CN101240114A - Composition of environmental protection plastic products and manufacturing method - Google Patents

Composition of environmental protection plastic products and manufacturing method Download PDF

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CN101240114A
CN101240114A CN 200710073289 CN200710073289A CN101240114A CN 101240114 A CN101240114 A CN 101240114A CN 200710073289 CN200710073289 CN 200710073289 CN 200710073289 A CN200710073289 A CN 200710073289A CN 101240114 A CN101240114 A CN 101240114A
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natural
green
plastic
plastic article
composition
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CN 200710073289
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CN101240114B (en
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曾子文
林崑堦
黄丰焜
黄柏蓁
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明助实业股份有限公司
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Abstract

The invention relates to a component of an environment-friendly plastic product and manufacturing method thereof, comprising: using couplant to treat with natural mineral, hard charcoal powder, natural plant starch and wood fiber powder, mixing with macromolecule thermoplastic polymer elastic resin and couplant to make polymeric particle, which is mixed with heat-resistant natural flavor ingredient to heat and stir to make flavor master batch, the environment-friendly plastic product with antibacterial function and flavor is prepared by mixing, film blowing and extruding or injection molding. The invention has the advantages of reducing consumption of plastics, toughness, recycling use, conservation of resources, low cost, being buried, being burning with toxic gas, no dioxin, being environment-friendly, with flavor, effectiveness of antibacterial and deodorization.

Description

一种环保塑料制品的组成物及制造方法【所属技术领域】本发明涉及一种具有可不断释放出香味的塑料产品,且该塑料产品本身同时兼具有抗菌、可堆肥处理不造成环境二次污染的环保塑料产品组成物及其制造方法。 Composition and method for producing an environmentally friendly plastic article [skilled] The present invention relates to a continuous release of fragrance may be a plastic product, the plastic product itself and has antibacterial and simultaneously, does not cause environmental compostable secondary green plastic compositions contaminated products and its manufacturing method. 【背景技术】现有塑料制品的废弃物,在自然环境或垃圾掩埋场中不易被微生物分解、腐烂,在燃烧焚化过程中又会产生大量浓烟及有毒气体,造成空气、土壤等各种环境污染。 BACKGROUND conventional waste plastics, is not easily decomposed in a natural environment or landfills microorganisms, decay, will generate a lot of smoke and toxic gases in the combustion of the incineration process, resulting in a variety of ambient air, soil, etc. Pollution. 现有具香味的塑料容器制造方法,通常由以下的步骤顺序完成;l.将开放式细胞孔的相同结构体的超微粒细孔洞塑料物浸渍于香精中,经浸泡后使之吸收饱和,而成为香母粒。 A method for producing plastic containers with conventional fragrance, usually done by the following sequence of steps;. L the same ultrafine particle structure of fine pores of the open cell plastic impregnated well in flavor, after saturation soaking allowed to absorb, and become fragrant masterbatch. 2.以相同结构体的聚合成油族塑料掺配上述的香母粒均匀混合,以完成射出配料,然后置于射出成型机中,以射出具有香味的塑料容器。 2. The same polyethylene plastic synthetic aromatic structure above perfumed masterbatch blending homogeneously mixed ingredients to complete exit, and then placed in the injection molding machine, having the fragrance emitted to the plastic container. 前述制造方法虽然可使制成的塑料容器具有自动散发香气的效益,但存在如下不足:制造过程中受限于物料吸附香精的作业时间较长,以致有产量无法有效提升的待改善处;此外,将超微粒细孔洞塑料物长时间的浸泡在香精过程中,香精会自然产生挥发作用,而且,当超微粒细孔洞塑料物将香精吸吮至饱和状态后,若未将其实时移入另一制造作业流程,则该塑料物料中的香精亦会处于不断地挥发流失中,试想此等无形中造成原物料快速消耗与浪费,乃物料成本居高不下的缺点。 Although the method of manufacturing a plastic container can be made having a perfuming effective automatically, but the following defects: the manufacturing process is limited by the adsorption material flavor longer working time, resulting in improvement of the yield can not be effectively improved; furthermore , ultra-fine particles of plastic material hole in a long soak process flavors, flavor volatilization naturally produce, and, when the ultrafine particle thin plastic material hole to suck the flavor saturation, if not the real-time into another manufacturing processes, the plastic material in the flavor will evaporate in a constant loss, the Imagine these potentially resulting in rapid consumption of raw materials and waste, the disadvantage is the high cost of materials. 有鉴于此,发明人经多年从事该项产业的经验,深知上述制造方法的缺点所在,乃全心专注投入研发,秉持着不懈怠的精神,始终开发出本案的创新技术,并提出专利申请。 