CN101254161B - Double-edged eyelid forming agent - Google Patents

Double-edged eyelid forming agent Download PDF

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Publication number
CN101254161B
CN101254161B CN200710139963XA CN200710139963A CN101254161B CN 101254161 B CN101254161 B CN 101254161B CN 200710139963X A CN200710139963X A CN 200710139963XA CN 200710139963 A CN200710139963 A CN 200710139963A CN 101254161 B CN101254161 B CN 101254161B
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synthetic resin
well
weight
resin emulsion
double
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CN101254161A (en
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本多美喜雄
堀井康信
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CHEMISTRY STUDY KINGDOM Co Ltd
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CHEMISTRY STUDY KINGDOM Co Ltd
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Abstract

The invention provides a double-fold eyelids formagen capable of surely forming doubl-fold eyelids for persons having tight upper eyelids, which comprises rubber latex, synthetic resin emulsion and alkanolamine, the w% (X) of the rubber latex, the w% (Y) of the synthetic resin emulsion and the w% (Z) of the alkanolamine are within a scope enclosed by a polygon formed by vetexes A to E in a composition diagram showing the w% (X, Y, Z) of three compositons, wherein A is (33.0,64.0,3.0), B is (49.0,48.0,3.0), C is (51.9,48.0,0.1), D is (34.9, 65.0, 0.1) and E is(33.0, 65.0, 2.0).

