CN101294351A - Fibre grey cloth, manufacturing method and fibre grey cloth with lapping cloth forming by bonding lapping cloth on the fibre grey cloth - Google Patents
Fibre grey cloth, manufacturing method and fibre grey cloth with lapping cloth forming by bonding lapping cloth on the fibre grey cloth Download PDFInfo
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- CN101294351A CN101294351A CNA2008100879899A CN200810087989A CN101294351A CN 101294351 A CN101294351 A CN 101294351A CN A2008100879899 A CNA2008100879899 A CN A2008100879899A CN 200810087989 A CN200810087989 A CN 200810087989A CN 101294351 A CN101294351 A CN 101294351A
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Abstract
The invention provides fiber grey cloth attached with given medicine and which is easy to fall off the perspiration and other dirt, has little effusion of the bond, has good contractibility to commercial washing, and has good bonding strength to lapping cloth using common bond, especially the polypropylene bond, a preparing method and the fiber grey cloth stuck with lapping cloth formed by bonding the lapping cloth on the fiber grey cloth. The solving method adopted by the invention is to use a fiber grey cloth attached with medicine having high bonding strength to the lapping cloth; the invention is characterized by attaching a medicine on the fiber grey cloth for bonding the lapping cloth by the bond; the medicine comprises polymer the same with the main component polymer of the bond.
Description
Technical field
The present invention relates to the fiber grey cloth good to the adhesion durability of lining cloth, specifically, relate to particularly when using the polypropylene type adhesive fiber grey cloth that adheres to particular agent that adhesive strength is good, its manufacture method and bonding lining cloth and the fiber grey cloth of the belt material cloth that forms on this medicament attachment fiber grey cloth as the adhesive of bonding lining cloth.
Background technology
In the past, when clothes is pasted lining cloth on grey cloth,, it was had wearing, use and wash to a certain degree durability repeatedly by using adhesive.For example,, use a kind of permanent adhesive lining cloth (topfuse), wash the non-water-soluble resin that also can not come off as adhesive even wherein adopt for neck sheet and cuff.At present, the adhesive of permanent adhesive lining cloth polyethylene kind adhesive normally.
Under the situation of lining cloth one lateral load adhesive, on by the fiber grey cloth of a bonding side, do not apply bonding composition usually.Otherwise, under the situation of fiber grey cloth one lateral load adhesive, on lining cloth, do not apply adhesive.In this case, the method that makes load adhesive on fiber grey cloth heat molten type bonding way normally.As the method for load adhesive, powder point (powderdot) mode and sinter (sinter) mode etc. are arranged.
Usually the polyethylene kind adhesive and the fiber that are widely used have good bonding force, but when applying by the heat molten type bonding way, the polyethylene of fusing usually can ooze out from the face side of shirt, thus sweat stain adhere to by force, or introduce greasy dirt sometimes.In addition, when the user used, because repeated home washing and commercial laundering, flatiron, this polyethylene can be penetrated into the face side of shirt equally, thereby causes sweat stain and greasy dirt.
Recently, people have developed with polyethylene kind and have compared, dirts such as sweat stain are easier to come off, adhesive lessly oozes out, the polypropylene type adhesive good to the anti-shrinkage of commercial laundering, and is used to various aspects, also is used in the permanent adhesive lining cloth (topfuse) of shirt.But polypropylene is higher about 10 ℃ than poly fusing point.Therefore, though have the less advantage of oozing out that causes by washing and pressing, polypropylene is lower than polyethylene on adhesive strength, instability.For the permanent adhesive lining cloth (topfuse) of shirt, compare with the lining cloth that uses the polyethylene kind adhesive, use the lining cloth of polypropylene type adhesive to exist the problem of peeling off that is easy to generate.Depend on kinds of fibers, exist not reach and to stand to wear and the problem of the peel strength of washing level.In addition,, therefore also have following inconvenience because bonding force changes with kinds of fibers, that is, need to investigate in advance with the cementability of bonding fiber.