In view of this, the inventor after years of experience in the industry, well aware of the shortcomings of the production method where, is dedicated focus on investment in research and development, uphold the spirit of slack not always develop innovative technology of the case, and filed a patent application . 【发明内容】本发明的目的,是提供一种具芳香、除臭及抗菌效果的环保塑料制品的组成物及制造方法,以使本发明的技术具有以下的功效增进:可有效降低塑料用量、保有传统塑料的韧性、可重复循环使用、节约资源有效降低制造成本、对环境不造成二次污染,可进行掩埋、或焚烧皆不会产生毒性气体、无戴奥辛物质,是以对环境无害等特征者。 SUMMARY OF THE INVENTION An object of the present invention is to provide an aromatic, deodorant and environmentally friendly plastics antimicrobial effects of compositions and manufacturing methods having to make the techniques of this invention has the effect of promotion: can effectively reduce the amount of plastic, toughness retain traditional plastics, repeat the cycle, saving resources effectively reducing the manufacturing cost, does not cause secondary pollution to the environment, can be buried, or does not produce toxic gases are incinerated, no dioxin substance, is harmless to the environment those features. 为实现上述目的,本发明提供一种环保塑料制品的组成物,包括:环保聚合粒、香母粒及塑料原料组成;该环保聚合粒成分主要由:数种天然矿物质、植物性淀粉及木纤粉、备长炭粉、高分子热塑性聚合物弹性体树脂、耦联剂等依适当百分比混炼而成的颗粒状;该香母粒,是以适量的环保聚合粒加上天然香精料加热搅拌而成,该天然香精料亦可为一种奈米银、或奈米氧化锌、或奈米二氧化钛、或奈米磁粉;该塑料原料可为聚乙烯(PE)、低密度聚乙烯(LDPE)、线性低密度聚乙烯(LLDPE)、高密度聚乙烯(HDPE)、聚丙烯(PP)、聚苯乙烯(PS)、丙烯晴-丁二烯-苯乙烯(ABS)共聚物其中任一种。 To achieve the above object, the present invention provides an environmentally friendly composition of the plastic article, comprising: polymeric particles green, fragrant base particles and plastic material composition; the green component mainly composed of polymeric particles: several natural minerals, vegetable starch and wood fiber powder, bincho charcoal, polymeric elastomer of thermoplastic polymer resins, obtained by kneading or the like coupled by a suitable percentage of particulate; the fragrance masterbatch, is a suitable amount of green particles plus polymeric material is heated natural flavors stirring together, the material may also be natural flavor as a nano silver, or nano-zinc oxide, or titanium oxide nano or nano magnetic powder; the plastic material may be polyethylene (PE), low density polyethylene (LDPE ), linear low density polyethylene (LLDPE), high density polyethylene (HDPE), polypropylene (PP), polystyrene (PS), acrylonitrile - butadiene - styrene (ABS) copolymer wherein either . 进一步地,本发明提供一种环保塑料制品的制造方法,包括: 步骤一:将天然矿物质、天然植物性淀粉、天然植物木纤粉及备长炭粉等多种超微细粉粒各依适量百分比例,再配合适量的高分子热塑性聚合物弹性体树脂及耦合剂混炼制成环保聚合粒,以作为第一组母料;其中, 第一组母料的环保聚合粒大小规格设定每颗粒直径在2-3公厘范围为最佳步骤二:先将适量的环保聚合粒和天然香精料加热搅拌,作为第二组香母料;步骤三:将第一组母料、第二组香母料及塑料原料依成型产品的需求设定适当比例混合加热,采用押出成型或射出成型方法的制成预定各类环保塑料成品。 Further, the present invention provides a method for producing an environmentally friendly plastic article, comprising: a step of: natural minerals, natural vegetable starches, natural plant and wood fiber bincho charcoal powder ultrafine particles each other by an appropriate amount percentage embodiment, together with a suitable amount of thermoplastic polymer resin and the polymeric elastomer coupling agent are mixed and kneaded environmental polymeric particles, as the first set of masterbatch; wherein, a first set of environmental polymeric masterbatch grain size specifications set each particle diameter range 2-3 mm for the best two steps: first a suitable amount of green particles and the polymerization charge was heated with stirring natural essences, fragrance as a second masterbatch; step 3: the first set of masterbatch, the second group Hong master batch of plastic raw materials on demand to set an appropriate ratio of mixed molded product was heated using extrusion molding or injection molding process into a predetermined various environmental plastic products. 采用上述技术方案,本发明有益的技术效果在于:1.采用由环保聚合粒、香母粒及塑料原料制成塑料制品,由于其中环保聚合粒成分主要由数种天然矿物质、植物性淀粉及木纤粉、备长炭粉、 高分子热塑性聚合物弹性体树脂、耦联剂等混炼而成的颗粒。 With the above technical solutions, advantageous technical effects of the present invention wherein: 1 by the use of environmentally friendly polymeric particles, plastic products and plastic masterbatch fragrance raw materials, since the polymeric particles in which the green component is mainly composed of several kinds of natural minerals, vegetable starch and wood fiber powder, bincho charcoal, polymeric elastomer of thermoplastic polymer resin, the coupling agent particles kneaded. 通过环保聚合粒中的矿物质碳酸钙和淀粉等可生物分解物质与塑料原料一起混炼,改变了塑料制品的形态并使其失去部分力学性能,通过堆肥化后其具有对环境无害的优点。 