Summary of the invention
The objective of the invention is to overcome the shortcoming of prior art, provide a kind of penetrating sense strong, texture is sparkling and crystal-clear, floral designs are clear, good hardness, radiationless, the easy Glomerocryst imitation jade ceramic tile that maintains.
The objective of the invention is to realize through following technical scheme:
A kind of Glomerocryst imitation jade ceramic tile, the weight percent of said ceramic tile main raw material is: soft-paste stone flour 15~30%, middle temperature porcelain sand 20~40%; Pate dure sand 9~21%, washing black mud 10~25%, opacifying agent 1~2%; Colorant 0.5~1.5%, liquefactent 0.5~1%.
The weight percent of said transparent material is: weathering albite 84~96%, washing black mud 3~15.5%, liquefactent 0.5~1%.
The transparent material thickness of said ceramic tile surface: 0.5~1.1cm.
Above-mentioned powder granularity weight percent is: 40 mesh screen residues: 40~50%; 60 mesh screen residues: 30~40%; 100 mesh screen residues: 5%.
Said drying temperature: 180~230 ℃.
Said time of drying: 50~80min.
Said blank forming pressure: 260~300bar.
Said firing temperature: face temperature: 1225~1380 ℃; End temperature: 1160~1220 ℃.
Said firing period: 60~90min.
The present invention can reach following beneficial effect after adopting technique scheme:
1, creativeness.The present invention is the impressing pattern decorative pattern as required, and is random strong, and because of the top layer is transparent, so the wearable flower pattern degree is high, and presents glittering and translucent texture, and the product elegance is luxurious, has improved the class of ceramic tile.
2, pass through sense by force.The present invention passes through at ice and improves on the material foundation again and mix colours, and uses multiple fine silicate material to prepare low-temperature transparent material and low temperature milkiness material; Its top layer adopts milkiness material and transparent material to hand over molten Recipe mutually, makes product that a kind of milkiness and transparent effect arranged; Have transparent and effect milkiness.
3, the formation of cloth texture.The present invention has improved the grid shelf structure on the basis of traditional moulding process, used 4 repeatedly distributors, makes micro mist spontaneous current movable property in mechanical activity of multicolour give birth to texture.
4, the control of firing temperature.The adding of low-temperature transparent material and milkiness material has improved alkali-metal content among the present invention, in the high temperature section control of burning till, has adopted surface temperature to be higher than end temperature, face temperature: 1225~1380 ℃; End temperature: 1160~1220 ℃, sintering effect is good.
5, be prone to maintenance.The present invention is because density is high, and the glossiness and the stain resistance on full sized brick surface are also higher; In use low suction, antifouling good, anti-aging, cleaning and maintenance more easily, and corrosion-resistant.
6, good product performance.The present invention is more common, and the polished tile PI is better: the product shrinking percentage does not occur bursting or crackle through 10 heat-shock resistance tests below 9%, and fastness to rubbing is more than 139, and the product water-intake rate is below 0.09%, more than the product folding strength 46MPa.
7, durable.Stable performance of the present invention receives time, environmental influence less, can keep for a long time like new sensation, long service life.
8, applied widely.The present invention does not receive the suitable environment conditionality, can be widely used in various interior exterior walls and ground decoration.
9, the market economy benefit is wide.Because the advantage that its body has can adapt to the demand of current society, the anticipations of profit of the present invention increase about 98% than common ceramic tile, and the market economy benefit is wide.
Embodiment
Below in conjunction with specific embodiment the present invention is done further explain:
Embodiment 1
The soft-paste stone flour of 15~30% weight parts is added the middle temperature porcelain sand of 20~40% weight parts, the pate dure sand of 9~21% weight parts, under normal temperature, stir, form mixed powder; Add the washing black mud of 10~25% weight parts again; Under normal temperature, stir, handle towards look, drying process with atomizing through ball milling, slurry and process compound, add the opacifying agent of 1~2% weight part again; 0.5 the colorant of~1.5% weight part; 0.5 the liquefactent of~1% weight part mixes under normal temperature, said powder granularity weight percent is: 40 mesh screen residues: 40~50%; 60 mesh screen residues: 30~40%; More than 100 mesh screen residues: 5%; Carry out granulating working procedure; With the blank compression moulding that aforementioned technical process was handled, said blank forming pressure: 260~300bar is under 180~230 ℃ of conditions; Handle through 50~80min drying process, will handle through oozing flower process through the adobe that aforementioned art breading is crossed again.