Description

Double-edged eyelid forming agent
Technical field
The present invention relates to by smearing in the lower edge portion of upper eyelid and make it dry, thereby can make upper eyelid become the double-edged eyelid forming agent of double eyelid.
Background technology
The inventor is willing to propose double-edged eyelid forming agent among the flat 1-3790 (spy opens flat 2-188512, special fair 6-62384) the spy.
This double-edged eyelid forming agent is with rubber latex, mixes with the synthetic resin that is selected from acrylic resin or polyurethane resin or vinyl resins, lower edge portion by spreading upon upper eyelid also makes it the dry inorganic agent that forms double eyelid, it is characterized in that mixing with following ratio: the synthetic resin that is selected from acrylic resin, polyurethane resin or vinyl resins of the above-mentioned rubber latex of 85～50 weight % and 15～50 weight %.
As the rubber latex that in this double-edged eyelid forming agent, uses, be no more than legal limit standard to human body and the deleterious material of environment, use for example LA latex of JIS K 6381 (total alkali content is below 0.8%).
In addition, the synthetic resin that in this double-edged eyelid forming agent, uses for the drying property of improving above-mentioned rubber latex, improve resistance to water, absorption of perspiration (anti-normal saline) and additional hardness as the dry coating rerum natura and add.
As such synthetic resin, can use with the intermiscibility of above-mentioned rubber latex good, minimum film formation temperature is below 20 ℃, and resistance to water, the resin that absorption of perspiration is good, for example can use solid constituent is vinyl resins such as the emulsion-type of 38～55 weight % commercially available acrylic resin, polyurethane resin or polrvinyl chloride, styrene resin, vinylacetate resin, but and without particular limitation.
When using this double-edged eyelid forming agent to form double eyelid,,, smear at the common 2mm of the lower edge portion of upper eyelid, and make its dry getting final product with interior width with hairbrush etc. as long as under the state of stretching upper eyelids such as closing one's eyes, look down.This drying can place under the room temperature, perhaps also can suitably heat to shorten drying time.
Thus obtained filming has hardness and caoutchouc elasticity, when shrinking upper eyelid because of opening eyes, do not smear the part of inorganic agent and shrinks, and do not shrink but film, and therefore forms folding line in the upper end of filming, and forms double eyelid.
Smear this double-edged eyelid forming agent and filming in daily life of forming must difficult drop-off, do not produce senses of discomfort such as pulling, have firm to eyelid adhibit quality and can be with the caoutchouc elasticity of the flexible appropriateness of eyelid, and, form and the maintenance double eyelid for stablizing, it is harder than eyelid, and not flexible.
Demonstrating as above, the concrete physics value of filming of character is preferably: percentage elongation 300～500% is 100～150 based on the hardness of JISK 6301 methods.Filming of physics value can't form and keep stable double eyelid beyond having this scope.
For example, only have filming of hardness, can't follow skin owing to the flexible of skins such as nictation and cause and come off, or allow user produce senses of discomfort such as pulling.
In addition, only demonstrate soft caoutchouc elasticity filming, for example under the situation that inorganic agent only is made of rubber latex, no matter natural rubber or synthetic rubber, because its (based on JIS K's 6301) hardness all is no more than 20～100, so the hardness deficiency, even under the state of opening eyes, film and to extend with skin, thereby can't form double eyelid.
In addition, the thickness that this double-edged eyelid forming agent is smeared is thick more, and user just can produce sense of discomfort more, simultaneously, not obvious for the difference in height that causes after formation is filmed, need extraization heavy make-up, though therefore the thickness of smearing is different because of the pliability of user eyelid, is preferably 50～5 μ.
As mentioned above, it is preferably thin as much as possible to film, especially inferior in the harder situation of the eyelid of user, substantially there is not difference between the hardness of eyelid and the hardness of filming, be difficult to form double eyelid, therefore can assist the eyelid that uses the thinner parts extrusion film upper end of end, thereby form double eyelid.
In addition, if frequent or this double-edged eyelid forming agent of life-time service even under the state of not smearing inorganic agent, also can continue to form folding line, the double eyelid that can keep nature.Therefore, this double-edged eyelid forming agent also can be used as simple and safe beauty treatment manufacturing process.