By minerals, calcium carbonate and starch particles in the polymerization environment biodegradable plastic raw material and kneaded together, changing the shape of the plastic article and allowed to lose some mechanical properties, by the advantage of having a composting environment friendly . 香母粒用环保聚合粒加上天然香精料加热搅拌而成,香精很难从环保聚合粒中挥发出去,解决了香精的挥发性问题。 Hong particles plus polymeric masterbatch with environmental charge was heated with stirring from natural flavors, flavor volatiles from the green hard grains out of the polymerization, solve the problem of volatile fragrance. 2、 本发明环保塑料制品的组成物中,采用高分子热塑性聚合物弹性体树脂,其不但在加工过程中可发挥与其它成分混合性佳、延展性高的特质,当被制成实物产品后,更具有可回收再制的效益,此外,成品本身可直接进行掩埋、焚烧不产生毒性气体,具无毒性及无公害性,不会对环境造成二次污染者。 2, the composition of green plastic article of the present invention, a polymeric elastomer thermoplastic polymer resin, which not only play a good miscibility with other components, high ductility characteristics in the processing, when made into a real product more effective reconstituted recyclability, in addition, the finished products themselves may be buried directly, without toxic incineration gas, with no toxicity and pollution, will not cause secondary environmental polluters. 3. 本发明的环保聚合粒成分中,通过使用高分子热塑性聚合物弹性体树脂,可有效将天然植物性木纤粉的成分百分比增加,最高可达到50%之多,以降低塑料使用量,达到成本缩减的实质功效。 3. Environmental polymeric pellet composition according to the present invention, by using a polymeric elastomer of thermoplastic polymer resin, the active ingredient may be natural plant percentage increase wood fiber powder, up to as much as 50%, to reduce the amount of plastic used, the efficacy of the substance to achieve cost reductions. 4、 通过在环保聚合粒中加入备长炭,利用备长炭具有能吸收有害化学物质,利用微生物使其无毒化,除臭功能,除湿与调湿,释放负离子, 净化空气等特点,可使本发明环保塑料制品具有保鲜、抗菌、除臭的功效5、 通过在环保聚合粒中加入天然植物木纤粉,可根据需要减轻环保塑料制品的重量。 4, by the addition of charcoal particles in the polymerization environment, the use of charcoal having a can absorb the harmful chemicals using microorganisms so non-toxic, deodorizing, dehumidification and humidity control, release negative ions, air purification, etc., can green plastic article of the present invention has the effect of preservation, antibacterial, deodorant 5, by the addition of natural plant environment wood fiber powder particles in the polymerization, can reduce the weight of green plastic article according to need. 6. 、通过使用奈米氧化锌,可使产品具有抗菌、增韧及耐磨的功效; 使用奈米银则可使产品具备抗菌、除臭的功效。 6, by using a nano-zinc oxide, the product can have an antibacterial effect, and abrasion resistant toughened; nano silver is used to make the product have antibacterial effect, deodorant. 7. 如附表(一)到(三)本发明环保聚合粒与一般塑料的比较所示, 本发明使用的环保聚合粒(EPCP)的制造过程,无论在任何阶段的加热时间传输的压力或速度设定、脱模的冷却时间等皆较采用单纯一般塑料的时间为短,可有效降低制造成本及提升产量的正面效益。 Table 7 (a) to (c) shown in more environmentally friendly polymeric particles of the invention with general plastics, environmental polymeric particles (EPCP) used in the present invention, the manufacturing process, regardless of the pressure of the heating time of transmission or any stage speed setting, cooling time mused demolding time than using a simple general plastic is short, can effectively reduce the manufacturing cost and enhance production efficiency of the front side. 综上所述,采用本发明,具有降低塑料用量、保有传统塑料的韧性、 可重复循环使用、节约资源、成本低、可掩理、可焚烧不产生毒性气体、 无戴奥辛,对环境无害、具芳香、除臭、抗菌的功效。 In summary, the present invention, having a reduced amount of plastic, the plastic retains the traditional toughness, repeat the cycle, saving resources, low cost, mask processing, does not produce toxic gases can be burned, no dioxin, harmful to the environment, with aromatic, deodorant, antibacterial effect. 本发明技术已具有产业实用性、新颖性与创造性,符合专利法的三性要求。 Technical Industrial Applicability The present invention has been, novelty and inventive, meet the three requirements of patent law. 【附图说明】图1所示为本发明本发明环保塑料制品的组成物制造流程方块图。 BRIEF DESCRIPTION FIG composition of the present invention, the manufacturing process flow diagram of green plastic article of the present invention shown in FIG. 图2所示为本发明本发明环保聚合粒制造流程方块图。 Environmental block polymerization process for producing particles of the present invention shown in FIG. 2 of the present invention in FIG. 标号说明:10环保聚合粒11超微细粉粒物111天然矿物质112天然植物性淀粉113天然植物性木纤粉114备长炭粉12高分子热塑性聚合物弹性体树脂13耦合剂131耦联剂132滑剂20香母粒21耐热天然香精料30塑料原料40塑料制品【具体实施方式】现结合附图将本发明较佳实施例详细说明如下:敬请参阅图1和图2,为本发明一种环保塑料制品的组成物及制造流程方块图。 