The weathering albite of 84~96% weight parts is added the washing black mud of 3~15.5% weight parts, the liquefactent of 0.5~1% weight part; Under normal temperature, stir; Process transparent material, transparent material is imposed on the blank, the transparent material thickness of said ceramic tile surface is 0.5~1.1cm; Under 180~230 ℃ of conditions, handle through 50~80min drying process.
At last, the blank that will cross through above-mentioned art breading is inserted kiln, 1225~1380 ℃ of face temperature, under 1160~1220 ℃ of conditions of end temperature, is sintered into finished product through 60~90min.
The Glomerocryst imitation jade ceramic tile performance of processing through above-mentioned technology can reach: the product shrinking percentage is below 9%, and the product water-intake rate is below 0.09%, and the product fastness to rubbing is more than 139, and more than the product folding strength 46MPa, the performance perameter ratio is superior to common polished tile.
Embodiment 2
The soft-paste stone flour of 15% weight part is added the middle temperature porcelain sand of 40% weight part, the pate dure sand of 17% weight part; Under normal temperature, stir, form mixed powder, add again 25% weight part the washing black mud, under normal temperature, stir; Process compound through ball milling, slurry towards look, drying process with atomizing processing; Add the opacifying agent of 2% weight part again, the colorant of 0.5% weight part, the liquefactent of 0.5% weight part; Under normal temperature, mix, said powder granularity weight percent is: 40 mesh screen residues: 40%; 60 mesh screen residues: 30%; More than 100 mesh screen residues: 5%, carry out granulating working procedure, the blank compression moulding that aforementioned technical process was handled; Said blank forming pressure: 260bar; Under 180 ℃ of conditions, handle through the 50min drying process, will handle through oozing flower process through the adobe that aforementioned art breading is crossed again.
The weathering albite of 84% weight part is added the washing black mud of 15.5% weight part, the liquefactent of 0.5% weight part; Under normal temperature, stir; Process transparent material, transparent material is imposed on the blank, the transparent material thickness of said ceramic tile surface is 0.5cm; Under 180 ℃ of conditions, handle through the 50min drying process.
At last, the blank that will cross through above-mentioned art breading is inserted kiln, 1225 ℃ of face temperature; Under 1160 ℃ of conditions of end temperature, be sintered into finished product through 60min.
The Glomerocryst imitation jade ceramic tile performance of processing through above-mentioned technology can reach: product shrinking percentage 8%, and product water-intake rate 0.08%, product fastness to rubbing 140, product folding strength 48MPa, the performance perameter ratio is superior to common polished tile.
Embodiment 3
The soft-paste stone flour of 30% weight part is added the middle temperature porcelain sand of 23% weight part, the pate dure sand of 21% weight part; Under normal temperature, stir, form mixed powder, add again 21% weight part the washing black mud, under normal temperature, stir; Process compound through ball milling, slurry towards look, drying process with atomizing processing; Add the opacifying agent of 2% weight part again, the colorant of 1.5% weight part, the liquefactent of 1% weight part; Under normal temperature, mix, said powder granularity weight percent is: 40 mesh screen residues: 43%; 60 mesh screen residues: 40%; More than 100 mesh screen residues: 5%, carry out granulating working procedure, the blank compression moulding that aforementioned technical process was handled; Said blank forming pressure: 280bar; Under 230 ℃ of conditions, handle through the 80min drying process, will handle through oozing flower process through the adobe that aforementioned art breading is crossed again.
The weathering albite of 96% weight part is added the washing black mud of 3% weight part, the liquefactent of 0.5% weight part; Under normal temperature, stir; Process transparent material, transparent material is imposed on the blank, the transparent material thickness of said ceramic tile surface is 0.6cm; Under 230 ℃ of conditions, handle through the 80min drying process.