Yet, though this double-edged eyelid forming agent so has the characteristic of various excellences, but for example under the too tight people's of the skin that compares youth and eyelid situation, even smear this double-edged eyelid forming agent and make its drying in the lower edge portion of upper eyelid sometimes, also be difficult to form double eyelid, so people expect to have a kind of double-edged eyelid forming agent that can form double eyelid really.
Patent documentation 1: special fair 6-62384 communique
Summary of the invention
The problem that the present invention will solve
The present invention will solve is that the too tight people of skin of upper eyelid is difficult to form this problem of double eyelid.
Be used to solve the method for problem
The present invention is topmost to be characterised in that, the people too tight for the skin that makes upper eyelid also can form double eyelid really, increased the ratio of synthetic resin emulsion.
Specifically, the invention is characterized in, comprise rubber latex, synthetic resin emulsion and alkanolamine, the weight % (Y) of the weight % of this rubber latex (X), synthetic resin emulsion and the weight % (Z) of alkanolamine in the composition diagram of 3 kinds of compositions of the weight % (X, Y, Z) of these 3 kinds of compositions of expression are in polygon that the summit the constitutes scope of being surrounded with A～E each point, wherein
A(33.0，64.0，3.0)
B(49.0，48.0，3.0)
C(51.9，48.0，0.1)
D(34.9，65.0，0.1)
E(33.0，65.0，2.0)
Preferable feature of the present invention is, comprise rubber latex, synthetic resin emulsion and alkanolamine, the weight % (Y) of weight % of this rubber latex (X) and synthetic resin emulsion and the weight % (Z) of alkanolamine in the composition diagram of 3 kinds of compositions of the weight % (X, Y, Z) of these 3 kinds of compositions of expression are in polygon that the summit the constitutes scope of being surrounded with F～J each point, wherein
F(37.0，61.0，2.0)
G(49.0，49.0，2.0)
H(50.9，49.0，0.1)
I(37.9，62.0，0.1)
J(37.0，62.0，1.0)
As the rubber latex that uses in this double-edged eyelid forming agent, be the material that is no more than the legal limit standard of human body and the deleterious material of environment, can use for example LA latex of JIS K 6381 (total alkali content is below 0.8%).
In addition, the synthetic resin that in this double-edged eyelid forming agent, uses for the drying property of improving above-mentioned rubber latex, improve resistance to water, absorption of perspiration (anti-normal saline) and additional hardness as the dry coating rerum natura and add.As such synthetic resin, can use with the intermiscibility of above-mentioned rubber latex is good, minimum film formation temperature is below 20 ℃ and resistance to water, resin that absorption of perspiration is good, for example can use solid constituent is the emulsion-type synthetic resin of 38～55 weight %.
As above-mentioned synthetic resin emulsion, can list for example acrylate resin emulsion, methacrylate resin emulsion, styrene resin fat liquor, styrene acrylic copolymer resins emulsion, styrene methacrylic acid copolymer resins emulsion, acrylamide copolymer resins emulsion, vinyl acetate modified copolymer resins emulsion, vinyl acetate copolymerized resin emulsion, vinylacetate acrylic copolymeric resin emulsion, acrylic acid polrvinyl chloride copolymer resins emulsion, ethylene vinyl acetate medium copolymer resins emulsion.
In addition, the synthetic resin molecular weight of above-mentioned synthetic resin emulsion is different because of the kind of synthetic resin, preferably in 300,000～2,000,000 scope.If this is because the molecular weight less than 300,000 of synthetic resin, the elasticity of then filming reduces, and if molecular weight surpasses 2,000,000, then the viscosity of double-edged eyelid forming agent is too high, is difficult to smear on eyelid.
As above-mentioned alkanolamine, can list monoethanolamine, diethanolamine, triethanolamine, single Propanolamine, dipropanolamine, tripropanol amine.
The effect of invention
Therefore double-edged eyelid forming agent of the present invention can form blocky film owing to increased the amount of synthetic resin emulsion, even have under the tight situation of skin, also can form the advantage of double eyelid really.
In addition, double-edged eyelid forming agent of the present invention has been owing to reduced the amount of rubber latex, and it is not shinny therefore to have filming of forming on the eyelid, and can not cause the advantage that other people note.
Description of drawings
Fig. 1 is the composition diagram of 3 kinds of compositions of representing the ratio of rubber latex, synthetic resin emulsion and alkanolamine with weight %.
The specific embodiment
Composition by the improvement double-edged eyelid forming agent also can form the purpose of double eyelid even realized the too tight people of the skin of upper eyelid.
Embodiment 1