DESCRIPTION OF REFERENCE NUMERALS: 114 natural minerals binchotan 111 112 113 natural vegetable starches natural plant environment wood fiber powder 10 11 ultrafine particles polymerized toner particles was 12 thermoplastic polymer resin 13 polymeric elastomer coupling agent couplant 131 132 fragrant slip agent masterbatch 20 21 30 heat natural flavor material 40 of plastic material dETAILED DESCRIPTION plastic article is now made to the drawings in conjunction with the preferred embodiments of the present invention is illustrated in detail as follows: please refer to FIGS. 1 and 2, the present invention is an environmentally friendly plastic article block composition and manufacturing process of FIG. 本发明环保塑料制品的组成物,主要包含:1〜50%环保聚合粒10、 1〜50%香母粒20及20〜80%塑料原料30,经加热混炼而成。 The composition of green plastic article of the present invention, comprising mainly: 1~50% recycled polymeric particles 10, 20 1~50% fragrance and 20 to 80% masterbatch of plastic material 30, the heated and kneaded together. 前述各组成分的重量百分比主要依据所欲制造成型的环保塑料产品特性而定。 The weight percentages of each set of components based primarily on desired manufacturing a molded green plastic product characteristics may be. 其中,所述环保聚合粒10的成分包括:数超微细粉粒物11、高分子热塑性聚合物弹性体树脂12及耦合剂13依重量百分比所制成的颗粒。 Wherein the polymeric particles 10 of the environmental component comprising: a number of ultra-fine particles was 11, according to the weight percentage of particles made of a thermoplastic polymer resin 12 and a polymeric elastomer couplant 13. 进一步地,所述多种超微细粉粒物ll的组成成分包括:20〜95%天然矿物质、1〜40%天然植物性淀粉、1〜75%天然木纤粉、1〜50%备长炭粉组成。 Further, the plurality of ultrafine particles was ll composition comprising: 20~95% natural minerals, 1~40% natural vegetable starch, flour 1~75% natural wood fiber, 1~50% bincho toner composition. 再进一步地优选为:30〜80%天然矿物质、5〜30%天然植物性淀粉、10〜70%天然木纤粉和5〜30%备长炭粉。 Still further preferably: 30~80% natural minerals, 5~30% natural vegetable starch, 10~70% natural wood fiber powder, carbon powder and 5~30% binchotan. 其中:天然矿物质111主要成分为碳酸钙Calcium carbonates,CaCCb,其可为大理石粉、方解石粉、滑石粉、石灰石粉、贝壳粉中一种或它们的混合物。 Wherein: natural mineral mainly composed of calcium carbonate 111 Calcium carbonates, CaCCb, which may be powdered marble, calcite powder, talc, limestone powder, shell powder of one or a mixture thereof. 采为天然矿物质的优点:材料价格成本低、增加塑料产品体积、减少成品制程收縮率、提高几何尺寸的稳定性,强化硬度及钢度、提高耐热性、抗擦伤性。 Natural mineral mining advantages: low cost material prices, increasing the volume of plastic products, to reduce the finished shrinkage process, to improve the stability of the geometry, hardness and rigidity strengthening, improving the heat resistance, scratch resistance. 天然矿物质取值范围的选择是兼顾既要便于焚烧不产生毒性气体、 不会对环境造成二次污染,又要便于超微细粉粒物的成形及满足塑料产品的一般强度要求。 Natural minerals selected range is both necessary to facilitate the burning gas is not toxic, it does not cause secondary pollution to the environment, but also facilitate forming ultrafine particles thereof and to meet the general requirements of strength plastic products. 如,当天然矿物质的加入量超过30%后,塑料制品焚烧后几乎全部变成灰。 For example, when the added amount of the natural mineral exceeds 30%, almost all of the plastic article into the incineration ash. 当天然矿物质的加入量不超过80%时,塑料制品具有较好的强度。 When the added amount of the natural minerals, no more than 80%, plastic article having a good strength. 天然植物性淀粉112可为玉米淀粉、或花生淀粉、或黄豆粉、或木薯淀粉或地瓜淀粉其中任一种。 Wherein the natural vegetable starch 112 may be any of a corn starch, or starch peanuts or soybean flour, or potato starch or tapioca starch. 加入天然植物性淀粉的优点是无毒性,无污染性,更重要的是可使废弃的塑料制品被埋在地下后能够自然分解。 Added advantage of natural vegetable starches are non-toxic, non-polluting, more importantly, it allows the waste plastic article can be buried in the ground after natural decomposition. 但天然植物性淀粉加入量过高又会便塑料制品分解过快,縮短塑料制品的使用寿命。 But natural vegetable starch amount is too high it will break down too fast plastic products, shorten the service life of plastic products. 天然植物性淀粉优选5〜30%。 Natural vegetable starch is preferably 5~30%. 天然植物性木纤粉113可为木屑纤粉、或稻壳纤粉、或麦杆纤粉、或玉米杆纤粉、或甘蔗渣纤粉、或豆渣纤粉、或椰子纤粉或其它等特性植物纤粉。 Natural plant powder 113 may be a wood fiber wood fiber powder, fiber or powder, rice husk, straw fiber, or powder, or corn flour fiber rods, bagasse fibers, or powder, or powder okara fiber, coconut fiber dust or the like, or other characteristics plant fiber powder. 天然植物性木纤粉的优点:比重轻、增加塑料产品体积、属天然农业废弃物、取得方便经济便宜、无毒性无污染性,可自然分解。 The advantages of natural vegetable wood fiber powder: light weight, increasing the volume of plastic products, agricultural waste is a natural, convenient and economical to obtain inexpensive, non-toxic non-polluting, natural decomposition. 但天然植物性木纤粉的加入量过多会降低塑料制品的强度。 However, addition of natural vegetable powder wood fiber is too large reduce the strength of the plastic products. 备长炭粉(白炭)114,可为竹备长炭粉或木备长炭粉。 