is mixed, pour the high-shear homogenizer into and stir homogeneous phase, pour sand mill again into and carry out sand milling, sand milling adds thickening material methylcellulose gum 0.5% and defoamer organosilicon 0.5% later again, obtains 30% secondary calcium phosphate suspension agent after fully stirring.Through check effective ingredient secondary calcium phosphate 29.9%, pH value 7.9, suspensibility 〉=95%, screening (by 75 μ m testing sieves) 〉=99.5%, mercury, arsenic, cadmium, lead, chromium harmful substance contents≤0.05%, topple over back residue≤1%, the residual spy in washing back≤0.05% quickens the heat storage and quickens cold storage qualified stability.Be used to prevent and treat the capsicum calcium deficiency in actual applications, use at the calcium deficiency initial stage, carry out foliar spray with fertilizer 200-300mg/L (effective ingredient consumption), prevention effect is 85-92%.
The secondary calcium phosphate suspension agent that adopts prescription of the present invention to process the results showed that this fertilizer agent has good dispersiveness, suspensibility height, better stability of preparation; In process of the test, the fertilizer agent tackiness is good, onset is rapid.Prove through field test that in production application effect calcium deficiency such as apple, tomato, grape, Chinese cabbage, capsicum, cucumber, Radix Dauci Sativae are had good result of treatment, prevention effect can reach 85-95%, and security is good, and crop is had no adverse effects.
Claims (7)
1, a kind of secondary calcium phosphate suspension agent, its effective ingredient is a secondary calcium phosphate, it is characterized in that this suspension agent is the sticky shape of high density.Its component content is as follows by percentage to the quality:
The former powder of secondary calcium phosphate: 20%-80%
Wetting agent: 1%-7%
Dispersion agent: 2%-10%
Frostproofer: 2%-6%
Defoamer: 0.2%-1.0%
Thickening material: 0.1%-0.8%
Thinner: 2.2%-76.7%
2, the secondary calcium phosphate suspension agent described in the claim 1, it is characterized in that wherein wetting agent can be a kind of of sodium alkyl sulfate, sodium alkyl benzene sulfonate, alkylphenol polyoxyethylene formaldehyde condensation products, nonyl phenol ethoxy compound (10EO), styroyl phenol polyethenoxy ether condenses, alkylphosphonic acid carboxylic acid sodium, styroyl phenol polyethenoxy ether sodium sulfate and alkylphenol-polyethenoxy base sodium sulfate.
3, the secondary calcium phosphate suspension agent described in the claim 1, it is characterized in that wherein dispersion agent can be how sodium sulfonate, sodium lignosulfonate, styroyl phenol polyethenoxy ether formaldehyde condensation products, sulfomethylated lignin acid amide, sodium alkyl naphthalene sulfonate formaldehyde condensation products, sulfonated lignin, fatty alcohol-ether phosphorylated ligand, nonyl phenol ether phosphate, polyoxyethylene polyoxypropylene block copolymer a kind of of fatty alcohol-ether Succinic Acid half ester sodium sulfonate, naphthalenesulfonic acid-formaldehyde condensate, nonyl phenolic ester Succinic Acid half ester sodium sulfonate, dialkyl group.
4, the secondary calcium phosphate suspension agent described in the claim 1 is characterized in that, wherein frostproofer can be a kind of of ethylene glycol, propylene glycol, glycerol, polyoxyethylene glycol, ethylene glycol methyl ether.
5, the secondary calcium phosphate suspension agent described in the claim 1, it is characterized in that wherein defoamer can be a kind of of methyl alcohol, ethanol, organosilicon, Virahol, phosphoric acid penta monooctyl ester, sec-butyl alcohol, tributyl phosphate, trioctyl phosphate, polypropylene glycol and derivative thereof, polyoxyethylene carboxylate, oleic acid.
6, the secondary calcium phosphate suspension agent described in the claim 1, it is characterized in that wherein thickening material can be a kind of of anhydrous Succinic Acid-isobutyl diene copolymers, xanthan gum, anhydrous Succinic Acid-styrol copolymer, methylcellulose gum, carboxymethyl cellulose Natvosol, polyvinyl acetate.