With rubber latex, synthetic resin emulsion and alkanolamine according to mixed shown in the left hurdle of table 1, table 2, add 5wt% water therein, this mixed liquor is smeared on the upper eyelid, film with regard to formed, its outward appearance, cohesive, the intensity of filming are studied, and but the keeping quality of this mixed liquor studied, its result is as shown in the right hurdle of table 1, table 2.
Table 1
Specimen coding Rubber latex (wt%) Synthetic resin emulsion (wt %) Alkanolamine (wt %) Outward appearance Cohesiveness Intensity But keeping quality Synthetic determination
1? 53? 47? 0? High transparent Well A little less than Difference ×?
2? 52.9? 47? 0.1? High transparent Well A little less than Well ×?
3? 52? 47? 1? High transparent Well A little less than Well ×?
4? 51? 47? 2? High transparent Well A little less than Well ×?
5? 50? 47? 3? High transparent Have A little less than Well ×?
6? 49? 47? 4? Slightly bleach A little less than A little less than Well ×?
7? 52? 48? 0? High transparent Well Can Difference ×?
8? 51.9? 48? 0.1? High transparent Well Can Well ○?
9? 51? 48? 1? High transparent Well Can Well ○?
10? 50? 48? 2? High transparent Well Can Well ○?
11? 49? 48? 3? High transparent Have Can Well ○?
12? 48? 48? 4? Slightly bleach A little less than Can Well ×?
13? 51? 49? 0? High transparent Well By force Difference ×?
14? 50.9? 49? 0.1? High transparent Well By force Well ○?
15? 50? 49? 1? High transparent Well By force Well ○?
16? 49? 49? 2? High transparent Well By force Well ○?
17? 48? 49? 3? High transparent Have By force Well ○?
18? 47? 49? 4? Slightly bleach A little less than By force Well ×?
19? 50? 50? 0? High transparent Well By force Difference ×?
20? 49.9? 50? 0.1? High transparent Well By force Well ◎?
21? 49? 50? 1? High transparent Well By force Well ◎?
22? 48? 50? 2? High transparent Well By force Well ◎?
23? 47? 50? 3? High transparent Have By force Well ○?
24? 46? 50? 4? Slightly bleach A little less than By force Well ×?
25? 45? 55? 0? High transparent Well By force Difference ×?
26? 44.9? 55? 0.1? High transparent Well By force Well ◎?
27? 44? 55? 1? High transparent Well By force Well ◎?
28? 43? 55? 2? High transparent Well By force Well ◎?
29? 42? 55? 3? High transparent Have By force Well ○?
30? 41? 55? 4? Slightly bleach A little less than By force Well ×?
Table 2
Specimen coding Rubber latex (wt%) Synthetic resin emulsion (wt%) Alkanolamine (wt%) Outward appearance Cohesiveness Intensity But keeping quality Synthetic determination
31? 40? 60? 0? High transparent Well By force Difference ×?
32? 39.9? 60? 0.1? High transparent Well By force Well ◎?
33? 39? 60? 1? High transparent Well By force Well ◎?
34? 38? 60? 2? High transparent Well By force Well ◎?
35? 37? 60? 3? In transparent Have By force Well ○?
36? 36? 60? 4? Slightly bleach A little less than By force Well ×?
37? 39? 61? 0? High transparent Well By force Difference ×?
38? 38.9? 61? 0.1? High transparent Well By force Well ◎?
39? 38? 61? 1? High transparent Well By force Well ◎?
40? 37? 61? 2? High transparent Well By force Well ◎?
41? 36? 61? 3? In transparent Have By force Well ○?
42? 35? 61? 4? Slightly bleach A little less than By force Well ×?
43? 38? 62? 0? High transparent Well By force Difference ×?
44? 37.9? 62? 0.1? High transparent Well By force Well ◎?
45? 37? 62? 1? High transparent Well By force Well ◎?
46? 36? 62? 2? In transparent Have By force Well ○?
47? 35? 62? 3? In transparent Have By force Well ○?
48? 34? 62? 4? Slightly bleach A little less than By force Well ×?
49? 37? 63? 0? In transparent Well By force Difference ×?
50? 36.9? 63? 0.1? In transparent Well By force Well ○?
51? 36? 63? 1? In transparent Have By force Well ○?
52? 35? 63? 2? In transparent Have By force Well ○?
53? 34? 63? 3? In transparent Have By force Well ○?
54? 33? 63? 4? Slightly bleach A little less than By force Well ×?
55? 36? 64? 0? In transparent Have By force Difference ×?
56? 35.9? 64? 0.1? In transparent Have By force Well ○?
57? 35? 64? 1? In transparent Have By force Well ○?
58? 34? 64? 2? In transparent Have By force Well ○?
59? 33? 64? 3? In transparent Have By force Well ○?
60? 32? 64? 4? Slightly bleach A little less than By force Well ×?
61? 35? 65? 0? In transparent Have By force Difference ×?
62? 34.9? 65? 0.1? In transparent Have By force Well ○?
63? 34? 65? 1? In transparent Have By force Well ○?
64? 33? 65? 2? In transparent Have By force Well ○?
65? 32? 65? 3? Slightly bleach A little less than By force Well ×?
66? 31? 65? 4? Bleach A little less than By force Well ×?
67? 34? 66? 0? Bleach A little less than By force Difference ×?
68? 33.9? 66? 0.1? Bleach A little less than By force Well ×?
69? 33? 66? 1? Bleach A little less than By force Well ×?
70? 32? 66? 2? Bleach A little less than By force Well ×?
71? 31? 66? 3? Bleach A little less than By force Well ×?
72? 30? 66? 4? Bleach A little less than By force Well ×?
At first, shown in the specimen coding 1～6 in these tables, be 47wt% in the ratio of synthetic resin emulsion, be under the few situation of the ratio junction point B of synthetic resin emulsion and the line of putting C, a little less than the hot strength of filming that forms,, be difficult to form double eyelid for the too tight people of the skin of upper eyelid.