As the means that address these problems, proposed to attempt adhesive is improved the method (patent documentation 3) of using the method (patent documentation 1) that contains the resinoid adhesive of ethene unsaturated silane compound modified olefin, the method (patent documentation 2) of using the polypropylene type adhesive of carbonyl modification, the multipolymer that will constitute by ethene, free-radical polymerised acid anhydrides and free-radical polymerised comonomer in addition and fusing point to use altogether at the polyolefin type resin layer more than 100 ℃.
But the method for these prior aries is that the adhesive that uses is carried out improved method, does not propose under the situation of using general purpose adhesive still effective method.In addition, there is not proposition to have the adhesive of the material of polyethylene kind and polypropylene type strong point concurrently yet.
No. 3885466 communique of [patent documentation 1] Japan Patent
No. 3580700 communique of [patent documentation 2] Japan Patent
No. 3098594 communique of [patent documentation 3] Japan Patent
Summary of the invention
The present invention makes in view of the above problems, purpose provides that dirts such as sweat stain come off easily, the oozing out less of adhesive, good to the anti-shrinkage of commercial laundering, to using general purpose adhesive, the fiber grey cloth that has adhered to particular agent that particularly adhesive strength of the lining cloth of polypropylene type adhesive is good, its manufacture method and adhere to bonding lining cloth on the fiber grey cloth of medicament and the fiber grey cloth of the belt material cloth that forms at this.
The inventor finds, by on the fiber grey cloth of wanting bonding lining cloth, applying medicament, even also can obtain good cementability for the bonding of lining cloth of using general purpose adhesive, the identical polymer of principal component polymer kind of the adhesive that described medicament uses when containing with bonding lining cloth on bad cloth of fiber, thus the present invention finished.
The present invention relates to substantially and has the fiber grey cloth that adheres to medicament, its manufacture method of high-adhesive-strength with lining cloth and bonding lining cloth and the fiber grey cloth of the belt material cloth that forms on this fiber grey cloth, the described fiber grey cloth that adheres to medicament is characterised in that and adheres to a kind of medicament that on the fiber grey cloth this medicament contains the polymer identical with the principal component polymer kind of bonding agent for adhesive cloths basically.The present invention serves as that the basis constitutes with following various technology.
(1) has the fiber grey cloth that adheres to medicament of high-adhesive-strength with lining cloth, it is characterized in that adhere to medicament on the fiber grey cloth with the bonding lining cloth of adhesive, described medicament contains the polymer identical with the principal component polymer kind of this adhesive.
(2) the fiber grey cloth that adheres to medicament described in (1), wherein, the polymer of above-mentioned adhesive and medicament is selected from a kind of in polyolefin polymers, polyamide polymers, polyester polymer, poly chlorine polyvinyl, ethylene-vinyl acetate copolymer base polymer, polyurethane polymer, acrylic polymer, styrenic polymer and the natural rubber base polymer.
(3) the fiber grey cloth that adheres to medicament described in (2) is characterized in that above-mentioned adhesive is the polypropylene type adhesive, and above-mentioned medicament is the polypropylene type medicament.
(4) the fiber grey cloth that adheres to medicament described in (3) is characterized in that the polypropylene type medicament forms polymer emulsification in water, the dispersion with its chlorinated polypropylene base polymer skeleton.
(5) each described fiber grey cloth that adheres to medicament in (1)～(4), wherein, above-mentioned fiber grey cloth and lining cloth are to be made of cotton/polyester blended silk.
(6) the fiber grey cloth of belt material cloth is characterized in that lining cloth is bonded in (1)～(5) on each described fiber grey cloth that adheres to medicament.
(7) the fiber grey cloth of the belt material cloth described in (6), it is shirt cloth, shoulder pad, upper garment, underpants, skirt, cap or bag.
(8) has the manufacture method of the fiber grey cloth that adheres to medicament of high-adhesive-strength with lining cloth, it is characterized in that, will adhere to medicament on the fiber grey cloth with the bonding lining cloth of adhesive by rolling the baking method, described medicament contains the polymer identical with the principal component polymer kind of this adhesive.
(9) manufacture method described in (8) is characterized in that above-mentioned medicament is added in resin finishing liquid or the softening working fluid, rolls baking.