At last, the blank that will cross through above-mentioned art breading is inserted kiln, 1230 ℃ of face temperature, under 1220 ℃ of conditions of end temperature, is sintered into finished product through 90min.
The Glomerocryst imitation jade ceramic tile performance of processing through above-mentioned technology can reach: product shrinking percentage 6%, and product water-intake rate 0.05%, product fastness to rubbing 148, product folding strength 56MPa, the performance perameter ratio is superior to common polished tile.
Embodiment 4
The soft-paste stone flour of 24% weight part is added the middle temperature porcelain sand of 38% weight part, the pate dure sand of 19% weight part; Under normal temperature, stir, form mixed powder, add again 16% weight part the washing black mud, under normal temperature, stir; Process compound through ball milling, slurry towards look, drying process with atomizing processing; Add the opacifying agent of 1.3% weight part again, the colorant of 0.8% weight part, the liquefactent of 0.6% weight part; Under normal temperature, mix, said powder granularity weight percent is: 40 mesh screen residues: 45%; 60 mesh screen residues: 33%; More than 100 mesh screen residues: 5%, carry out granulating working procedure, the blank compression moulding that aforementioned technical process was handled; Said blank forming pressure: 272bar; Under 188 ℃ of conditions, handle through the 60min drying process, will handle through oozing flower process through the adobe that aforementioned art breading is crossed again.
The weathering albite of 88% weight part is added the washing black mud of 11% weight part, the liquefactent of 0.8% weight part; Under normal temperature, stir; Process transparent material, transparent material is imposed on the blank, the transparent material thickness of said ceramic tile surface is 0.8cm; Under 189 ℃ of conditions, handle through the 59min drying process.
At last, the blank that will cross through above-mentioned art breading is inserted kiln, 1240 ℃ of face temperature, under 1190 ℃ of conditions of end temperature, is sintered into finished product through 76min.
The Glomerocryst imitation jade ceramic tile performance of processing through above-mentioned technology can reach: product shrinking percentage 5.6%, and product water-intake rate 0.03%, product fastness to rubbing 150, product folding strength 60MPa, the performance perameter ratio is superior to common polished tile.
Embodiment 5
The soft-paste stone flour of 25% weight part is added the middle temperature porcelain sand of 31% weight part, the pate dure sand of 19% weight part; Under normal temperature, stir, form mixed powder, add again 21% weight part the washing black mud, under normal temperature, stir; Process compound through ball milling, slurry towards look, drying process with atomizing processing; Add the opacifying agent of 1.5% weight part again, the colorant of 0.9% weight part, the liquefactent of 0.8% weight part; Under normal temperature, mix, said powder granularity weight percent is: 40 mesh screen residues: 48%; 60 mesh screen residues: 36%; More than 100 mesh screen residues: 5%, carry out granulating working procedure, the blank compression moulding that aforementioned technical process was handled; Said blank forming pressure: 270bar; Under 190 ℃ of conditions, handle through the 58min drying process, will handle through oozing flower process through the adobe that aforementioned art breading is crossed again.
The weathering albite of 91% weight part is added the washing black mud of 8% weight part, the liquefactent of 0.8% weight part; Under normal temperature, stir; Process transparent material, transparent material is imposed on the blank, the transparent material thickness of said ceramic tile surface is 0.7cm; Under 210 ℃ of conditions, handle through the 60min drying process.
At last, the blank that will cross through above-mentioned art breading is inserted kiln, 1300 ℃ of face temperature, under 1196 ℃ of conditions of end temperature, is sintered into finished product through 75min.
The Glomerocryst imitation jade ceramic tile performance of processing through above-mentioned technology can reach: product shrinking percentage 4%, and product water-intake rate 0.01%, product fastness to rubbing 180, product folding strength 68MPa, the performance perameter ratio is superior to common polished tile.