7, the secondary calcium phosphate suspension agent described in the claim 1 is characterized in that, wherein thinner is a water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101085251A CN101302129B (en) | 2008-05-22 | 2008-05-22 | Calcium hydrophosphate suspending agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101085251A CN101302129B (en) | 2008-05-22 | 2008-05-22 | Calcium hydrophosphate suspending agent |
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| CN101302129A true CN101302129A (en) | 2008-11-12 |
| CN101302129B CN101302129B (en) | 2011-11-30 |
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| CN2008101085251A Active CN101302129B (en) | 2008-05-22 | 2008-05-22 | Calcium hydrophosphate suspending agent |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102173940A (en) * | 2011-02-02 | 2011-09-07 | 安徽国祯生物质发电有限责任公司 | Carbon black as anticaking agent of compound fertilizer and production process of carbon black |
| CN102584385A (en) * | 2012-01-11 | 2012-07-18 | 深圳中航资源有限公司 | Preparation method of anti-aging, long-acting and multifunctional phosphate fertilizer |
| CN103304297A (en) * | 2013-05-29 | 2013-09-18 | 深圳市芭田生态工程股份有限公司 | Water-soluble silicon fertilizer |
| CN104163708A (en) * | 2014-08-01 | 2014-11-26 | 成都新柯力化工科技有限公司 | Water-soluble compound fertilizer suspension agent and preparation method and application thereof |
| CN105085049A (en) * | 2015-08-17 | 2015-11-25 | 北京沃土天地生物科技有限公司 | High-nitrogen suspension-type liquid fertilizer and preparation method thereof |
| CN105645367A (en) * | 2015-12-26 | 2016-06-08 | 华润赛科药业有限责任公司 | Treatment mode of calcium hydrogen phosphate used as amlodipine besylate-containing medicinal preparation auxiliary material |
| CN106220310A (en) * | 2016-07-13 | 2016-12-14 | 汝南禾尓丰流体肥业有限公司 | Water soluble composite fertilizer calcium boron suspending agent and preparation method thereof |
| CN110436988A (en) * | 2019-06-27 | 2019-11-12 | 广西壮族自治区林业科学研究院 | A kind of bacteria fermentation type high phosphorus masson pine fertilizer, preparation method and its application method |
| CN113896592A (en) * | 2021-09-30 | 2022-01-07 | 东莞一翔液体肥料有限公司 | Liquid calcium fertilizer and preparation method and application thereof |
| CN115959944A (en) * | 2023-01-13 | 2023-04-14 | 天津市汉邦植物保护剂有限责任公司 | Calcium phytate suspension fertilizer and preparation method thereof |
Family Cites Families (3)
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| CN1039309C (en) * | 1992-11-30 | 1998-07-29 | 山东大学 | High-effect compound plant promoting agent and preparing process |
| CN1064330C (en) * | 1997-11-20 | 2001-04-11 | 张晓宇 | Method for leaching phosphate from low-grade powdered rock phosphate |
| CN1215011C (en) * | 2003-01-10 | 2005-08-17 | 宋才富 | Treating method of phosphogypsum |
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2008
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102173940A (en) * | 2011-02-02 | 2011-09-07 | 安徽国祯生物质发电有限责任公司 | Carbon black as anticaking agent of compound fertilizer and production process of carbon black |
| CN102584385A (en) * | 2012-01-11 | 2012-07-18 | 深圳中航资源有限公司 | Preparation method of anti-aging, long-acting and multifunctional phosphate fertilizer |
| CN102584385B (en) * | 2012-01-11 | 2015-10-28 | 中航化肥有限公司 | A kind of preparation method of anti-aging long acting multifunction phosphate fertilizer |
| CN103304297A (en) * | 2013-05-29 | 2013-09-18 | 深圳市芭田生态工程股份有限公司 | Water-soluble silicon fertilizer |
| CN103304297B (en) * | 2013-05-29 | 2015-05-13 | 深圳市芭田生态工程股份有限公司 | Water-soluble silicon fertilizer |
| CN104163708A (en) * | 2014-08-01 | 2014-11-26 | 成都新柯力化工科技有限公司 | Water-soluble compound fertilizer suspension agent and preparation method and application thereof |
| CN105085049A (en) * | 2015-08-17 | 2015-11-25 | 北京沃土天地生物科技有限公司 | High-nitrogen suspension-type liquid fertilizer and preparation method thereof |
| CN105645367A (en) * | 2015-12-26 | 2016-06-08 | 华润赛科药业有限责任公司 | Treatment mode of calcium hydrogen phosphate used as amlodipine besylate-containing medicinal preparation auxiliary material |
| CN105645367B (en) * | 2015-12-26 | 2018-01-26 | 华润赛科药业有限责任公司 | Processing mode as the calcium monohydrogen phosphate of the pharmaceutical preparation auxiliary material containing Amlodipine Besylate Tablet |
| CN106220310A (en) * | 2016-07-13 | 2016-12-14 | 汝南禾尓丰流体肥业有限公司 | Water soluble composite fertilizer calcium boron suspending agent and preparation method thereof |
| CN110436988A (en) * | 2019-06-27 | 2019-11-12 | 广西壮族自治区林业科学研究院 | A kind of bacteria fermentation type high phosphorus masson pine fertilizer, preparation method and its application method |
| CN113896592A (en) * | 2021-09-30 | 2022-01-07 | 东莞一翔液体肥料有限公司 | Liquid calcium fertilizer and preparation method and application thereof |
| CN115959944A (en) * | 2023-01-13 | 2023-04-14 | 天津市汉邦植物保护剂有限责任公司 | Calcium phytate suspension fertilizer and preparation method thereof |
| CN115959944B (en) * | 2023-01-13 | 2024-02-13 | 天津市汉邦植物保护剂有限责任公司 | Calcium phytate suspension fertilizer and preparation method thereof |
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| CN101302129B (en) | 2011-11-30 |
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Assignee: Zhonggang Taifu (Beijing) Hi-Tech Co., Ltd. Assignor: Dongguan Shipuwang Biological Technology Co., Ltd. Contract record no.: 2012110000006 Denomination of invention: Calcium hydrophosphate suspending agent Granted publication date: 20111130 License type: Exclusive License Open date: 20081112 Record date: 20120116 |