According to the present invention, can provide that dirt such as sweat stain comes off easily, the oozing out less of adhesive, good to the anti-shrinkage of commercial laundering, to the bad cloth of fiber that applied particular agent, particularly used the good fiber grey cloth that has adhered to medicament of the polypropylene type adhesive and durable cementability lining cloth and on this fiber grey cloth bonding lining cloth and the fiber grey cloth of the belt material cloth that forms.
In addition, owing to can carry out in the operation identical with fiber process operations such as in the past resin finishing and softening processing in the means that apply medicament on the fiber grey cloth, fiber process factory does not need new equipment investment.
The specific embodiment
Below of the present invention and lining cloth are had the fiber grey cloth that adheres to medicament, its manufacture method of high-adhesive-strength and bonding lining cloth and the fiber grey cloth of the belt material cloth that forms is specifically described on this fiber grey cloth.
Herein, in the present invention, the fiber grey cloth is meant the grey cloth of wanting bonding lining cloth, does not adhere to the medicament that contains the polymer identical with the principal component polymer kind of the adhesive that uses, and can also adhere to the crosslinking agent that uses in the common fiber treatment and softening agent etc. on this fiber grey cloth.Make adhere to the medicament that contains the polymer identical on this fiber grey cloth with the principal component polymer kind of adhesive after, formed material is called as the fiber grey cloth that adheres to medicament, not bonding lining cloth on it.The fiber grey cloth that is called as belt material cloth here, behind the bonding lining cloth.
As fiber grey cloth of the present invention, can will use the fiber grey cloth of lining cloth and fibre integral body as object.Representational is shirt cloth (collar, cuff etc.), but the material of a relative side (fiber grey cloth) of the bonding lining cloth of clothes accessories such as shoulder pad, the upper garment that comprises coats such as western-style clothes, trousers, skirt, cap, bag class etc. is so long as can carry out the fiber grey cloth of chemicals treatment form and can both be suitable for.
Material as fiber grey cloth of the present invention, can enumerate native cellulose fibres such as cotton, fiber crops, regenerated celulose fibres such as viscose rayon, copper rayon (ammonia copper wire), day silk (テ Application セ Le), Pori's nosik, semi-regenerated fibre cellulose fibers such as acetate fiber.In addition, as synthetic fiber, can enumerate general synthetic fiber such as polyester fiber, polyamide-based fiber.In addition, also can be the blend fibre of these cellulose fiber peacekeeping synthetic fiber.For example, under the situation with the blending of cellulosic fibre such as cotton and polyester, the ratio of polyester is for containing more than the 20 quality %, and particularly 35 quality % are above is preferred for obtaining effect of the present invention, and polyester also can be 100 quality %.
The lining cloth that uses among the present invention has no particular limits, and can use lining cloth such as textiles, braided fabric, nonwoven fabric.As the fiber that constitutes these lining cloth, can enumerate and the identical fiber of fiber that describes at above-mentioned fiber grey cloth.Lining cloth knit that marshalling is knitted, thickness, hardness etc. can suitably be selected according to use, for employed lining cloth,, suitably select to get final product corresponding to the fiber grey cloth of bonding lining cloth as long as consider the use position of fiber grey cloth, necessary feel etc.
The adhesive that uses during as bonding lining cloth on the fiber grey cloth has no particular limits, and can use known in the past material.For example, can enumerate with polyolefin polymers such as polyethylene kind, polypropylene type, polyamide polymers, polyester polymer, poly chlorine polyvinyl, ethylene-vinyl acetate copolymer base polymer, polyurethane polymer, acrylic polymer, styrenic polymer, polymer such as natural rubber base polymer are the adhesive of principal component.In the adhesive of Shi Yonging, preferably contain the above above-mentioned polymer of 50 quality % in the present invention, also can contain the above-mentioned polymer about 100 quality %.
As the adhesive that uses among the present invention,, with the polypropylene based polymers polypropylene type adhesive of principal component especially again wherein particularly for polyolefin polymers, the present invention improves the effective of cementability, can preferably use.As this polypropylene type adhesive, can use the commercial goods, for example Off ロ-プ レ Application (Sumitomo refine (strain) system).