On the contrary, shown in specimen coding 8～11, be 48wt% in the ratio of synthetic resin emulsion, be under the many situations of the ratio junction point B of synthetic resin emulsion and the line of putting C, the hot strength of filming that forms improves, and for the too tight people of the skin of upper eyelid, also can form double eyelid.
In addition, shown in specimen coding 1,7,13,19,25,31,37,43,49,55,61,67, when the ratio of alkanolamine was 0wt%, promptly under the situation of not adding alkanolamine, but the keeping quality of mixed liquor was poor, solidifies sometimes when preserving for a long time.In addition, if do not add alkanolamine, resistance to water of filming and film property are also relatively poor.
On the contrary, shown in specimen coding 2,8,14,20,26,32,38,44,50,56,62,68, if the ratio of alkanolamine is 0.1wt%, promptly the line of the ratio junction point C of alkanolamine and some D for a long time, mixed liquor can not solidify under long-time situation of preserving yet.
In addition, shown in specimen coding 6,12,18,24,30,36,42,48,54,60,66,72, if the ratio of alkanolamine is 4wt%, the ratio that is alkanolamine has surpassed the line of junction point A with some B, the cohesiveness of filming that forms dies down, occur situation about very easily coming off when touching moisture such as sweat, be difficult on upper eyelid, form double eyelid.
On the contrary, shown in specimen coding 5,11,17,23,29,35,41,47,53,59,65,71, if the ratio of alkanolamine is 3wt%, be that the ratio junction point A of alkanolamine and the line of putting B are few, then the cohesiveness of filming of Xing Chenging is stronger, be not subjected to the influence of moisture such as sweat, can on upper eyelid, form double eyelid.
In addition, shown in specimen coding 65,67～72, ratio at synthetic resin emulsion is 65wt% or 66wt%, promptly, under the situation of the ratio of synthetic resin emulsion above the line of junction point D, some E and some A, filming of forming bleaches in appearance, easily form film on form fold or crack, be difficult on upper eyelid, form double eyelid.
On the contrary, shown in specimen coding 62,63,64, be 64wt% or 65wt% in the ratio of synthetic resin emulsion, that is, under the few situation of line of the ratio junction point D of synthetic resin emulsion, some E and some A, the slightly white opacity of filming of formation, but do not have the crack, can use.
By above found that, as shown in Figure 1, in the scope that if the weight % (Z) of the weight % (Y) of the weight % of rubber latex (X), synthetic resin emulsion and alkanolamine in the composition diagram of 3 kinds of compositions of the weight % (X, Y, Z) of these 3 kinds of compositions of expression is polygon that the summit constitutes with A～E each point to be surrounded, even the too tight people of the skin of upper eyelid then, also can obtain to be enough to form double eyelid, filming of having the characteristic expected, wherein
A(33.0，64.0，3.0)
B(49.0，48.0，3.0)
C(51.9，48.0，0.1)
D(34.9，65.0，0.1)
E(33.0，65.0，2.0)。
In addition, shown in specimen coding 14～17, can find, ratio at synthetic resin emulsion is more than the 49wt%, the ratio that is synthetic resin emulsion surpasses under the situation of junction point G and the line of some H, even can obtain enough hot strengths that the too tight people of the skin of upper eyelid also can form double eyelid completely.
In addition, shown in specimen coding 40,44,45, can find, ratio at synthetic resin emulsion is 61wt% or 62wt%, that is, the ratio of synthetic resin emulsion is no more than under the situation of line of junction point I, some J and some F, the transparency height of filming, filming of forming can not recognized by other people, can obtain the sensation of nature.
In addition, shown in specimen coding 4,10,16,22,28,34,40,46,52,58,64,70, can find, ratio at alkanolamine is 2.0wt%, the ratio that is alkanolamine is no more than under the situation of junction point F and the line of some G, the resistance to water of filming that forms is improved, and is better to the cohesiveness of skin.
Can find by above result, as shown in Figure 1, in the scope that if the weight % (Y) of the weight % (X) of rubber latex and synthetic resin emulsion and the weight % (Z) of alkanolamine in the composition diagram of 3 kinds of compositions of the weight % (X, Y, Z) of these 3 kinds of compositions of expression are the polygon of summit formation with F～J each point to be surrounded, then can obtain to have filming of more gratifying characteristic, wherein
F(37.0，61.0，2.0)
G(49.0，49.0，2.0)
H(50.9，49.0，0.1)
I(37.9，62.0，0.1)
J(37.0，62.0，1.0)。
In addition, composition of the present invention but in the scope that does not hinder its characteristic, can also add ammonia, antiseptic, pigment, spice, water etc. as mentioned above.