Binchotan toner (white carbon) 114, may be a wooden or bamboo charcoal powder preparation bincho charcoal long. 加入备长炭粉的优点:比重轻、无毒性、释放负离子、天然矿物质、产生远红外线热能、净化空气、除臭、除余氯具调湿等功效。 Bincho charcoal powder added advantage: light weight, non-toxic, release negative ions, natural minerals, generate far-infrared heat, air purification, deodorant, with a humidity addition to chlorine and other effects. 缺点是:材料价格成本高。 The disadvantages are: the high price of materials costs. 高分子热塑性聚合物弹性体树脂12 (High Molecule Polymer Resin),可采用热塑性离子交键聚合物树脂(lonomer),或乙烯一辛烯或a型烯聚合的共聚物弹性体。 Polymeric elastomer thermoplastic polymer resin 12 (High Molecule Polymer Resin), can be cross-linked ionic thermoplastic polymer resin (lonomer), or ethylene octene or a copolymer of the olefin polymerization type elastomers. 采用高分子热塑性聚合物弹性体树脂,不但在加工过程中可发挥与其它成分混合性佳、延展性高的特质,当被制成实物产品后, 更具有可回收再制的效益,此外,成品本身可直接进行掩埋、焚烧不产生毒性气体,焚烧后全部为灰尽,不会产生焦状残渣,具无毒性及无公害性,不会对环境造成二次污染者。 The thermoplastic elastomer macromolecule polymer resin, during processing, not only can play a good miscibility with other components, high ductility characteristics, when made into a real product, a more effective system recyclable, in addition, the finished product can be directly buried itself, does not produce toxic gases incineration, incineration all gray do not produce a coke-like residue with a non-toxic and pollution, will not cause secondary environmental polluters. 3.本发明的环保聚合粒成分中,通过使用高分子热塑性聚合物弹性体树脂,可有效将天然植物性木纤粉的成分百分比增加,最高可达到50%之多,以降低塑料使用量,达到成本缩减的实质功效。 3. Environmental polymeric pellet composition according to the present invention, by using a polymeric elastomer of thermoplastic polymer resin, the active ingredient may be natural plant percentage increase wood fiber powder, up to as much as 50%, to reduce the amount of plastic used, the efficacy of the substance to achieve cost reductions. 耦合剂13,包括:1〜5%耦联剂131和1〜5%滑剂132,耦联剂可为乙烯基三乙氧基硅烷、或乙烯基三甲氧基硅烷、或钛酸脂其中任一种。 13, a coupling agent comprising: 1 ~ 5% 1 ~ 5% coupling agent, and lubricant 131 132, may be a coupling agent vinyltriethoxysilane, or vinyltrimethoxysilane, wherein any aliphatic or titanate one kind. 耦联剂的加入量少时,分散性差,但加入过多时,增加成本。 When a small amount of coupling agent added, the dispersibility is poor, but addition of too much increase in cost. 滑剂起辅助作用,可为硬脂酸锌、或硬脂酸钙、或硬脂酸镁、氧化聚乙烯蜡任一种。 Slip agents play a supporting role, may be zinc stearate, or calcium stearate, or magnesium stearate, oxidized polyethylene wax, either. 采用上述物料组成,经加热混炼挤出成径宽大小在2〜3公厘(mm)的环保聚合细颗粒状。 With the above composition of the material, the heated and kneaded extruded into a diameter of 2 to 3 mm width size (mm) polymerization of fine granular green. 该香母粒20,包括环保聚合粒10及耐热天然香精料21组成,其重量百分比为:20〜50%环保聚合粒10, 0.05〜6%耐热天然香精料21,加热均匀搅拌而成。 The fragrance masterbatch 20, comprising polymeric particles 10 and the heat environment natural flavor material 21, whose percentage weight: 20~50% recycled polymeric particles 10, the heat 0.05~6% natural flavor material 21, is heated uniformly stirred from . 其中,该耐热天然香精料21采用油性、或蜡性、或粉性具不易挥发的香料,亦可为奈米银、或奈米氧化锌、或奈米氧化钛或奈米磁粉其中任一种或多种混合、或等特性的材料取代之。 Wherein the heat-resistant material 21 has natural flavor oil, a wax, or resistance, or powdering resistance with less volatile perfumes, it may also be nano-silver, or nano-zinc oxide, or titanium oxide nano-magnetic particle or nano either the material substituted with one or more mixed, or other characteristics. 香精料加入量过少时, 一是吸附性差,二是没有香味。 Flavor feed amount is too small, one differential adsorption, the second is no fragrance. 但当香精料加入量过多时, 一是成本高, 二是香味过浓,不宜采用。 But when the flavor material is added an excessive amount, first, the high costs, the second flavor is too thick, should not be used. 20〜80^塑料原料30可为聚乙烯(PE)、低密度聚乙烯(LDPE)、线性低密度聚乙烯(LLDPE)、高密度聚乙烯(HDPE)、聚丙烯(PP)、聚苯乙烯(PS)、 丙烯晴-丁二烯-苯乙烯(ABS)共聚物其中任一种,依产品物性需求选用塑料原料。 30 ^ 20 to 80 may be a plastic material polyethylene (PE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), high density polyethylene (HDPE), polypropylene (PP), polystyrene ( PS), acrylonitrile - butadiene - styrene (ABS) copolymer wherein any one, depending on product use plastic raw material requirements. 据此,上述组成分构成的环保塑料,即可进行押出成型或射出成型等方式,制成各类的塑料制品40。 Accordingly, the above-described set of components green plastic configuration, can be carried out injection molding or extrusion molding, etc., made of various types of plastic products 40. 