In the present invention, the medicament that adheres on the fiber grey cloth is to contain and the bonding medicament with the identical polymer of the principal component polymer kind of adhesive of lining cloth.In this case, the main chain of the polymer of preferred agents and the polymer phase of adhesive are same, but also can be its modifier or derivative.
Solvent as the medicament that uses among the present invention, can use ad lib, so long as can being used as the solvent of the solvent of common fiber with medicament, water, ethanol, methyl alcohol, acetone, isopropyl alcohol etc. gets final product, in medicament, preferably contain above-mentioned polymer 10～70 quality %, particularly 20～40 quality %.In addition, in addition, can also contain compositions such as emulsifying agent and stabilizing agent.
At adhesive is under the situation of polypropylene type adhesive, uses the polypropylene type medicament.The polypropylene type pharmacy optimization uses the polymer emulsification in water will have the polypropylene based polymers skeleton, dispersion and the medicament that forms.In the polypropylene type medicament, its chlorinated polypropylene paraffin emulsifier ((about 145 ℃ of softening points), eastern nation chemical industry (strain) Ha イ テ Star Network P-5300) is for example arranged.
Manufacture method to the fiber grey cloth of fiber grey cloth that adheres to medicament of the present invention and belt material cloth describes.
At first, the method that medicament is attached on the fiber grey cloth can be any method, as long as can apply this medicament on the fiber grey cloth, can adopt and roll known method such as method in baking method, rubbing method, spraying process, the bath.Wherein, from the viewpoint of operability and good economy performance, the preferred especially baking method of rolling of using.
As rolling the baking method, preferably with 40～100%, particularly 50～80% pick-up (pick up) adheres to above-mentioned medicament on the fiber grey cloth, and preferably at 60～170 ℃, particularly 80～150 ℃ were descended particularly 30～180 seconds dry 20～300 seconds.
Medicament also can be to carry out resin finishing with general fiber process and softening to add and soak medicament man-hour, processing.Therefore, productivity is good, just can obtain to improve the effect of cementability with small amounts of medicament.In addition because and fiber process be same operation, therefore do not need the investment of new equipment.
In this case, in resin finishing liquid and soft working fluid, adding above-mentioned medicament, making when adhering to resin, softener on the fiber grey cloth, also adhering to medicament by the above-mentioned baking method of rolling.As the interpolation concentration of medicament, the ratio of medicament is 0.5～10 quality % in the preferred soak, more preferably 1～5 quality %.
The fiber process that applies the medicament operation that comprises of the present invention can be carried out according to the mode of for example bleaching process → mercerising manufacturing procedure → resin finishing (adding medicament of the present invention in soak) operation.
Adhering in this manner on the fiber grey cloth of medicament,, making the fiber grey cloth of belt material cloth with the bonding lining cloth of adhesive.Adhesive can be applied on the fiber grey cloth and either party or two sides in the lining cloth that adheres to medicament, considers from convenience, cost aspect, preferably is applied on the lining cloth.In addition, can be point-like, wire, planar etc. with adhesive coated according to use.Can select coating processes such as rubbing method and spraying process according to the proterties (that is, be solid or liquid, the viscosity height is also low etc.) and the operability of adhesive.
Then, the fiber grey cloth and the lining cloth that will adhere to medicament are superimposed, use roll shape, garment press such as plate to carry out heating and pressurizing, make the fiber grey cloth and the lining cloth that adhere to medicament bonding.Heating-up temperature and pressure also depend on the kind of fiber and adhesive, but preferably at 120～200 ℃, especially preferably under 140～180 ℃, apply 1～5kgf/cm
2, 1.5～4kgf/cm especially preferably
2Pressure, suppressed especially preferably 5～30 seconds 5～60 seconds.
Embodiment
The present invention will be described below to enumerate embodiment and comparative example, but the present invention is not limited to these embodiment, can change this embodiment in the scope that does not break away from purport of the present invention.
In embodiments of the invention and comparative example, based on grey cloth, resin finishing agent, catalyst, medicament, the processing method of table 1, allocate resin finishing agent (A) 15 quality %, catalyst (B) 3 quality % into, medicament 3 quality % handle.