Embodiment 6
The soft-paste stone flour of 26% weight part is added the middle temperature porcelain sand of 36% weight part, the pate dure sand of 16% weight part; Under normal temperature, stir, form mixed powder, add again 18% weight part the washing black mud, under normal temperature, stir; Process compound through ball milling, slurry towards look, drying process with atomizing processing; Add the opacifying agent of 1.5% weight part again, the colorant of 0.9% weight part, the liquefactent of 0.8% weight part; Under normal temperature, mix, said powder granularity weight percent is: 40 mesh screen residues: 48%; 60 mesh screen residues: 38%; More than 100 mesh screen residues: 5%, carry out granulating working procedure, the blank compression moulding that aforementioned technical process was handled; Said blank forming pressure: 293bar; Under 200 ℃ of conditions, handle through the 68min drying process, will handle through oozing flower process through the adobe that aforementioned art breading is crossed again.
The weathering albite of 86% weight part is added the washing black mud of 13% weight part, the liquefactent of 0.85% weight part; Under normal temperature, stir; Process transparent material, transparent material is imposed on the blank, the transparent material thickness of said ceramic tile surface is 0.95cm; Under 200 ℃ of conditions, handle through the 68min drying process.
At last, the blank that will cross through above-mentioned art breading is inserted kiln, 1260 ℃ of face temperature, under 1200 ℃ of conditions of end temperature, is sintered into finished product through 75min.
The Glomerocryst imitation jade ceramic tile performance of processing through above-mentioned technology can reach: product shrinking percentage 5%, and product water-intake rate 0.01%, product fastness to rubbing 210, product folding strength 96MPa, the performance perameter ratio is superior to common polished tile.
Embodiment 7
The soft-paste stone flour of 25% weight part is added the middle temperature porcelain sand of 33% weight part, the pate dure sand of 15% weight part; Under normal temperature, stir, form mixed powder, add again 23% weight part the washing black mud, under normal temperature, stir; Process compound through ball milling, slurry towards look, drying process with atomizing processing; Add the opacifying agent of 1.3% weight part again, the colorant of 1.3% weight part, the liquefactent of 0.75% weight part; Under normal temperature, mix, said powder granularity weight percent is: 40 mesh screen residues: 46%; 60 mesh screen residues: 39%; More than 100 mesh screen residues: 5%, carry out granulating working procedure, the blank compression moulding that aforementioned technical process was handled; Said blank forming pressure: 292bar; Under 198 ℃ of conditions, handle through the 74min drying process, will handle through oozing flower process through the adobe that aforementioned art breading is crossed again.
The weathering albite of 87% weight part is added the washing black mud of 12.2% weight part, the liquefactent of 0.8% weight part; Under normal temperature, stir; Process transparent material, transparent material is imposed on the blank, the transparent material thickness of said ceramic tile surface is 0.9cm; Under 210 ℃ of conditions, handle through the 69min drying process.
At last, the blank that will cross through above-mentioned art breading is inserted kiln, 1380 ℃ of face temperature, under 1193 ℃ of conditions of end temperature, is sintered into finished product through 83min.
The Glomerocryst imitation jade ceramic tile performance of processing through above-mentioned technology can reach: product shrinking percentage 1%, and product water-intake rate 0.04%, product fastness to rubbing 230, product folding strength 120MPa, the performance perameter ratio is superior to common polished tile.
Embodiment 8
The soft-paste stone flour of 23% weight part is added the middle temperature porcelain sand of 37% weight part, the pate dure sand of 20% weight part; Under normal temperature, stir, form mixed powder, add again 16% weight part the washing black mud, under normal temperature, stir; Process compound through ball milling, slurry towards look, drying process with atomizing processing; Add the opacifying agent of 1.4% weight part again, the colorant of 1.1% weight part, the liquefactent of 0.9% weight part; Under normal temperature, mix, said powder granularity weight percent is: 40 mesh screen residues: 47%; 60 mesh screen residues: 34%; More than 100 mesh screen residues: 5%, carry out granulating working procedure, the blank compression moulding that aforementioned technical process was handled; Said blank forming pressure: 296bar; Under 220 ℃ of conditions, handle through the 79min drying process, will handle through oozing flower process through the adobe that aforementioned art breading is crossed again.