进一步地,再说明本发明一种环保塑料制品的制造方法,其作业流程如下所述:步骤一:捏合机温度设在摄氏100〜130度之间,先将重量百分比5〜 30%的高分子热塑性聚合物弹性体树脂12捏合5〜15分钟,使之均匀软化后,再加入25〜95%的超微细粉粒天然矿物质lll(碳酸钙)、1〜30%的超微细粉粒天然植物性淀粉112、 1〜75%的超微细粉粒天然植物木纤粉113 及1〜50%的超微细粉粒备长炭粉114、 1〜5%的耦联剂113、 1〜5%的滑剂132继续混合捏合5〜15分钟后,送入螺杆式押出机混炼挤出制成环保聚合颗粒状,该颗粒直径设定在2〜3公厘(mm),以作为第一组母料;其中,前述进行混炼挤出造粒的螺杆式押出机的温度设定在摄氏100〜180度之间为最佳,此外,螺杆式押出机可为单螺杆式押出机或双螺杆式押出机,又以采用双螺式押出机制造为最佳。 Further, again illustrating a method of manufacturing a plastic article of the present invention is environmentally friendly, which processes as follows: Step 1: kneader temperature was set between 100 to 130 ° C, -5 to 30% by weight first polymer after the thermoplastic polymeric elastomer resin kneaded 5~15 12 minutes and uniformly softened, then add ultra fine particles of 25~95% LLL natural minerals (calcium carbonate), 1~30% of ultrafine particles of natural plant 112 starch, 1~75% of ultrafine particles of natural wood fiber plant powder 113 and ultrafine particles 1~50% bincho charcoal 114, 113 ~ 5% of coupling agent, the 1 ~ 5% after slip agent 132 continues 5~15 minutes mixing and kneading, into a screw extruder kneading extruder made environmental particulate polymerization, the particle diameter is set to 2 to 3 millimeters (mm), as the first set of master material; wherein the kneading temperature of the extruder screw extruder granulation is set between 100~180 ° C is preferred, in addition, the screw extruder may be a single screw or twin screw extruder extrusion machines, again using a twin screw type extruder manufactured as optimal. 步骤二:将上述第一组母料取20〜50%的环保聚合粒10与0.05〜6%的耐热天然番精料21以摄氏30〜70度加热搅拌至1〜5小时,作为第二组香母料20;其中,前述加热温度的设定范围依各种不同的香料耐燃点调整加热温度;而加热搅拌的时间,则视第一组母料的数量多寡而定;步骤三:以押出成型或射出成犁方式制造成环保胶料制品40,其成分百分比包括:1〜50%第一组母料暨环保聚合粒10、 1〜50%第二组香母料20及20〜80%塑料原料30均匀混合后,以摄氏120〜220度(最佳温度设定为170度)押出或射出成型制造各类具抗菌除臭、可长时效释放出香气、以达到除臭消除异味的环保塑料成品。 Step 2: Take the first set of 20~50% masterbatch environmental polymeric particles 10 and the heat 0.05~6% natural lycopene concentrate is heated to 21 degrees Celsius and stirred until 30~70 ~ 5 hours, as a second Hong masterbatch group 20; wherein the heating temperature range is set by adjusting the heating temperature of various spices flame point; stirring and heating time, depending on the number of the first group may be the amount of the masterbatch; step III: extrusion or injection molding to plow into green rubber manufactured article 40, which is the percentage of components comprising: a first group of 1~50% masterbatch and environmental Protection polymeric particles 10, a second group of 1~50% fragrance 20 and 20 to 80 a masterbatch 30% plastic raw materials uniformly mixed to 120~220 ° C (optimum temperature was set to 170 degrees) for manufacturing various types of injection molding or extrusion with antibacterial deodorant, fragrance release or long aging, to achieve deodorizing odor eliminating environmentally friendly plastic products. 该环保塑料成品,可为各式的垃圾袋、购物袋、衣物保存袋、浴帽、雨衣、透气膜、不织布、纺织纤维、玩具、家俱日用品塑料产品、汽车内装板、电子周边产品、发泡制品等。 The green plastic products, it may be all kinds of garbage bags, shopping bags, clothing storage bags, shower cap, raincoats, breathable film, nonwoven fabric, woven fabric, toys, furniture and plastic products, daily necessities, automotive interior panels, electronic peripherals, expanded products. 附表给出了使用EPCP环保聚合粒与一般塑料比较参考。 Table shows the use of polymeric particles and the general environmental EPCP plastic comparison reference. 根据该附表可以看出,无论在任何阶段的加热时间、传输的压力或速度设定、脱模的冷却时间等皆较采用单纯一般塑料的时间为短,且制造成本降低,产量提高。 According to this schedule can be seen that, regardless of the heating time at any stage, the pressure or the transmission speed is set, the cooling time mused demolding time than using a simple general plastic is short, and the manufacturing cost, improve the yield. 添加EPCP原料可有效降低成型品之几何尺寸收縮率及变形,可縮短开模冷却时间,提高生产力。 Add EPCP geometry feedstock can effectively reduce shrinkage and deformation of the molded product, mold cooling time can be shortened to improve productivity. 附表: 使用EPCP环保聚合粒与一般塑料比较参考:(一)PE押出吹袋成型\\<table>table see original document page 10</column></row> <table><table>table see original document page 11</column></row> <table> Schedule: Environmental polymeric particles using EPCP Comparative Reference general plastic :( a) PE bags extrusion blow molding \\ <table> table see original document page 10 </ column> </ row> <table> <table> table see original document page 11 </ column> </ row> <table>

Claims (20)

1. 一种环保塑料制品的组成物,其特征在于包括:环保聚合粒、香母粒及塑胶原料,经加热混炼而成。 An environmentally friendly plastics composition, characterized by comprising: green polymeric particles, base particles and plastic fragrance raw materials, heating and kneaded together.