＜embodiment 1 〉
The shirt cloth (destarch that process is common at table 1, concise, bleaching, grey cloth after the mercerising processing) on, be used in resin finishing agent A (ペ Star カ ミ Application LF-55P コ Application Network, Dainippon Ink and Chemicals, Inc's system, glyoxal (グ リ オ キ ザ-Le) resinoid) 15 quality %, catalyst B (カ リ ス ト GT-3, Dainippon Ink and Chemicals, Inc's system, the metal species catalyst) added polypropylene type medicament a (the Ha イ テ Star Network P-5300 of 3 quality % in the conventional resin formula liquid of 3 quality %, Dong Bang KCC system) treatment fluid (aqueous solution) that forms pads (padding) (pick-up 70%), dry (120 ℃ * 1 minute), heat-treat (160 ℃ * 2 minutes), the shirt cloth that obtains improveing.
Should illustrate that pick-up is calculated as follows.
Pick-up=[(handling the weight of back object)-(weight of object before handling)]/(weight of object before handling) * 100
Table 1
＜comparative example 1 〉
Shirt cloth with above-mentioned conventional resin formula liquid his-and-hers watches 1 carries out same processing, with the cloth that obtains as shirt cloth usually.
＜comparative example 2 〉
Be used in polyethylene kind medicament b (the Off ア イ Application テ Star Network ス PE140E that adds 3 quality % in the above-mentioned conventional resin formula liquid, Dainippon Ink and Chemicals, Inc's system) the shirt cloth of the treatment fluid his-and-hers watches 1 that form carries out same processing, with the cloth that obtains shirt cloth 1 as a comparison.
＜comparative example 3 〉
Be used in polyurethanes medicament c (the エ バ Off エ ノ-Le N-7 that adds 3 quality % in the above-mentioned conventional resin formula liquid, Nicca Chemical Co., Ltd's system) the shirt cloth of the treatment fluid his-and-hers watches 1 that form carries out same processing, with the cloth that obtains shirt cloth 2 as a comparison.
＜comparative example 4 〉
Be used in the above-mentioned conventional resin formula liquid polyesters medicament d (パ-マ リ Application MR100, Sanyo change into the industry system) that adds 3 quality % and the shirt cloth of the treatment fluid his-and-hers watches 1 that form carries out same processing, with the cloth that obtains shirt cloth 3 as a comparison.
＜evaluation test: peel strength JIS L1089 〉
On the cloth that forms polyester/cotton 65/35 (quality %) [23/2 * 23/2/ (mariages of 23 monofilament)/through 51 * latitude 55 (root/inch)] being carried out common destarch, concise, bleaching, stiffening processing, coating is as the polypropylene type adhesive (trade name: Off ロ-Block レ Application of bonding agent, the Sumitomo society's system of refining), form bonding lining cloth.
At 170 ℃ * 2.5kgf/cm
2Under * 15 seconds the condition this lining cloth and each shirt cloth are suppressed bondingly, measured peel strength.Measurement result is shown in table 2.
Table 2
As shown in Table 2, the fiber grey cloth that adheres to medicament that the present invention relates to (the shirt cloth of improvement) has good than goods peel strength frequently.
Can confirm from this result,,, also can obtain good peel strength even then under the situation of using suitable conventional adhesive if adopt the fiber grey cloth that has applied medicament of the present invention.
According to the present invention, can provide the adhesive that dirt such as sweat stain comes off easily, commercial pressurization causes ooze out less, to the good fiber grey cloth that adheres to medicament of the anti-shrinkage of commercial laundering and the fiber grey cloth of belt material cloth.In addition, can also use adhesive, particularly the polypropylene type adhesive is as many-sided adhesive.
At the adhesive that does not use special structure, and the use general purpose adhesive, particularly the polypropylene type adhesive is bonding with under the situation of adhesive as lining cloth, can obtain having the fiber grey cloth that adheres to medicament of high-adhesive-strength and the fiber grey cloth of belt material cloth, from this point, be very useful invention in practice.
In addition, owing to can in the operation identical, apply medicament,, be very useful invention so fiber process factory does not need the investment of new equipment etc. to the fiber grey cloth with operations such as resin finishing and softening processing.