The weathering albite of 89% weight part is added the washing black mud of 10% weight part, the liquefactent of 0.9% weight part; Under normal temperature, stir; Process transparent material, transparent material is imposed on the blank, the transparent material thickness of said ceramic tile surface is 1.02cm; Under 220 ℃ of conditions, handle through the 58min drying process.
At last, the blank that will cross through above-mentioned art breading is inserted kiln, 1346 ℃ of face temperature, under 1210 ℃ of conditions of end temperature, is sintered into finished product through 86min.
The Glomerocryst imitation jade ceramic tile performance of processing through above-mentioned technology can reach: product shrinking percentage 3%, and product water-intake rate 0.02%, product fastness to rubbing 260, product folding strength 265MPa, the performance perameter ratio is superior to common polished tile.
Embodiment 9
The soft-paste stone flour of 28% weight part is added the middle temperature porcelain sand of 36% weight part, the pate dure sand of 12% weight part; Under normal temperature, stir, form mixed powder, add again 20% weight part the washing black mud, under normal temperature, stir; Process compound through ball milling, slurry towards look, drying process with atomizing processing; Add the opacifying agent of 1.6% weight part again, the colorant of 1.2% weight part, the liquefactent of 0.9% weight part; Under normal temperature, mix, said powder granularity weight percent is: 40 mesh screen residues: 47%; 60 mesh screen residues: 38%; More than 100 mesh screen residues: 5%, carry out granulating working procedure, the blank compression moulding that aforementioned technical process was handled; Said blank forming pressure: 286bar; Under 225 ℃ of conditions, handle through the 78min drying process, will handle through oozing flower process through the adobe that aforementioned art breading is crossed again.
The weathering albite of 92% weight part is added the washing black mud of 6.5% weight part, the liquefactent of 0.8% weight part; Under normal temperature, stir; Process transparent material, transparent material is imposed on the blank, the transparent material thickness of said ceramic tile surface is 1.05cm; Under 216 ℃ of conditions, handle through the 69min drying process.
At last, the blank that will cross through above-mentioned art breading is inserted kiln, 1330 ℃ of face temperature, under 1196 ℃ of conditions of end temperature, is sintered into finished product through 80min.
The Glomerocryst imitation jade ceramic tile performance of processing through above-mentioned technology can reach: product shrinking percentage 2%, and product water-intake rate 0.04%, product fastness to rubbing 360, product folding strength 160MPa, the performance perameter ratio is superior to common polished tile.
Embodiment 10
The soft-paste stone flour of 20% weight part is added the middle temperature porcelain sand of 30% weight part, the pate dure sand of 21% weight part; Under normal temperature, stir, form mixed powder, add again 25% weight part the washing black mud, under normal temperature, stir; Process compound through ball milling, slurry towards look, drying process with atomizing processing; Add the opacifying agent of 1.4% weight part again, the colorant of 1.4% weight part, the liquefactent of 0.9% weight part; Under normal temperature, mix, said powder granularity weight percent is: 40 mesh screen residues: 48%; 60 mesh screen residues: 39%; More than 100 mesh screen residues: 5%, carry out granulating working procedure, the blank compression moulding that aforementioned technical process was handled; Said blank forming pressure: 289bar; Under 205 ℃ of conditions, handle through the 66min drying process, will handle through oozing flower process through the adobe that aforementioned art breading is crossed again.
The weathering albite of 87% weight part is added the washing black mud of 11.5% weight part, the liquefactent of 0.8% weight part; Under normal temperature, stir; Process transparent material, transparent material is imposed on the blank, the transparent material thickness of said ceramic tile surface is 0.98cm; Under 225 ℃ of conditions, handle through the 78min drying process.
At last, the blank that will cross through above-mentioned art breading is inserted kiln, 1360 ℃ of face temperature, under 1210 ℃ of conditions of end temperature, is sintered into finished product through 83min.
The Glomerocryst imitation jade ceramic tile performance of processing through above-mentioned technology can reach: product shrinking percentage 7%, and product water-intake rate 0.03%, product fastness to rubbing 360, product folding strength 260MPa, the performance perameter ratio is superior to common polished tile.
Other technical process of the present invention can be adopted prior art.