2. 如权利要求1所述环保塑料制品的组成物,其特征在于:其中,该环保聚合粒包括:由超微细粉粒物、高分子热塑性聚合物弹性体树脂及耦合剂所制成的颗粒。 2. The plastic article of a composition as claimed in claim environmental, wherein: wherein the environmental polymeric particles comprising: particles composed of ultrafine particles thereof, polymer resin and a thermoplastic polymeric elastomer made of couplant .
3. 如权利要求2所述环保塑料制品的组成物,其特征在于:其中,所述环保聚合粒的重量百分比为1〜50%、香母粒的重量百分比为1〜50%、塑料原料的重量百分比为20〜80%。 3. The composition of claim 2 green plastic article as claimed in claim wherein: wherein said weight percentages are environmentally friendly polymeric particles 1~50%, by weight of the perfumed masterbatch percentage of 1~50%, plastic raw materials 20 to 80 wt%.
4. 如权利要求3所述环保塑料制品的组成物,其特征在于:其中,该超微细粉粒包括:20〜95%天然矿物质、1〜40%天然植物性淀粉、1〜75 %天然木纤粉、1〜50%备长炭粉组成。 4. The composition of 3 green plastic article as claimed in claim, wherein: wherein the ultrafine particles comprising: 20~95% natural minerals, 1~40% natural vegetable starch, natural 1~75% powder, wood fiber, 1~50% bincho charcoal powder composition.
5. 如权利要求4所述环保塑料制品的组成物,其特征在于:其中,该超微细粉粒包括:30〜80。 4 5. The composition of green plastic article according to claim, wherein: wherein the ultrafine particles comprising: 30~80. /。 /. 天然矿物质、5〜300%天然植物性淀粉、10〜70 Q/^天然木纤粉和5〜30。 Natural minerals, 5~300% natural vegetable starch, 10~70 Q / ^ 5~30 natural wood fiber and powder. %备长炭粉。 % Binchotan toner.
6. 如权利要求5所述环保塑料制品的组成物,其特征在于:其中,该耦合剂包括占总重量1〜5%的耦联剂及1〜5%的滑剂。 5 6. The composition as claimed in claim environmentally friendly plastic article, wherein: wherein the coupling agent comprises a 1 ~ 5% of the total weight of the coupling agent 1 ~ 5% of a slip agent.
7. 如权利要求1至6任意一项所述环保塑料制品的组成物,其特征在于:其中,该香母粒由所述环保聚合粒加上0.05〜6%的所述耐热天然香精料加热搅拌而成。 1-6 7. The composition of any one of green plastic article as claimed in claim, wherein: wherein the masterbatch by the environmental polymeric fragrance particles plus the heat 0.05~6% natural flavor materials heated and stirred together.
8. 如权利要求至7所述环保塑料制品的组成物,其特征在于:其中,该耐热天然香精料采用油性、或蜡性、或粉性具不易挥发的香料。 8. The composition of claim 7 green plastic article to claim, wherein: wherein the heat-resistant material using natural flavor oil, a wax, or resistance, or powdering resistance with less volatile perfumes.
9. 如权利要求1至6任意一项所述环保塑料制品的组成物,其特征在于:其中,该香母粒由所述环保聚合粒加上0.05〜6%的奈米银、或奈米氧化锌、奈米二氧化钛、或奈米磁粉其中任一种或多种的混合加热搅拌而成。 1-6 9. The composition of any one of green plastic article as claimed in claim, wherein: wherein the masterbatch by the environmental polymeric fragrance particles plus 0.05~6% of nano-silver, or nano zinc oxide, titanium dioxide nanometer, nm, or wherein any of a magnetic powder mixed together with stirring or more heated.
10. 如权利要求1至6任意一项所述环保塑料制品的组成物,其特征在于:其中,该塑料原料可为聚乙烯、低密度聚乙烯、线性低密度聚乙烯、 高密度聚乙烯、聚丙烯、聚苯乙烯、丙烯晴-丁二烯-苯乙烯共聚物其中任一种。 1-6 10. The composition according to any one of green plastic article as claimed in claim, wherein: wherein the plastic material may be polyethylene, low density polyethylene, linear low density polyethylene, high density polyethylene, polypropylene, polystyrene, acrylonitrile - butadiene - styrene copolymer wherein either.
11. 一种环保塑料制品的制造方法,其制程包括:步骤一:高分子热塑性聚合物弹性体树脂以捏合机加热软化,再加入天然超微细粉粒及耦合剂均匀混炼制成环保聚合粒,以此作为第一组母粒; 步骤二:将部分第一组母料加入耐热天然香精料加热搅拌,作为第二组香母料;步骤三:将第一组母粒、第二组香母料及塑胶原料均匀混合,直接通过成型机制成各类的成型产品。 A method for manufacturing environmentally friendly plastic products, which process comprises the steps of: a: molecular thermoplastic polymeric elastomer resin kneader heated and softened, then add ultra fine particles uniformly natural and environmental couplant made kneading granulation polymerization , as a first set of base particles; step two:;: a first group a second group of the base particles, the step portion of the first set of three master batch was heated with stirring resistant natural flavor, fragrance as a second masterbatch Hong master batch plastic materials were uniformly mixed, directly through the molding machine into various molded products.