Claims (9)
1, has the fiber grey cloth that adheres to medicament of high-adhesive-strength with lining cloth, it is characterized in that adhere to medicament on the fiber grey cloth with the bonding lining cloth of adhesive, described medicament contains the polymer identical with the principal component polymer kind of this adhesive.
2, the described fiber grey cloth that adheres to medicament of claim 1, wherein, the polymer of above-mentioned adhesive and medicament is selected from a kind of in polyolefin polymers, polyamide polymers, polyester polymer, poly chlorine polyvinyl, ethylene-vinyl acetate copolymer base polymer, polyurethane polymer, acrylic polymer, styrenic polymer and the natural rubber base polymer.
3, the described fiber grey cloth that adheres to medicament of claim 2 is characterized in that above-mentioned adhesive is the polypropylene type adhesive, and above-mentioned medicament is the polypropylene type medicament.
4, the described fiber grey cloth that adheres to medicament of claim 3 is characterized in that, the polypropylene type medicament forms polymer emulsification in water, the dispersion with its chlorinated polypropylene base polymer skeleton.
5, each described fiber grey cloth that adheres to medicament in the claim 1～4, wherein, above-mentioned fiber grey cloth and lining cloth are to be made by cotton/polyester blended silk.
6, the fiber grey cloth of belt material cloth is characterized in that, lining cloth is bonded in the claim 1～5 on each described fiber grey cloth that adheres to medicament.
7, the fiber grey cloth of the described belt material cloth of claim 6, it is shirt cloth, shoulder pad, upper garment, trousers, skirt, cap or bag.
8, has the manufacture method of the fiber grey cloth that adheres to medicament of high-adhesive-strength with lining cloth, it is characterized in that, will adhere to medicament on the fiber grey cloth with the bonding lining cloth of adhesive by rolling the baking method, described medicament contains the polymer identical with the principal component polymer kind of this adhesive.
9, the described manufacture method of claim 8 is characterized in that above-mentioned medicament is added in resin finishing liquid or the softening working fluid, rolls baking.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007-090067 | 2007-03-30 | ||
| JP2007090067A JP2008248420A (en) | 2007-03-30 | 2007-03-30 | Textile product having high bonding strength to interlining cloth and method for producing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101294351A true CN101294351A (en) | 2008-10-29 |
Family
ID=39973696
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008100879899A Pending CN101294351A (en) | 2007-03-30 | 2008-03-28 | Fibre grey cloth, manufacturing method and fibre grey cloth with lapping cloth forming by bonding lapping cloth on the fibre grey cloth |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP2008248420A (en) |
| CN (1) | CN101294351A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104351989A (en) * | 2014-11-27 | 2015-02-18 | 湖南中医药大学 | Health-care scarf for neck muscle strain |
| CN104846500A (en) * | 2015-05-20 | 2015-08-19 | 浙江蓝天海纺织服饰科技有限公司 | Polyesteramide short fiber and cotton fiber blended yarn |
| CN109930393A (en) * | 2019-02-28 | 2019-06-25 | 宁波三同编织有限公司 | A kind of laying-in inlaid thread adhesive lining and preparation method thereof |
-
2007
- 2007-03-30 JP JP2007090067A patent/JP2008248420A/en not_active Withdrawn
-
2008
- 2008-03-28 CN CNA2008100879899A patent/CN101294351A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104351989A (en) * | 2014-11-27 | 2015-02-18 | 湖南中医药大学 | Health-care scarf for neck muscle strain |
| CN104846500A (en) * | 2015-05-20 | 2015-08-19 | 浙江蓝天海纺织服饰科技有限公司 | Polyesteramide short fiber and cotton fiber blended yarn |
| CN104846500B (en) * | 2015-05-20 | 2017-01-18 | 浙江蓝天海纺织服饰科技有限公司 | Polyesteramide short fiber and cotton fiber blended yarn |
| CN109930393A (en) * | 2019-02-28 | 2019-06-25 | 宁波三同编织有限公司 | A kind of laying-in inlaid thread adhesive lining and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2008248420A (en) | 2008-10-16 |
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Open date: 20081029 |