Claims (2)

1. double-edged eyelid forming agent, comprise rubber latex and synthetic resin emulsion, described rubber latex is the LA latex of JISK6381, described synthetic resin emulsion is an acrylate resin emulsion, the styrene resin fat liquor, acrylamide copolymer resins emulsion, vinyl acetate copolymerized resin emulsion or polrvinyl chloride copolymer resins emulsion, it is characterized in that also comprising alkanolamine, described alkanolamine is a monoethanolamine, and the weight % of this rubber latex (X), the weight % (Z) of weight % of synthetic resin emulsion (Y) and alkanolamine is at the weight % (X of these 3 kinds of compositions of expression, Y, be in polygon that the summit the constitutes scope of being surrounded with A～E each point in the composition diagram of 3 kinds of compositions Z), wherein
A(33.0，64.0，3.0)
B(49.0，48.0，3.0)
C(51.9，48.0，0.1)
D(34.9，65.0，0.1)
E(33.0，65.0，2.0)，
The molecular weight of the synthetic resin of above-mentioned synthetic resin emulsion is 300,000～2,000,000.
2. double-edged eyelid forming agent as claimed in claim 1, it is characterized in that, the weight % (Y) of weight % of this rubber latex (X) and synthetic resin emulsion and the weight % (Z) of alkanolamine in the composition diagram of 3 kinds of compositions of the weight % (X, Y, Z) of these 3 kinds of compositions of expression are in polygon that the summit the constitutes scope of being surrounded with F～J each point, wherein
F(37.0，61.0，2.0)
G(49.0，49.0，2.0)
H(50.9，49.0，0.1)
I(37.9，62.0，0.1)
J(37.0，62.0，1.0)，
The molecular weight of the synthetic resin of above-mentioned synthetic resin emulsion is 300,000～2,000,000.
CN200710139963XA 2007-02-27 2007-08-07 Double-edged eyelid forming agent Expired - Fee Related CN101254161B (en)

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JP2007-046909 2007-02-27
JP2007046909A JP2008208076A (en) 2007-02-27 2007-02-27 Double eyelid-forming agent
JP2007046909 2007-02-27

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JP5414289B2 (en) * 2009-01-26 2014-02-12 有限会社ローヤル化研 Eyelash correction cosmetics and eyeliner
CN104490622B (en) * 2009-01-28 2017-06-30 岩垣直子 Application device and container and the method for forming Dual-eyelid
EP3284465B1 (en) 2015-04-15 2019-10-23 Hisamitsu Pharmaceutical Co., Inc. Transdermal patch containing ropinirole

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JPH0662384B2 (en) * 1989-01-12 1994-08-17 株式会社ローヤル美研 Double eyelid forming treatment
JPH07102236A (en) * 1993-10-06 1995-04-18 Aica Kogyo Co Ltd Adhesive for woody plate
DE19613011A1 (en) * 1996-03-25 1997-10-02 Schill & Seilacher Preserved and stabilized natural latex, process for its preparation and use of water-soluble carboxylic acid salts for its preservation and stabilization
JP2005330222A (en) * 2004-05-19 2005-12-02 Mikuni Color Ltd Water-based pigment dispersion for makeup, and eyeliner and cosmetic each using the same

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