12. 如权利要求11所述环保塑料制品的制造方法,其特征在于:其中, 该环保聚合粒包括:由5〜30%高分子热塑性聚合物弹性体树脂、20〜95%天然矿物质、1〜40%天然植物性淀粉、1〜75%天然木纤粉、1〜50%备长炭粉、1〜5%的耦联剂及1〜5%滑剂组成。 12. The method for producing the plastic article of claim 11 green claims, characterized in that: wherein the environmental polymeric particles comprising: a polymer of 5~30% thermoplastic polymeric elastomer resin, 20~95% natural minerals, 1 ~ 40% natural vegetable starch, 1~75% natural wood fiber powder, carbon powder bincho 1~50%, ~ 5% ~ 5% coupling agent and slip agent. 组成。 composition.
13. 如权利要求12所述环保塑料制品的制造方法,其特征在于:其中30〜80%天然矿物质、5〜30%天然植物性淀粉、10〜70%天然木纤粉和5〜 30%备长炭粉。 13. The method of manufacturing a plastic article 12 of the green claim, wherein: wherein 30~80% natural minerals, 5~30% natural vegetable starch, 10~70% natural wood fiber powder and -5 to 30% Bincho charcoal.
14. 如权利要求11所述环保塑料制品的制造方法,其特征在于:其中, 该制程步骤一的高分子热塑性聚合物弹性体树脂以捏合机加热软化的温度设定在100〜130度之间。 14. The method for producing the plastic article of claim 11 green claims, characterized in that: wherein the process step of a high molecular thermoplastic polymeric elastomer resin softened by heating kneader temperature was set between 100 to 130 degrees .
15. 如权利要求11所述环保塑料制品的制造方法,其特征在于:其中, 该制程步骤一的环保聚合粒,最后以螺杆式押出机混炼挤出造粒,其颗粒直径在2〜3公厘(mm)之间。 15. The method for producing the plastic article of claim 11 green claims, characterized in that: wherein the process step of polymerization of a green grain, and finally a screw-type extruder kneading extruder granulation, the particle diameter of 2 to 3 between mm (mm).
16. 如权利要求15所述环保塑料制品的制造方法,其特征在于:其中, 该押出机温度设定在摄氏100〜180度之间。 16. The method for producing the plastic article of claim 15 green claims, characterized in that: wherein the extruder temperature was set between 100~180 ° C.
17. 如权利要求11所述环保塑料制品的制造方法,其特征在于:其中, 该制程步骤二的成分百分比为:1〜50%的所述第一组母粒、0.05〜6%耐热天然香精料,以摄氏30〜70度加热搅拌而成。 17. The method for producing the plastic article of claim 11 green claims, characterized in that: wherein the two components of the process steps percentage: 1~50% of the masterbatch of the first set, 0.05~6% natural heat flavor material, heated and stirred at 30~70 degrees Celsius made.
18. 如权利要求11所述环保塑料制品的制造方法,其特征在于:其中, 该制程步骤三的成分百分比为:第一组母粒1〜50%、第二组香母料1〜50 %、塑胶原料20〜80%,各依成型产品用途相异作调整。 18. The method for producing the plastic article of claim 11 green claims, characterized in that: wherein the process step three component percentages are: a first group of 1~50% masterbatch, the masterbatch second set of 1~50% fragrance , plastic materials 20 to 80%, depending on each product uses different shaped adjusted.
19. 如权利要求11所述环保塑料制品的制造方法,其特征在于:其中, 该耐热天然香精料,为一种油性、或蜡性、或粉性具不易挥发的香料。 19. The method for producing the plastic article of claim 11 green claims, characterized in that: wherein the heat-resistant material natural flavor, as an oily, or waxy, or powdering resistance with less volatile perfumes.
20. 如权利要求11所述环保塑料制品的制造方法,其特征在于:其中,该塑胶原料可为聚乙烯、低密度聚乙烯、线性低密度聚乙烯、高密度聚乙烯、聚丙烯、聚苯乙烯、丙烯晴-丁二烯-苯乙烯共聚物其中任一种。 20. The method for producing the plastic article of claim 11 green claims, characterized in that: wherein, the plastic materials may be polyethylene, low density polyethylene, linear low density polyethylene, high density polyethylene, polypropylene, polyphenylene ethylene, acrylonitrile - butadiene - styrene copolymer wherein either.
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CN102069671A (en) * 2009-11-20 2011-05-25 汉达精密电子(昆山)有限公司 Method for making multicolor graph with bright shining effect
CN101805523A (en) * 2010-04-06 2010-08-18 王文广 Superfine biological powder filling masterbatch and method for preparing same
CN101899180A (en) * 2010-06-30 2010-12-01 百氏得森(上海)精细化工有限公司 Fragrant electrical appliance panel, preparation method and use thereof
CN102286208A (en) * 2011-06-24 2011-12-21 明助实业股份有限公司 Antibacterial plastic master batch and manufacturing method thereof and antibacterial chopping board prepared from antibacterial plastic master batch
CN102286208B (en) * 2011-06-24 2014-10-01 明助实业股份有限公司 Antibacterial plastic master batch and manufacturing method thereof and antibacterial chopping board prepared from antibacterial plastic master batch
WO2014110792A1 (en) * 2013-01-18 2014-07-24 Zhang Dong Degradable environment-friendly plastic and preparation method thereof
CN104032484A (en) * 2014-04-26 2014-09-10 绩溪袁稻农业产业科技有限公司 Inexpensive nonwoven fabric sound absorption cotton containing rice hulls
US10093776B2 (en) 2014-08-07 2018-10-09 Polyone-Shanghai, China Masterbatch containing heat-sensitive functional additive
TWI656157B (en) * 2017-12-22 2019-04-11 遠東科技大學 Wood substrates and manufacturing method thereof

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